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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Spatiotemporal and Statistical Mapping of Transition Metal Equilibria in Alkaline Media

Transition metal dissolution and redeposition (D/R) kinetics in alkaline media play a critical role in various chemical and electrochemical processes. Competitive reaction kinetics between different transition metals can modulate individual metal behavior in these processes. To date, these phenomena have remained largely unmeasured, and even when captured, they are difficult to statistically characterize due to their dynamic nature, simultaneous occurrence, and spatially heterogeneous nature. Here, in this study, we develop a statistical analysis framework based on in situ and operando X-ray fluorescence microscopy (XFM) to investigate the relative D/R kinetics of multiple transition metals in alkaline media. By employing statistical analysis, we quantify the spatial distribution of D/R species and assess the rate at which the system reaches equilibrium under varying reaction conditions. We show that pH does not simply change the rate of dissolution and redeposition, but reorganizes the cross-element kinetic correlations among Ni, Fe, and Mn and accelerates the spatial equilibration of D/R events, as quantified through correlation analysis, reaction-rate estimation, probability function distributions, and texture-based monitoring statistics. Additionally, we demonstrate how modifying the solvent environment can influence D/R kinetics, providing a pathway for tuning materials synthesis and process optimization. Our study offers valuable insights into the complex interplay between different transition metals and provides a reliable statistical framework for spatial analysis of diverse imaging data sets, enabling deeper extraction of latent information across multiple modalities.

36 MATERIALS SCIENCE↗

Statistical analysis of displacement damage in small devices from neutron and ion irradiation

Modern semiconductor devices, such as gate-all-around nanosheet field-effect transistors (GAA NS FETs), are smaller than displacement damage cascades from fission neutrons. In this regime, device failure may occur through low-probability single events, rather than by parametric degradation previously seen in larger devices. Here, we present a statistical model that predicts the probability of a damage event in a small device and the probability distribution of the magnitude, i.e., number of displacements within the device, from each event. The model is developed first for neutron irradiation and then for energetic ion irradiation. The model is consistent with results from recent experiments in which lithium-ion irradiation produced stepwise increases in subthreshold current in GAA NS FETs.

Wampler, W. R.↗

Frame synchronization methods based on channel symbol measurements

The current DSN frame synchronization procedure is based on monitoring the decoded bit stream for the appearance of a sync marker sequence that is transmitted once every data frame. The possibility of obtaining frame synchronization by processing the raw received channel symbols rather than the decoded bits is explored. Performance results are derived for three channel symbol sync methods, and these are compared with results for decoded bit sync methods reported elsewhere. It is shown that each class of methods has advantages or disadvantages under different assumptions on the frame length, the global acquisition strategy, and the desired measure of acquisition timeliness. It is shown that the sync statistics based on decoded bits are superior to the statistics based on channel symbols, if the desired operating region utilizes a probability of miss many orders of magnitude higher than the probability of false alarm. This operating point is applicable for very large frame lengths and minimal frame-to-frame verification strategy. On the other hand, the statistics based on channel symbols are superior if the desired operating point has a miss probability only a few orders of magnitude greater than the false alarm probability. This happens for small frames or when frame-to-frame verifications are required.

Dolinar, S.↗

Regional land use studies

Remote sensing technology and data from instrumented satellites and high altitude aircraft are proposed for mapping land use on a current national basis, for monitoring changes and trends, and for creating statistical models which can be manipulated to demonstrate the probable effects of proposed land use and of environmental changes over large areas. Both Apollo spacecraft and aircraft photography were used; the spacecraft pictures delineated the cropland and urban boundaries more clearly. A computer model is also proposed for statistical analysis and for printing out updated maps automatically; this model will include a data bank which can be updated rapidly with changes detected by the computer.

Place, J. L.↗

Flight inspection data and crack initiation times

Lockheed C-130 service-flight inspection data is reduced by means of fracture mechanics and statistical analysis into a form from which the probability of time to crack initiation and the distribution of initial flaw sizes for various locations on the aircraft can be determined. Crack sizes are normalized by extrapolating a growing crack backwards from its first recorded size to .03 inches (crack initiation size) yielding the time to crack initiation. In a similar fashion, the crack is grown backwards to a time equal to zero to yield an initial flaw size. In order to perform the discussed computations, crack growth constants were computed for each individual location and were analyzed statistically. Statistical distributions were fitted to times to crack initiation and to initial flaw sizes in order to describe their expected behavior. Weibull and Johnson distributions have been found to fit the data reasonably well but for a better fit convolution integrals of Poisson load distributions and Weibull strength distributions are needed.

