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At least 343 records · Page 19

Chuar Group of the Grand Canyon: record of breakup of Rodinia, associated change in the global carbon cycle, and ecosystem expansion by 740 Ma

The Chuar Group (approximately 1600 m thick) preserves a record of extensional tectonism, ocean-chemistry fluctuations, and biological diversification during the late Neoproterozoic Era. An ash layer from the top of the section has a U-Pb zircon age of 742 +/- 6 Ma. The Chuar Group was deposited at low latitudes during extension on the north-trending Butte fault system and is inferred to record rifting during the breakup of Rodinia. Shallow-marine deposition is documented by tide- and wave-generated sedimentary structures, facies associations, and fossils. C isotopes in organic carbon show large stratigraphic variations, apparently recording incipient stages of the marked C isotopic fluctuations that characterize later Neoproterozoic time. Upper Chuar rocks preserve a rich biota that includes not only cyanobacteria and algae, but also heterotrophic protists that document increased food web complexity in Neoproterozoic ecosystems. The Chuar Group thus provides a well-dated, high-resolution record of early events in the sequence of linked tectonic, biogeochemical, environmental, and biological changes that collectively ushered in the Phanerozoic Eon.

NASA Discipline Exobiology↗

DCE and Legacy Systems - An Experience Report What Really Happened

The Multimission Ground Data System (MGDS) in use at the Jet Propulsion Laboratory (JPL) was developed in the latter half of the 1980s. It was a major departure from the one-of-a-kind, non-distributed ground data system previously employed. Today, a project is underway to determine if the Distributed Computing Environment (DCE) has a place in MGDS. The initial component targeted for replacement is an application layer built on top of TCP/IP which handles the MGDS message-passing requirements.

Multimission Ground Data System MGDS Distributed C↗

Carbon Nanotube Based Light Sensor

A light sensor substrate comprises a base made from a semi-conductive material and topped with a layer of an electrically non-conductive material. A first electrode and a plurality of carbon nanotube (CNT)-based conductors are positioned on the layer of electrically non-conductive material with the CNT-based conductors being distributed in a spaced apart fashion about a periphery of the first electrode. Each CNT-based conductor is coupled on one end thereof to the first electrode and extends away from the first electrode to terminate at a second free end. A second or gate electrode is positioned on the non-conductive material layer and is spaced apart from the second free end of each CNT-based conductor. Coupled to the first and second electrode is a device for detecting electron transfer along the CNT-based conductors resulting from light impinging on the CNT-based conductors.

Wincheski, russell A.↗

Near-Real Time Cloud Retrievals from Operational and Research Meteorological Satellites

A set of cloud retrieval algorithms developed for CERES and applied to MODIS data have been adapted to analyze other satellite imager data in near-real time. The cloud products, including single-layer cloud amount, top and base height, optical depth, phase, effective particle size, and liquid and ice water paths, are being retrieved from GOES- 10/11/12, MTSAT-1R, FY-2C, and Meteosat imager data as well as from MODIS. A comprehensive system to normalize the calibrations to MODIS has been implemented to maximize consistency in the products across platforms. Estimates of surface and top-of-atmosphere broadband radiative fluxes are also provided. Multilayered cloud properties are retrieved from GOES-12, Meteosat, and MODIS data. Native pixel resolution analyses are performed over selected domains, while reduced sampling is used for full-disk retrievals. Tools have been developed for matching the pixel-level results with instrumented surface sites and active sensor satellites. The calibrations, methods, examples of the products, and comparisons with the ICESat GLAS lidar are discussed. These products are currently being used for aircraft icing diagnoses, numerical weather modeling assimilation, and atmospheric radiation research and have potential for use in many other applications.

