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NASA NTRS1974

Provenance of KREEP and the exotic component - Elemental and isotopic studies of grain size fractions in lunar soils

Sieve fraction analyses of lunar soils reveal the presence of a fine-grained exotic component enriched in K, Rb, Sr, Ba, and in radiogenic Sr in all soils. The probable source of this exotic component is the areas of high-surficial radioactivity observed by orbital gamma ray spectrometry, such as those at Fra Mauro and Archimedes. If the exotic component is fine-grained KREEP, the origin and distribution of KREEP fragments in the soils are identified. It is suggested that the exotic component represents trace element enriched material located at some depth in the Imbrium area which was surficially deposited during Imbrium excavation.

Evensen, N. M.↗
NASA NTRS2005

Lunar and Planetary Science XXXVI, Part 15

Contents include the following: Impact Metamorphism of Subsurface Organic Matter on Mars: A Potential Source for Methane and Surface Alteration. Preliminary Study of Polygonal Impact Craters in Argyre Region, Mars. Geochemistry of the Dark Veinlets in the Granitoids from the Souderfjarden Impact Structure, Finland: Preliminary Results. An Experimental Method to Estimate the Chemical Reaction Rate in Vapor Clouds: An Application to the K/T Impact. Study of the Apollo 16 Landing Site: Re-Visit as a Standard Site for the SELENE Multiband Imager. First X-Ray Observation of Lunar Farside from Hayabusa X-Ray Spectrometer. Lunar X-Ray Fluorescence Spectrometry from SELENE Lunar Polar Orbiter. Origin and Thermal History of Lithic Materials in the Begaa LL3 Chondrite. Evidence of Normal Faulting and Dike Intrusion at Valles Marineris from Pit Crater Topography. Evidence of Tharsis-Radial Dike Intrusion in Southeast Alba Patera from MOLA-based Topography of Pit Crater Chains. Are They Really Intact? Evaluation of Captured Micrometeoroid Analogs by Aerogel at the Flyby Speed of Stardust. Numerical Simulations of Impactor Penetration into Ice-Over-Water Targets. A Probable Fluid Lava Flow in the Hebes Mensa (Mars) Studied by HRSC Images. New Drill-Core Data from the Lockne Crater, Sweden: The Marine Excavation and Ejection Processes, and Post-Impact Environment. Cross-Sectional Profile of Baltis Vallis Channel on Venus: Reconstruction from Magellan SAR Brightness Data.

Source record↗
NASA NTRS2011

Thickness of Proximal Ejecta from the Orientale Basin from Lunar Orbiter Laser Altimeter (LOLA) Data: Implications for Multi-Ring Basin Formation

Quantifying the ejecta distribution around large lunar basins is important to understanding the origin of basin rings, the volume of the transient cavity, the depth of sampling, and the nature of the basin formation processes. We have used newly obtained altimetry data of the Moon from the Lunar Orbiter Laser Altimeter (LOLA) instrument to estimate the thickness of ejecta in the region surrounding the Orientale impact basin, the youngest and best preserved large basin on the Moon. Our measurements yield ejecta thicknesses of approx.2900 m near the Cordillera Mountains, the topographic rim of Orientale, decaying to approx.1 km in thickness at a range of 215 km. These measurements imply a volume of ejecta in the region from the Cordillera ring to a radial range of one basin diameter of approx.2.9 x 10(exp 6)cu km and permit the derivation of an ejecta-thickness decay model, which can be compared with estimates for the volume of excavation and the size of the transient cavity. These data are consistent with the Outer Rook Mountains as the approximate location of the transient cavity s rim crest and suggest a volume of approx.4.8 x 10(exp 6)cu km for the total amount of basin ejecta exterior to this location.

Fassett, Caleb I.a↗
NASA NTRS1979

Geology of the lunar farside crater Necho

The ejecta morphology and distribution as well as the interior materials of the 30-km-diameter, Necho lunar crater is discussed and the effects of regional preimpact topography on the formation structure and modification of the crater are described. Three types of ejecta: hummocky, lineated, and smooth, that are concentrated in a band extending from the rim crest to a distance of less than one crater diameter are examined. The crater's interior, divided into floor units of textured, bubbled, and smooth material is analyzed and hypotheses of their origin are presented. The last area of study is the preimpact setting, characterized by a series of large, degraded, pre-Nectarian craters. Results showed that the Necho, in comparison with surrounding craters, was the freshest, insuring that the data from its excavation was preserved without a significant amount of degradation.

