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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
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NASA NTRS1978

Sputtering of uranium

Results are presented for an experimental study of the sputtering of U-235 atoms from foil targets by hydrogen, helium, and argon ions, which was performed by observing tracks produced in mica by fission fragments following thermal-neutron-induced fission. The technique used allowed measurements of uranium sputtering yields of less than 0.0001 atom/ion as well as yields involving the removal of less than 0.01 monolayer of the uranium target surface. The results reported include measurements of the sputtering yields for 40-120-keV protons, 40-120-keV He-4(+) ions, and 40- and 80-keV Ar-40(+) ions, the mass distribution of chunks emitted during sputtering by the protons and 80-keV Ar-40(+) ions, the total chunk yield during He-4(+) sputtering, and some limited data on molecular sputtering by H2(+) and H3(+). The angular distribution of the sputtered uranium is discussed, and the yields obtained are compared with the predictions of collision cascade theory.

Gregg, R.↗
NASA NTRS1992

Viscosity of dissociating gases

Recent calculations of the viscosity of iodine suggest that existing predictions of viscosities of high-temperature (up to several thousands degrees) gases should be revised, with much more attention being paid to the atomic and molecular interactions in the gas. As the gas starts to dissociate, the frequency of atom-molecule and atom-atom interactions increases, and those collisions must be taken into account in calculations of viscosity at high temperature. In this study, the iodine is chosen as an example, and the dependence of its viscosity on the gas dissociation degree is shown. Several possible channels for I+I interaction are considered in addition to I+I2 and I2+I2 collisions, and the resulting collision integrals are averaged over all the important channels.

Kang, S. H.↗
NASA NTRS2000

The Hummingbird GC-IMS: In Situ Analysis of a Cometary Nucleus

Comets are of enormous scientific interest for many reasons. They are primitive bodies that date back to the earliest stages of solar system formation and, because of their small size and because they have been stored in the outer reaches of the solar system, their pristine nature has been preserved better than for any other class of body. They are extremely rich in highly volatile elements, many in the form of ices, and are richer in organic matter than any other known solar system body. It is strongly suspected that in addition to their content of primordial solar nebular material, they also incorporate unprocessed matter from the interstellar medium. Impacts by comets occur onto all the planets and satellites, often with major consequences (e.g., the dinosaur extinction event at the KIT boundary), or sometimes just providing a spectacular cosmic event (e.g., the collision of comet Shoemaker-Levy 9 with Jupiter). A mission to analyze a cometary nucleus must be capable of detecting and identifying over 30 molecular species among several different chemical groups. The Hummingbird Mission will rendezvous with, orbit, characterize, and make multiple descents to the nucleus of a comet. Hummingbird will employ a Gas Chromatograph - Ion Mobility Spectrometer (GC-IMS) as part-of a suite of sophisticated instruments for a comprehensive in situ elemental, molecular, and isotopic analysis of the comet.

Kojiro, Daniel R.↗
NASA NTRS2022

Sequential Star Formation in the Young SMC Region NGC 602: Insights from ALMA

NGC 602 is a young, low-metallicity star cluster in the "Wing" of the Small Magellanic Cloud. We reveal the recent evolutionary past of the cluster through analysis of high-resolution (∼0.4 pc) Atacama Large Millimeter/submillimeter Array observations of molecular gas in the associated H ii region N90. We identify 110 molecular clumps (R < 0.8 pc) traced by CO emission, and study the relationship between the clumps and associated young stellar objects (YSOs) and pre-main-sequence (PMS) stars. The clumps have high virial parameters (typical αvir = 4–11) and may retain signatures of a collision in the last ≲8 Myr between H i components of the adjacent supergiant shell SMC-SGS 1. We obtain a CO-bright-to-H2 gas conversion factor of XCO,B = (3.4 ± 0.2) × 10 20 cm−2 (K km s −1 ) −1 , and correct observed clump properties for CO-dark H 2 gas to derive a total molecular gas mass in N90 of 16,600 ± 2400 M ⊙ . We derive a recent (≲1 Myr) star formation rate of 130 ± 30 M ⊙ Myr −1 with an efficiency of 8% ± 3% assessed through comparing total YSO mass to total molecular gas mass. Very few significant radial trends exist between clump properties or PMS star ages and distance from NGC 602. We do not find evidence for a triggered star formation scenario among the youngest (≲2 Myr) stellar generations, and instead conclude that a sequential star formation process in which NGC 602 did not directly cause recent star formation in the region is likely.

