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NASA NTRS2007

Persistent Seroconversion after Accidental Eye Exposure to Calcifying Nanoparticles

Biosafety of nanomaterials has attracted much attention recently. We report here a case where accidental human eye exposure to biogenic nanosized calcium phosphate in the form of calcifying nanoparticles (CNP) raised a strong IgG immune response against proteins carried by CNP. The antibody titer has persisted over ten years at the high level. The IgG was detected by ELISA using CNPs propagated in media containing bovine and human serum as antigen. The exposure incident occurred to a woman scientist (WS) at a research laboratory in Finland at 1993. CNP, also termed "nanobacteria", is a unique self-replicating agent that has not been fully characterized and no data on biohazards were available at that time. Before the accident, her serum samples were negative for both CNP antigen and anti-CNP antibody using specific ELISA tests (Nanobac Oy, Kuopio, Finland). The accident occurred while WS was harvesting CNP cultures. Due to a high pressure in pipetting, CNP pellet splashed into her right eye. Both eyes were immediately washed with water and saline. The following days there was irritation and redness in the right eye. These symptoms disappeared within two weeks without any treatment. Three months after the accident, blood and urine samples of WS were tested for CNP cultures (2), CNP-specific ELISA tests, and blood cell counts. Blood cell counts were normal, CNP antigen and culture tests were negative. A high IgG anti-CNP antibody titer was detected (see Figure). The antibodies of this person have been used thereafter as positive control and standard in ELISA manufacturing (Nano-Sero IgG ELISA, Nanobac Oy, Kuopio, Finland).

Ciftcioglu, Neva↗

NASA NTRS2011

Development of Space Shuttle Rescue and Recovery Operations

As the first Space Shuttle launch was still in our future, many from NASA, the Department of Defense (DoD) and NASA contractors were busy planning for not only a nominal launch and return, but contingency operations at the launch pad and landing sites. Prior to the first launch, detailed coordination, planning and simulations were conducted at all three locations and internal rescue procedures were taught at Kennedy Space Center (KSC). Later in the Program, the Transoceanic Abort Landing (TAL) sites were added in Europe and Africa. For the 51L mission a new TAL site was brought on line in Morocco. However, upon launch, the Shuttle Program experienced it's first lost. During the following months a complete review of all contingency operations (launch and landing) was completed. Many enhancements were made based on the reviews following. A Mode VIII water rescue was developed for NASA by the DoD before the STS-26 launch. Different concepts were explored and being debated by NASA. Training of the contingency forces was required before final decisions were made forcing the teaching of two different sets of procedures. To assist with training, a video was developed for the fire/crash/rescue personnel. This accompanied the detailed extraction procedures that were developed by a combination of KSC and DoD firemen. Training for the fire/crash/rescue personnel at Vandenberg AFB was also being planned before the accident happen. The fire/crash/rescue mockup that was being built at Chanute AFB was diverted to Edwards AFB. Educational Objectives: With the emphasis on Commercial Crew Programs for Space flight it is important that all involved understand what is required to prepare for contingencies. Cost effective means of being prepared for contingencies are needed. Questions: 1. When should planning for nominal and contingency operations begin? 2. What type of training aids are needed for contingency operations? 3. Who were the major contributors to Shuttle contingency operations?

Chandler, Michael↗

NASA NTRS2013

Jovian Tour Design for Orbiter and Lander Missions to Europa

Europa is one of the most interesting targets for solar system exploration, as its ocean of liquid water could harbor life. Following the recommendation of the Planetary Decadal Survey, NASA commissioned a study for a flyby mission, an orbiter mission, and a lander mission. This paper presents the moon tours for the lander and orbiter concepts. The total delta v and radiation dose would be reduced by exploiting multi-body dynamics and avoiding phasing loops in the Ganymede-to- Europa transfer. Tour 11-O3, 12-L1 and 12-L4 are presented in details and their performaces compared to other tours from previous Europa mission studies.