Gifford, A. W.↗
NASA NTRS1975

Intracrystalline cation order in a lunar crustal troctolite

Lunar sample 76535 appears to be one of the most slowly cooled bits of silicate material yet studied. It provides, therefore, a unique opportunity for the study of ordering processes in the minerals present. A better understanding of these processes may permit better characterization of the thermal history of this and similar rocks. The cation ordering in the olivine is consistent with terrestrial olivines favoring the interpretation that ordering in olivines increases with increasing temperature. In low bronzite, the deviations from the common orthopyroxene space group appear to be caused by cation order on the basis of four M sites instead of two. The degree of cation order in each of these minerals is consistent with the rock having been excavated from its depth of formation by tectonic or impact processes without being reheated above 300 C.

Smyth, J. R.↗
NASA NTRS1975

A Monte Carlo model for the gardening of the lunar regolith

The processes of movement and turnover of the lunar regolith are described by a Monte Carlo model. The movement of material by the direct cratering process is the dominant mode, but slumping is also included for angles exceeding the static angle of repose. Using a group of interrelated computer programs, a large number of properties are calculated, including topography, formation of layers, depth of the disturbed layer, nuclear-track distributions, and cosmogenic nuclides. In the most complex program, the history of a 36-point square array is followed for times up to 400 million years. The histories generated are complex and exhibit great variety. Because a crater covers much less area than its ejecta blanket, there is a tendency for the height change at a test point to exhibit periods of slow accumulation followed by sudden excavation. In general, the agreement with experiment and observation seems good, but two areas of disagreement stand out. First, the calculated surface is rougher than that observed. Second, the observed bombardment ages, of the order 400 million are shorter than expected (by perhaps a factor of 5).

Arnold, J. R.↗
NASA NTRS1972

King Crater and its environs, part M

Superb photographs of King Crater were returned by the Apollo 16 crew. The metric and panoramic cameras provided stereoscopic coverage with which high quality topographic maps may be made. King crater, approximately 75 km in diameter and, on the average, 3.8 km deep, is among the most significant features photographed and visually studied from lunar orbit on the Apollo 16 mission. It is the freshest crater on the far side in its size range and has several unique characteristics. (1) Although its ejecta blanket displays very sharp features, the crater does not appear to have extensive ray systems and secondary crater chains. (2) As depicted for the first time by Apollo 16 photographs, the ejecta blanket is strewn with numerous flow fronts and scarps. (3) A flat and smooth, dark, lavalike deposit 15 km across is on the northern rim of the crater. (4) The central peak of the crater is a Y-shaped structure that begins at the southern rim. (5) Bright units that are aligned with the central peak on the northern wall and rim suggest that a preexisting tabular body was excavated by the cratering process.

El-Baz, F.↗
NASA NTRS1982

Distribution and provenance of lunar highland rock types at North Ray Crater, Apollo 16

In connection with its selenographic setting in the central lunar highlands, the Apollo 16 landing site in the Descartes area is highly important as a prime sampling area for rocks which formed as part of the primordial crust and as a key location for the analysis of the deformation and transport of crustal material by impact processes. The present investigation is concerned with the North Ray crater, which is located on the N-S running boundary between the smooth Cayley plains to the west and the Descartes mountains to the east. Attention is given to aspects of selenography and location of samples, the ejecta distribution of post-Cayley impact craters, sample classification, the frequency distribution of rock types in the North Ray Crater ejecta, an interpretation of compositional and age data, a model of the target stratigraphy and excavation of North Ray Crater, and implications for the emplacement and provenance of North Ray target rocks.