Theo J O’Neill↗
NASA NTRS2022

Solar Wind Ion Sputtering of Sodium from Silicates Using Molecular Dynamics Calculations of Surface Binding Energies

For nearly 40 yr, studies of exosphere formation on airless bodies have been hindered by uncertainties in our understanding of the underlying ion collisional sputtering by the solar wind (SW). These ion impacts on airless bodies play an important role in altering their surface properties and surrounding environment. Much of the collisional sputtering data needed for exosphere studies come from binary collision approximation (BCA) sputtering models. These depend on the surface binding energy (SBE) for the atoms sputtered from the impacted material. However, the SBE is not reliably known for many materials important for planetary science, such as plagioclase feldspars and sodium pyroxenes. BCA models typically approximate the SBE using the cohesive energy for a monoelemental solid. We use molecular dynamics (MD) to provide the first accurate SBE data we are aware of for Na sputtered from the above silicate minerals, which are expected to be important for exospheric formation at Mercury and the Moon. The MD SBE values are ∼8 times larger than the Na monoelemental cohesive energy. This has a significant effect on the predicted SW ion sputtering yield and energy distribution of Na and the formation of the corresponding Na exosphere. We also find that the SBE is correlated with the coordination number of the Na atoms within the substrate and with the cohesive energy of the Na-bearing silicate. Our MD SBE results will enable more accurate BCA predictions for the SW ion sputtering contribution to the Na exosphere of Mercury and the Moon.

Lunar surface↗
NASA NTRS2020

High Angular Resolution ALMA Images of Dust and Molecules in the SN 1987A Ejecta

We present high angular resolution (∼80 mas) ALMA continuum images of the SN1987A system, together with CO J = 21, J = 65, and SiO J = 54 to J = 76 images, which clearly resolve the ejecta (dust continuum and molecules) and ring (synchrotron continuum) components. Dust in the ejecta is asymmetric and clumpy, and overall the dust fills the spatial void seen in Hα images, filling that region with material from heavier elements. The dust clumps generally fill the space where CO J = 6 5 is fainter, tentatively indicating that these dust clumps and CO are locationally and chemically linked. In these regions, carbonaceous dust grains might have formed after dissociation of CO. The dust grains would have cooled by radiation, and subsequent collisions of grains with gas would also cool the gas, suppressing the CO J = 6 5 intensity. The data show a dust peak spatially coincident with the molecular hole seen in previous ALMA CO J = 2 1 and SiO J = 5 4 images. That dust peak, combined with CO and SiO line spectra, suggests that the dust and gas could be at higher temperatures than the surrounding material, though higher density cannot be totally excluded. One of the possibilities is that a compact source provides additional heat at that location. Fits to the far-infrared–millimeter spectral energy distribution give ejecta dust temperatures of 18–23 K. We revise the ejecta dust mass to Mdust = 0.2–0.4 Mfor carbon or silicate grains, or a maximum of <0.7 Mfor a mixture of grain species, using the predicted nucleosynthesis yields as an upper limit.

