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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

The relationship between interannual and long-term cloud feedbacks

The analyses of Coupled Model Intercomparison Project phase 5 simulations suggest that climate models with more positive cloud feedback in response to interannual climate fluctuations also have more positive cloud feedback in response to long-term global warming. Ensemble mean vertical profiles of cloud change in response to interannual and long-term surface warming are similar, and the ensemble mean cloud feedback is positive on both timescales. However, the average long-term cloud feedback is smaller than the interannual cloud feedback, likely due to differences in surface warming pattern on the two timescales. Low cloud cover (LCC) change in response to interannual and long-term global surface warming is found to be well correlated across models and explains over half of the covariance between interannual and long-term cloud feedback. In conclusion, the intermodel correlation of LCC across timescales likely results from model-specific sensitivities of LCC to sea surface warming.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Fuel cell electrodes

A process includes patterning a surface of a platinum group metal-based electrode by contacting the electrode with an adsorbate to form a patterned platinum group metal-based electrode including platinum group metal sites blocked with adsorbate molecules and platinum group metal sites which are not blocked.

30 DIRECT ENERGY CONVERSION↗
NASA NTRS1991

Io's volcanic and sublimation atmospheres

Fully 3D axisymmetric gasdynamic equations simulating SO2 and H2S frost sublimation and SO2 dayside and nightside volcanic atmospheres on Io are numerically solved, using a time-explicit finite-volume formulation. Both the sublimation and volcanic atmospheres generate horizontal supersonic winds away from the subsolar point or the volcanic vent. While the sublimation atmosphere is primarily driven by horizontal pressure gradients determined by surface temperatures, the volcanic atmosphere is driven by pressure gradients that are determined by the source rate. Sublimation and condensation produce patterns of surface deposits which are characteristic of the two types of atmospheres. The volcanic model is quantitatively consistent with Voyager observations of ring deposits.

Moreno, Miguel A.↗
DOE OSTI2015

Precise, reproducible nano-domain engineering in lithium niobate crystals

We present a technique for domain engineering the surface of lithium niobate crystals with features as small as 100 nm. A film of chromium (Cr) is deposited on the lithium niobate surface and patterned using electron beam lithography and lift-off and then irradiated with a wide diameter beam of intense visible laser light. The regions patterned with chromium are domain inverted while the uncoated regions are not affected by the irradiation. With the ability to realize nanoscale surface domains, this technique could offer an avenue for fabrication of nano-photonic and phononic devices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2014

Far-infrared surface emissivity and climate

Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate model projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m⁻² difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m⁻², and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.

58 GEOSCIENCES↗
DOE OSTI2015

Accessing a growth window for SrVO{sub 3} thin films

Stoichiometric SrVO{sub 3} thin films were grown over a range of cation fluxes on (001) (La{sub 0.3}Sr{sub 0.7})(Al{sub 0.65}Ta{sub 0.35})O{sub 3} substrates using hybrid molecular beam epitaxy, where a thermal effusion cell was employed to generate a Sr flux and V was supplied using the metal-organic precursor vanadium oxytriisopropoxide (VTIP). By systematically varying the VTIP flux while keeping the Sr flux constant, a range of flux ratios were discovered in which the structural and electronic properties of the SrVO{sub 3} films remained unaltered. The intrinsic film lattice parameter and residual resistivity were found to be the smallest inside the growth window, indicating the lowest defect concentration of the films, and rapidly increased for cation flux ratios deviating from ideal growth condition. Reflection high-energy electron diffraction showed that films grown within this range had smooth surfaces and diffraction patterns were free of additional spots, while otherwise the growing surface was rough and contained additional crystalline phases. Results show the existence of a SrVO{sub 3} growth window at sufficiently high growth temperature, in which high-quality, stoichiometric films can be grown in a robust, highly reproducible manner that is invulnerable to unintentional flux variation.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Unhinging the Surfaces of Higher-Order Topological Insulators and Superconductors

Here, we show that the chiral Dirac and Majorana hinge modes in three-dimensional higher-order topological insulators (HOTIs) and superconductors (HOTSCs) can be gapped while preserving the protecting C$_{2n}\mathcal{T}$ symmetry upon the introduction of non-Abelian surface topological order. In both cases, the topological order on a single side surface breaks time-reversal symmetry, but appears with its time-reversal conjugate on alternating sides in a C$_{2n}\mathcal{T}$ preserving pattern. In the absence of the HOTI/HOTSC bulk, such a pattern necessarily involves gapless chiral modes on hinges between C$_{2n}\mathcal{T}$-conjugate domains. However, using a combination of K -matrix and anyon condensation arguments, we show that on the boundary of a 3D HOTI/HOTSC these topological orders are fully gapped and hence “anomalous.” Our results suggest that new patterns of surface and hinge states can be engineered by selectively introducing topological order only on specific surfaces.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Soil bacterial and fungal community responses to nitrogen addition across soil depth and microhabitat in an arid shrubland

