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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

SiC Recession Due to SiO2 Scale Volatility Under Combustor Conditions

One of today's most important and challenging technological problems is the development of advanced materials and processes required to design and build a fleet of supersonic High Speed Civil Transport (HSCT) airliners, a follow-up to the Concorde SST. The innovative combustor designs required for HSCT engines will need high-temperature materials with long-term environmental stability. Higher combustor liner temperatures than today's engines and the need for lightweight materials will require the use of advanced ceramic-matrix composites (CMC's) in hot-section components. The HSCT is just one example being used to demonstrate the need for such materials. This thesis evaluates silicon carbide (SiC) as a potential base material for HSCT and other similar applications. Key issues are the environmental durability for the materials of interest. One of the leading combustor design schemes leads to an environment which will contain both oxidizing and reducing gas mixtures. The concern is that these environments may affect the stability of the silica (SiO2) scale on which SiC depends for environmental protection. A unique High Pressure Burner Rig (HPBR) was developed to simulate the combustor conditions of future gas turbine engines, and a series of tests were conducted on commercially available SiC material. These tests are intended as a feasibility study for the use of these materials in applications such as the HSCT. Linear weight loss and surface recession of the SiC is observed as a result of SiO2 volatility for both fuel-lean and fuel-rich gas mixtures. These observations are compared and agree well with thermogravimetric analysis (TGA) experiments. A strong Arrhenius-type temperature dependence exists. In addition, the secondary dependencies of pressure and gas velocity are defined. As a result, a model is developed to enable extrapolation to points outside the experimental space of the burner rig, and in particular, to potential gas turbine engine conditions.

Robinson, Raymond Craig↗

Anthropogenic Sulfate, Clouds, and Climate Forcing

This research work is a joint effort between research groups at the Battelle Pacific Northwest Laboratory, Virginia Tech University, Georgia Institute of Technology, Brookhaven National Laboratory, and Texas A&M University. It has been jointly sponsored by the National Aeronautics and Space Administration, the U.S. Department of Energy, and the U.S. Environmental Protection Agency. In this research, a detailed tropospheric aerosol-chemistry model that predicts oxidant concentrations as well as concentrations of sulfur dioxide and sulfate aerosols has been coupled to a general circulation model that distinguishes between cloud water mass and cloud droplet number. The coupled model system has been first validated and then used to estimate the radiative impact of anthropogenic sulfur emissions. Both the direct radiative impact of the aerosols and their indirect impact through their influence on cloud droplet number are represented by distinguishing between sulfuric acid vapor and fresh and aged sulfate aerosols, and by parameterizing cloud droplet nucleation in terms of vertical velocity and the number concentration of aged sulfur aerosols. Natural sulfate aerosols, dust, and carbonaceous and nitrate aerosols and their influence on the radiative impact of anthropogenic sulfate aerosols, through competition as cloud condensation nuclei, will also be simulated. Parallel simulations with and without anthropogenic sulfur emissions are performed for a global domain. The objectives of the research are: To couple a state-of-the-art tropospheric aerosol-chemistry model with a global climate model. To use field and satellite measurements to evaluate the treatment of tropospheric chemistry and aerosol physics in the coupled model. To use the coupled model to simulate the radiative (and ultimately climatic) impacts of anthropogenic sulfur emissions.

Ghan, Steven J.↗

Fabrication and Qualification of Coated Chip-on-Board Technology for Miniaturized Space Systems

The results of a study carried out in order to manufacture and verify the quality of chip-on-board (COB) packaging technology are presented. The COB, designed for space applications, was tested under environmental stresses, temperature cycling, and temperature-humidity-bias. Both robustness in space applications and in environmental protection on the ground-complete reliability without hermeticity were searched for. The epoxy-parylene combinations proved to be superior to other materials tested.