Interstellar dust↗
NASA NTRS2017

The HITRAN2016 Molecular Spectroscopic Database

This paper describes the contents of the 2016 edition of the HITRAN molecular spectroscopic compilation. The new edition replaces the previous HITRAN edition of 2012 and its updates during the intervening years. The HITRAN molecular absorption compilation is composed of five major components: the traditional line-by-line spectroscopic parameters required for high-resolution radiative-transfer codes, infrared absorption cross-sections for molecules not yet amenable to representation in a line-by-line form, collision-induced absorption data, aerosol indices of refraction, and general tables such as partition sums that apply globally to the data. The new HITRAN is greatly extended in terms of accuracy, spectral coverage, additional absorption phenomena, added line-shape formalisms, and validity. Moreover, molecules, isotopologues, and perturbing gases have been added that address the issues of atmospheres beyond the Earth. Of considerable note, experimental IR cross-sections for almost 300 additional molecules important in different areas of atmospheric science have been added to the database. The compilation can be accessed through www.hitran.org. Most of the HITRAN data have now been cast into an underlying relational database structure that offers many advantages over the long-standing sequential text-based structure. The new structure empowers the user in many ways. It enables the incorporation of an extended set of fundamental parameters per transition, sophisticated line-shape formalisms, easy user-defined output formats, and very convenient searching, filtering, and plotting of data. A powerful application programming interface making use of structured query language (SQL) features for higher-level applications of HITRAN is also provided.

HITRAN↗
NASA NTRS1977

The molecular composition of dense interstellar clouds

Presented in this paper is an ab initio chemical model for dense interstellar clouds that incorporates 598 grain surface reactions, with small grains providing the reaction area. Gas-phase molecules are depleted through collisions with grains. The abundances of 372 chemical species are calculated as a function of time and are found to be of sufficient magnitude to explain most observations. Peak abundances are achieved on time scales of the order of 100,000 to 1 million years, depending on cloud density and kinetic temperature. The reaction rates for ion-molecule chemistry are approximately the same, indicating that surface and gas-phase chemistry may be coupled in certain regions. The composition of grain mantles is shown to be a function of grain radius. In certain grain-size ranges, large molecules containing two or more heavy atoms are more predominant than lighter 'ices' - H2O, NH3, and CH4. It is possible that absorption due to these large molecules in the mantle may contribute to the observed 3-micron band in astronomical spectra.

Allen, M.↗
NASA NTRS1987

Cometary MHD and chemistry

An MHD and chemical comet-coma model was developed, applying the computer program of Huebner (1985) for the detailed chemical evolution of a spherically expanding coma and the program of Schmidt and Wegman (1982) and Wegman (1987) for the MHD flow of plasma and magnetic field in a comet to the Giotto-mission data on the ion abundances measured by the HIS ion mass spectrometer. The physics and chemistry of the coma are modeled in great detail, including photoprocesses, gas-phase chemical kinetics, energy balance with a separate electron temperature, multifluid hydrodynamics with a transition to free molecular flow, fast-streaming atomic and molecular hydrogen, counter and cross streaming of the ionized species relative to the neutral species in the coma-solar wind interaction region with momentum exchange by elastic collisions, mass-loading through ion pick-up, and Lorentz forces of the advected magnetic field. The results, both inside and outside of the contact surface, are discussed and compared with the relevant HIS ion mass spectra.

Wegmann, R.↗
NASA NTRS1990

H2 line emission in three Seyfert nuclei: Evidence against UV-excitation

Line emission from vibrationally excited molecular hydrogen has been detected in a considerable number of active galactic nuclei (AGNs), including those generally believed to contain compact and luminous central engines (e.g., Seyfert nuclei) and those in which the luminosity is believed to arise from massive bursts of star formation (starburst nuclei). In most of these AGNs, only the bright 1-0 S(1) line (rest wavelength 2.12 microns) has been searched for and detected to date. Line-emitting H2 can be excited directly either by energetic collisions created by shock waves or by absorption of UV radiation. Each of these excitation mechanisms has been clearly identified in galactic and extragalactic regions. In active galactic nuclei strong sources of UV and (in some case) x rays are present. If the nuclear molecular matter is quiescent (i.e., isolated from the active nucleus and not set into motion by episodes of star formation) the H2 line emission will be dominated by fluorescence, or possibly by thermal emission due to heating by x rays (Krolik, this conference). However, it is expected or indeed observed that a significant fraction of the interstellar medium in and near these nuclei is undergoing rapid motions; either generated by the central engine or by a nuclear starburst, which are capable of producing strong shock phenomena in nearby molecular gas. Thus, a priori it is not obvious which mechanism is responsible for the H2 line emission from the nucleus of an active galaxy.

Geballe, T. R.↗
NASA NTRS1972

Molecular beams in chemistry.