Arid shrublands are stressful environments, typified by alkaline soils low in organic matter, with biologically-limiting extremes in water availability, temperature, and UV radiation. The widely-spaced plants and interspace biological soil crusts in these regions provide soil nutrients in a localized fashion, creating a mosaic pattern of plant- or crust-associated microhabitats with distinct nutrient composition. With sporadic and limited rainfall, nutrients are primarily retained in the shallow surface soil, patterning biological activity. We examined soil bacterial and fungal community responses to simulated nitrogen (N) deposition in an arid Larrea tridentata-Ambrosia dumosa field experiment in southern Nevada, USA, using high-throughput sequencing of ribosomal RNA genes. To examine potential interactions among the N application, microhabitat and soil depth, we sampled soils associated with shrub canopies and interspace biological crusts at two soil depths (0–0.5 or 0–10 cm) across the N-amendment gradient (0, 7, and 15 kg ha –1 yr –1 ). We hypothesized that localized compositional differences in soil microbiota would constrain the impacts of N addition to a microhabitat distribution that would reflect highly localized geochemical conditions and microbial community composition. The richness and community composition of both bacterial and fungal communities differed significantly by microhabitat and with soil depth in each microhabitat. Only bacterial communities exhibited significant responses to the N addition. Community composition correlated with microhabitat and depth differences in soil geochemical features. Provided the distinct roles of soil bacteria and fungi in major nutrient cycles, the resilience of fungi and sensitivity of bacteria to N amendments suggests that increased N input predicted for many arid ecosystems could shift nutrient cycling toward pathways driven primarily by fungal communities.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2016

Observed Trend in Surface Wind Speed Over the Conterminous USA and CMIP5 Simulations

There has been no spatial surface wind map even over the conterminous USA due to the difficulty of spatial interpolation of wind field. As a result, the reanalysis data were often used to analyze the statistics of spatial pattern in surface wind speed. Unfortunately, no consistent trend in wind field was found among the available reanalysis data, and that obstructed the further analysis or projection of spatial pattern of wind speed. In this study, we developed the methodology to interpolate the observed wind speed data at weather stations using random forest algorithm. We produced the 1-km daily climate variables over the conterminous USA from 1979 to 2015. The validation using Ameriflux daily data showed that R2 is 0.59. Existing studies have found the negative trend over the Eastern US, and our study also showed same results. However, our new datasets also revealed the significant increasing trend over the southwest US especially from April to June. The trend in the southwestern US represented change or seasonal shift in North American Monsoon. Global analysis of CMIP5 data projected the decrease trend in mid-latitude, while increase trend in tropical region over the land. Most likely because of the low resolution in GCM, CMIP5 data failed to simulate the increase trend in the southwest US, even though it was qualitatively predicted that pole ward shift of anticyclone help the North American Monsoon.

simulations↗
NASA NTRS1977

Surface micro-discharges on spacecraft dielectrics

Extensive measurements on Teflon and Kapton in a scanning electron microscope indicate the existence of a well-defined family of surface micro-discharges characteristic of the dielectric material. For a given small region exposed to the 16-20 kV electron beam, the strongest discharge pulses are similar in shape and amplitude. For Teflon, typical pulse durations are 2-3 ns, rise and fall times are sometimes as low as 0.2 ns, current amplitudes are approximately 100 mA flowing down to the pedestal and the pulses are unidirectional with no ringing. The use of a rapid-scan electron microscope with a secondary-electron imaging system reveals complex charge distributions resembling Lichtenberg figures on a supposedly flat homogeneous dielectric surface. These patterns undergo extensive alteration at each micro-discharge pulse and indicate that both the charging and discharging processes are highly nonuniform over the dielectric surface. The use of floodbeam causes the occurrence of a large-scale macro-discharges, in which a typical peak current is 40 A with a duration of 120 ns.

