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At least 343 records · Page 19

Studies of mechanochemical interactions in the tribological behavior of materials

Mechanochemical interaction studies can contribute to the understanding of wear and friction of materials. Specific examples of experimental results relative to the subject are discussed. There are two parts: one describes the synergistic effect of corrosion and wear of iron sliding on sapphire in sulfuric acid, and the other describes the effect of surface films on the wear and friction of plasma-deposited diamondlike carbon (amorphous hydrogenated carbon) films in sliding contact with silicon nitride. The concentration of acid (pH) is an important factor in controlling the iron loss caused by wear-corrosion processes in sulfuric acid. The mechanical action can cause chemical reactions to proceed much faster than they would otherwise. The diamondlike carbon (DLC) films are shown to behave tribologically much like bulk diamond. In a dry nitrogen environment, a mechanochemical reaction produces a substance which greatly decreases the coefficient of friction. In a moist air environment, mechanochemical interactions drastically reduce the wear life of DLC films and water vapor greatly increases friction.

Miyoshi, Kazuhisa↗

Studies of mechano-chemical interactions in the tribological behavior of materials

Mechano-chemical interaction studies can contribute to the understanding of wear and friction of materials. Specific examples of experimental results relative to the subject are discussed. There are two parts: one describes the synergistic effect of corrosion and wear of iron sliding on sapphire in sulfuric acid, and the other describes the effect of surface films on the wear and friction of plasma-deposited diamondlike carbon (amorphous hydrogenated carbon) films in sliding contact with silicon nitride. The concentration of acid (pH) is an important factor in controlling the iron loss caused by wear-corrosion processes in sulfuric acid. The mechanical action can cause chemical reactions to proceed much faster than they would otherwise. The diamondlike carbon (DLC) films are shown to behave tribologically much like bulk diamond. In a dry nitrogen environment, a mechano-chemical reaction produces a substance which greatly decreases the coefficient of friction. In a moist air environment, mechano-chemical interactions drastically reduce the wear life of DLC films and water vapor greatly increases friction.

Miyoshi, Kazuhisa↗

Scaling differences between large interplate and intraplate earthquakes

A study of large intraplate earthquakes with well determined source parameters shows that these earthquakes obey a scaling law similar to large interplate earthquakes, in which M sub o varies as L sup 2 or u = alpha L where L is rupture length and u is slip. In contrast to interplate earthquakes, for which alpha approximately equals 1 x .00001, for the intraplate events alpha approximately equals 6 x .0001, which implies that these earthquakes have stress-drops about 6 times higher than interplate events. This result is independent of focal mechanism type. This implies that intraplate faults have a higher frictional strength than plate boundaries, and hence, that faults are velocity or slip weakening in their behavior. This factor may be important in producing the concentrated deformation that creates and maintains plate boundaries.

Scholz, C. H.↗

Stress intensity factors in a cracked infinite elastic wedge loaded by a rigid punch

A plane elastic wedge-shaped solid was split through the application of a rigid punch. It was assumed that the coefficient of friction on the the contact area was constant, and the problem had a plane of symmetry with respect to loading and geometry, with the crack in the plane of symmetry. The problem was formulated in terms of a system of integral equations with the contact stress and the derivative of the crack surface displacement as the unknown functions. The solution was obtained for an internal crack and for an edge crack. The results include primarily the stress intensity factors at the crack tips, and the measure of the stress singularity at the wedge apex, and at the end points of the contact area.

Erdogan, F.↗

Tribomaterial factors in space mechanism brake performance

The asbestos/phenolic pads of Shuttle Remote Manipulator System (SRMS) brakes are unsuitable for use in long life space mechanisms because their friction decreases on extended sliding in high vacuum. Dehydration of the material and accumulation of wear debris in the conforming interface of this tribosystem induces the permanent friction changes. Other polymer and some ceramic based materials exhibit similar frictional torque behavior due to the development of minimal contact patches by the interfacial debris. In contrast, high friction occurs when other ceramics form many small contacts throughout fine debris beds. Generating this latter interfacial structure during run-in ensures that the in-vacuo friction remains stable thereafter. Such materials with low wear rates are potential candidates for friction elements in SSRMS and similar mechanisms.

Hawthorne, H. M.↗

A numerical investigation of the severe thunderstorm gust front

The structure of the thunderstorm gust front is investigated by a nonhydrostatic, two-dimensional (x,z) numerical model. In the model, which is dry, the production of negatively buoyant air by evaporation is parameterized via an externally imposed, local-cooling function. This parameterization sustains a steady cold downdraft, which drives the surface outflow and associated gust front. It is shown that two dominant factors influencing gust front structure in the vertical plane are the solenoidal field coincident with the front and surface friction, modeled by means of a simple bulk aerodynamic drag formulation. The circulation theorem is invoked to illustrate how solenoidal accelerations oppose the deceleration by surface friction. After the onset of a downdraft in the model, these opposing tendencies soon reach a balance. Thus, following a brief transient stage, the model gust front exhibits a persistent configuration as it propagates rapidly forward. The essential features of this configuration are examined and compared with both tower observations of gust fronts and laboratory models of gravity currents.