lander↗

NASA NTRS2015

Report on GMI Special Study #15: Radio Frequency Interference

This report contains the results of GMI special study #15. An analysis is conducted to identify sources of radio frequency interference (RFI) to the Global Precipitation Measurement (GPM) Microwave Imager (GMI). The RFI impacts the 10 GHz and 18 GHz channels at both polarities. The sources of RFI are identified for the following conditions: over the water (including major inland water bodies) in the earth view, and over land in the earth view, and in the cold sky view. A best effort is made to identify RFI sources in coastal regions, with noted degradation of flagging performance due to the highly variable earth scene over coastal regions. A database is developed of such sources, including latitude, longitude, country and city of earth emitters, and position in geosynchronous orbit for space emitters. A description of the recommended approach for identifying the sources and locations of RFI in the GMI channels is given in this paper. An algorithm to flag RFI contaminated pixels which can be incorporated into the GMI Level 1Base/1B algorithms is defined, which includes Matlab code to perform the necessary flagging of RFI. A Matlab version of the code is delivered with this distribution.

radio frequency interference↗

NASA NTRS2018

Overview of the Origins Space Telescope: Science Drivers to Observatory Requirements

e Origins Space Telescope (OST) mission concept study is the subject of one of the four science and technology definition studies supported by NASA Headquarters to prepare for the 2020 Astronomy and Astrophysics Decadal Survey. OST will survey the most distant galaxies to discern the rise of metals and dust and to unveil the co-evolution of galaxy and blackhole formation, study the Milky Way to follow the path of water from the interstellar medium to habitable worlds in planetary systems, and measure biosignatures from exoplanets. This paper describes the science drivers and how they drove key requirements for OST Mission Concept 2, which will operate between ~5 and ~600 microns with a JWST sized telescope. Mission Concept 2 for the OST study optimizes the engineering for the key science cases into a powerful and more economical observatory compared to Mission Concept 1.

Meixner, Margaret↗

NASA NTRS2022

The First Returned Samples From A C-Type Asteroid Show Kinship to the Chemically Most Primitive Meteorites

Bulk chemical and isotopic compositions, and mineralogy in the asteroid (162173) Ryugu samples show that Ryugu is mainly composed of materials related to the CI (Ivuna-like) carbonaceous chondrite group. The samples consist predominantly of minerals produced by aqueous alteration in a parent planetesimal from which Ryugu was derived. The 53Mn-53Cr systematics of dolomite suggest that this alteration occurred 5.2 (+0.7/–0.8) million years after formation of Ca-Al-rich inclusions, the first solids formed in the Solar System. The aqueous alteration temperature at the time dolomite and magnetite coprecipitated was 37±10°C. Unlike in CI chondrites, phyllosilicates in Ryugu have lost most of their interlayer water, but retained structural water. This indicates that following aqueous alteration the Ryugu samples avoided heating above ~90°C.

Tetsuya Yokoyama↗

NASA NTRSDate not supplied

Integrated Computational Fluid Dynamics and Thermal Desktop Thermal Modeling for Assessment of the EMU in Support of ISS EVA 80

Following the reports of water accumulation in the Extravehicular Mobility Unit (EMU) helmet during the ISS US EVA-80, various efforts for mitigation and further understanding of this phenomenon have been undertaken with the goal of prevention and to ensure crew safety in future EVAs. In support of this goal, a combination of Thermal Desktop thermal modeling and Computational Fluid Dynamics (CFD) has been performed in order to characterize the performance of the EMU components, specifically those within the ventilation/cooling water loops. This modeling effort evaluates the dry/wet gas pressure drop and flow distribution through gas and liquid flow paths using CFD, as well as a two-phase flow assessment of condensation production and water separation/removal performance using an integrated Thermal Desktop model of important EMU ventilation loop components. The models assess this overall thermal-fluid performance in comparison with previous existing models, design points, and historical EVA data using their inputs.

