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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
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NASA NTRS1977

Non Urban Troposphere Composition Symposium, Hollywood, Fla., November 10-12, 1976, Proceedings

Papers are presented which originate from a conference on 'The Non-Urban Troposphere Composition', held in 1976. Attention is given to distributions of nitrous oxide in the atmosphere, and to tropospheric and stratospheric compositions which are perturbed by NO(x) emissions from high-altitude aircraft. Ozone is studied in terms of in situ measurements; various meteorological analyses of tropopause folding, ozone measurements in the Boston area, and ozone measurements in rural areas are presented. A one-dimensional model used to study tropospheric photochemistry numerically is presented as are vertical profiles of tropospheric and stratospheric molecular hydrogen. The oxidation of ammonia, methane, and hydrogen sulfide is assessed in nonurban tropospheres along with nonurban measurements of ethane and methane for various atmospheric conditions. With reference to the particle size distribution of chloride in the marine aerosol, organic and inorganic chlorine concentrations are evaluated, and measurements of sea-air CO2 flux by eddy correlation are investigated.

Source record↗
NASA NTRS1978

The photochemical role of tropospheric nitrogen oxides

The role of nitrogen oxides in the tropospheric photochemical system is re-evaluated in the light of recent measurements of the rate constants for two key reactions. A model for nitrogen oxides is discussed which yields surface NO(x) (NO+NO2) levels approaching 1 ppb in NO(x) source regions but less than 0.1 ppb outside source regions. Applying the new rate coefficients implies increased radical concentrations and a more intense O3 and CO photochemistry. Even for densities of 0.1 ppb or less, NO(x) still leads to significant local O3 production and conversion of HO2 to OH. Unrealistic O3 profiles are obtained with the new rate coefficients for surface NO(x) densities of about 1 ppb, while reasonable agreement with observation is obtained with lower NO(x) densities. Feedback processes between CO, NO(x), OH, and CH4 are also discussed.

Chameides, W. L.↗
NASA NTRS1978

Carbonate formation in Marslike environments

A finely ground basaltic rock subjected to Marslike temperatures, atmospheric pressures and compositions and UV-rich illumination has provided a simulation system for studying carbonate growth in the Martian regolith. Growth rates of about 10 to the 12th or 13th power molecules per cu cm per sec are observed with or without the presence of liquid-phase water. The role of UV illumination in the photochemistry of water, a process which influences chemical alteration activity, is discussed. The study suggests that carbonate formation is an important aspect of Martian chemical weathering and that it provides a major chemical reservoir for outgassed carbon dioxide.

Booth, M. C.↗
NASA NTRS1978

Organic chemistry on Titan

Observations of nonequilibrium phenomena on the Saturn satellite Titan indicate the occurrence of organic chemical evolution. Greenhouse and thermal inversion models of Titan's atmosphere provide environmental constraints within which various pathways for organic chemical synthesis are assessed. Experimental results and theoretical modeling studies suggest that the organic chemistry of the satellite may be dominated by two atmospheric processes: energetic-particle bombardment and photochemistry. Reactions initiated in various levels of the atmosphere by cosmic ray, Saturn wind, and solar wind particle bombardment of a CH4 - N2 atmospheric mixture can account for the C2-hydrocarbons, the UV-visible-absorbing stratospheric haze, and the reddish color of the satellite. Photochemical reactions of CH4 can also account for the presence of C2-hydrocarbons. In the lower Titan atmosphere, photochemical processes will be important if surface temperatures are sufficiently high for gaseous NH3 to exist. Hot H-atom reactions initiated by photo-dissociation of NH3 can couple the chemical reactions of NH3 and CH4 and produce organic matter.

Chang, S.↗
NASA NTRS1978

Aeronomy of Saturn and Titan

The Saturn system presents exciting and unique objects for planetary aeronomy. The photochemistry of H2 and He leads to the formation of an ionosphere. Methane photolysis results in the formation of spectroscopically detectable amounts of C2H6 and C2H2 and in the case of Titan, C2H4. Density profiles of C2H6, C2H2, and PH3 should be indicative of the strength of atmospheric mixing processes.

Strobel, D. F.↗
NASA NTRS1978

STRATCOM 8 Data Workshop and supplement

The STRATCOM-8 effort took place at Holloman Air Force Base and White Sands Missile Range, New Mexico, on September 28-30, 1977. The prime emphasis was on the study of stratospheric photochemistry involving ozone, with secondary objectives including a study of the balloon environment, comparison of independent techniques for the measurement of O3 and NO, and the development of new sensor systems. More than forty sensors were included on the two large balloons, a U-2 aircraft, and several rockets and small balloons, in addition to meteorological balloons and rockets. Most of the systems performed as expected.

