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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Microstructure and Mechanical Properties of Multilayer α-AlN/α-BCN Coating as Functions of the Current Density during Sputtering of a B{sub 4}C Target

Multilayer AlN/BCN coating of nanometer scale have been prepared by magnetron sputtering of Al and B{sub 4}C targets in an argon–nitrogen atmosphere during deposition on a Si substrate. These coating have an X-ray amorphous structure and the maximum Knoop hardness of 27 GPa (at the current density 100 mA). The first-principle molecular dynamics calculations show that the B4–BN layer is dynamically unstable; thus, it will not be epitaxial and will be amorphous or have a structure different from the B4–BN structure. The thermal vacuum annealing from 600 to 800°C of samples with multilayer nanosized coating leads to the decrease in the Knoop hardness to 18 GPa; however, the coating structure is retained X-ray amorphous.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

The Element Composition Variation in Lead Zirconate Titanate upon the Ion-Plasma Deposition: Experiment and Simulation

The element composition modification is experimentally studied in PZT thin films obtained via the RF magnetron sputtering with variable working gas pressure. The experimental data were interpreted through the statistic simulation of thermalization and diffusion of sprayed Pb, Zr, and Ti atoms during the ion-plasma deposition of PZT thin films. The simulation data are shown to adequately describe (within the limits of 5%) the change in element composition at various pressures of the gas environment. The study conducted enables one to produce PZT thin films with a set element composition, which is essential for optimizing the electric and physical properties of solid solutions at the morphotropic phase boundary.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Photoluminescence of Cu{sub 2}O Crystals of Different Origins

Low-temperature luminescence spectra of Cu{sub 2}O crystals grown by different methods (copper oxidation, induction charge melting, magnetron sputtering, and hydrothermal), as well as natural crystals, have been compared. It is suggested that the high quality of natural crystals and crystals grown by the hydrothermal method is due to the fact that they grow for a long time at relatively low temperatures, which facilitates the minimization of stress.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Influence of Silver and Gold Nanoparticles and Thin Layers on Charge Carrier Generation in InGaN/GaN Multiple Quantum Well Structures and Crystalline Zinc Oxide Films

It has been shown that Ag and Au nanoparticles and thin layers influence charge carrier generation in InGaN/GaN multiple quantum well structures and crystalline ZnO films owing to the surface morphology heterogeneity of the semiconductors. When nanoparticles 10 < d < 20 nm in size are applied on InGaN/GaN multiple quantum well structures with surface morphology less nonuniform than that of ZnO films, the radiation intensity has turned out to grow considerably because of a plasmon resonance with the participation of localized plasmons. The application of Ag or Au layers on the surface of the structures strongly attenuates the radiation. When Ag and Au nanoparticles are applied on crystalline ZnO films obtained by rf magnetron sputtering, the radiation intensity in the short-wavelength part of the spectrum increases insignificantly because of their highly heterogeneous surface morphology.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2018

Condensation Surface Temperature as a Means for Studying Film Formation Mechanisms

A rise in the condensation surface temperature during film growth is a result of energy dissipation on the condensation surface. An example of energy dissipation is the dissipation of chemical reaction heat, which releases during film deposition by reactive magnetron sputtering. The monitoring of the surface temperature during TiN film deposition by reactive (Ti–in–N{sub 2}) and nonreactive (TiN–in–Ar or TiN–in–N{sub 2}) sputtering methods has shown that this temperature is higher in the reactive case and decreases in the (TiN–in–Ar)–(TiN–in–N{sub 2}) sequence of nonreactive sputtering modifications. It has been found that the composition and crystal structure of TiN films do not depend on the growth method and are identical to those of bulk titanium nitride. Based on these results, a formation mechanism of films obtained by the above methods has been suggested. In the case of reactive sputtering, the film was supposed to grow on the condensation surface through a reaction between titanium and nitrogen atoms. In the cases of nonreactive sputtering, the film forms from TiN molecules.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Manufacturing of Sputtering Composite Targets Containing Phases of Co{sub 2}FeSi or Co{sub 2}MnSi Heusler Alloy

