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At least 343 records · Page 19

Elemental abundance determinations for meteors by spectroscopy.

Relative elemental abundance determinations for meteors by spectroscopy are discussed. Relative abundances of spectroscopically accessible elements of four major shower meteors and one sporadic meteor are presented. A sporadic meteor with dominant sodium radiation and an iron-deficient sporadic meteor are analyzed. Empirical and theoretical tests for self-absorption in optical meteor plasmas have been conducted. Both ionization and incomplete dissociation are found to severely deplete certain neutral atoms from meteor plasmas.

Harvey, G. A.↗

The Transition Region And Coronal Explorer (TRACE)

The objectives and the characteristics of TRACE, selected as a NASA small explorer mission for development and flight in late 1997, is presented. The TRACE science investigation explores the connections between fine-scale magnetic fields and the associated plasma structures on the sun. The instrument collects images of solar plasmas at temperatures from 10(exp 4) to 10(exp 7) K, with an arc second spatial resolution and good temporal resolution and continuum. TRACE and SOHO will gather simultaneous, digital measurements of all temperature regimes of the solar atmospheric, in both high-resolution imaging and spectroscopy, and magnetogram to photosphere. The 30 cm aperture TRACE telescope uses three normal-incidence coatings for the extreme ultraviolet and one for the ultraviolet on quadrants of the primary and secondary mirrors. Interference filters isolate five different ultraviolet bands. The images are aligned and internally stabilized against spacecraft jitter. TRACE will be launched into a sun-synchronous orbit, allowing continuous observing for eight months of the baseline one-year mission. It will be operated in coordination with the SOHO experiment operations facility.

Tarbell, T. D.↗

Surface Morphology of Undoped and Doped ZnSe Films

Rare-earth doped ions in polar II-VI semiconductors have recently played an important role in the optical properties of materials and devices. In this study, undoped ZnSe and erbium doped ZnSe films were grown by radio frequency (RF) magnetron sputtering method. Atomic Force Microscopy (AFM) was used together with optical microscopy and UV-Vis spectroscopy to characterize the films. Doped samples were found to have higher surface roughness and quite different surface morphology compared to that of undoped samples. The grown films generally show a relatively smooth and uniform surface indicating that they are of overall good quality. The impact of plasma etching on ZnSe:Er film examined under AFM is also discussed.

George, T.↗

Defect Clustering and Nano-Phase Structure Characterization of Multi-Component Rare Earth Oxide Doped Zirconia-Yttria Thermal Barrier Coatings

Advanced oxide thermal barrier coatings have been developed by incorporating multi- component rare earth oxide dopants into zirconia-yttria to effectively promote the creation of the thermodynamically stable, immobile oxide defect clusters and/or nano-scale phases within the coating systems. The presence of these nano-sized defect clusters has found to significantly reduce the coating intrinsic thermal conductivity, improve sintering resistance, and maintain long-term high temperature stability. In this paper, the defect clusters and nano-structured phases, which were created by the addition of multi-component rare earth dopants to the plasma- sprayed and electron-beam physical vapor deposited thermal barrier coatings, were characterized by high-resolution transmission electron microscopy (TEM). The defect cluster size, distribution, crystallographic and compositional information were investigated using high-resolution TEM lattice imaging, selected area diffraction (SAD), and energy dispersive spectroscopy (EDS) analysis techniques. The results showed that substantial defect clusters were formed in the advanced multi-component rare earth oxide doped zirconia-yttria systems. The size of the oxide defect clusters and the cluster dopant segregation was typically ranging fiom 5 to 50 nm. These multi-component dopant induced defect clusters are an important factor for the coating long-term high temperature stability and excellent performance.

Zhu, Dongming↗

Su Lyn: Diagnosing the Boundary Layer with UV and Hard X-Ray Data

Symbiotic stars in which the symbiotic phenomenon is powered solely by accretion, often at an average rate that is higher than in cataclysmic variable stars, provide an important opportunity to diagnose boundary layers around disk-accreting white dwarfs. Here, we investigate SU Lyncis (SU Lyn), a recently discovered example of a purely accretion-powered symbiotic star, using the first reliable X-ray spectroscopy, obtained with NuSTAR, and ultraviolet (UV) photometry obtained with Swift. SU Lyn has hard, thermal, X-ray emission that is strongly affected by a variable local absorber that has little impact on the UV emission. Its X-ray spectrum is described well using a plasma cooling from kT ≈ 21 keV, with a 3-30 keV luminosity of approximately 4.9 × 10(exp 32) erg s(exp -1). The spectrum is also consistent with the presence of reflection with an amplitude of 1.0, although in that case, the bestfit plasma temperature is 20%-25% lower. The UV to X-ray luminosity ratio of SU Lyn changed significantly between 2015 and 2016. We interpret this as a consequence of a drop by almost 90% in the accretion rate. Whereas the UV luminosity of the disk responded linearly, the luminosity of the optically thin (hard X-ray) emission from the boundary layer remained roughly constant because the boundary layer changed from partially optically thick to almost completely optically thin. Under this interpretation, we place a lower limit on the white dwarf mass of 0.7 solar mass (0.8 solar mass if we neglect reflection).