The molecular-beam technique is a means for producing isolated atoms or molecules within a narrow range of speed and solid angle. The phenomena studied with molecular beams can be classified as single-particle interactions, many-particle interactions, and two particle-interactions. The results of scattering experiments fall into two categories including collisions that do not result in atomic rearrangements and collisions that do. Experimental methods are discussed, giving attention to low-energy beams, high-energy beams, and intermediate-energy beams. Examples are presented to illustrate the information that can be obtained from elastic, inelastic, and reactive scattering.

Jordan, J. E.↗
NASA NTRS1978

Collisional excitation of interstellar molecules - Linear molecules CO, CS, OCS, and HC3N

Rates for excitation of CO, CS, OCS, and HC3N by collisions with He atoms and H2 molecules are presented. These have been obtained from extensive theoretical calculations using methods of known reliability. In general, rates necessary for modeling interstellar molecular clouds with kinetic temperatures to 100 K have been included. Methods for fitting these rates in more compact form are discussed.

Green, S.↗
NASA NTRS1994

Collisional excitation of interstellar sulfur monoxide

Excitation rates among fine structure levels of sulfur monoxide in collisions with hydrogen and molecules are estimated using methods expected to provide adequate accuracy for modeling millimeter and submillimeter observations of this species in relatively warm (100-300 K) molecular clouds.

Green, Sheldon↗
NASA NTRS1979

Vibrational dependence of pressure induced spectral linewidths and line shifts - Application of the infinite order sudden scattering approximation

The infinite order sudden (IOS) approximation to molecular rotation is applied to simplify the theory of linewidths and shifts in vibration-rotation spectra. This approximation is expected to be most accurate for hard, short-range collisions and is therefore complementary to Anderson theory which is best for weak, glancing collisions. The IOS approximation predicts identical linewidths and shifts for P- and R-branch transitions with the same line number. It also predicts zero line shifts for pure rotational spectra. The dependence of linewidths and shifts on vibrational band is seen to be due mainly to variation in diagonal vibrational matrix elements of the intermolecular potential. Calculations are performed for the 0-0, 0-1, and 0-2 bands of CO perturbed by He, using a theoretical interaction potential with no semiempirical or adjustable parameters; results are in satisfactory accord with experimental data.

Green, S.↗
NASA NTRS1986

Collisional excitation of interstellar methyl cyanide

Theoretical calculations are used to determine the collisional excitation rates of methyl cyanide under interstellar molecular cloud conditions. The required Q(L,M) as a function of kinetic temperature were determined by averaging fixed energy IOS (infinite order sudden) results over appropriate Boltzmann distributions of collision energies. At a kinetic temperature of 40 K, rates within a K ladder were found to be accurate to generally better than about 30 percent.

Green, Sheldon↗
NASA NTRS1993

Molecular gas in powerful radio galaxies detected by IRAS

The present CO(J = 1 to 0) line survey of powerful radio galaxies has led to the detection of five sources in eight IRAS-determined radio galaxies. The range of the computed molecular gas masses is 1-7 times the H2 mass of the Milky Way and strikingly contrasts with the low molecular gas masses found in radio-quiet FIR-selected elliptical galaxies. These new CO observations lend support to the hypothesis that powerful radio galaxies result from disk galaxy collisions that evolve into gas-rich, peculiar E/S0 galaxies in the course of their merging.

Mazzarella, J. M.↗
NASA NTRS1977

Validity of approximate methods in molecular scattering. III - Effective potential and coupled states approximations for differential and gas kinetic cross sections

Two dimensionality-reducing approximations, the j sub z-conserving coupled states (sometimes called the centrifugal decoupling) method and the effective potential method, were applied to collision calculations of He with CO and with HCl. The coupled states method was found to be sensitive to the interpretation of the centrifugal angular momentum quantum number in the body-fixed frame, but the choice leading to the original McGuire-Kouri expression for the scattering amplitude - and to the simplest formulas - proved to be quite successful in reproducing differential and gas kinetic cross sections. The computationally cheaper effective potential method was much less accurate.

Monchick, L.↗