Ferromagnetic L1 0 -Structured CoPt Nanoparticles for Permanent Magnets and Low Pt-Based Catalysts
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We applied adaptive genetic algorithm (AGA) to search for low-energy crystal structures of Fe 3 S. A number of structures with energies lower than that of the experimentally reported Pnma and I-4 structures have been obtained from our AGA searches. These low-energy structures can be classified as layer-motif and column-motif structures. In the column-motif structures, Fe atoms self-assemble into rods with bcc type of underlying lattice, which are separated by the holes terminated by S atoms. In the layer-motif structures, the bulk Fe is broken into slabs of several layers passivated by S atoms. Magnetic properties calculations showed that the column-motif structures exhibit reasonably high uniaxial magnetic anisotropy. In addition, we examined the effect of Co doping to Fe 3 S and found magnetic anisotropy can be enhanced through Co doping.
Structural and magnetic properties of iron-free and iron-substituted SmCo 5 have been investigated theoretically and experimentally. The nanocrystalline ribbons of SmCo 5–x Fe x (0 ≤ x ≤ 2), which were produced by rapid solidification, crystallize in the hexagonal CaCu5 structure for x ≤ 0.75. Small Fe additions (x = 0.25) substantially improve the coercivity, from 0.45 to 2.70 T, which we interpret as combined intrinsic and extrinsic effect. Most of our findings are consistent with past samarium-cobalt research, but some are at odds with findings that have seemingly been well established through decades of rare-earth transition-metal research. In particular, our local spin-density approximation with Hubbard parameter calculations indicate that the electronic structure of the Sm atoms violates Hund's rules and that the orbital moment is strongly quenched. Possible reasons for the apparent disagreement between theory and experiment are discussed. Here, we explicitly determine the dependence of the Sm 4$f$ charge distribution, arguing that an accurate density-functional description of SmCo 5 is a challenge to future research.
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A new methodology for adaptive sliding mode control (ASMC) has been widely used to improve the control performance in various systems. This method exhibits several advantages, including low sliding mode control (SMC) chattering, no knowledge of the system disturbance bound, and no overestimation of the control gain. Despite its advantages, this method can be hampered by the spike phenomenon, slow control gain convergence, and difficulty in achieving optimal performance under varying disturbances. Consequently, this article proposes a spike-free ASMC method with a disturbance observer (DOB) to address these problems. Previous ASMC methods have been analyzed via simulations to verify the aforementioned problems. Here, this analysis highlights the need for disturbance compensation and improvements in the SMC gain adaptation law. Therefore, a DOB is designed to mitigate the spike phenomenon by compensating for disturbances. Subsequently, an SMC gain adaptation law based on disturbance error estimation is designed to eliminate the spike phenomenon completely. The proposed adaptation law makes the SMC gain to converge to a slightly higher value than the disturbance estimation error. Consequently, the proposed method not only eliminates the spike phenomenon, but also ensures optimal performance under varying disturbances. The performance of the proposed method is experimen tally validated through a comparative study.
This paper derives here the closed form 3-D analytical torque equations for an ideal radial Halbach rotor magnetic coupling. The performance of the radial Halbach coupling is then compared with an ideal axial Halbach rotor coupling. The closed form equations and comparison gives insight into the upper torque density limits of Nd-Fe-B based magnetic devices.
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