Reed, E. L.↗
NASA NTRS1979

An investigation and analysis of the density and thermal balance of the Martian ionosphere

The major photochemistry consisted of solar EUV and photoelectrons comprising 70 percent and 30 percent respectively, of the initial source of CO2(+) and O(+). The energetic O2(+) provided a substantial source of energy to the ambient ions, distributing of the order of 1.6 x 10 to the -7 power W/sq m at an average of 160 km. This input can be compared to that from the ambient electrons of 1.3 x 10 to the -7 power W/sq m with average deposition at 145 km and from the calculated thermal conduction of 1 x 10 to the -9 power W/sq m at 270 km and 1 x 10 to the -8 power at 230 km for assumed dip angles of 2 deg and 12 deg respectively, for a 10nT magnetic field. At altitudes above 250 km upward, vertical fluxes of the order 6 x 10 to the 10th power/sq m/sec for the thermal ions were calculated. The net ionization of O(+) and CO2(+) by charge exchange with incoming solar wind protons varied from 5 x 10 to the 8th power to 5 x 10 to the 12th power /sq m/sec for assumed field strengths of 50nT to 2nT on the dayside of the planet.

Rohrbaugh, R. P.↗
NASA NTRS1978

Gaseous fuel reactors for power systems

The Los Alamos Scientific Laboratory is participating in a NASA-sponsored program to demonstrate the feasibility of a gaseous uranium fueled reactor. The work is aimed at acquiring experimental and theoretical information for the design of a prototype plasma core reactor which will test heat removal by optical radiation. The basic goal of this work is for space applications, however, other NASA-sponsored work suggests several attractive applications to help meet earth-bound energy needs. Such potential benefits are: small critical mass, on-site fuel processing, high fuel burnup, low fission fragment inventory in reactor core, high temperature for process heat, optical radiation for photochemistry and space power transmission, and high temperature for advanced propulsion systems.

Helmick, H. H.↗
NASA NTRS1978

The role of computational chemistry in the science and measurements of the atmosphere

The role of computational chemistry in determining the stability, photochemistry, spectroscopic parameters, and parameters for estimating reaction rates of atmospheric constituents is discussed. Examples dealing with the photolysis cross sections of HOCl and (1 Delta g) O2 and with the stability of gaseous NH4Cl and asymmetric ClO3 are presented. It is concluded that computational chemistry can play an important role in the study of atmospheric constituents, particularly reactive and short-lived species which are difficult to investigate experimentally.

Phillips, D. H.↗
NASA NTRS1978

The impact of chlorofluoromethane and NO/x/ injections on stratospheric ozone

The chlorofluoromethane problem and the SST problem have been subject to continuing evaluation by the use of one-dimensional stratospheric photochemistry models. The problems to some extent appear to be inversely related to one another through hydroxyl radical reactions; in other words, processes which tend to increase the amount of OH in a model tend to increase the sensitivity of the ozone column to ClX perturbations, while at the same time decreasing the sensitivity to NO(x) perturbations. Evaluations of sensitivity to ClX and NO(x) have varied as new input information has become available and modeling techniques have improved. It is clear that either NO(x) or ClX, or both, will affect the distribution of ozone with altitude.

Stolarski, R. S.↗
NASA NTRS1978

Properties of the stratospheric aerosol layer studied with a one-dimensional computer model

Aerosol particle effects are often neglected in theoretical studies of stratospheric phenomena. In reality, the particulate matter normally found above the tropopause may influence the terrestrial radiation balance, catalyze heterogeneous chemical interactions, and serve as a tracer of atmospheric motions. The paper proposes a one-dimensional model of the stratospheric aerosol layer, and it is used to compare aerosol theory with observational data. The model considers gaseous sulfur photochemistry and the physical aerosol processes of nucleation, coagulation, sedimentation, and diffusion. Calculations of the effects on the aerosol layer of stratospheric injections of aluminum oxide particles by Space Shuttle engines and of sulfur dioxide molecules by volcanic activity are performed. The relation between measured aerosol variability and changes in stratospheric air temperatures and vertical transport rates are discussed.

Turco, R. P.↗
NASA NTRS1978

Rapid laser induced energy transfer in atomic systems

Analytical and experimental studies of the rapid transfer of stored populations from metastable states to selected target states of a different species are reported. Both laser-induced or laser-switched collision and laser-induced two-photon spontaneous emission are described. It is shown that the laser-induced collision method is particularly useful in the visible and UV spectral regions. It has applications in photochemistry, gas-phase kinetics, and in high-power, high-energy gas-phase lasers. The anti-Stokes source is useful in the VUV and soft X-ray spectral regions.