Minnis, Patrick↗

Characterization of Deposits on Glass Substrate as a Tool in Failure Analysis: The Orbiter Vehicle Columbia Case Study

In connection with the accident investigation of the space shuttle Columbia, an analysis methodology utilizing well established microscopic and spectroscopic techniques was implemented for evaluating the environment to which the exterior fused silica glass was exposed. Through the implementation of optical microscopy, scanning electron microscopy, energy dispersive spectroscopy, transmission electron microscopy, and electron diffraction, details emerged regarding the manner in which a charred metallic deposited layer formed on top of the exposed glass. Due to nature of the substrate and the materials deposited, the methodology proved to allow for a more detailed analysis of the vehicle breakup. By contrast, similar analytical methodologies on metallic substrates have proven to be challenging due to strong potential for error resulting from substrate contamination. This information proved to be valuable to not only those involved in investigating the break up of Columbia, but also provides a potential guide for investigating future high altitude and high energy accidents.

Olivas, J. D.↗

Vertical Carbon Nanotube Device in Nanoporous Templates

A modified porous anodic alumina template (PAA) containing a thin CNT catalyst layer directly embedded into the pore walls. CNT synthesis using the template selectively catalyzes SWNTs and DWNTs from the embedded catalyst layer to the top PAA surface, creating a vertical CNT channel within the pores. Subsequent processing allows for easy contact metallization and adaptable functionalization of the CNTs and template for a myriad of applications.

Maschmann, Matthew Ralph↗

Quantifying TOLNet Ozone Lidar Accuracy During the 2014 DISCOVER-AQ and FRAPPE Campaigns

The Tropospheric Ozone Lidar Network (TOLNet) is a unique network of lidar systems that measure high-resolution atmospheric profiles of ozone. The accurate characterization of these lidars is necessary to determine the uniformity of the network calibration. From July to August 2014, three lidars, the TROPospheric OZone (TROPOZ) lidar, the Tunable Optical Profiler for Aerosol and oZone (TOPAZ) lidar, and the Langley Mobile Ozone Lidar (LMOL), of TOLNet participated in the Deriving Information on Surface conditions from Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) mission and the Front Range Air Pollution and Photochemistry Experiment (FRAPPA) to measure ozone variations from the boundary layer to the top of the troposphere. This study presents the analysis of the intercomparison between the TROPOZ, TOPAZ, and LMOL lidars, along with comparisons between the lidars and other in situ ozone instruments including ozonesondes and a P-3B airborne chemiluminescence sensor. The TOLNet lidars measured vertical ozone structures with an accuracy generally better than +/-15 % within the troposphere. Larger differences occur at some individual altitudes in both the near-field and far-field range of the lidar systems, largely as expected. In terms of column average, the TOLNet lidars measured ozone with an accuracy better than +/-5 % for both the intercomparison between the lidars and between the lidars and other instruments. These results indicate that these three TOLNet lidars are suitable for use in air quality, satellite validation, and ozone modeling efforts.

TOLNet↗

A13H-2537: Above Cloud Aerosol Optical Properties in the South East Atlantic from airborne observations during ORACLES

Aerosol overlying marine stratocumulus clouds is a persistent feature in the southeast Atlantic during the biomass burning season, July through November. We sampled aerosol and cloud from an airborne research platform, the NASA P3, during the deployments of ObseRvations of CLouds above Aerosols and their intEractionS (ORACLES) encompassing the peak biomass burning season. We used the Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) to quantify the aerosol’s optical properties, notably the aerosol optical depth (AOD) by directly measuring the amount of light attenuation. We present an overview of very recent AOD measurements and contrast those to previous deployments. We observed an average AOD at 500 nm of 0.33 (0.30) in September 2016 (August 2017), with similar spatial dependence as observed by the MODIS instrument on board the TERRA and AQUA satellites. We also show full spectral vertical dependence of AOD from flight profiles, which compares favorably to the integrated aerosol extinction profile obtained by the active remote sensing High Spectral Resolution Lidar-2 (HSRL-2). We also present a quantification of the gap extent separating cloud top and aerosol layer bottom. Using hyperspectral transmitted light measurements from 4STAR, in conjunction with hyperspectral hemispheric irradiance measurements from the Solar Spectral Flux Radiometers (SSFR), we retrieved aerosol intensive properties (asymmetry parameter, single scattering albedo), aerosol size distributions, cloud optical depth (COD), cloud particle effective radius, and cloud thermodynamic phase. Cloud properties, also presented here, are obtained from 4STAR measurements of scattered light below clouds.