Balmain, K. G.↗
NASA NTRS1985

Bidirectional Reflectance Modeling of Non-homogeneous Plant Canopies

The objective of this research is to develop a 3-dimensional radiative transfer model for predicting the bidirectional reflectance distribution function (BRDF) for heterogeneous vegetation canopies. The model (named BIGAR) considers the angular distribution of leaves, leaf area index, the location and size of individual subcanopies such as widely spaced rows or trees, spectral and directional properties of leaves, multiple scattering, solar position and sky condition, and characteristics of the soil. The model relates canopy biophysical attributes to down-looking radiation measurements for nadir and off-nadir viewing angles. Therefore, inversion of this model, which is difficult but practical should provide surface biophysical pattern; a fundamental goal of remote sensing. Such a model also will help to evaluate atmospheric limitations to satellite remote sensing by providing a good surface boundary condition for many different kinds of canopies. Furthermore, this model can relate estimates of nadir reflectance, which is approximated by most satellites, to hemispherical reflectance, which is necessary in the energy budget of vegetated surfaces.

Norman, J. M.↗
NASA NTRS1989

Statistical geometry of a small surface patch in a developed sea

The fractal and marginal fractal regimes in surface geometry are studied. The basic notions of fractal geometry are applied to a small surface patch in a developed sea, corresponding to the equilibrium wave number spectrum. Topothesy, outer and inner boundaries of the fractal range, and a cascade pattern in surface geometry are discussed. Theoretical predictions of whitecap and foam coverage are presented. A fractal decomposition for a surface patch is developed based on the Karhunen-Loeve expansion. The resulting series formalizes the cascade process of constructing realization of a Gaussian random patch. The implications of the research for microwave remote sensing signatures are considered.

Glazman, Roman E.↗
NASA NTRS1981

Evaluation of HCMM satellite data for estuarine tidal circulation patterns and thermal inertia soil moisture measurements

Digital thermal maps of the Cooper River (SC) and the Potomac River estuaries were prepared from heat capacity mapping radiometer (HCMR) tapes. Tidal phases were correctly interpreted and verified. Synoptic surface circulation patterns were charted by location thermal fronts and water mass boundaries within the estuaries. Thermal anomalies were detected adjacent of a conventional power plant on the Potomac. Under optimum conditions, estuaries as small as the Cooper River can be monitored for generalized thermal/tidal circulation patterns by the HCMM-type IR sensors. The HCMM thermal inertia approach to estimating soil moisture at the Luverne (MN) test site was found to be unsatisfactory as a NESS operational satellite technique because of cloud cover interference. Thermal-IR data show similar structure of the Baltimore and Washington heat islands when compared to NOAA AVHRR thermal-IR data. Thermal anomalies from the warm water discharge water of a nuclear power plant were mapped in Lake Anna, Virginia.

Wiesnet, D. R.↗
DOE OSTI2015

Using Scanning-Probe Block Copolymer Lithography and Electron Microscopy To Track Shape Evolution in Multimetallic Nanoclusters

Here we describe a general method for synthesizing multimetallic core–shell nanoclusters on surfaces. By patterning seeds at predesignated locations using scanning-probe block copolymer lithography, we can track shape evolution in nanoclusters and elucidate their growth pathways using electron microscopy. The growth of core–shell nanostructures on surface-bound seeds is a highly anisotropic process and often results in multimetallic anisotropic nanostructures. Lastly, the shell grows at specific edge and corner sites of the patterned seeds and propagates predominately from the top hemisphere of the seeds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Effects of surface vacancy-adatom pair formation on PFC tungsten surface morphological response

Abstract We report a simulation study of the effect of He-irradiation-induced surface vacancy-adatom pair formation on the surface morphological evolution of plasma-facing component (PFC) tungsten and examine a number of factors that impact such evolution. Our analysis is based on self-consistent dynamical simulations according to an atomistically-informed, continuum-scale surface evolution model that has been developed following a hierarchical multiscale modeling strategy and can access the spatiotemporal scales of relevance to fuzz formation. The model accounts for the flux of surface adatoms generated as a result of the surface vacancy-adatom pair formation effect upon He implantation, which contributes to the anisotropic growth of surface nanostructural features due to the different rates of adatom diffusion along and across step edges of islands on the tungsten surface. We have carried out atomic-scale computations of optimal diffusion pathways along and across island step edges on the W(110) surface and calculated Ehrlich–Schwoebel (ES) barriers in adatom diffusion along and across such step edges. This aspect of surface adatom diffusion contributes to anisotropic surface atomic fluxes, terrace and step diffusive currents, and has been incorporated into our PFC surface evolution model, which predicts the formation of preferentially aligned nanoridge stripe patterns on the PFC surface. We establish that these anisotropic diffusive currents accelerate nanotendril growth on the PFC surface and the onset of surface nanostructure pattern formation. We also explore systematically the dependence of the PFC surface morphological response on the surface temperature and He ion incident flux, characterize in detail the resulting surface topographies and growth kinetics, and compare the predicted surface morphologies with experimental observations. Our simulation predictions for the emerging surface nanostructure patterns under certain plasma exposure conditions are consistent with experimental findings in the literature.