Blain Ryan Lancaster↗

NASA NTRSDate not supplied

Integrated Computational Fluid Dynamics and Thermal Desktop Thermal Modeling for Assessment of the EMU in Support of ISS EVA 80

EVA 80↗

NASA NTRS1973

Reflectance of vegetation, soil, and water

The author has identified the following significant results. The ability to read the 24-channel MSS CCT tapes, select specified agricultural land use areas from the CCT, and perform multivariate statistical and pattern recognition analyses has been demonstrated. The 5 optimum channels chosen for classifying an agricultural scene were, in the order of their selection the far red visible, short reflective IR, visible blue, thermal infrared, and ultraviolet portions of the electromagnetic spectrum, respectively. Although chosen by a training set containing only vegetal categories, the optimum 4 channels discriminated pavement, water, bare soil, and building roofs, as well as the vegetal categories. Among the vegetal categories, sugar cane and cotton had distinctive signatures that distinguished them from grass and citrus. Acreages estimated spectrally by the computer for the test scene were acceptably close to acreages estimated from aerial photographs for cotton, sugar cane, and water. Many nonfarmable land resolution elements representing drainage ditch, field road, and highway right-of-way as well as farm headquarters area fell into the grass, bare soil plus weeds, and citrus categories and lessened the accuracy of the farmable acreage estimates in these categories. The expertise developed using the 24-channel data will be applied to the ERTS-1 data.

Wiegand, C. L.↗

DOE OSTI2025

Profiles of Radiative Fluxes at ENA

Profiles of radiative fluxes observed at the Atmospheric Radiation Measurement (ARM)’s Eastern North Atlantic (ENA) observatory along with the ancillary measurements are reported. The below-cloud drizzle properties were derived by combining the data from the ceilometer and Ka-band ARM Zenith Radar (KAZR) following the technique explained by Ghate et al. (2021 JAMC). The cloud and drizzle water path values were derived from the brightness temperatures reported by the microwave radiometer following the technique of Cadeddu et al. (2020 AMT). The cloud water path was then scaled to the KAZR-reported radar reflectivity to calculate profiles of liquid water content (LWC). Following the analysis from Ghate et al. (2023 JGR), cloud droplet effective radius was calculated using the number concentration value of 100 cm-3. The cloud properties, along with the thermodynamic properties, served as an input to the Rapid Radiative Transfer Model (RRTM) to yield profiles of radiative fluxes at a 1-minute temporal and 50-m vertical resolution. The fluxes were then averaged to hourly temporal resolution for analysis. In Mitra et al. (2025 JClim), the calculated profiles were compared against those derived from the satellite measurements (SYN1deg). Flux profiles from the SYN1deg and the thermodynamic and cloud properties used for deriving them are also reported here. Both all-sky and clear-sky radiative flux profiles were calculated. Due to the large data volume, the surface and top-of-atmosphere (TOA) radiative fluxes for the six-year period, and the hourly profiles of the radiative fluxes for January 2018, are submitted here. Full profiles of radiative fluxes calculated from the thermodynamic and cloud properties measured at the ENA site at 1-minute temporal and 50-m vertical resolution for a six-year period are available from the authors. Six files here correspond to the following data: 1_ENARAD_CERES_with_cld_amount_timeseries.nc: Time-series of hourly values of RRTM-simulated values of upwelling and downwelling fluxes at the surface and TOA, observed boundary-layer cloud fractions, and upwelling and downwelling fluxes from the SYN1deg from July 2015 to January 2022. 2_CERES_2018_at_CERES_levels.nc: SYN1deg radiative fluxes at six levels for the year 2018. 3_ENARad_2018_at_CERES_levels.nc: RRTM calculated fluxes at the SYN1deg vertical levels for the year 2018. 4_ENARad_rrtminputs_hourly_201801.nc: Thermodynamic and cloud properties used as an input to the RRTM for January 2018. 5_CERES_inputs_hourly_201801.nc: Thermodynamic and cloud properties utilized by SYN1deg algorithm for January 2018. 6_ENARAD_hourly_201801.nc: Full profiles of hourly averaged radiative fluxes from the RRTM simulations for January 2018.