The paper presents a method for manufacturing mechanically strong sputtering composite targets containing the phase of the Co{sub 2}FeSi or Co{sub 2}MnSi Heusler alloy of the stoichiometric composition, which can be used for fabrication of spin electronic devices by high-frequency magnetron deposition and pulsed laser deposition of thin films.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Composition, Structure, and Mechanical Properties of (Ti–Hf)N Coatings on Titanium Alloy

Variations of the composition, structure, and mechanical properties (hardness, elastic modulus) of (Ti–Hf)N coatings with increasing Hf content (Ti : Hf ratio) are reported. As test samples, VT6 titanium alloy plates covered by a magnetron-sputtered titanium hafnium nitride coating have been taken. To see how the coating characteristics depend on Hf content, samples with rated compositions (Ti{sub 0.9}Hf{sub 0.1})N, (Ti{sub 0.85}Hf{sub 0.15})N, (Ti{sub 0.8}Hf{sub 0.2})N, and (Ti{sub 0.7}Hf{sub 0.3})N have been studied. The surface and depth element distributions have been found, and the phase composition and the dependence of the titanium nitride lattice parameter on Hf content in the coating have been determined. The depth profiling of a coating’s hardness and elastic modulus has been conducted by instrumental indentation. Hardness and elastic modulus have been found to be maximal (~35 and ~500 GPa, respectively) in (Ti{sub 0.85}Hf{sub 0.15})N and (Ti{sub 0.8}Hf{sub 0.2})N coatings. In addition, the depth distribution of Hf in these coatings has turned out to be most uniform.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Optical, Mechanical, and Thermal Properties of Free-Standing MoSi{sub 2}N{sub x} and ZrSi{sub 2}N{sub y} Nanocomposite Films

The optical, mechanical, and thermal properties of free-standing structures based on nitrided molybdenum and zirconium silicides have been studied. It has been shown that silicide nitriding considerably improves the thermal stability of films. While as-prepared amorphous MoSi{sub 2} and ZrSi{sub 2} films crystallize in the interval 330–370°C, nitriding of films has made it possible to increase their working temperatures in vacuum to 600–700°C (at least, for x ≥ 0.25, y ≥ 1.3). Tensile tests have shown that the ultimate strength of MoSi{sub 2}N{sub x} films (0 ≤ x ≤ 0.55) depends on nitrogen content only slightly. Comparison between the properties of MoSi{sub 2}N{sub x} and ZrSi{sub 2}N{sub y} films magnetron-sputtered at the same partial pressure of nitrogen has demonstrated that with transmission coefficients of films at a wavelength of 13.5 nm being close to each other, ZrSi{sub 2} films are more effective as protection coatings (they are less prone to oxidation and more degradation-resistant).

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2017

UV-assisted growth of transparent conducting layers based on zinc oxide

A comparative study of the microstructure and optical and electrical characteristics of gallium-doped ZnO films synthesized by magnetron sputtering with and without assistance to the growth process by UV radiation has been carried out. It was found that the UV assistance to the growth process of ZnO-based transparent conducting layers improves their electrical characteristics because of the formation of additional donor centers and the lower carrier scattering at grain boundaries, without any strong inf luence on the layer morphology and on the average optical transmittance in the visible spectral range.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

An Experimental Study of the Influence of an External Signal on the Generation Mode of a Megawatt-Power Gyrotron

The frequency capture of radiation by an external signal was experimentally studied for the first time for a megawatt-power gyrotron. An external signal from the magnetron at a frequency of 35 GHz entered the working space of the gyrotron through a synthesized two-mirror quasi-optical converter that allowed transforming the input signal into a working mode. This converter has been recently developed and implemented in the Institute of Applied Physics, Russian Academy of Sciences. The radiation spectra were experimentally obtained in modes of frequency capture and frequency beats. The dependence of the frequency capture bandwidth on the power of the external signal was found. Comparison of experimental results with the data of numerical modelling of gyrotron equations with an external signal showed their good agreement.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Exchange Spring in a Heterostructure with Pd{sub 0.96}Fe{sub 0.04} Low-Temperature Ferromagnet