NuSTAR↗

Defect Clustering and Nano-Phase Structure Characterization of Multi-Component Rare Earth Oxide Doped Zirconia-Yttria Thermal Barrier Coatings

Advanced oxide thermal barrier coatings have been developed by incorporating multi-component rare earth oxide dopants into zirconia-yttria to effectively promote the creation of the thermodynamically stable, immobile oxide defect clusters and/or nano-scale phases within the coating systems. The presence of these nano-sized defect clusters has found to significantly reduce the coating intrinsic thermal conductivity, improve sintering resistance, and maintain long-term high temperature stability. In this paper, the defect clusters and nano-structured phases, which were created by the addition of multi-component rare earth dopants to the plasma-sprayed and electron-beam physical vapor deposited thermal barrier coatings, were characterized by high-resolution transmission electron microscopy (TEM). The defect cluster size, distribution, crystallographic and compositional information were investigated using high-resolution TEM lattice imaging, selected area diffraction (SAD), electron energy-loss spectroscopy (EELS) and energy dispersive spectroscopy (EDS) analysis techniques. The results showed that substantial defect clusters were formed in the advanced multi-component rare earth oxide doped zirconia- yttria systems. The size of the oxide defect clusters and the cluster dopant segregation was typically ranging from 5 to 50 nm. These multi-component dopant induced defect clusters are an important factor for the coating long-term high temperature stability and excellent performance.

Zhu, Dongming↗

Spectroscopy from 2 to 200 keV

The astrophysical processes responsible for line and continuum emission in the spectra range 2 keV to 200 keV are examined from the viewpoint of designing a spectrometer which would operate in this regime. Phenomena considered include fluorescent line radiation in X-ray binaries, magnetically shifted iron lines and cyclotron emission from neutron star surfaces, line emission from cosmically abundant elements in thermal plasmas, and nuclear deexcitation lines in fresh nucleosynthetically produced matter. An instrument consisting of a approximately 10 sq cm array of planar germanium detectors surrounded by a large sodium-iodide anticoincidence shield is described and projected background rates and sensitivities are considered. A sample observing program for a two-day shuttle-based mission is included as an example of the wide range of scientific questions which could be addressed by such an instrument.

Helfand, D. J.↗

High mass resolution, high angular acceptance time-of-flight mass spectroscopy for planetary missions under the Planetary Instrument Definition and Development Program (PIDDP)

This final report covers three years and several phases of work in which instrumentation for the Planetary Instrument Definition and Development Program (PIDDP) were successfully developed. There were two main thrusts to this research: (1) to develop and test methods for electrostatically scanning detector field-of-views, and (2) to improve the mass resolution of plasma mass spectrometers to M/delta M approximately 25, their field-of-view (FOV) to 360 degrees, and their E-range to cover approximately 1 eV to 50 keV. Prototypes of two different approaches to electrostatic scanning were built and tested. The Isochronous time-of-flight (TOF) and the linear electric field 3D TOF devices were examined.

Young, David T.↗

Redshifts for a Sample of Radio-Selected Poor Clusters

Multifiber optical spectroscopy has been performed on galaxies in the vicinity of strong, nearby radio galaxies. These radio galaxies were selected from the, 3CR and B2 catalogs based on their exclusion from the Abell catalog, which is puzzling given the hypothesis that an external medium is required to confine the radio plasma of such galaxies. Velocities derived from the spectra were used to confirm the existence of groups and poor clusters in the fields of most of the radio galaxies. We find that all radio galaxies with classical Fanaroff-Riley type I morphologies prove to reside in clusters, whereas the other radio galaxies often appear to be recent galaxy-galaxy mergers in regions of low galaxy density. These findings confirm the earlier result that the existence of extended X-ray emission combined with a statistical excess of neighboring galaxies can be used to identify poor clusters associated with radio galaxies.