Mitchell, K. E.↗

On dynamic loads in parallel shaft transmissions. 1: Modelling and analysis

A model of a simple parallel-shaft, spur-gear transmission is presented. The model is developed to simulate dynamic loads in power transmissions. Factors affecting these loads are identified. Included are shaft stiffness, local compliance due to contact stress, load sharing, and friction. Governing differential equations are developed and a solution procedure is outlined. A parameter study of the solutions is presented in NASA TM-100181 (AVSCOM TM-87-C-3).

Lin, Edward Hsiang-Hsi↗

Tribological properties of Ag/Ti films on Al2O3 ceramic substrates

Ag solid lubricant films, with a thin Ti interlayer for enhanced adhesion, were sputter deposited on Al2O3 substrate disks to reduce friction and wear. The dual Ag/Ti films were tested at room temperature in a pin-on-disk tribometer sliding against bare, uncoated Al2O3 pins under a 4.9 N load at a sliding velocity of 1 m/s. The Ag/Ti films reduced the friction coefficient by 50 percent to about 0.41 compared to unlubricated baseline specimens. Pin wear was reduced by a factor of 140 and disk wear was reduced by a factor of 2.5 compared to the baseline. These films retain their good tribological properties including adhesion after heat treatments at 850 C and thus may be able to lubricate over a wide temperature range. This lubrication technique is applicable to space lubrication, advanced heat engines, and advanced transportation systems.

Dellacorte, Christopher↗

Percussive Force Magnitude in Permafrost

An in-depth look at percussive drilling shows that the transmission efficiency is very important; however, data for percussive drilling in hard rock or permafrost is rarely available or the existing data are very old. Transmission efficiency can be used as a measurement of the transmission of the energy in the piston to the drill steel or bit and from the bit to the rock. Having a plane and centralized impact of the piston on the drill steel can optimize the transmission efficiency from the piston to the drill steel. A transmission efficiency of near 100% between piston and drill steel is possible. The transmission efficiency between bit and rock is dependent upon the interaction within the entire system. The main factors influencing this transmission efficiency are the contact area between cutting structure and surrounding rock (energy loss due to friction heat), damping characteristics of the surrounding rock (energy dampening), and cuttings transport. Some of these parameters are not controllable. To solve the existing void regarding available drilling data, an experiment for gathering energy data in permafrost for percussive drilling was designed. Fifteen artificial permafrost samples were prepared. The samples differed in the grain size distribution to observe a possible influence of the grain size distribution on the drilling performance. The samples were then manually penetrated (with a sledge-hammer) with two different spikes.

Eustes, A. W., III↗

Measurements of Erosion Wear Volume Loss on Bare and Coated Polymer Matrix Composites

An investigation was conducted to examine the erosion behavior of uncoated and coated polymer matrix composite (PMC) specimens subjected to solid particle impingement using air jets. The PMCs were carbon-Kevlar (DuPont, Wilmington, DE) fiber-epoxy resin composites with a temperature capability up to 393 K (248 F). Tungsten carbide-cobalt (WC-Co) was the primary topcoat constituent. Bondcoats were applied to the PMC substrates to improve coating adhesion; then, erosion testing was performed at the University of Cincinnati. All erosion tests were conducted with Arizona road-dust (ARD), impinging at angles of 20 and 90 on both uncoated and two-layer coated PMCs at a velocity of 229 m/s and at a temperature of 366 K (200 F). ARD contains primarily 10-m aluminum oxide powders. Vertically scanning interference microscopy (noncontact, optical profilometry) was used to evaluate surface characteristics, such as erosion wear volume loss and depth, surface topography, and surface roughness. The results indicate that noncontact, optical interferometry can be used to make an accurate determination of the erosion wear volume loss of PMCs with multilayered structures while preserving the specimens. The two-layered (WC-Co topcoat and metal bondcoat) coatings on PMCs remarkably reduced the erosion volume loss by a factor of approximately 10. The tenfold increase in erosion resistance will contribute to longer PMC component lives, lower air friction, reduced related breakdowns, decreased maintenance costs, and increased PMC reliability. The decrease in the surface roughness of the coated vanes will lead to lower air friction and will subsequently reduce energy consumption. Eventually, the coatings could lead to overall economic savings.

