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Automating sky object classification in astronomical survey images

We describe the application of machine classification techniques to the development of an automated tool for the reduction of a large scientific data set. The 2nd Palomer Observatory Sky Survey is nearly completed. This survey provides comprehensive coverage of the northern celestial hemisphere in the form of photographic plates. The plates are being transformed into digitized images whose quality will probably not be surpassed in the next ten to twenty years. The images are expected to contain on the order of 10(exp 7) galaxies and 10(exp 8) stars. Astronomers wish to determine which of these sky objects belong to various classes of galaxies and stars. The size of this data set precludes manual analysis. Our approach is to develop a software system which integrates the functions of independently developed techniques for image processing and data classification. Digitized sky images are passed through image processing routines to identify sky objects and to extract a set of features for each object. These routines are used to help select a useful set of attributes for classifying sky objects. Then GID3* and O-BTree, two inductive learning techniques, learn classification decision trees from examples. These classifiers will be used to process the rest of the data. This paper gives an overview of the machine learning techniques used, describes the details of our specific application, and reports the initial encouraging results. The results indicate that our approach is well-suited to the problem. The primary benefits of the approach are increased data reduction throughput and consistency of classification. The classification rules which are the product of the inductive learning techniques will form an object, examinable basis for classifying sky objects. A final, not to be underestimated benefit is that astronomers will be freed from the tedium of an intensely visual task to pursue more challenging analysis and interpretation problems based on automatically cataloged data.

Fayyad, Usama M.↗

The Urban Fabric of the City as Its Affects Thermal Energy Responses Derived from Remote Sensing Data

The physical geography of the city affects numerous aspects of its interlinked biophysical, social, and land-atmosphere characteristics - those attributes that come together to form the total urban environment. One approach to studying the multitude of interactions that occur as a result of urbanization is to view the city from a systems ecology perspective, where energy and material cycle into and out of the urban milieu. Thus, the urban ecosystem is synergistic in linking land, air, water, and living organisms in a vast network of interrelated physical, human, and biological process. Given the number and the shear complexity of the exchanges and, ultimately, their effects, that occur within the urban environment, we are focusing our research on looking at how the morphology or urban fabric of the city, drives thermal energy exchanges across the urban landscape. The study of thermal energy attributes for different cities provides insight into how thermal fluxes and characteristics are partitioned across the city landscape in response to each city's morphology. We are using thermal infrared remote sensing data obtained at a high spatial resolution from aircraft, along with satellite data, to identify and quantify thermal energy characteristics for 4 U.S. cities: Atlanta, GA, Baton Rouge, LA, Salt Lake City, UT, and Sacramento, CA. Analysis of how thermal energy is spatially distributed across the urban landscapes for these cities provides a unique perspective for understanding how the differing morphology of cities forces land-atmosphere exchanges, such as the urban heat island effect, as well as related meteorological and air quality interactions. Keyword: urban ecosystems, remote sensing, urban heat island

Quattrochi, Dale A.↗

Medical System Requirements Development for Lunar Operations

The major health hazards of spaceflight include higher levels of damaging radiation, altered gravity, extended periods of isolation and confinement, a closed and potentially hostile living environment, and the stress associated with being a long distance from Earth. As we increase the duration of lunar stays with foreseeable communication latencies and disruptions, there will be a progressive need for crew to maintain their own health and independently respond to critical medical events. The Exploration Medical Capability element of the NASA Human Research Program is developing a set of Medical System requirements for lunar transit and surface operations. These requirements specify the capabilities, processes and procedures of a habitat Medical System needed for a range of conditions known to occur during spaceflight. Requirement text is written so as not to constrain innovative design solutions necessary for a resilient system. The requirement set includes attributes and functions the Medical System imposes on eight additional habitat systems. A key property of the Medical System is the provision of medical knowledge that will be stored, updated, analyzed, and secured within a Habitat Data System. A Task Performance Support System will aid in medical data acquisition and interpretation, crew training, medical condition prevention, diagnosis and treatment, provide interactive procedures, and track medical inventory. A Wellness System will focus on the provision of countermeasures to prevent, mitigate or treat adverse physical and behavioral health effects while the Medical System recommends adjustments to these countermeasures to maintain crew health. An Environmental Monitoring System will share out-of-bounds readings of air and water quality, acoustics, and radiation exposure levels with the Medical System to help identify issues before they affect crew health and performance. A Communications System will provide secured and private consultations between crew and the ground medical team and their loved ones on Earth. The Medical System also imposes requirements on a Research & Testbed System, fostering advanced medical science such as human research. A Waste Management System provides biohazard waste containment and waste disposal options (recycle and reuse). An Extravehicular Activity System supports crew health during lunar surface activities. And finally, a Maintenance Support System ensures that medical equipment is performing as expected. These requirements are being specifically developed for lunar surface operations but could help to identify Medical System requirements for any space habitat (e.g., I-Hab, commercial endeavors, etc.).