Samuel E LeBlanc↗

Simultaneous lidar profiling of water vapor, aerosol, and wind over the eastern Pacific and implications for observational challenges on clouds, circulation, and climate sensitivity

Moist convective processes and related circulations are key components of the Earth’s climate system. Improving our understanding of moisture and cloud processes over oceans is especially challenging due to observational limitations, but also important due to the large radiative effects of cloud over ocean as well as the ties to local and global-scale circulations. A unique dataset for addressing these topics was collected over 5 flights with the NASA HALO (water vapor DIAL and aerosol HSRL) and DAWN (Doppler wind) lidar systems onboard the NASA DC-8 aircraft during the spring 2019 ADM-Aeolus Cal/Val test flight campaign. High-resolution water vapor, aerosol/cloud, and wind profiles were simultaneously collected and complimented with in situ high-resolution dropsonde measurements of temperature, relative humidity, and wind profiles. Airborne lidar measurements of these key variables captured both large-scale spatial variability across different cloud and atmospheric conditions as well as finer features, providing insight into processes from large-scale circulations down to aerosol/cloud interactions. The 5 flights spanned the northeast Pacific and southwest U.S. from 6 N to 52 N and 112 W to 157 W and captured several features of interest including moist layers from the ascending region of the Hadley circulation, very dry layers above midlatitude marine stratocumulus and cloud-free planetary boundary layers, and cloud top height and spatial variability. High covariance of aerosol and water vapor in the free troposphere was also observed for the first time. Preliminary analysis of these data sets will be presented as they apply to clouds and circulations, supplemented by model reanalysis to inform how regional water vapor structure and large-scale motion may contribute to observed shallow cloud formations and other meteorological processes that underpin our current understanding of how these state variables couple to impact the Earth’s weather and climate systems. The potential of complementary measurements in future field campaigns will also be mentioned.

Brian James Carroll↗

Mars Atmospheric Chemistry Simulations with the GEM-Mars General Circulation Model

General Circulation Models with interactive physical and chemistry processes are the state-of-the-art tools for an integrated view and understanding of the Martian atmosphere and climate system. The GEM-Mars model currently includes 16 tracers for chemical composition and applies a fully online, interactive calculation of the photo- and gas phase chemistry of carbon dioxide (CO2) and water vapor (H2O). These species largely control the chemical composition of the neutral Mars atmosphere through their photolysis products and their subsequent interactions. Water vapor undergoes a complex cycle on Mars as it is transported and interacts with ice reservoirs both at the planet's surface and at water ice clouds, which in turn provide radiative feedbacks. In the photochemical cycles involving CO2 and H2O, the abundances of 5 species have been reported by previous investigations with significant spatio-temporal coverage: CO2, H2O, CO, O3 and H2O2. This paper presents the current status of the atmospheric chemistry simulations in GEM-Mars by comparing them to a selection of these observational datasets as well as to oxygen dayglow emission from O2(a1∆g). The results are consistent with previous model-data comparisons and illustrate that the water cycle and the photochemistry are well implemented in the model. In particular, the simulation of the key reservoir species H2O2 provides a good match to the available data. Model-data biases for ozone columns and oxygen airglow are related to the simulated water vapor vertical profile, as these species have important column contributions from vertical layers at the top of the hygropause.

F Daerden↗

Chromium on Mercury: New Results From the MESSENGER X-Ray Spectrometer and Implications for the Innermost Planet’s Geochemical Evolution