Atmosphere↗

NASA NTRS1973

Reflectance of vegetation, soil, and water

The author has identified the following significant results. A study was conducted in a 340-acre (139 hectares) field of grain sorghum (Sorghum bicolor (L.) Moench) to determine if multispectral data from ERTS-1 could be used to detect differences in chlorophyll concentration between iron-deficient (chlorotic) and apparently normal (green) grain sorghum. Chlorotic sorghum areas 2.8 acres (1.1 hectares) or larger in size were identified on a computer printout of band 5 data which contains the chlorophyll absorption band at the 0.65 micron wavelength. ERTS resolution is sufficient for practical applications in detecting iron-deficient sorghum in otherwise uniform fields. The first classification map of the study county has been produced. Vegetation (crops), rangeland, bare soil, water, and an undefined (all other) category occupied 15.2, 45.0, 19.1, 0.02, and 20.6% of the land area, respectively.

Wiegand, C. L.↗

NASA NTRS1975

In situ spectroradiometric calibration of EREP imagery and estuarine and coastal oceanography of Block Island sound and adjacent New York coastal waters

The author has identified the following significant results. The first part of the study resulted in photographic procedures for making multispectral positive images which greatly enhance the color differences in land detail using an additive color viewer. An additive color analysis of the geologic features near Willcox, Arizona using enhanced black and white multispectral positives allowed compilation of a significant number of unmapped geologic units which do not appear on geologic maps of the area. The second part demonstrated the feasibility of utilizing Skylab remote sensor data to monitor and manage the coastal environment by relating physical, chemical, and biological ship sampled data to S190A, S190B, and S192 image characteristics. Photographic reprocessing techniques were developed which greatly enhanced subtle low brightness water detail. Using these photographic contrast-stretch techniques, two water masses having an extinction coefficient difference of only 0.07 measured simultaneously with the acquisition of S190A data were readily differentiated.

Yost, E. F.↗

NASA NTRS1980

Installation guidelines for solar heating system, single-family residence at New Castle, Pennsylvania

The solar heating system installer guidelines are presented for each subsystem. This single family residential heating system is a solar-assisted, hydronic-to-warm-air system with solar-assisted domestic water heating. It is composed of the following major components: (1) liquid cooled flat plate collectors; (2) water storage tank; (3) passive solar-fired domestic water preheater; (4) electric hot water heater; (5) heat pump with electric backup; (6) solar hot water coil unit; (7) tube-and-shell heat exchanger, three pumps, and associated pipes and valving in an energy transport module; (8) control system; and (9) air-cooled heat purge unit. Information is provided on the operating procedures, controls, caution requirements, and routine and schedule maintenance in the form of written descriptions, schematics, detail drawings, pictures, and manufacturer's component data.

Source record↗

NASA NTRS1993

Microbiological test results of the environmental control and life support systems vapors compression distillation subsystem recycle tank components following various pretreatment protocols

Microbiological samples were collected from the recycle tank of the vapor compression distillation (VCD) subsystem of the water recovery test at NASA MSFC following a 68-day run. The recycle tank collects rejected urine brine that was pretreated with a commercially available oxidant (Oxone) and sulfuric acid and pumps it back to the processing component of the VCD. Samples collected included a water sample and two swab samples, one from the particulate filter surface and a second from material floating on the surface of the water. No bacteria were recovered from the water sample. Both swab samples contained a spore-forming bacterium, Bacillus insolitus. A filamentous fungus was isolated from the floating material. Approximately 1 month after the pretreatment chemicals were changed to sodium hypochlorite and sulfuric acid, a swab of the particulate filter was again analyzed for microbial content. One fungus was isolated, and spore-forming bacteria were observed. These results indicate the inability of these pretreatments to inhibit surface attachment. The implications of the presence of these organisms are discussed.