Maurer, R. H.↗

The Successful Transfer of Space Derived Convergent Spray: An Application for Industrial Roof Coatings and Interstate Bridge Repair

A partnership was formed between the National Aeronautics and Space Administration (NASA), the Environmental Protection Agency (EPA), and United Technologies USBI Company to develop, demonstrate, and evaluate a technology that uses a solventless spray process for depositing a lightweight, highly filled roof coating on low-sloped commercial roofs. Although the levels of volatile organic compound (VOC) emissions from industrial roof coating's and paint operations have been reduced in recent years, this partnership,was an effort to further reduce VOC emission levels and to also demonstrate the use of reclaimed automobile tire rubber as a filler material in roof coating systems. Different materials and coatings were evaluated and tested before the final selection used to coat the roofs of two small buildings at NASA's Marshall Space Flight Center during fiscal year 1997. The project successfully leveraged the investment of EPA, NASA and private sector resources to demonstrate a pre-commercial roofing coating process. This process utilizes the Convergent Spray Technologies process, which was initially developed by USBI to apply highly-filled, thermal protection coatings to the Space Shuttle Solid Rocket Boosters. A second partnership between the NASA, Federal Highway Administration, Alabama Department of Transportation and USBI Company was formed to develop and demonstrate the Convergent Spray Technology as a method of applying a skid resistant coating to interstate roads and concrete bridge decking's. Again, different materials and coatings were evaluated and tested before the final selection of ground flint and resin. Two field demonstrations were performed during fiscal year 1997 for the purpose of evaluating the coating system under actual highway conditions. These coatings were applied on Interstate 65 near Huntsville Alabama, and in the Mobile Bankhead tunnel. The system performed this task without the use of harmful solvents, and accomplished the process in a single application. This project successfully leveraged the investment of NASA, Federal Highway Administration, the Alabama Department of Transportation, and private sector funding.

McMillan, Vernotto C.↗

The Role of Monitoring in Controlling Water Pollution

The purpose of this paper is to provide an overview of trends in the national water pollution control effort and to describe the role of monitoring in that effort, particularly in relation to the responsibilities of the Environmental Protection Agency (EPA). I hope the paper will serve as a useful framework for the more specific discussions of monitoring technology to follow.

Hirsch, Allan↗

The Urban Heat Island Phenomenon and Potential Mitigation Strategies

A survey of urban heat island research is provided to describe how heat islands develop, urban landscape and meteorological characteristics that facilitate development, use of aircraft remote sensing data, and why heat islands are of interest to planners, elected officials, and the public. The roles of the National Aeronautics and Space Administration (NASA), the Environmental Protection Agency (EPA), other federal agencies, national laboratories and universities, state and local governments, and non-governmental organizations (NGOS) in studying the urban heat island effect and developing mitigation strategies are explored. Barriers that hamper mitigation efforts and case studies in Atlanta and Salt Lake City are discussed.

Estes, Maurice G., Jr.↗

Aeronautics and Space Report of the President: Fiscal Year 1998 Activities

The National Aeronautics and Space Act of 1958 directed the annual Aeronautics and Space Report to include a "comprehensive description of the programmed activities and the accomplishments of all agencies of the United States in the field of aeronautics and space activities during the preceding calendar year. In recent years, the reports have been prepared on a fiscal year (FY) basis, consistent with the budgetary period now used in programs of the Federal Government. This year's report covers activities that took place from October 1, 1997, through September 30, 1998. The activities of agencies included are NASA, the Department of Defense, The Federal Aviation Administration, the Department of Commerce, the Department of the Interior, the Federal Communications Commission, the Department of Agriculture, the National Science Foundation, the Department of State, the Department of Energy, the Smithsonian Institution, the Arms Control and Disarmament Agency, the Environmental Protection Agency, and the U.S. Information Agency. Appendices cover the U.S. Government Spacecraft Record, World Record of Space Launches Successful in Attaining Earth Orbit or Beyond , Successful Launches to Orbit on U.S. Launch Vehicles, October 1, 1997-September 30, 1998, U.S. and Russian Human Space Flights, 1961-September 30, 1998, U.S. Space Launch Vehicles, Space Activities of the U.S. Government-Historical Budget Summary, Space Activities of the U.S. Government-Budget Authority in Equivalent FY 1998 Dollars, Federal Space Activities Budget, Federal Aeronautics Budget, and a glossary

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Present State of Knowledge of the Upper Atmosphere 1999: An Assessment Report