Johnson, W. S.↗

Dark energy survey year 3 results: likelihood-free, simulation-based w CDM inference with neural compression of weak-lensing map statistics

We present simulation-based cosmological wcold dark matter (wCDM) inference using dark energy survey year 3 weak-lensing maps, via neural data compression of weak-lensing map summary statistics: power spectra, peak counts, and direct map-level compression/inference with convolutional neural networks (CNN). Using simulation-based inference, also known as likelihood-free or implicit inference, we use forward-modelled mock data to estimate posterior probability distributions of unknown parameters. This approach allows all statistical assumptions and uncertainties to be propagated through the forward-modelled mock data; these include sky masks, non-Gaussian shape noise, shape measurement bias, source galaxy clustering, photometric redshift uncertainty, intrinsic galaxy alignments, non-Gaussian density fields, neutrinos, and non-linear summary statistics. We include a series of tests to validate our inference results. This paper also describes the Gower Street simulation suite: 791 full-sky pkdgrav3 dark matter simulations, with cosmological model parameters sampled with a mixed active-learning strategy, from which we construct over 3000 mock dark energy survey lensing data sets. For wCDM inference, for which we allow –1 < w < –$\frac{1}{3}$⁠, our most constraining result uses power spectra combined with map-level (CNN) inference. Using gravitational lensing data only, this map-level combination gives Ω m = 0.283$^{+0.020}_{–0.027}$⁠, S 8 = 0.804$^{+0.025}_{–0.017⁠}$, and w < –0.80 (with a 68 per cent credible interval); compared to the power spectrum inference, this is more than a factor of two improvement in dark energy parameter (Ω⁠ DE , w⁠) precision.

79 ASTRONOMY AND ASTROPHYSICS↗

Truncated ARQ Statistical Link Analysis for Dynamic Links

The future deep space links are migrating towards higher frequency bands such as Ka band and optical. These links are susceptible to non Gaussian and non linear effects such as atmospheric turbulence, scintillation, antenna mis-pointing, jitter, etc. These dynamic links thus will experience various degrees of fading loss, and some of these link disruptions cannot be effectively mitigated by forward error correction coding and/or interleaving. One effective way to ensure reliable communication is by using Automatic Repeat Request (ARQ) protocol, where the receiver acknowledges to the transmitter whether or not a data unit is successfully received. If a data unit is not successfully received (such as after a pre-set time-out), the transmitter would then re-transmit the lost data unit to the receiver. In a previous paper, we derived a statistical link analysis method of finding the optimal operating Signal-to-Noise Ratio (SNR) and estimating the latency of an ARQ scheme. In a more recent paper, we demonstrated the above method using the SNR distribution constructed from the Ka-band (32 GHz) flight data. To simplify the discussion, we considered the academic approach that the ARQ scheme allows for an infinite number of retransmissions. In this paper, we consider the more practical case of a truncated ARQ scheme, where there is a limit on the number of retransmissions. We derive the error probability, the optimal SNR setting, and the latency statistics of the correctly received frames of the truncated ARQ schemes. We first discuss the truncated ARQ link analysis principles using the Gaussian assumption for SNR distribution with a large variance. Next, we demonstrate the statistical truncated ARQ link analysis using the SNR distribution constructed from the Ka-band flight data. The results in this paper can be applied in the design of reliable communication systems such as the Consultative Committee for Space Data System (CCSDS) File Transfer Protocol (CFTP) and the Delay Tolerant Network (DTN).

Morabito, David↗

Scalar dissipation and mixing in turbulent reacting flows

The mixing term that appears in probability density function-based formulations of the statistical behavior of turbulent reacting flows was studied with the use of direct numerical simulations of an irreversible, second-order, isothermal chemical reaction between initially segregated reactants in decaying, homogeneous turbulence. Three-dimensional, time-dependent pseudospectral calculations with 64-cubed Fourier modes were made as well as were Monte Carlo simulations of the joint concentration pdf equations for coalescence-dispersion (C/D) models. It was found that the development of the scalar microscales depends largely on the initial concentration distributions (both isotropic and nonisotropic distributions were used) and is relatively independent of the reaction rate constant. Joint concentration probability density functions were compared to predictions of D/D models that make use of parameters evaluated from the nonreacting or inert system.

Leonard, Andy D.↗

Safeguarding a Lunar Rover with Wald's Sequential Probability Ratio Test

The virtual bumper is a safeguarding mechanism for autonomous and remotely operated robots. In this paper we take a new approach to the virtual bumper system by using an old statistical test. By using a modified version of Wald's sequential probability ratio test we demonstrate that we can reduce the number of false positive reported by the virtual bumper, thereby saving valuable mission time. We use the concept of sequential probability ratio to control vehicle speed in the presence of possible obstacles in order to increase certainty about whether or not obstacles are present. Our new algorithm reduces the chances of collision by approximately 98 relative to traditional virtual bumper safeguarding without speed control.

safeguarding↗

Circuit analysis method for thin-film solar cell modules

The design of a thin-film solar cell module is dependent on the probability of occurrence of pinhole shunt defects. Using known or assumed defect density data, dichotomous population statistics can be used to calculate the number of defects expected in a module. Probability theory is then used to assign the defective cells to individual strings in a selected series-parallel circuit design. Iterative numerical calculation is used to calcuate I-V curves using cell test values or assumed defective cell values as inputs. Good and shunted cell I-V curves are added to determine the module output power and I-V curve. Different levels of shunt resistance can be selected to model different defect levels.