Stoeffler, D.↗
NASA NTRS2004

Remote Sensing of the Haughton Impact Structure (HIS): A Terrestrial Proof of Concept for Using the Remote Sensing of Martian Craters as a Probe of Subsurface Composition

Impact cratering is the most widespread geological process in the Solar System. Impact craters can provide 'windows' into the subsurfaces of planetary bodies through excavation and uplift. By utilizing remote methods in the visible and near infrared (VNIR; 0.4-1.4 micron), short-wavelength infrared (SWIR; 1.4-2.5 micron) and thermal infrared (TIR 7-14 micron), subsurface mineral compositions may be identified and mapped via impact craters. Complex craters in particular, expose minerals from both the shallow and deep-seated subsurface, which may be identified spectroscopically. Complex craters have morphological features such as central peaks or peak rings, which are composed of relatively coherent lithologies tapped from deep-seated crustal components. While near-surface crustal components can be observed as coherent rocks uplifted and exposed in the rim and the crater walls, and from the ejecta deposits. Only two previously published studies using this approach have been successful on large planetary bodies. Tompkins and Pieters utilized ultraviolet and VNIR from Clementine to characterize near- and deep-subsurface materials in and around lunar craters. The work of Ramsey and Wright was the first remote spectroscopic study to successfully identify near-subsurface materials in the ejecta and crater wall of a terrestrial impact structure, namely Meteor Crater. Here we present early results of a third such study, a remote spectroscopy evaluation of the Haughton impact structure (HIS). The purpose of this study is to serve as terrestrial proof of concept that remote visible/infrared spectroscopic methods in this case, analysis of LANDSAT 7 ETM+ and ASTER data of the well-preserved HIS can be utilized in deciphering the subsurface composition of planetary crusts. This technique is particularly promising for Mars were limited tectonic uplift and ubiquitous dust-mantling offer few opportunities to access subsurface information.

Tornabene, L. L.↗
NASA NTRS2009

In Situ Resource Utilization (ISRU) on the Moon: Moessbauer Spectroscopy as a Process Monitor for Oxygen Production

Essential consumables like oxygen must to be produced from materials on the lunar surface to enable a sustained, long-term presence of humans on the Moon. The Outpost Precursor for ISRU and Modular Architecture (OPTIMA) field test on Mauna Kea, Hawaii, facilitated by the Pacific International Space Center for Exploration Systems (PISCES) of the University of Hawaii at Hilo, was designed to test the implementation of three hardware concepts to extract oxygen from the lunar regolith: Precursor ISRU Lunar Oxygen Testbed (PILOT) developed by Lockheed Martin in Littleton, CO; Regolith & Environmental Science and Oxygen & Lunar Volatiles Extraction (RESOLVE) developed at the NASA Kennedy Space Center in Cape Canaveral, FL; and ROxygen developed at the NASA Johnson Space Center in Houston, TX. The three concepts differ in design, but all rely on the same general principle: hydrogen reduction of metal cations (primarily Fe2+) bonded to oxygen to metal (e.g., Fe0) with the production of water. The hydrogen source is residual hydrogen in the fuel tanks of lunar landers. Electrolysis of the water produces oxygen and hydrogen (which is recycled). We used the miniaturized M ssbauer spectrometer MIMOS II to quantify the yield of this process on the basis of the quantity of Fe0 produced. Iron M ssbauer spectroscopy identifies iron-bearing phases, determines iron oxidation states, and quantifies the distribution of iron between mineral phases and oxidation states. The oxygen yield can be calculated by quantitative measurements of the distribution of Fe among oxidation states in the regolith before and after hydrogen reduction. A M ssbauer spectrometer can also be used as a prospecting tool to select the optimum feedstock for the oxygen production plants (e.g., high total Fe content and easily reduced phases). As a demonstration, a MIMOS II backscatter spectrometer (SPESI, Germany) was mounted on the Cratos rover (NASA Glenn Research Center in Cleveland, OH), which is one of several rover concepts designed to excavate and transfer regolith to the stationary hydrogen reduction plants. Spaceflight versions of the MIMOS II are part of the instrument payloads of NASA s Mars Exploration Rovers and still operating five years after landing on the surface of the planet. MIMOS II was also selected for Phobos-Grunt, a Russian sample return mission to the martian moon Phobos scheduled to launch in 2009, and ESA s ExoMars rover, an exobiology mission scheduled to launch in 2013. An advanced version of the instrument is currently under development. A new detector system with a higher energy resolution will not only reduce the necessary measurement time considerably, but also allow the simultaneous acquisition of an X-ray fluorescence spectrum to determine the elemental composition of samples.