Mercury, the innermost planet, formed under highly reduced conditions, based mainly on surface Fe, S, and Si abundances determined from MESSENGER mission data. The minor element Cr may serve as an independent oxybarometer but only very limited Cr data have been previously reported for Mercury. We report Cr/Si abundances across Mercury's surface based on MESSENGER X-Ray Spectrometer data throughout the spacecraft's orbital mission. The heterogeneous Cr/Si ratio ranges from 3.6 × 10 -5 in the Caloris Basin to 0.0012 within the high-magnesium region, with an average southern hemisphere value of 0.0008 (corresponding to about 200 ppm Cr). Absolute Cr/Si values have systematic uncertainty of at least 30%, but relative variations are more robust. By combining experimental Cr partitioning data along with planetary differentiation modeling, we find that if Mercury formed with bulk chondritic Cr/Al, Cr must be present in the planet's core and differentiation must have occurred at log ƒO 2 in the range of IW-6.5 to IW-2.5 in the absence of sulfides in its interior and a range of IW-5.5 to IW-2 with an FeS layer at the core-mantle boundary. Models with large fractions of Mg-Ca-rich sulfides in Mercury's interior are more compatible with moderately reducing conditions (IW-5.5 to IW-4) owing to the instability of Mg-Ca-rich sulfides at elevated ƒO 2 . These results indicate that if Mercury differentiated at a log ƒO 2 lower than IW-5.5, the presence of sulfides whether in the form of a FeS layer at the top of the core or Mg-Ca-rich sulfides within the mantle would be unlikely.

Larry R. Nittler↗

Thin Layer Composite Unimorph Ferroelectric Driver and Sensor

A method for forming ferroelectric wafers is provided. A prestress layer is placed on the desired mold. A ferroelectric wafer is placed on top of the prestress layer. The layers are heated and then cooled, causing the ferroelectric wafer to become prestressed. The prestress layer may include reinforcing material and the ferroelectric wafer may include electrodes or electrode layers may be placed on either side of the ferroelectric layer. Wafers produced using this method have greatly improved output motion.

Helbaum, Richard F.↗

Thin Layer Composite Unimorph Ferroelectric Driver and Sensor

A method for forming ferroelectric wafers is provided. A prestress layer is placed on the desired mold. A ferroelectric wafer is placed on top of the prestress layer. The layers are heated and then cooled causing the ferroelectric wafer to become prestressed. The prestress layer may include reinforcing material and the ferroelectric wafer may include electrodes or electrode layers may be placed on either side of the ferroelectric layer. Wafers produced using this method have greatly improved output motion.

Hellbaum, Richard F.↗

Thin layer composite unimorph ferroelectric driver and sensor

A method for forming ferroelectric wafers is provided. A prestress layer is placed on the desired mold. A ferroelectric wafer is placed on top of the prestress layer. The layers are heated and then cooled, causing the ferroelectric wafer to become prestressed. The prestress layer may include reinforcing material and the ferroelectric wafer may include electrodes or electrode layers may be placed on either side of the ferroelectric layer. Wafers produced using this method have greatly improved output motion.

Hellbaum, Richard F.↗

Optically Transparent Split-Ring Antennas for 1 to 10 GHz

Split-ring antennas made from optically transparent, electrically conductive films have been invented for applications in which there are requirements for compact antennas capable of operation over much or all of the frequency band from 1 to 10 GHz. Primary examples of such applications include wireless local-area networks and industrial, scientific, and medical (ISM) applications. These antennas can be conveniently located on such surfaces as those of automobile windows and display screens of diverse hand-held electronic units. They are fabricated by conventional printed-circuit techniques and can easily be integrated with solid-state amplifier circuits to enhance gain. The structure of an antenna of this type includes an antenna/feed layer supported on the top or outer face of a dielectric (e.g., glass) and, optionally, a ground layer on the bottom or inner face of the substrate. The ring can be in the form of either a conductive strip or a slot in the antenna/feed layer. The ring can be of rectangular, square, circular, elliptical, or other suitable shape and can be excited by means of a microstrip, slot line, or coplanar waveguide. For example, the antenna shown in the figure features a square conductive-strip split ring with a microstrip feed. In general, an antenna fed at its external boundary in the manner of this invention presents very high impedance, thereby creating an impedance-matching problem. Splitting the ring . that is, cutting a notch through the ring . offers a solution to the problem in that the notch fixes the location of maximum electric field, which location is directly related to the impedance. Thus, an excellent impedance match can be achieved through proper choice of the location of the notch. In geometric layout, such a ring antenna structure is typically between 1.4 and 1.3 the size of a patch antenna capable of operating in the same frequency range. This miniaturization of the antenna is desirable, not only because it contributes to overall miniaturization of equipment, but also because minimization of the extent of the optically transparent, electrically conductive film helps to minimize the electrical loss associated with the surface resistance ( 5 ohms per square) of the transparent, electrically conductive film material. Incidentally, even at 5 ohms per square, this surface resistance is significantly less than that of indium tin oxide film (typically > 25 ohms per square), which, heretofore has been the transparent, electrically conductive film material of choice. At the time of writing this article, information on the composition of the lower-resistance film used in the antennas of this invention was not available.