This document is issued in response to the Clean Air Act Amendment of 1990, Public Law 101-549, which mandates that the National Aeronautics and Space Administration (NASA) and other key agencies submit triennial reports to the Congress and the Environmental Protection Agency. NASA specifically is charged with the responsibility of reporting on the state of our knowledge of the Earth's upper atmosphere, particularly the stratosphere. Part l of this report summarizes the objectives, status, and accomplishments of the research tasks supported under NASA's Upper Atmosphere Research Program and Atmospheric Chemistry Modeling and Analysis Program for the period of 1997-1999. Part 2 (this document) is a compilation of several scientific assessments, reviews, and summaries. Section B (Scientific Assessment of Ozone Depletion: 1998), Section C (a summary of the 1998 Stratospheric Processes and their Role in Climate, SPARC, ozone trends report), Section D (the policymakers summary of the Intergovernmental Panel on Climate Change, IPCC, report on Aviation and the Global Atmosphere), and Section E (the executive summary of the NASA Assessment of the Effects of High-Speed Aircraft in the Stratosphere: 1998) are summaries of the most recent assessments of our current understanding of the chemical composition and the physical structure of the stratosphere, with particular emphasis on how the abundance and distribution of ozone is predicted to change in the future. Section F (the executive summary of NASA's Second Workshop on Stratospheric Models and Measurements, M&M 11) and Section G (the end-of-mission statement for the Photochemistry of ozone Loss in the Arctic Region in Summer, POLARIS, campaign) describe the scientific results for a comprehensive modeling intercomparison exercise and an aircraft and balloon measurement campaign, respectively. Section H (Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling: Update to Evaluation Number 12 of the NASA Panel for Data Evaluation) highlights the latest of NASA's reviews of this important aspect of the atmospheric sciences. A list of contributors to each of the included documents appears in Section I of this report.

Kurylo, M. J.↗

Mineral Mapping Using AVIRIS Data at Ray Mine, AZ

Imaging Spectroscopy enables the identification and mapping of surface mineralogy over large areas. This study focused on assessing the utility of Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data for environmental impact analysis over the Environmental Protection Agency's (EPA) high priority Superfund site Ray Mine, AZ. Using the Spectral Angle Mapper (SAM) algorithm to analyze AVIRIS data makes it possible to map surface materials that are indicative of acid generating minerals. The improved performance of the AVIRIS sensor since 1996 provides data with sufficient signal to noise ratio to characterize up to 8 image endmembers. Specifically we employed SAM to map minerals associated with mine generated acid waste, namely jarositc, goethite, and hematite, in the presence of a complex mineralogical background.

McCubbin, Ian↗

Space Suit Thermal Dynamics

The present NASA space suit (the Shuttle EMU) is a self-contained environmental control system, providing life support, environmental protection, earth-like mobility, and communications. This study considers the thermal dynamics of the space suit as they relate to astronaut thermal comfort control. A detailed dynamic lumped capacitance thermal model of the present space suit is used to analyze the thermal dynamics of the suit with observations verified using experimental and flight data. Prior to using the model to define performance characteristics and limitations for the space suit, the model is first evaluated and improved. This evaluation includes determining the effect of various model parameters on model performance and quantifying various temperature prediction errors in terms of heat transfer and heat storage. The observations from this study are being utilized in two future design efforts, automatic thermal comfort control design for the present space suit and design of future space suit systems for Space Station, Lunar, and Martian missions.

Campbell, Anthony B.↗

Karst Groundwater Hydrologic Analyses Based on Aerial Thermography

On February 23, 1999, thermal imagery of Marshall Space Flight Center, Alabama was collected using an airborne thermal camera. Ground resolution was I in. Approximately 40 km 2 of thermal imagery in and around Marshall Space Flight Center (MSFC) was analyzed to determine the location of springs for groundwater monitoring. Subsequently, forty-five springs were located ranging in flow from a few ml/sec to approximately 280 liter/sec. Groundwater temperatures are usually near the mean annual surface air temperature. On thermography collected during the winter, springs show up as very warm spots. Many of the new springs were submerged in lakes, streams, or swamps; consequently, flow measurements were difficult. Without estimates of discharge, the impacts of contaminated discharge on surface streams would be difficult to evaluate. An approach to obtaining an estimate was developed using the Environmental Protection Agency (EPA) Cornell Mixing Zone Expert System (CORMIX). The thermography was queried to obtain a temperature profile down the center of the surface plume. The spring discharge was modeled with CORMIX, and the flow adjusted until the surface temperature profile was matched. The presence of volatile compounds in some of the new springs also allowed MSFC to unravel the natural system of solution cavities of the karst aquifer. Sampling results also showed that two springs on either side of a large creek had the same water source so that groundwater was able to pass beneath the creek.