Morris, R.V.↗
NASA NTRS1978

Impact flows and crater scaling on the moon

The axisymmetric distribution of stress, internal energy, and particle velocity resulting from the impact of an iron meteoroid with a gabbroic anorthosite lunar crust has been calculated for the regime in which shock-induced melting and vaporization take place. Comparison of impact flow fields, with phase changes in silicates taken into account, with earlier results demonstrate that in the phase-change case where the 15-km/s projectile has penetrated some two projectile radii into the moon, the peak stress in the flow is about 0.66 Mbar at a depth of 66 km, and the stress has decayed to about 66 kbar at a depth of 47 km. Rapid attenuation occurs because of the high rarefaction velocity of the high-pressure phases associated with a 35% (zero-pressure) density increase. This feature of the phase-change flow tends to concentrate strongly the maximum shock pressures along the meteoroid trajectory (axis) and makes the conical zone along which high internal energy deposition occurs both shallow and narrow. Examination of the gravitational energies required to excavate larger craters on the moon indicates the importance of gravity forces acting during the excavation of craters having radii in the range greater than about 2 to 140 km.

Okeefe, J. D.↗
NASA NTRS1976

Missile impact craters (White Sands Missile Range, New Mexico) and applications to lunar research: Contributions to astrogeology

Craters in natural materials at White Sands Missile Range, N. Mex., were produced by the impact of high-velocity to hypervelocity missiles traveling along oblique trajectories with kinetic energies between 2.1 and 81 × 1014 ergs. The oblique impacts produce craters 2 to 10 m across with morphologies and ejecta that are bilaterally symmetrical with respect to the plane of the missile trajectory. Rims are high and the amount of ejecta large in down-trajectory and lateral directions, whereas rims are low to nonexistent and ejecta thin to absent up-trajectory. Symmetry development and modifications of the symmetry are a function of target material, local topography, and angle of impact. Seven mappable units can be recognized in and around the craters. Three of these are ejecta: thick ejecta near the crater, thin to discontinuous ejecta at greater distances, and scattered ejecta at the greatest distances to the limit of throwout. These ejecta units may be absent on the up-trajectory side; if present, they are rarely as thick or continuous as on other sides of the crater. Three units are target materials: undeformed target material exposed in local patches through thin to discontinuous ejecta and everywhere between the fragments of scattered ejecta, tilted and broken target material exposed in upper crater walls, and shattered and fractured target material exposed on the up-trajectory crater wall. The seventh unit is slope material composed of talus and fallback within the crater. Development, character, and exposure of these units varies chiefly with the target material. Ejecta from the craters is chiefly broken but relatively undeformed target material that may range in size from very fine grained debris to large blocks. Where the target is porous, significant amounts of the ejecta are composed of sheared and compressed fragments, some coated with dark layers of mixed projectile pieces, powder, and fused metal mixed with crushed target material. For layered targets, the original stratigraphic sequence is crudely preserved and in inverted order in thick ejecta. Secondary impact craters are produced by the impact of ejected fragments when the surrounding surface materials are sufficiently weak. A wide variety of secondary impact crater relations may result. Secondary craters nearest the primary crater have blocks in them that are larger than or the same size as the crater they produced. Farther from the primary crater, the fragments are generally smaller than the secondary crater and are ejected from it. Excavation of four craters revealed a mixed breccia beneath the crater floor composed of missile pieces, sheared and compressed target material, and crushed debris. Banded, disaggregated target material and nonmixed breccia surrounded the mixed breccia, and these breccias were surrounded by a zone of conjugate fractures. Beneath the ejecta on the lateral and down-trajectory crater flanks, the target materials were tilted upward and broken. Up-trajectory, open fractures and downward displacement occurred in two of the craters. No displacement was observed for the other two. Beneath the down-trajectory rims of craters with distinct layering, overturned synclines were observed. Missile breakup and behavior during cratering are a function of target and missile properties. Missile breakup depends on missile velocity and is most extensive at high velocities, where the missile is fragmented, powdered, and partly fused. Burial of missile or its fragmented, powdered, and fused remains is greatest for porous targets and least for dense cohesive targets. For very porous targets, camouflet structures containing the fragmented missile may form. Least squares fit to the data on craters in dry to moist targets indicate V(a) = 10^(-11.433)E(p)^(1.205) where V(a) is the volume of the apparent crater and E(p) is the kinetic energy of the missile. This equation is consistent with expectations of the equations relating apparent depth and radius to kinetic energy. Extrapolation of displaced masses and kinetic energies for laboratory impacts with sand and rock converge near 10^(15) to 10^(16) ergs, where the extrapolations are near the data on missile impact craters, corrected for impact angle. Displaced masses of craters produced by missile impacts and by chemical explosives with small scaled depths of burial are about the same when the kinetic energies of the missiles (corrected for angle of impact) are equal to the TNT equivalent energy of the explosive. The problem of equivalent scaled depth of burst for an impact crater is complicated and not entirely resolved, however. Both missile impact craters and chemical explosive craters in water-saturated targets are larger than their counterparts in dry to moist materials. Data collected during the study of missile impact craters have helped resolve a number of problems in lunar research: (1) the soillike nature of lunar surface materials was predicted, (2) sizes of craters produced by artificial impacts were correctly predicted, (3) certain features imaged by Surveyor were found to be analogous to features associated with missile impact craters, {4) missile impacts were used in support of the Apollo passive seismic experiment, (5) craters seen in Apollo orbital photographs were found to be similar to some missile impact craters, (6) missile impact craters supplied data on sample collection and crater phenomenology used in training astronauts, and (7) some returned lunar samples are similar to coated, sheared, and compressed fragments ejected from missile impact craters.