technology↗

Characterizing the Vertical Profile of Aerosol Particle Extinction and Linear Depolarization over Southeast Asia and the Maritime Continent: The 2007-2009 View from CALIOP

Vertical profiles of 0.532 μm aerosol particle extinction coefficient and linear volume depolarization ratio are described for Southeast Asia and the Maritime Continent. Quality-screened and cloud-cleared Version 3.01 Level 2 NASA Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) 5-km Aerosol Profile datasets are analyzed from 2007 to 2009. Numerical simulations from the U.S. Naval Aerosol Analysis and Predictive System (NAAPS), featuring two-dimensional variational assimilation of NASA Moderate Resolution Imaging Spectroradiometer and Multi-angle Imaging Spectro- Radiometer quality-assured datasets, combined with regional ground-based lidar measurements, are considered for assessing CALIOP retrieval performance, identifying bias, and evaluating regional representativeness. CALIOP retrievals of aerosol particle extinction coefficient and aerosol optical depth (AOD) are high over land and low over open waters relative to NAAPS (0.412/0.312 over land for all data points inclusive, 0.310/0.235 when the per bin average is used and each is treated as single data points; 0.102/0.151 and 0.086/0.124, respectively, over ocean). Regional means, however, are very similar (0.180/0.193 for all data points and 0.155/0.159 when averaged per normalized bin), as the two factors offset one another. The land/ocean offset is investigated, and discrepancies attributed to interpretation of particle composition and a-priori assignment of the extinction-to-backscatter ratio ("lidar ratio") necessary for retrieving the extinction coefficient from CALIOP signals. Over land, NAAPS indicates more dust present than CALIOP algorithms are identifying, indicating a likely assignment of a higher lidar ratio representative of more absorptive particles. NAAPS resolvesmore smoke overwater than identified with CALIOP, indicating likely usage of a lidar ratio characteristic of less absorptive particles to be applied that biases low AOD there. Over open waters except within the Bay of Bengal, aerosol particle scattering is largely capped below 1.5 km MSL, though ground-based lidar measurements at Singapore differ slightly from this finding. Significant aerosol particle presence over land is similarly capped near 3.0 km MSL over most regions. Particle presence at low levels regionally, except over India, is dominated by relatively non-depolarizing particles. Industrial haze, sea salt droplets and fresh smoke are thus most likely present.

linear volume depolarization ratio↗

Airborne Observations of the Spatial and Temporal Variability of Tropospheric Carbon Dioxide during the INTEX-B Campaign

The Intercontinental Chemical Transport Experiment-North America (INTEX-NA) is an international field campaign envisioned to investigate the transport and transformation of gases and aerosols on transcontinental/intercontinental scales and assess their impact on air quality and climate. Phase B (INTEX-B) of the mission was conducted during a 10- week period from March 1 to May 15, 2006 and focused initially on pollution outflow from the Mexico City Metropolitan Area, later addressing the transport of pollution from Asia to North America during springtime meteorological conditions. During the deployment, fast-response (1-s resolution) CO2 measurements were recorded aboard the NASA DC-8 providing valuable regional-scale information on carbon sources and sinks over sparsely sampled areas of North America and adjacent ocean basins. When coupled with the enormously sophisticated chemistry payload on the DC-8, these measurements collectively afford extremely powerful multi-tracer constraints for carbon source/sink attribution. Preliminary examination of the two data sets from the INTEX-B campaign, acquired one month apart, reveals not only the influence of the CO2 seasonal cycle, but also the preponderance of human population and industrial activity in the northern hemisphere. In this presentation, a synergy of the ensemble of airborne and surface observations, bottomup emission inventories, as well as transport history are invoked in a GIS framework to elucidate the source/sink processes reflected in the observations. The airborne CO2 data, along with simultaneous surface measurements (e.g. NOAA ESRL), are examined to establish the vertical distribution and variability of CO2 as a function of location. The role of localized sources, long-range transport, the biosphere, stratospheric exchange, and dynamical processes on the CO2 spatial variability observed throughout the tropospheric column will be discussed.

Vay, Stephanie A.↗

Test progress on the electrostatic membrane reflector

NASA is currently developing a low mass antenna which derives its reflector surface quality from the application of electrostatic forces to form a thin membrane into the desired concave reflector surface. The shuttle-deployed antenna would have a diameter of 100 m and an RMS surface smoothness of 10 to 1 mm for operation at 1 to 10 GHz. Surface quality measurements have been made on a highly deformable elastic membrane, pressurized by electrostatic forces. Included are the effects of the perimeter boundary, splicing of the membrane, the long-scale smoothness of commercial membranes, and the spatial controllability of the membrane using voltage adjustments to alter the electrostatic forces. The electrostatic membrane was found to operate well in an open-loop sense, showing a high degree of position stability and negligible power consumption in dry air. Visco-electric creep was not evident, but the polymer membrane did expand and contract considerably due to its hygroscopic expansion coefficient. A residual roughness of about 0.75 mm existed with the polymer used in these tests; this error is attributed to seams and membrane anisotropy where the material is stiffer in one direction.