Campbell, C. Warren↗

Development of a Reference Dose for Perchlorate: Current Issues and Status

The perchlorate anion (ClO4) is typically manufactured as the ammonium salt. The most common use of ammonium perchlorate is in the aerospace program as a component of solid rocket fuel. The perchlorate anion is exceedingly stable under environmental conditions and has been found in ground and surface waters in CA, NV, UT, AZ, TX, AK, NY, MD, WV and FL. The National Center for Environmental Assessment (NCEA) of the U.S. Environmental Protection Agency (US EPA) is in the process of developing an oral reference dose (RfD) for perchlorate. An oral RfD is a body-weight-adjusted dose that can be consumed daily over an entire lifetime with the expectation of no adverse health effects. Once developed, the new RfD will be used by US EPA as the basis of a safe-drinking-water level (SDWL) guideline. US EPA and regional regulatory agencies will then jointly or separately propose clean-up action levels for ground and surface waters at contaminated sites. The toxicological database on CIO4- as of March 1997 was determined by an expert peer-review panel to be inadequate for the purpose of deriving an oral RfD. For example, little or no experimental data existed on the subchronic, reproductive, or developmental toxicity of perchlorate. To fill gaps in the toxicological database, eight animal studies were designed by a government-industry consortium that included US EPA and AFRL. These studies were performed in 1997-1998. It has been known for many years that in the thyroid, high doses of perchlorate block the function of iodide by competing for iodide binding sites. Perchlorate was used in the 1950s-60s as a treatment for Graves' disease (a hyperthyroid condition). Because of what was already known about the pharmacological mode of action of perchlorate, specific concerns addressed in the design of the recent animal studies included the potential for developmental toxicity, notably neurological development. Upon review of complete study reports from four of the studies and incomplete data from the other two, US EPA/NCEA issued a document in December 1998 stating that the critical effects were hormone and histology data from the neurodevelopmental/behavioral toxicity study that had been performed in rats; an RfD was proposed based upon the observation of thyroid-follicular-cell hypertrophy in the 5-day-old pups (PND) of dams given perchlorate in drinking water at 0.1 mg/kg-day (the lowest dose tested) in this study. US EPA/NCEA also focused attention on a nonsignificant increase in motor activity observed in 14-day-old male pups in the same study at the same dose. In February 1999, a public workshop was convened at which an external peer-review panel determined that there was still insufficient data to support the development of a RfD. Additional studies were recommended. Since that time a clinical study revealed significant depression of thyroidal uptake of iodide in volunteers receiving potassium perchlorate at 10 mg/day for 14 days. Follow-up studies currently underway include a pathology working-group review of histology slides from the all of the previous studies, a motor activity study similar to the first behavioral study, an additional immunotoxicity study, male and female rat kinetic studies, a hormone interlaboratory study, and an effects study for thyroid and brain in developing rats. These studies are expected to be complete by mid-2000. A clinical study is planned to determine inhibition of iodide uptake and kinetic parameters in humans following 14-day perchlorate ingestion. The kinetics studies will provide data for developing physiologically based pharmacokinetic (PBPK) models for rats and humans needed to establish the RfD.

Pleus, R. C.↗

Joint EPA/NASA/USAF Interagency Depainting Study

Environmental regulations such as National Emission Standards for Hazardous Air Pollutants (NESHAPs) are drivers for the implementation of environmentally compliant methodologies in the manufacture of aerospace hardware. In 1995, the Environmental Protection Agency (EPA) promulgated the NESHAP for the Aerospace Manufacture and Rework (Aerospace NESHAP) industry. Affected facilities were to be in compliance by September 1998. Several aerospace manufacturing operations are regulated within the Aerospace NESHAP including Depainting operations. The National Aeronautics and Space Administration (NASA), EPA, and United States Air Force (USAF) combined resources to evaluate the performance of nine alternative depainting processes. The seven alternative depainting processes were: (1) Chemical stripping (non-methylene chloride); (2) Carbon Dioxide Blasting; (3) Xenon Flashlamp; (4) Carbon Dioxide Laser Stripping; (5) Plastic Media Blasting; (6) Sodium Bicarbonate Wet Stripping; and (7) Waterjet Blasting and Wheat Starch Blasting. All epoxy primer and polyurethane top coat system was applied to 2024-T3 clad and non-clad aluminum test specimens. Approximately 200 test specimens were evaluated in this study. Each coupon was subjected to three, four, or five complete depainting cycles. This paper discusses the conclusions from the study including the test protocol, test parameters, and achievable strip rates for the alternative depainting processes. Test data includes immersion corrosion testing, sandwich corrosion testing and hydrogen embrittlement testing for the non-methylene chloride chemical strippers. Additionally, the cumulative effect of the alternative depainting processes on the metallurgical integrity of the test substrate is addressed with the results from tensile and fatigue evaluations.