H. J. Moore↗
NASA NTRS2013

NASA Tech Briefs, January 2013

Topics include: Single-Photon-Sensitive HgCdTe Avalanche Photodiode Detector; Surface-Enhanced Raman Scattering Using Silica Whispering-Gallery Mode Resonators; 3D Hail Size Distribution Interpolation/Extrapolation Algorithm; Color-Changing Sensors for Detecting the Presence of Hypergolic Fuels; Artificial Intelligence Software for Assessing Postural Stability; Transformers: Shape-Changing Space Systems Built with Robotic Textiles; Fibrillar Adhesive for Climbing Robots; Using Pre-Melted Phase Change Material to Keep Payloads in Space Warm for Hours without Power; Development of a Centrifugal Technique for the Microbial Bioburden Analysis of Freon (CFC-11); Microwave Sinterator Freeform Additive Construction System (MS-FACS); DSP/FPGA Design for a High-Speed Programmable S-Band Space Transceiver; On-Chip Power-Combining for High-Power Schottky Diode-Based Frequency Multipliers; FPGA Vision Data Architecture; Memory Circuit Fault Simulator; Ultra-Compact Transputer-Based Controller for High-Level, Multi-Axis Coordination; Regolith Advanced Surface Systems Operations Robot Excavator; Magnetically Actuated Seal; Hybrid Electrostatic/Flextensional Mirror for Lightweight, Large-Aperture, and Cryogenic Space Telescopes; System for Contributing and Discovering Derived Mission and Science Data; Remote Viewer for Maritime Robotics Software; Stackfile Database; Reachability Maps for In Situ Operations; JPL Space Telecommunications Radio System Operating Environment; RFI-SIM: RFI Simulation Package; ION Configuration Editor; Dtest Testing Software; IMPaCT - Integration of Missions, Programs, and Core Technologies; Integrated Systems Health Management (ISHM) Toolkit; Wind-Driven Wireless Networked System of Mobile Sensors for Mars Exploration; In Situ Solid Particle Generator; Analysis of the Effects of Streamwise Lift Distribution on Sonic Boom Signature; Rad-Tolerant, Thermally Stable, High-Speed Fiber-Optic Network for Harsh Environments; Towed Subsurface Optical Communications Buoy; High-Collection-Efficiency Fluorescence Detection Cell; Ultra-Compact, Superconducting Spectrometer-on-a-Chip at Submillimeter Wavelengths; UV Resonant Raman Spectrometer with Multi-Line Laser Excitation; Medicine Delivery Device with Integrated Sterilization and Detection; Ionospheric Simulation System for Satellite Observations and Global Assimilative Model Experiments - ISOGAME; Airborne Tomographic Swath Ice Sounding Processing System; flexplan: Mission Planning System for the Lunar Reconnaissance Orbiter; Estimating Torque Imparted on Spacecraft Using Telemetry; PowderSim: Lagrangian Discrete and Mesh-Free Continuum Simulation Code for Cohesive Soils; Multiple-Frame Detection of Subpixel Targets in Thermal Image Sequences; Metric Learning to Enhance Hyperspectral Image Segmentation; Basic Operational Robotics Instructional System; Sheet Membrane Spacesuit Water Membrane Evaporator; Advanced Materials and Manufacturing for Low-Cost, High-Performance Liquid Rocket Combustion Chambers; Motor Qualification for Long-Duration Mars Missions.