Huff, Tim↗

DOE OSTI2021

Preliminary Evidence of Gas-Phase Water Splitting on Holmium Nitrogen Oxide Clusters

Preliminary Evidence of Gas-Phase Water Splitting on Holmium Nitrogen Oxide Clusters Christopher A. Zarzana1, Makayla R. Baxter , Introduction: Molecular hydrogen is a potential energy carrier that could be used to help implement a clean energy economy if it is generated from splitting of water. Improvements in the efficiencies of water-splitting electrolyzers relies on development of novel materials with enhanced performance. However, research in this area is slowed due to underdeveloped understanding of the mechanisms of device performance due to challenges interrogating the fundamental chemical reactions at play in bulk materials. Studies of the intrinsic reactivity of clusters that are representative of the reactive sites of these materials can increase understanding of the fundamental reaction mechanisms involved in hydrogen production, allowing for more efficient development of new water-splitting materials. Methods: Holmium tetranitrato ([Ho(NO3)4]-) clusters were generated in gas-phase using the electrospray ionization source of a Bruker (Billerica, MA, USA) micrOTOF-Q II quadrupole time-of-flight mass spectrometer. Spray solutions consisted of aqueous holmium (Ho) nitrate solutions (at nominally 3 mM) diluted to 30 µM in acetonitrile. The holmium (Ho) tetranitrato clusters were isolated using the quadrupole and were subsequently activated and allowed to react with background water in the collision cell. High resolution, high mass accuracy spectra were recorded using the time-of-flight. Mass accuracy was ensured using external calibration with Agilent (Santa Clara, CA, USA) ESI-L Low Concentration tuning mix. Preliminary data: Collisional activation of the holmium tetranitrato complexes ([Ln(NO3)4]-) resulted in an expected series of ions resulting from the loss of ·NO and ·NO2. This included an ion at m/z = 382.885 assigned as [HoO2(NO3)3]- (theoretical m/z=382.884, error=-1.2 ppm), resulting from loss of ·NO, and an ion at m/z=366.890 assigned as [HoO(NO3)3]- (theorical m/z=366.889, error=-1.8 ppm), resulting from loss of ·NO2. Additional ions were detected that would result from more complicated losses from [Ho(NO3)4]-, including ions at m/z=320.898 assigned as [HoO2(NO3)2]- (theoretical m/z=320.896, error=-4.9 ppm), at m/z=304.904 assigned as [HoO(NO3)2]- (theoretical m/z=304.901, error=-8.1 ppm, very low signal), and at m/z=288.908 assigned as [Ho(NO3)2]- (theoretical m/z=288.907, error=-3.4 ppm). This ion series would arise from loss of some combination of ·NO, ·NO2, and ·NO3, although it is not known whether these losses occur sequentially (e.g. loss of ·NO and ·NO3 to yield [HoO2(NO3)2]-) or as a single species (e.g. direct loss of N2O4). These ions were accompanied by a complementary series representing addition of a single water molecule. This included an ion at m/z=338.908 assigned as [HoO2(NO3)2H2O]- (theoretical m/z=338.907, error=-4.1 ppm), an ion at m/z=322.912 assigned as [HoO(NO3)2H2O]- (theoretical m/z=322.912, error=1.2 ppm), and an ion at m/z=306.918 assigned as [Ho(NO3)2H2O]-, (theoretical m/z=306.918, error=-3.7 ppm). An additional hydrated ion was observed at m/z=276.921 assigned as [HoO2(NO3) H2O]- (theoretical m/z=276.919, error=-7.3 ppm), although corresponding dehydrated ion was not observed. An additional ion was observed at m/z=367.898 that has been assigned as [Ho(NO3)3OH]- (theoretical m/z=367.897, error=-2.5 ppm). It is hypothesized that this ion arises from addition of water to [Ho(NO3)3]- followed by elimination of a hydrogen radical. Neither [Ho(NO3)3]- nor [Ho(NO3)3H2O]- were detected, suggesting that, if the hypothesis is correct, addition of water to [Ho(NO3)3]- and its subsequent splitting is rapid. Elimination of HNO3 from [Ho(NO3)4H2O]- could also yield [Ho(NO3)3OH]-; however, no [Ho(NO3)4H2O]- ions were observed. Novelty: Potential evidence of water splitting on gas-phase lanthanide clusters offers a way to study the intrinsic reactivity of hydrogen-generation materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1973