Miyoshi, Kazuhisa↗

A Preliminary Foil Gas Bearing Performance Map

Recent breakthrough improvements in foil gas bearing load capacity, high temperature tribological coatings and computer based modeling have enabled the development of increasingly larger and more advanced Oil-Free Turbomachinery systems. Successful integration of foil gas bearings into turbomachinery requires a step wise approach that includes conceptual design and feasibility studies, bearing testing, and rotor testing prior to full scale system level demonstrations. Unfortunately, the current level of understanding of foil gas bearings and especially their tribological behavior is often insufficient to avoid developmental problems thereby hampering commercialization of new applications. In this paper, a new approach loosely based upon accepted hydrodynamic theory, is developed which results in a "Foil Gas Bearing Performance Map" to guide the integration process. This performance map, which resembles a Stribeck curve for bearing friction, is useful in describing bearing operating regimes, performance safety margins, the effects of load on performance and limiting factors for foil gas bearings.

DellaCorte, Christopher↗

Friction, Wear, and Surface Damage of Metals as Affected by Solid Surface Films

As predicted by friction theory, experiments showed that friction and surface damage of metals can be reduced by solid surface films. The ability of materials to form surface films that prevent welding was a very important factor in wear of dry and boundary lubricated surfaces. Films of graphitic carbon on cast irons, nio on nickel alloys, and feo and fe sub 3 o sub 4 on ferrous materials were found to be beneficial. Abrasive films such as fe sub 2 o sub 3 or moo sub 3 were definitely detrimental. It appears that the importance of oxide films to friction and wear processes has not been fully appreciated.

Bisson, Edmond E↗

Pressure-gradient effects on hypersonic turbulent skin friction and boundary-layer profiles.

Local skin friction, total-temperature profiles, and pitot-pressure profiles were measured on the wall of a Mach-7.4 wind tunnel. The wall to adiabatic wall temperature ratio was varied from 0.3 to 0.5. Boundary-layer characteristics were compared with those predicted by a finite-difference method. Local skin friction was predicted to within 15%. Pressure-gradient effects on the temperature and Mach number distributions and the shape factor (displacement thickness/momentum thickness) were underpredicted, but the velocity distributions were closely predicted.

Hopkins, E. J.↗

Friction and wear of plasma-deposited diamond films

Reciprocating sliding friction experiments in humid air and in dry nitrogen and unidirectional sliding friction experiments in ultrahigh vacuum were conducted with a natural diamond pin in contact with microwave-plasma-deposited diamond films. Diamond films with a surface roughness (R rms) ranging from 15 to 160 nm were produced by microwave-plasma-assisted chemical vapor deposition. In humid air and in dry nitrogen, abrasion occurred when the diamond pin made grooves in the surfaces of diamond films, and thus the initial coefficients of friction increased with increasing initial surface roughness. The equilibrium coefficients of friction were independent of the initial surface roughness of the diamond films. In vacuum the friction for diamond films contacting a diamond pin arose primarily from adhesion between the sliding surfaces. In these cases, the initial and equilibrium coefficients of friction were independent of the initial surface roughness of the diamond films. The equilibrium coefficients of friction were 0.02 to 0.04 in humid air and in dry nitrogen, but 1.5 to 1.8 in vacuum. The wear factor of the diamond films depended on the initial surface roughness, regardless of environment; it increased with increasing initial surface roughness. The wear factors were considerably higher in vacuum than in humid air and in dry nitrogen.

Miyoshi, Kazuhisa↗

Implementation of thermal residual stresses in the analysis of fiber bridged matrix crack growth in titanium matrix composites

In this research, thermal residual stresses were incorporated in an analysis of fiber-bridged matrix cracks in unidirectional and cross-ply titanium matrix composites (TMC) containing center holes or center notches. Two TMC were investigated, namely, SCS-6/Timelal-21S laminates. Experimentally, matrix crack initiation and growth were monitored during tension-tension fatigue tests conducted at room temperature and at an elevated temperature of 200 C. Analytically, thermal residual stresses were included in a fiber bridging (FB) model. The local R-ratio and stress-intensity factor in the matrix due to thermal and mechanical loadings were calculated and used to evaluate the matrix crack growth behavior in the two materials studied. The frictional shear stress term, tau, assumed in this model was used as a curve-fitting parameter to matrix crack growth data. The scatter band in the values of tau used to fit the matrix crack growth data was significantly reduced when thermal residual stresses were included in the fiber bridging analysis. For a given material system, lay-up and temperature, a single value of tau was sufficient to analyze the crack growth data. It was revealed in this study that thermal residual stresses are an important factor overlooked in the original FB models.