Lee, Richard Q.↗

Iridium Interfacial Stack (IRIS)

An iridium interfacial stack ("IrIS") and a method for producing the same are provided. The IrIS may include ordered layers of TaSi.sub.2, platinum, iridium, and platinum, and may be placed on top of a titanium layer and a silicon carbide layer. The IrIS may prevent, reduce, or mitigate against diffusion of elements such as oxygen, platinum, and gold through at least some of its layers.

Spry, David James↗

Influence of Subpixel Scale Cloud Top Structure on Reflectances from Overcast Stratiform Cloud Layers

Recent observational studies have shown that satellite retrievals of cloud optical depth based on plane-parallel model theory suffer from systematic biases that depend on viewing geometry, even when observations are restricted to overcast marine stratus layers, arguably the closest to plane parallel in nature. At moderate to low sun elevations, the plane-parallel model significantly overestimates the reflectance dependence on view angle in the forward-scattering direction but shows a similar dependence in the backscattering direction. Theoretical simulations are performed that show that the likely cause for this discrepancy is because the plane-parallel model assumption does not account for subpixel, scale variations in cloud-top height (i.e., "cloud bumps"). Monte Carlo simulation, comparing ID model radiances to radiances from overcast cloud field with 1) cloud-top height variation, but constant cloud volume extinction; 2) flat tops but horizontal variations in cloud volume extinction; and 3) variations in both cloud top height and cloud extinction are performed over a approximately equal to 4 km x 4 km domain (roughly the size of an individual GAC AVHRR pixel). The comparisons show that when cloud-top height variations are included, departures from 1D theory are remarkably similar (qualitatively) to those obtained observationally. In contrast, when clouds are assumed flat and only cloud extinction is variable, reflectance differences are much smaller and do not show any view-angle dependence. When both cloud-top height and cloud extinction variations are included, however, large increases in cloud extinction variability can enhance reflectance difference. The reason 3D-1D reflectance differences are more sensitive to cloud-top height variations in the forward-scattering direction (at moderate to low, sun elevations) is because photons leaving the cloud field in that direction experience fewer scattering events (low-order scattering) and are restricted to the topmost portions of the cloud. While reflectance deviations from 1D theory are much larger for bumpy clouds than for flat clouds with variable cloud extinction, differences in cloud albedo are comparable for these two cases.

Loeb, N. G.↗

The Effect of Interface Roughness and Oxide Film Thickness on the Inelastic Response of Thermal Barrier Coatings to Thermal Cycling

The effects of interfacial roughness and oxide film thickness on thermally-induced stresses in plasma-sprayed thermal barrier coatings subjected to thermal cycling are investigated using the recently developed higher-order theory for functionally graded materials. The higher-order theory is shown to be a viable alternative to the finite-element approach, capable of modeling different interfacial roughness architectures in the presence of an aluminum oxide layer and capturing the high stress gradients that occur at the top coat/bond coat interface. The oxide layer thickness is demonstrated to have a substantially greater effect on the evolution of residual stresses than local variations in interfacial roughness. Further, the location of delamination initiation in the top coat is predicted to change with increasing oxide layer thickness. This result can be used to optimize the thickness of a pre-oxidized layer introduced at the top coat/bond coat interface in order to enhance TBC durability as suggested by some researchers. The results of our investigation also support a recently proposed hypothesis regarding delamination initiation and propagation in the presence of an evolving bond coat oxidation, while pointing to the importance of interfacial roughness details and specimen geometry in modeling this phenomenon.

Pindera, Marek-Jerzy↗