Miller, Neal A.↗

Work function reduction in lanthanum hexaboride hollow cathodes operated in gas discharges

Thermal characterization of lanthanum hexaboride (LaB6) hollow cathodes has revealed lower than expected electron emitter temperatures when the cathode reaches steady state. This phenomenon is observed at discharge currents ranging from 5 to 35 A and xenon mass ow rates of 5 to 25 sccm in cathodes with three di erent ori ce diameters. Thus, the accepted value of the work function for polycrystalline LaB6, 2.66 eV, does not describe well the emission characteristics of LaB6 hollow cathodes operating with internal gas discharges at steady state. The measured temperatures and a model of the hollow cathode emitter and xenon discharge were used to estimate the value of the work function in these experiments, yielding a value ranging from 2.1 - 2.44 eV. Measurements of the work function as a function of depth on a hollow cathode emitter using X-ray photoelectron spectroscopy and ion beam milling indicate that the work function in a thin layer near the emitting surface is lower than in the bulk material. We postulate that a lanthanum-rich emitting surface with a lower work function develops as a result of lanthanum recycling in the internal plasma.

Lopez Ortega, Alejandro↗

Light hydrocarbons from plasma discharge in H2-He-CH4 - First results and Uranian auroral chemistry

The production of light hydrocarbons by precipitating magnetospheric electrons in the Uranian stratosphere is simulated in laboratory experiments. The products of continuous-flow glow discharges of H2-He-CH4 mixtures containing 0.0012 or 0.022 mol pct CH4 at pressures 0.63-57 mbar are trapped at 77 K, measured manometrically, and identified by gas chromatography and mass spectroscopy; the results are presented in tables and characterized in detail. The globally averaged rate for the production of higher hydrocarbons by this mechanism on Uranus is estimated as 3 x 10 to the 6th C/sq cm sec and shown to be similar to that for photochemical production, while the local rate for the auroral zones is significantly higher than the corresponding photochemical rate. A decrease in yield with increasing molecular complexity is also noted.

Thompson, W. Reid↗

Electromagnetic inductive heating of the asteroids and moon as evidence bearing on the primordial solar wind

Thermal evolutionary models of the asteroids and the moon based on the hypothesis of electrical inductive heating by a dense primordial solar wind are compared with observation. Inferences (derived from spectroscopy) of asteroidal mineralogy when compared with electrical heating models, the variation of cooling rates recorded in iron meteorites, and the occurrence of the lunar magma ocean event lend support to the hypothesis of inductive heating. A high primordial solar rotation rate and magnetic field together with the loss due to plasma outflow of a substantial fraction of the initial solar mass would follow.

Herbert, F.↗

Broad-Band Continuum and Line Emission of the gamma-Ray Blazar PKS 0537-441

PKS 0537-441, a bright gamma ray emitting blazar was observed at radio, optical, UV and X-ray frequencies during various EGRET paintings, often quasi-simultaneously. In 1995 the object was found in an intense emission state at all wavelengths. BeppoSAX observations made in 1998, non-simultaneously with exposures at other frequencies, allow us to characterize precisely the spectral shape of the high energy blazer component, which we attribute to inverse Compton scatter in The optical-to-gamma-ray spectral energy distributions at the different epochs show that the gamma-ray luminosity dominates the barometric output. This, together with the presence of optical and UV line emission, suggests that, besides the synchrotron self-Compton mechanism, the Compton upscattering of photons external to the jet (e.g., in the broad line region) may have a significant role for high energy radiation. The multiwavelength variability can be reproduced by changes of the plasma bulk Lorentz factor. The spectrum secured by ICE in 1995 appears to be partially absorbed shortward of approximately 1700 Angstroms. However, this signature is not detected in the HST spectrum taker during a lower state of the source. The presence of intervening absorbers is not supported by optical imaging and spectroscopy of the field.

Pian, E.↗

Chemical investigation of Titan and Triton tholins

We report chromatographic and spectroscopic analyses of both Titan and Triton tholins, organic solids made from the plasma irradiation of 0.9:0.1 and 0.999:0.001 N2/CH4 gas mixtures, respectively. The lower CH4 mixing ratio leads to a nitrogen-richer tholin (N/C greater than 1), probably including nitrogen heterocyclic compounds. Unlike Titan tholin, bulk Triton tholin is poor in nitriles. From high-pressure liquid chromatography, ultraviolet and infrared spectroscopy, and molecular weight estimation by gel filtration chromatography, we conclude that (1) several H2O-soluble fractions, each with distinct UV and IR spectral signatures, are present, (2) these fractions are not identical in the two tholins, (3) the H2O-soluble fractions of Titan tholins do not contain significant amounts of nitriles, despite the major role of nitriles in bulk Titan tholin, and (4) the H2O-soluble fractions of both tholins are mainly molcules containing about 10 to 50 (C + N) atoms. We report yields of amino acids upon hydrolysis of Titan and Triton tholins. Titan tholin is largely insoluble in the putative hydrocarbon lakes or oceans on Titan, but can yield the H2O-soluble species investigated here upon contact with transient (e.g., impact-generated) liquid water.