Source record↗
NASA NTRS1979

The Apollo 17 drill core - Petrologic systematics and the identification of a possible Tycho component

Modal data support a five-unit stratigraphy for the Apollo 17 drill core. The upper unit E (0-22 cm depth) is marked by high content of fused soil, brown glass, and mare basalt fragments. This unit corresponds with a portion of the core excavated and refilled within the last 2 m.y. The underlying unit D (22071 cm depth) has a low abundance of fused soil (i.e., low maturity) and is rich in coarse (less than 200 microns) mare fragments. A large section of the core, unit C (71-224 cm depth), is finer-grained, more mature (richer in agglutinates), more feldspathic and has more highland lithic, mineral and glass fragments than unit D. The next underlying unit, B (224-256 cm depth), has yellow/colorless KREEP glasses with a high Si, low-alkali composition unlike the common Apollo 15 or Apollo 17 KREEP series. The petrologic (fused soil) and Is/FeO maturity of this layer is also lower than the units above and below. The deepest unit, A (256-284 cm depth), is marked by its relatively higher maturity and lower yellow/colorless KREEP glass content. The most prominent petrographic/stratigraphic indicators are the pyroxene-rich immature mare unit D and the abundance of KREEP glass in unit B. This KREEP glass is distinctive petrographically and compositionally, and is probably exotic to the Apollo 17 site. It is suggested here that the KREEP glass in unit B is derived from Tycho, which implies widespread distribution of KREEP on the lunar nearside.

Vaniman, D. T.↗
NASA NTRS1999

Lateral and Vertical Heterogeneity of Thorium in the Procellarum KREEP Terrane: As Reflected in the Ejecta Deposits of Post-Imbrium Craters