Burger, D. R.↗

Application of the Maximum Amplitude-Early Rise Correlation to Cycle 23

On the basis of the maximum amplitude-early rise correlation, cycle 23 could have been predicted to be about the size of the mean cycle as early as 12 mo following cycle minimum. Indeed, estimates for the size of cycle 23 throughout its rise consistently suggested a maximum amplitude that would not differ appreciably from the mean cycle, contrary to predictions based on precursor information. Because cycle 23 s average slope during the rising portion of the solar cycle measured 2.4, computed as the difference between the conventional maximum (120.8) and minimum (8) amplitudes divided by the ascent duration in months (47), statistically speaking, it should be a cycle of shorter period. Hence, conventional sunspot minimum for cycle 24 should occur before December 2006, probably near July 2006 (+/-4 mo). However, if cycle 23 proves to be a statistical outlier, then conventional sunspot minimum for cycle 24 would be delayed until after July 2007, probably near December 2007 (+/-4 mo). In anticipation of cycle 24, a chart and table are provided for easy monitoring of the nearness and size of its maximum amplitude once onset has occurred (with respect to the mean cycle and using the updated maximum amplitude-early rise relationship).

Willson, Robert M.↗

Void statistics, scaling, and the origins of large-scale structure

The probability that a volume of the universe of given size and shape spaced at random will be void of galaxies is used here to study various models of the origin of cosmological structures. Numerical simulations are conducted on hot-particle and cold-particle-modulated inflationary models with and without biasing, on isothermal or initially Poisson models, and on models where structure is seeded by loops of cosmic string. For the Pisces-Perseus redshift compilation of Giovanelli and Haynes (1985), it is found that hierarchical scaling is obeyed for subsamples constructed with different limiting magnitudes and subsamples taken at random. This result confirms that the hierarchical ansatz holds valid to high order and supports the idea that structure in the observed universe evolves by a regular process from an almost Gaussian primordial state. Neutrino models without biasing show the effect of a strong feature in the initial power spectrum. Cosmic string models do not agree well with the galaxy data.

Fry, J. N.↗

The Effect of General Statistical Fiber Misalignment on Predicted Damage Initiation in Composites

A micromechanical method is employed for the prediction of unidirectional composites in which the fiber orientation can possess various statistical misalignment distributions. The method relies on the probability-weighted averaging of the appropriate concentration tensor, which is established by the micromechanical procedure. This approach provides access to the local field quantities throughout the constituents, from which initiation of damage in the composite can be predicted. In contrast, a typical macromechanical procedure can determine the effective composite elastic properties in the presence of statistical fiber misalignment, but cannot provide the local fields. Fully random fiber distribution is presented as a special case using the proposed micromechanical method. Results are given that illustrate the effects of various amounts of fiber misalignment in terms of the standard deviations of in-plane and out-of-plane misalignment angles, where normal distributions have been employed. Damage initiation envelopes, local fields, effective moduli, and strengths are predicted for polymer and ceramic matrix composites with given normal distributions of misalignment angles, as well as fully random fiber orientation.

Micromechanical↗

A statistical model of the photomultiplier gain process with applications to optical pulse detection

A Markov diffusion model was used to determine an approximate probability density for the random gain. This approximate density preserves the correct second-order statistics and appears to be in reasonably good agreement with experimental data. The receiver operating curve for a pulse counter detector of PMT cathode emission events was analyzed using this density. The error performance of a simple binary direct detection optical communication system was also derived.

Tan, H. H.↗

A statistical model of the photomultiplier gain process with applications to optical pulse detection

A Markov diffusion model was used to determine an approximate probability density for the random gain. This approximate density preserves the correct second-order statistics and appears to be in reasonably good agreement with experimental data. The receiver operating curve for a pulse counter detector of PMT cathode emission events was analyzed using this density. The error performance of a simple binary direct detection optical communication system was also derived. Previously announced in STAR as N82-25100

Tan, H. H.↗

The definition and specification of the near earth environmental criteria for spacecraft thermal design

The variation of the earth's thermal and albedo radiation received by a near-earth orbiting space vehicle or space payload as a result of temporal variation of the earth atmosphere is discussed. A statistical study of current satellite data for determining probability distributions is proposed. With these distributions the thermal designer can define confidence levels on predicted temperature ranges which are compatible with engineering models for use in design, failure probabilities, and spacecraft cost estimates. Use of the distributions in environmental criteria guidelines is also considered.

Gary, G. A.↗