Bakuckas, John G., Jr.↗

Wear of iron and nickel in corrosive liquid environments

Friction and wear behavior of Fe and Ni sliding on aluminum oxide in aerated sulfuric acid and hydrochloric acid were investigated. The results show that the concentration of acid is an important factor in controlling the metal loss caused by wear corrosion processes in the acids. At very dilute acid concentration (10 to the -4 N), Fe behaves differently from Ni. Fe develops a soft, friable deposit, while Ni develops no corrosion layer. The formation and removal of the corrosion deposit on Fe resulted in high metal loss and coefficient of friction, as compared to the relatively low metal loss and coefficient of friction observed for Ni. At slightly higher acid concentration (10 to the -3 and 10 to the -2 N), no corrosion products were produced on both Fe and Ni. Wear of Fe and Ni was generally at a minimum. At higher acid concentration (10 to the -1 N and above), loss of Fe and Ni increased as the acid concentration increased. In sulfuric acid the maximum loss of both Fe and Ni was at 7.5 N (30%) concentration, and the metal losses of both Fe and Ni dropped markedly at 15 N (50%) and above. In hydrochloric acid, however, the Fe loss continued to increase with the increase of acid concentration, and the maximum Fe loss occurred in the most concentrated acid (12.1 N, 37%). There were variations in loss with Ni from specimen to specimen examined in hydrochloric acids (10 to the -1 N and above). The coefficient of friction for Ni increased slightly with an increase in acid concentration up to 10 to the -2 N. When corrosion started to dominate in the wear-corrosion process, the coefficient of friction decreased in both sulfuric and hydrochloric acids at 10 to the -1 N and above.

Miyoshi, Kazuhisa↗

Wear of iron and nickel in corrosive liquid environments

Friction and wear behavior of Fe and Ni sliding on aluminum oxide in aerated sulfuric acid and hydrochloric acid were investigated. The results show that the concentration of acid is an important factor in controlling the metal loss caused by wear corrosion processes in the acids. At very dilute acid concentration (10 to the -4 N), Fe behaves differently from Ni. Fe develops a soft, friable deposit, while Ni develops no corrosion layer. The formation and removal of the corrosion deposit on Fe resulted in high metal loss and coefficient of friction, as compared to the relatively low metal loss and coefficient of friction observed for Ni. At slightly higher acid concentration (10 to the -3 and 10 to the -2 N), no corrosion products were produced on both Fe and Ni. Wear of Fe and Ni was generally at a minimum. At higher acid concentration (10 to the -1 N and above), loss of Fe and Ni increased as the acid concentration increased. In sulfuric acid the maximum loss of both Fe and Ni was at 7.5 N (30 percent) concentration, and the metal losses of both Fe and Ni dropped markedly at 15 N (50 percent) and above. In hydrochloric acid, however, the Fe loss continued to increase with the increase of acid concentration, and the maximum Fe loss occurred in the most concentrated acid (12.1 N, 37 percent). There were variations in loss with Ni from specimen to specimen examined in hydrochloric acids (10 to the -1 N and above). The coefficient of friction for Ni increased slightly with an increase in acid concentration up to 10 to the -2 N. When corrosion started to dominate in the wear-corrosion process, the coefficient of friction decreased in both sulfuric and hydrochloric acids at 10 to the -1 N and above.

Miyoshi, Kazuhisa↗

Discrete Measurements of the Least Horizontal Principal Stress from Core Data: An Application of Viscoelastic Stress Relaxation

Summary The emerging Paradox Oil Play in southeastern Utah is among the most significant unconventional plays in the western USA. The mean total undiscovered oil resources within just the Pennsylvanian Cane Creek interval of the Paradox Basin are believed to exceed 215 million barrels. However, to date, less than 5% (~9 million barrels) of the total Cane Creek resource has been produced from fewer than 40 wells, and only approximately one-half of those are horizontal wells. More than 95% of production is from the central Cane Creek Unit (CCU). Natural fractures are a key feature of many production wells, but stimulation by induced hydraulic fractures is not consistently successful. We hypothesize that more effective production in this play will rely on better fundamental characterization, especially on better quantification of the state of stress. Approximately 110 ft of core, well logs, and a diagnostic fracture injection test (DFIT) were acquired from the State 16-2 well within the CCU. With these data, we applied two methods to constrain and clarify the state of stress. The first technique, the Simpson’s coefficient method, provides lower bounds on the two horizontal principal stresses and relies on only limited data. Alternatively, the viscoelastic stress relaxation (VSR) method is used to estimate the least horizontal principal stress, building on observations that principal stresses become more isotropic as the viscous behavior of a rock is more pronounced. Results of these two methods support the hypothesis that the state of stress in the CCU of the Paradox Basin is nearly lithostatic and isotropic. Other factors consistent with this hypothesis include high formation pore pressure, which tends to reduce the possible stress states by changing the frictional failure equilibrium; lack of induced fractures in the core, which should be present in the case of stress anisotropy; and interbedded halite layers, which given their high degree of ductility, probably lead to greater VSR for the entire sedimentary package.

Energy & Fuels↗