The exchange bias of the magnetic hysteresis loop and the exchange-spring effect have been observed in thin-film heterostructures comprising layers of Pd{sub 0.96}Fe{sub 0.04} low-temperature ferromagnet, metallic cobalt, and cobalt monoxide (CoO) grown on single-crystalline sapphire by methods of magnetron sputtering and molecular beam epitaxy in an ultrahigh-vacuum system. It is established that the exchange anisotropy of Pd{sub 0.96}Fe{sub 0.04} layer in Pd{sub 0.96}Fe{sub 0.04}/CoO/Co/Al{sub 2}O{sub 3} thin-film heterostructure is absent and the exchange-spring effect in this system is not manifested. In the case of a Pd{sub 0.96}Fe{sub 0.04}/Co/CoO/Al{sub 2}O{sub 3} structure, it is shown that, according to the results of magnetometric measurements, the inversion of the order of antiferromagnetic and ferromagnetic layers leads to pinning of the magnetic moment of Pd{sub 0.96}Fe{sub 0.04} layer at the interface with cobalt and to realization of the exchange-spring effect. Additional evidence in favor of this interpretation was obtained using the micromagnetic modeling of magnetic hysteresis loops.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Structural Changes in Si–CuSi Films upon Intercalation of Lithium Ions

We studied the possibility of using composite films representing amorphous silicon reinforced with crystalline inclusions of copper silicide as an anode material for lithium-ion batteries with liquid electrolyte. The films were made by layer-by-layer magnetron sputtering of amorphous silicon and copper, followed by low-temperature (100–200°C) annealing of the structure. The tests of the anodes revealed the effect of prolonged intense growth of their reversible capacity. To describe the effect, a phenomenological model based on the multidirectional migration of silicon and copper atoms in an inhomogeneous field of elastic mechanical stresses arising during electrode cycling is proposed.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2016

TEM Study of Zircaloy 2 with FeCrAl Layer under Simulated BWR Environment

Zircaloy 2 is widely used as nuclear fuel cladding in light-water nuclear reactors, which is resistive to corrosion, creep, and swelling. Due to water chemical reactivity and high-temperature steam exposure, oxidation in zirconium cladding is possible during transients. To mitigate the zirconium oxidation and the hydrogen generation at elevated temperature, we have coated Zircaloy 2 with oxide resistant FeCrAl thin film layers using magnetron sputtering. Transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM), and electron energy-dispersive X-ray spectroscopy (EDX) are used to understand the behavior of the protective FeCrAl layer under typical BWR operation conditions. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2017

Multi-Functional Zirconium-Silicide Coatings on Zirconium-alloy for Improved Accident Tolerance

Recently, development of protective coatings on zirconium-alloy (Zr-alloy) fuel cladding in light water reactors has been extensively investigated to enhance safety margins in accident scenarios. One accident scenario is degradation of the reactor core under a coolant-limited condition, where a large amount of Zr-alloy claddings would react with high temperature steam, leading to oxidation, hydrogen production, and loss of intrinsic mechanical properties of the fuel cladding. Although, total replacement of Zr-alloy with SiC-SiCf composites or FeCrAl is being considered for the long-term, application of oxidation resistant coatings on zirconium-alloy is being investigated as a near-term solution to mitigate oxidation of Zr-alloy and increase the accident coping time. Coatings, such as chromium, Ti{sub 2}AlC, SiC, and Cr{sub 3}C{sub 2}- NiCr, deposited by various deposition techniques have been investigated. In addition, recent studies on modified heating surface for heat transfer enhancement provides basis on the optimal design of coated Zr-alloy claddings so that the new cladding can be achieve accident tolerance and heat transfer efficiency for both accident and normal operation conditions. Therefore, boiling heat transfer from the coated surface to water environment must be evaluated in parallel. In heat transfer performance, boiling heat transfer is characterized by nucleate boiling, critical heat flux (CHF), transition boiling, minimum film boiling temperature (T{sub min}), and film boiling. Zirconium-silicide (ZrSi{sub 2}) is a potentially attractive protective coating material for cladding applications. Although this material has not been studied extensively, it appears to be a promising candidate because of the high melting points, and the low neutron penalty, and the generally good oxidation resistance to transition metal silicides. It has been reported that oxidation of ZrSi{sub 2} powder in a flowing air environment at elevated temperatures produced ZrO{sub 2}, SiO{sub 2}, and ZrSiO{sub 4}, pointing to the possibility of achieving highly protective surface layers of SiO{sub 2} and ZrSiO{sub 4} that would protect the material from further oxidation. In this study, magnetron sputter deposition of ZrSi{sub 2} on zirconium-alloy flats and cylindrical rods was performed. The coated samples were oxidized in high temperature air (700 deg. C, 1000 deg. C and 1200 deg. C) to evaluate their oxidation resistance. The coated cylindrical rods were quenched in saturated water to observe transition boiling, T{sub min}, film boiling regime, while the coated flats were tested in pool boiling facility to investigate nucleation boiling and CHF.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Fast X-ray Nanotomography with Sub-10 nm Resolution as a Powerful Imaging Tool for Nanotechnology and Energy Storage Applications