The Procellarum KREEP Terrane displays the highest concentrations of Th on the Moon. However, locations of elevated Th in this region appear to be random. As observed in the 5 deg per pixel equal-area Th data, and made more evident in the preliminary 2 deg data, Th is enhanced around the craters Aristillus, Aristarchus, Kepler, Mairan, the Apennine Bench formation, and the Fra Mauro region, while noticeably and unexpectedly lower in other locations (e.g., Archimedes, Copernicus, Eratosthenes, and Plato). We have examined the composition of the materials present in these regions with the goal of understanding the patchy nature to the distribution of Th and ultimately to decipher the geologic processes that have concentrated the Th. At present time, the published resolution of the Lunar Prospector Th gamma-ray data is low (5 deg per pixel), but this will soon be superceded by significantly higher-resolution data (2 deg per pixel). Even at this improved resolution, however, it is difficult to resolve the units that are the major source of Th. In an attempt to circumvent this problem, we employ the higher-resolution Clementine multispectral data for those regions mentioned above. We use the UV-VIS-derived compositional information and the spectral properties of craters, and their ejecta as drill holes through the mare-basalt surface to investigate the thickness and composition of underlying material. With this information we attempt to piece together the stratigraphy and geologic history of the Imbrium-Procellanim region. We processed the five-band multispectral data from the Clementine Mission (415, 750,900,950, and 1000nm) using ISIS software and calibration parameters developed by the USGS, Flagstaff, Arizona. Final image mosaics are in equal-area sinusoidal projection, and have a resolution of 250 m/pixel. Using the method of we produced maps of FeO and Ti02 composition. Here we examine the Th, FeO, and Ti02 composition and spectral properties of the craters discussed above and their ejecta, with the goal of describing the materials they excavate. One interpretation for the origin of the high-Th material is that subsurface KREEPy materials have been excavated by impact craters. The material excavated may be either volcanic KREEP (e,g., Apennine Bench Formation), KREEPy impact-melt breccia formed by the Imbrium impact (e.g., Fra Mauro Formation), or other KREEP-rich crustal material. Determining which type of material is responsible for the elevated Th and its extent is important to understanding the premare and possibly the prebasin stratigraphy of the Imbrium-Procellarum Region. Merging the 5 deg. Th data with the shaded relief map, we observe that the highest Th concentrations are not related to pre-Imbrium upper crustal materials. The Apennines, Alpes, and Caucasus Mountains represent the pre-Imbrian highlands material and do not express concentrations of Th, FeO, and TiO2 as high as the most Th-fich materials exposed within the Procellarum KREEP Terrane. We observe that, in general, these massifs contain 10-14 wt% FeO and 4-7 ppm Th. Determining whether the Th signal is from KREEP basalts or KREEPy impact-melt breccias cannot be done with the Clementine data because the two rock types are compositionally and mineralogically too similar (e.g., the Th-rich, mafic impact-melt breccias in the Apollo sample collection are dominated by a KREEP-basalt like component. Mapping-the distribution and sizes of craters and whether they display elevated Th concentrations or not, should reveal the depth and thickness of the KREEP-rich materials, and whether they are ubiquitous (i.e., impact-melt breccia) or more randomly distributed; this might be taken as an indicator of localized KREEP-basalt flows. Within the southeastern region of the Imbrium basin, there are two Th hot spots. The first is associated with the crater Aristillus, and the latter with the Apennine Bench Formation. Adjacent to these two hot spots are craters with a lower Th signature: Archimedes and Autolycus. We observe in the ejecta of Aristillus, a region of significantly lower FeO (10-14 wt%) relative to the surrounding mare basalt. The crater Autolycus, 50 km to the south, did not excavate similar low-FeO material. We suggest that the lower-FeO material in the ejecta of Aristillus corresponds to Th-rich material; the FeO content observed in Aristillus ejecta is comparable to that of KREEP basalt or mafic impact melt breccia (10-12 wt% FeO). We determine that this low FeO, Th-rich material is volcanic KREEP, as opposed to Imbrium impact melt, on the basis that the low-Fe material is exposed more prominently in ejecta in the northern portion of Aristillus. Our assumption is that if the layer underlying Aristillus was continuous, a more widespread and uniform low-Fe signature wouldbe observed in the ejecta deposit. Archimedes, 110 km southwest of Aristillus, impacted the northern portion of the Apennine Bench prior to the eruption of KREEP basalt. Archimedes rim material is not as enriched in Th as the Apennine Bench, and there are differences between the two in FeO concentration and in their continuum slope. Archimedes exhibits a much steeperor "redder" continuum slope than the Apennine Bench. This steepslope suggests the presence of glassy material. The glassy material is concentrated around an unnamed crater on the southern rim of Archimedes (4.5W, 28.2N) and along the northern rim of Archimedes. We suggest two possibilities, or a combination of the two, to explain the low-Th signal from Archimedes: (1) The Apennine Bench prior to KREEP basalt eruption was lower in Th (4-7 ppm, e.g., similar to the Apennine massifs) and KREEP basalts are absent in the rim of Archimedes; or (2) the glassy (possibly pyroclastic) material layering the rim of the Archimedes, dilutes any high-Th material present with low-Th material. (Additional information is contained in the original)