Clark-Ingram, M.↗

High-Performance, Low Environmental Impact Refrigerants

Refrigerants used in process and facilities systems in the US include R-12, R-22, R-123, R-134a, R-404A, R-410A, R-500, and R-502. All but R-134a, R-404A, and R-410A contain ozone-depleting substances that will be phased out under the Montreal Protocol. Some of the substitutes do not perform as well as the refrigerants they are replacing, require new equipment, and have relatively high global warming potentials (GWPs). New refrigerants are needed that addresses environmental, safety, and performance issues simultaneously. In efforts sponsored by Ikon Corporation, NASA Kennedy Space Center (KSC), and the US Environmental Protection Agency (EPA), ETEC has developed and tested a new class of refrigerants, the Ikon (registered) refrigerants, based on iodofluorocarbons (IFCs). These refrigerants are nonflammable, have essentially zero ozone-depletion potential (ODP), low GWP, high performance (energy efficiency and capacity), and can be dropped into much existing equipment.

McCullough, E. T.↗

Advanced Lubricants

Three Sun Coast Chemicals (SCC) of Daytona, Inc. products were derived from NASA technology: Train Track Lubricant, Penetrating Spray Lube, and Biodegradable Hydraulic Fluid. NASA contractor Lockheed Martin Space Operations contacted SCC about joining forces to develop an environmentally safe spray lubricant for the Shuttle Crawler. The formula was developed over an eight-month period resulting in new products which are cost effective and environmentally friendly. Meeting all Environmental Protection Agency requirements, the SCC products are used for applications from train tracks to bicycle chains.

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Sensors for Environmental Control

Under a Kennedy Space Center Small Business Innovation Research contract, GEO-CENTERS, Inc. developed a sensing element or 'optrode,' which NASA needed for space life support research to measure a hydroponic culture's pH factor. The company then commercialized the technology in the PC Based pH Monitoring System. The system employs the optrode to enable long term continuous monitoring of the pH level of fluids in standing and flowing conditions, an optoelectronic board with light sensors and detectors that fits into a desktop computer, and a fiber optic cable that connects the two. The system is effective in monitoring the pH output of industries to maintain ranges acceptable to the Environmental Protection Agency.

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Water Quality Monitor

An automated water quality monitoring system was developed by Langley Research Center to meet a need of the Environmental Protection Agency (EPA). Designed for unattended operation in water depths up to 100 feet, the system consists of a subsurface buoy anchored in the water, a surface control unit (SCU) and a hydrophone link for acoustic communication between buoy and SCU. Primary functional unit is the subsurface buoy. It incorporates 16 cells for water sampling, plus sensors for eight water quality measurements. Buoy contains all the electronic equipment needed for collecting and storing sensor data, including a microcomputer and a memory unit. Power for the electronics is supplied by a rechargeable nickel cadmium battery that is designed to operate for about two weeks. Through hydrophone link the subsurface buoy reports its data to the SCU, which relays it to land stations. Link allows two-way communications. If system encounters a problem, it automatically shuts down and sends alert signal. Sequence of commands sent via hydrophone link causes buoy to release from anchor and float to the surface for recovery.

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Smokestack Monitor

Environmental Protection Agency monitors emissions from industrial smokestacks to obtain such information as how much pollutant material is being discharged into the atmosphere, how rapidly it is being discharged, and how the smoke plume disperses after leaving the stack. Raytheon's invisible laser beam, adapted from NASA's laser doppler technology, measures emission from one of the stacks. Aimed from a van's interior, the beam is projected from the roof mounted scanning pod near the rear of the vehicle. Particles in the smoke coming out of the stack reflect the beam back to light-detecting equipment in the van. The frequency of the returned beam is different from that of outgoing beam; analysis of the difference in frequencies, called "doppler shift" allows determination of the velocity.

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