Harris, S. E.↗
NASA NTRS1978

Distribution of atmospheric ozone and how it is measured

The total amount of ozone in a vertical column has been measured spectroscopically at near ultraviolet and visible wavelengths, using ground- and satellite-based instruments. The vertical distribution of ozone from the surface up to approximately 100 km has been measured by a variety of techniques - chemical and optical - and from a number of observing platforms, including balloon, rocket, and satellite platforms. The various methods presently used for determining the atmospheric ozone distribution are reviewed, along with a discussion of their advantages and disadvantages. The observed average distribution of total ozone for the period 1958-1975 shows the expected geographic and seasonal variations. The variations of total ozone, including hemispheric differences, are clearly associated with large-scale circulation processes in the lower stratosphere. Approximately ten years of observations of the vertical ozone distribution, up through the ozone maximum, also show geographic and seasonal variations strongly related to the lower stratosphere circulation. The distribution above the maximum, however, results from the interaction of photochemistry and stratospheric motions.

London, J.↗
NASA NTRS1979

Lyman-alpha and Balmer-series fluorescence from hydrogen photofragments of H2O vapor

Production cross sections associated with the atomic hydrogen Lyman-alpha and Balmer-series (3-9 to 2) fluorescence observed in H2O photodissociation are measured, and maximum fluorescence production cross sections for the two series are reported. Repulsive potential energy curves corresponding to the respective pseudodiatomic OH-H(n) molecule are constructed according to the Franck-Condon principle, and the efficiencies for converting H(2S) to H(2P) by H2 collisions and by H2O collisions are estimated. The data are considered with reference to cometary photochemistry.

Wu, C. Y. R.↗
NASA NTRS1979

Detection of SO2 in the UV spectrum of Venus

The broad absorption feature below 3300 A in the Venus UV spectrum is identified as primarily due to SO2 absorption based on new higher resolution spectra of the 3000-3400 A region showing broad (10 A), unresolved absorptions in the regions at all SO2 band origins between 3000 and 3300 A. SO2 mixing ratios vary from 5 x 10 to the -7th down to an upper limit of 2 x 10 to the -8th at a phase angle of 138 deg. Previous observational determinations of the SO2 mixing ratio were biased toward large phase angles, and consequently did not detect any SO2 absorption at the 10 to the -8th level. The upper limit derived from the CS2 band head at 3206 A is not greater than 5 x 10 to the -8th. The observed range of SO2 mixing ratios is consistent with model predictions based on the sulfur photochemistry at the cloud tops. Ground-based observations of SO2 mixing ratio will provide constraints on models and check on the Venera and Pioneer Venus measurements of the mixing ratios of SO2 and other sulfur-bearing gases with altitude.

Barker, E. S.↗
NASA NTRS1979

Possible existence and role of excited ozone precursors in the stratosphere

Laboratory kinetic experiments, quantum theoretical studies and certain recently discovered infrared emissions from the stratosphere together imply the possible existence of a metastable, energetic, and reactive form of ozone in the upper atmosphere. This species can potentially affect the upper atmospheric photochemistry and heat balance. For these reasons there is a need for further quantum theoretical and laboratory chemical kinetic studies addressing some of the relevant properties of the internally excited ozone precursors.

Prasad, S. S.↗
NASA NTRS1979

Measurements of spectrally integrated atmospheric transmittance in the O2 Schumann-Runge bands and derived oxygen column densities - 76-102 km

Atmospheric transmittances integrated over wavelength intervals corresponding approximately to the (15-0) through (4-0) Schumann-Runge bands of O2 have been determined from EUV solar spectra (wavelengths between 1768 and 1948 A) photographed at seven altitudes between 102 and 76 km with a rocket-borne spectrograph having a resolution of 0.07 A. The observed transmittances are compared with atmospheric transmittances predicted from three models of the O2 absorption cross section. The predicted transmittances have also been used to derive column densities of atmospheric O2 from the observations. The results are compared with values calculated from the U.S. Standard Atmosphere (1976) and with oxygen column densities determined by Prinz and Brueckner (1977) from EUV solar spectra of the Schumann-Runge continuum (wavelength below 1750 A) and of the H-Lyman alpha line (1216 A) recorded on the same films used in the present research. The comparisons test the utility of the models for studies of atmospheric photochemistry, suggest which models may be best for this purpose, and indicate how the models can be improved.

Longmire, M. S.↗
NASA NTRS1979

A one-dimensional model describing aerosol formation and evolution in the stratosphere. I - Physical processes and mathematical analogs. II - Sensitivity studies and comparison with observations

A new time-dependent one-dimensional model of the stratospheric sulfate aerosol layer is developed. The model treats atmospheric photochemistry and aerosol physics in detail and includes the interaction between gases and particles explicitly. It is shown that the numerical algorithms used in the model are quite precise. Sensitivity studies and comparison with observations are made. The simulated aerosol physics generates a particle layer with most of the observed properties. The sensitivity of the calculated properties to changes in a large number of aeronomic aerosol parameters is discussed in some detail. The sensitivity analysis reveals areas where the aerosol model is most uncertain. New observations are suggested that might help resolve important questions about the origin of the stratospheric aerosol layer.

Turco, R. P.↗