In the last decade, transmission X-ray microscopes (TXMs) have come into operation in most of the synchrotrons worldwide. They have proven to be outstanding tools for non-invasive ex and in situ 3D characterization of materials at the nanoscale across varying range of scientific applications. However, their spatial resolution has not improved in many years, while newly developed functional materials and microdevices with enhanced performances exhibit nanostructures always finer. Here, optomechanical breakthroughs leading to fast 3D tomographic acquisitions (85 min) with sub-10 nm spatial resolution, narrowing the gap between X-ray and electron microscopy, are reported. These new achievements are first validated with 3D characterizations of nanolithography objects corresponding to ultrahigh-aspect-ratio hard X-ray zone plates. Then, this powerful technique is used to investigate the morphology and conformality of nanometer-thick film electrodes synthesized by atomic layer deposition and magnetron sputtering deposition methods on 3D silicon scaffolds for electrochemical energy storage applications.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Controlled Growth of Single‐Crystal Graphene Wafers on Twin‐Boundary‐Free Cu(111) Substrates

Single-crystal graphene (SCG) wafers are needed to enable mass-electronics and optoelectronics owing to their excellent properties and compatibility with silicon-based technology. Controlled synthesis of high-quality SCG wafers can be done exploiting single-crystal Cu(111) substrates as epitaxial growth substrates recently. However, current Cu(111) films prepared by magnetron sputtering on single-crystal sapphire wafers still suffer from in-plane twin boundaries, which degrade the SCG chemical vapor deposition. Here, in this study, it is shown how to eliminate twin boundaries on Cu and achieve 4 in. Cu(111) wafers with ≈95% crystallinity. The introduction of a temperature gradient on Cu films with designed texture during annealing drives abnormal grain growth across the whole Cu wafer. In-plane twin boundaries are eliminated via migration of out-of-plane grain boundaries. SCG wafers grown on the resulting single-crystal Cu(111) substrates exhibit improved crystallinity with >97% aligned graphene domains. As-synthesized SCG wafers exhibit an average carrier mobility up to 7284 cm 2 V −1 s −1 at room temperature from 103 devices and a uniform sheet resistance with only 5% deviation in 4 in. region.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Stable p-i-n FAPbBr 3 devices with improved efficiency using sputtered ZnO as electron transport layer [Stable p-i-n FAPbBr 3 devices with improved efficiency using sputtered inorganic electron transport layer]

Here, radio-frequency magnetron sputtering is demonstrated as an effective tool to deposit highly crystalline thin zinc oxide (ZnO) layer directly on perovskite absorber as an electron transport layer (ETL). As an absorber, formamidinium lead tribromide (FAPbBr 3 ) is fabricated through a modified single-step solution process using hydrogen bromide (HBr) as an additive resulting in complete surface coverage and highly crystalline material. A planar p-i-n device architecture with spin-coated poly-(3,4-ethylenedioxythiophene):poly-styrenesulfonic acid (PEDOT:PSS) as hole transport material (HTM) and sputtered ZnO as ETL results in a short circuit current density of 9.5 mA cm -2 and an open circuit potential of 1.19 V. Numerical simulations are performed to validate the underlying loss mechanisms. The use of phenyl C 60 butyric acid methyl ester (PCBM) interface layer between FAPbBr 3 and sputter-coated ZnO offers shielding from potential plasma-related interface damage. The modified interface results in a better device efficiency of 8.3% with an open circuit potential of 1.35 V. Such devices offer better stability under continuous illumination under ambient conditions in comparison with the conventional organic ETL (PCBM)-based devices.

14 SOLAR ENERGY↗