Gillis, J. J.↗
NASA NTRS2011

Downhole Elemental Analysis with LIBS

In this paper we discuss a novel instrument, currently under development at Honeybee Robotics with SBIR funding from NASA. The device is designed to characterize elemental composition as a function of depth in non-terrestrial geological formations. The instrument consists of a miniaturized laser-induced breakdown spectrometer (LIBS) analyzer integrated in a 2" diameter drill string. While the drill provides subsurface access, the LIBS analyzer provides information on the elemental composition of the borehole wall. This instrument has a variety of space applications ranging from exploration of the Moon for which it was originally designed, to Mars, as well as a variety of terrestrial applications. Subsurface analysis is usually performed by sample acquisition through a drill or excavator, followed by sample preparation and subsequent sample presentation to an instrument or suite of instruments. An alternative approach consisting in bringing a miniaturized version of the instrument to the sample has many advantages over the traditional methodology, as it allows faster response, reduced probability of cross-contamination and a simplification in the sampling mechanisms. LIBS functions by focusing a high energy laser on a material inducing a plasma consisting of a small fraction of the material under analysis. Optical emission from the plasma, analyzed by a spectrometer, can be used to determine elemental composition. A triangulation sensor located in the sensor head determines the distance of the sensor from the borehole wall. An actuator modifies the position of the sensor accordingly, in order to compensate for changes due to the profile of the borehole walls. This is necessary because LIBS measurements are negatively affected by changes in the relative position of the focus of the laser with respect to the position of the sample (commonly referred to as the "lens to sample distance"). Profiling the borehole is done by adjusting the position of the sensor with a vertical stage; a second actuator at the top of the downhole probe allows radial scanning of the borehole. Analysis of iron and titanium in lunar simulant with LIBS was performed in air using the method of standard addition. The results for lunar simulant NU-LHT-2M show a value for the concentration of iron ranging between 2.29% and 3.05% depending on the atomic line selected. The accepted value for the sample analyzed is 2.83%, showing the capability for the system in development to provide qualitative and semi-quantitative analysis in real-time.

Moreschini, Paolo↗
NASA NTRS1992

Asteroids and Archaean crustal evolution: Tests of possible genetic links between major mantle/crust melting events and clustered extraterrestrial bombardments

Since the oldest intact terrestrial rocks of ca. 4.0 Ga and oldest zircon xenocrysts of ca. 4.3 Ga measured to date overlap with the lunar late heavy bombardment, the early Precambrian record requires close reexamination vis a vis the effects of megaimpacts. The identification of microtektite-bearing horizons containing spinals of chondritic chemistry and Ir anomalies in 3.5-3.4-Ga greenstone belts provides the first direct evidence for large-scale Archaean impacts. The Archaean crustal record contains evidence for several major greenstone-granite-forming episodes where deep upwelling and adiabatic fusion of the mantle was accompanied by contemporaneous crustal anatexis. Isotopic age studies suggest evidence for principal age clusters about 3.5, 3.0, and 2.7 (+/- 0.8) Ga, relics of a ca. 3.8-Ga event, and several less well defined episodes. These peak events were accompanied and followed by protracted thermal fluctuations in intracrustal high-grade metamorphic zones. Interpretations of these events in terms of internal dynamics of the Earth are difficult to reconcile with the thermal behavior of silicate rheologies in a continuously convecting mantle regime. A triggering of these episodes by mantle rebound response to intermittent extraterrestrial asteroid impacts is supported by (1) identification of major Archaean impacts from microtektite and distal ejecta horizons marked by Ir anomalies; (2) geochemical and experimental evidence for mantle upwelling, possibly from levels as deep as the transition zone; and (3) catastrophic adiabatic melting required to generate peridotitic komatites. Episodic differentiation/accretion growth of sial consequent on these events is capable of resolving the volume problem that arises from comparisons between modern continental crust and the estimated sial produced by continuous two-stage mantle melting processes. The volume problem is exacerbated by projected high accretion rates under Archaean geotherms. It is suggested that impact shock effects have been largely obscured by (1) outpouring of voluminous basic/ultrabasic lavas, inundating shock-deformed crust and extending beyond the perimeters of impact excavated basins; (2) gravity subsidence and downfaulting of terrestrial maria, accounting for the burial and anatexis of subgreenstone basement; and (3) extensive shearing and recrystallization at elevated temperatures of impact structure, breccias, and mineral deformation features beneath impact-excavated basins, relics of which may be retained in structural windows in high-grade metamorphic terranes.

Glikson, A. Y.↗