Reflectance of vegetation, soil, and water

The author has identified the following significant results. A ratio of MSS channels 5 and 7 (5/7) and 5 to 6 (5/6) signals resulted in a correct recognition of 86.9% of the members of representative crop and soil conditions, compared with recognitions of 60.0, 64.1, 74.1, and 81.4% for channels 4, 5, 6, and 7 taken individually. Based on this result a satellite channel ratio procedure has been developed that enhances line printer gray maps for more efficient experimental test site location in the CCT data. Because independent estimates are not available to judge acreage estmates derived from ERTS-1 data against, except for a few crops, an interpenetrating sample constituting 3.5% of the county is ground truthed periodically. The crop of land uses and their acreages, respectively, as estimated from the interpenetrating samples, are: cotton, 129, 714; sorghum, 182,783; mixed citrus, 53,954; oranges, 16,929; grapefruit, 13,863; rangeland, 137,845; and, improved pastures, 57.169.

Wiegand, C. L.↗

NASA NTRS1974

Reflectance of vegetation, soil, and water

The author has identified the following significant results. Iron deficient and normal grain sorghum plants were sufficiently different spectrally in ERTS-1 band 5 CCT data to detect chlorotic sorghum areas 2.8 acres (1.1 hectares) or larger in size in computer printouts of the MSS data. The ratio of band 5 to band 7 or band 7 minus band 5 relates to vegetation ground cover conditions and helps to select training samples representative of differing vegetation maturity or vigor classes and to estimate ground cover or green vegetation density in the absence of ground information. The four plant parameters; leaf area index, plant population, plant cover, and plant height explained 87 to 93% of the variability in band 6 digital counts and from 59 to 90% of the variation in bands 4 and 5. A ground area 2244 acres in size was classified on a pixel by pixel basis using simultaneously acquired aircraft support and ERTS-1 data. Overall recognition for vegetables, immature crops and mixed shrubs, and bare soil categories was 64.5% for aircraft and 59.6% for spacecraft data, respectively. Overall recognition results on a per field basis were 61.8% for aircraft and 62.8% for ERTS-1 data.

Wiegand, C. L.↗

NASA NTRS1974

Reflectance of vegetation, soil, and water

The author has identified the following significant results. The Kubelka-Munk model, a regression model, and a combination of these models were used to extract plant, soil, and shadow reflectance components of vegetated surfaces. The combination model was superior to the others; it explained 86% of the variation in band 5 reflectance of corn and sorghum, and 90% of the variation in band 6 reflectance of cotton. A fractional shadow term substantially increased the proportion of the digital count sum of squares explained when plant parameters alone explained 85% or less of the variation. Overall recognition of 94 agricultural fields using simultaneously acquired aircraft and spacecraft MSS data was 61.8 and 62.8%, respectively; recognition of vegetable fields larger than 10 acres and taller than 25 cm, rose to 88.9 and 100% for aircraft and spacecraft, respectively. Agriculture and rangeland, were well discriminated for the entire county but level 2 categories of vegetables, citrus, and idle cropland, except for citrus, were not.

Wiegand, C. L.↗