36 MATERIALS SCIENCE↗
NASA NTRSDate not supplied

Progress Toward Evaluating Roughness-Resolved Aerothermodynamic Simulations for the Mars Sample Return Earth Entry System

This work pursues the efficient Navier-Stokes simulation, using NASA’s standard LAURA and DPLR simulation tools, of the flowfield and convective heating resulting from the patterned-roughness surface of the Mars Sample Return (MSR) Earth Entry System (EES). This type of simulation has been infeasible for past NASA missions. However, for EES, the combination of a patterned roughness heatshield approximated with a sinusoidal pattern, the zero degrees angle of attack nominal flow, and the supersonic boundary layer edge Mach number, all combine to make these roughness resolved grid simulations feasible. The patterned roughness and zero degrees angle of attack nominal flow allow the simulation domain to be reduced to a thin axial flowfield slice that captures a minimum of single period of the roughness pattern. With a periodic boundary condition applied along the boundaries of this slice, simulation on the reduced domain is identical to the full domain but with significant cost saving. The supersonic boundary layer edge Mach number prevents the upstream influence, which allows the smooth stagnation region to be frozen. This freezing of the stagnation region flow is required because of the numerical instability resulting from the tight spacing of the grid in the axial direction as the stagnation point is approached. Applying the developed analysis approach to a peak heating EES case results in a roughness augmentation factor for the convective heating of 1.32, which agrees well with correlations that predict values between 1.30 and 1.37. Analysis approach developed in this work provides the framework for future studies of turbulence modeling impacts and the influence of an ablating surface.

Earth Entry System↗
NASA NTRS1961

Interaction of Highly Underexpanded Jets with Simulated Lunar Surfaces

Pressure distributions and erosion patterns on simulated lunar surfaces (hard and soft) and interference effects between the surface and two representative lunar vehicles (cylindrical and spherical) were obtained with cold-air jets at various descent heights and nozzle total-pressure ratios up to 288,000. Surface pressure distributions were dependent on both nozzle area ratio and, nozzle contour. Peak pressures obtained with a sonic nozzle agreed closely with those predicted theoretically for a near-sonic jet expanding into a vacuum. Short bell-shaped nozzles gave annular pressure distributions; the low center pressure resulted from the coalescence of shocks that originated within the nozzle. The high surface pressures were contained within a circle whose diameter was about 16 throat diameters, regardless of nozzle area ratio or contour. The peak pressure increased rapidly as the vehicle approached the surface; for example, at a descent height of 40 throat diameters the peak pressure was 0.4 percent of the chamber pressure, but increased to 6 percent at 13 throat diameters. The exhaust jet eroded a circular concave hole in white sand at descent heights from about 200 to 600 throat diameters. The hole diameter was about 225 throat diameters, while the depth was approximately 60 throat diameters. The sand particles, which formed a conical sheet at a semivertex angle of 50 deg, appeared to follow a ballistic trajectory and at no time struck the vehicle. An increase in pressure was measured on the base of the cylindrical lunar vehicle when it approached to within 14 throat diameters of the hard, flat surface. No interference effects were noted between the spherical model and the surface to descent heights as low as 8 throat diameters.

Stitt, Leonard E.↗
NASA NTRS2010

Orbiter BLT Flight Experiment Wind Tunnel Simulations: Nearfield Flowfield Imaging and Surface Thermography

This paper reports a series of wind tunnel tests simulating the near-field behavior of the Space Shuttle Orbiter Boundary Layer Transition Detailed Test Objective (BLT DTO) flight experiment. Hypersonic flow over a flat plate with an attached BLT DTO-shaped trip was tested in a Mach 10 wind tunnel. The sharp-leading-edge flat plate was oriented at an angle of 20 degrees with respect to the freestream flow, resulting in post-shock edge Mach number of approximately 4. The flowfield was visualized using nitric oxide (NO) planar laser-induced fluorescence (PLIF). Flow visualizations were performed at 10 Hz using a wide-field of view and high-resolution NO PLIF system. A lower spatial resolution and smaller field of view NO PLIF system visualized the flow at 500 kHz, which was fast enough to resolve unsteady flow features. At the lowest Reynolds number studied, the flow was observed to be laminar and mostly steady. At the highest Reynolds number, flow visualizations showed streak instabilities generated immediately downstream of the trip. These instabilities transitioned to unsteady periodic and spatially irregular structures downstream. Quantitative surface heating imagery was obtained using the Temperature Sensitive Paint (TSP) technique. Comparisons between the PLIF flow visualizations and TSP heating measurements show a strong correlation between flow patterns and surface heating trends.

Danehy, Paul M.↗