Mcdonald, Gene D.↗

Dusty Plasma Experiments Using an Electrodynamic Balance

Knowledge of the formation, distribution, physical, chemical and optical characteristics of interstellar, interplanetary, and planetary dust grains provide valuable information about many issues dealing with the origin and formation of the solar system bodies, interplanetary and interstellar environments as well as various industrial processes. Understanding the microphysics of individual grains and their interaction with the surrounding environment is key to properly model various conditions and interpret existing data. The theory and models of individual dust grains are well developed for environments that vary from dense planetary atmospheres to dusty plasmas to diffuse environments such is interplanetary space. However, experimental investigations of individual dust grains in equilibrium are less common, perhaps due to the difficult of these experiments. Laboratory measurements of dust grains have primarily measured ensemble properties or transient properties of single grains. A technique developed in the 1950's for ion spectroscopy, known as a quadrupole trap or 'Paul Trap', has recently been used to investigate single micron-sized dust grains. This scaled ion trap called an electrodynamic balance has been used for atmospheric aerosol research. A description of this technique is provided. Recent results from experiments to investigate the equilibrium potential of dust grains exposed to far ultraviolet light or to -,in electron or ion beam are presented. This laboratory technique ]ends itself to many applications that relate to planetary atmospheres, heliospheric environments, pre-stellar and pre-planetary conditions, and industrial settings. Several planned experimental approaches are presented. Potential experiments to investigate the interaction of multiple dust grains using an electrodynamic balance are proposed.

Spann, J. F.↗

Electrodynamic Balance for Studies of Cosmic Dust Particles

Knowledge of the formation and distribution of interstellar, interplanetary, and planetary dust grains, and their physical, chemical and optical characteristics provide valuable information about many issues dealing with the origin and formation of the solar system bodies, interplanetary and interstellar environments as well as various industrial processes. Understanding the microphysics of individual grains and their interaction with the surrounding, environment is key to properly model various conditions and interpret existing data. The theory and models of individual dust grains are well developed for environments that vary from dense planetary atmospheres to dusty plasmas to diffuse environments such as interplanetary space. However, experimental investigations of individual dust grains in equilibrium are less common, perhaps due to the difficulty of these experiments. Laboratory measurements of dust grains have primarily measured ensemble properties or transient properties of single grains. A technique developed in the 1950's for ion spectroscopy, generally referred to as a quadrupole trap has recently been employed as an electrodynamic balance to investigate single micron-sized dust grains and for atmospheric aerosol research. A description of the theoretical basis and the experimental setup of the electrodynamic balance being developed in our laboratory are given. This laboratory technique lends itself to many applications that relate to planetary atmospheres, heliospheric environments, pre-stellar and pre-planetary conditions, and industrial settings. We present results from some recent experiments carried out to investigate the equilibrium potential of dust grains exposed to far ultraviolet light or to an electron beam. Some future experiments using an electrodynamic balance to investigate the optical characteristics, and condensation process involving dust grains in various astrophysical environments are discussed.

Spann, J. F.↗

Coaxial carbon plasma gun deposition of amorphous carbon films

A unique plasma gun employing coaxial carbon electrodes was used in an attempt to deposit thin films of amorphous diamond-like carbon. A number of different structural, compositional, and electrical characterization techniques were used to characterize these films. These included scanning electron microscopy, scanning transmission electron microscopy, X ray diffraction and absorption, spectrographic analysis, energy dispersive spectroscopy, and selected area electron diffraction. Optical absorption and electrical resistivity measurements were also performed. The films were determined to be primarily amorphous, with poor adhesion to fused silica substrates. Many inclusions of particulates were found to be present as well. Analysis of these particulates revealed the presence of trace impurities, such as Fe and Cu, which were also found in the graphite electrode material. The electrodes were the source of these impurities. No evidence of diamond-like crystallite structure was found in any of the film samples. Details of the apparatus, experimental procedure, and film characteristics are presented.

Sater, D. M.↗

Free-standing thin film Ge single crystals grown by plasma-enhanced chemical vapor deposition

The films, which are approximately 10 microns in thickness, are grown epitaxially on polished (100) NaCl substrates at 450 C by plasma enhanced chemical vapor deposition. Upon cooling, the films are separated from the substrate by differential shear stress, leaving free-standing films of Ge which can be handled. Growths are attained by nucleating at minimum plasma power for very brief intervals and then raising the power to 65 W to increase the growth rate to approximately 10 microns/h. It is found that substrate exposure to the plasma at too high a power for too long a time sputters and erodes the surface, thereby substantially degrading the nucleation process and the ultimate growths. It is noted that the free-standing films are visually specular and exhibit a high degree of crystalline order when examined by X-ray diffraction. Auger electron spectroscopy and energy dispersive analysis of X-rays reveal no detectable bulk contamination.

Outlaw, R. A.↗