Goslee, J. W.↗

Comparison of visible and near-infrared reflectance spectra of CM2 carbonaceous chondrites and primitive asteroids

Spectra of primitive asteroids (defined as C, P, and D classes and associated subclasses) were compared to the limited number of spectra of CM2 carbonaceous chondrites. An absorption feature located at 0.7 microns attributed to an Fe(+2) - Fe(+3) charge transfer absorption in iron oxides in phyllosilicates is apparent in some of the CM2 carbonaceous chondrite spectra and many of the asteroid spectra. Sawyer found a correlation between the area of the 0.7 micron feature and the mean semimajor axis of the asteroids. Spectra of a larger sample of carbonaceous chondrites, including 7 CM2 chondrites, covering a spectral interval of 0.30-2.5 microns were recently obtained using the Relab instrument at Brown University. These spectra were compared with spectrophotometric asteroid observations in a separate abstract. Those spectra of CM2 chondrites were isolated into the UV, visible and near-infrared spectral regions in order to compare them with high-quality narrowband reflectance spectra.

Vilas, F.↗

Intelligent Entity Behavior Within Synthetic Environments

This paper describes some elements in the development of realistic performance and behavior in the synthetic entities (players) which support Modeling and Simulation (M&S) applications, particularly military training. Modern human-in-the-loop (virtual) training systems incorporate sophisticated synthetic environments, which provide: 1. The operational environment, including, for example, terrain databases; 2. Physical entity parameters which define performance in engineered systems, such as aircraft aerodynamics; 3. Platform/system characteristics such as acoustic, IR and radar signatures; 4. Behavioral entity parameters which define interactive performance, including knowledge/reasoning about terrain, tactics; and, 5. Doctrine, which combines knowledge and tactics into behavior rule sets. The resolution and fidelity of these model/database elements can vary substantially, but as synthetic environments are designed to be compose able, attributes may easily be added (e.g., adding a new radar to an aircraft) or enhanced (e.g. Amending or replacing missile seeker head/ Electronic Counter Measures (ECM) models to improve the realism of their interaction). To a human in the loop with synthetic entities, their observed veridicality is assessed via engagement responses (e.g. effect of countermeasures upon a closing missile), as seen on systems displays, and visual (image) behavior. The realism of visual models in a simulation (level of detail as well as motion fidelity) remains a challenge in realistic articulation of elements such as vehicle antennae and turrets, or, with human figures; posture, joint articulation, response to uneven ground. Currently the adequacy of visual representation is more dependant upon the quality and resolution of the physical models driving those entities than graphics processing power per Se. Synthetic entities in M&S applications traditionally have represented engineered systems (e.g. aircraft) with human-in-the-loop performance characteristics (e.g. visual acuity) included in the system behavioral specification. As well, performance affecting human parameters such as experience level, fatigue and stress are coming into wider use (via AI approaches) to incorporate more uncertainty as to response type as well as performance (e.g. Where an opposing entity might go and what it might do, as well as how well it might perform).

Kruk, R. V.↗

Characterizing performance of ultra-sensitive accelerometers

An overview is given of methodology and test results pertaining to the characterization of ultra sensitive accelerometers. Two issues are of primary concern. The terminology ultra sensitive accelerometer is used to imply instruments whose noise floors and resolution are at the state of the art. Hence, the typical approach of verifying an instrument's performance by measuring it with a yet higher quality instrument (or standard) is not practical. Secondly, it is difficult to find or create an environment with sufficiently low background acceleration. The typical laboratory acceleration levels will be at several orders of magnitude above the noise floor of the most sensitive accelerometers. Furthermore, this background must be treated as unknown since the best instrument available is the one to be tested. A test methodology was developed in which two or more like instruments are subjected to the same but unknown background acceleration. Appropriately selected spectral analysis techniques were used to separate the sensors' output spectra into coherent components and incoherent components. The coherent part corresponds to the background acceleration being measured by the sensors being tested. The incoherent part is attributed to sensor noise and data acquisition and processing noise. The method works well for estimating noise floors that are 40 to 50 dB below the motion applied to the test accelerometers. The accelerometers being tested are intended for use as feedback sensors in a system to actively stabilize an inertial guidance component test platform.

Sebesta, Henry↗

Collaborative Research: Properties and Dynamics of the Shallow Crust (Final Report)

Ground motions recorded at one location are often extrapolated to nearby regions within a given radius. Here, we explore the appropriateness of spatial extrapolation using data from seven small aperture seismic network deployments in southern California. Six of these deployments are linear arrays of 4-13 stations, and one is a 2D array of 13 stations at Pinyon Flats Observatory. The spatial footprint array diameters are 3 km or less, and each array was operational for a year or more. From our base catalog (M2.5+ earthquakes; 4038 events; September 2010 - June 2023), automated methods remove temporally overprinted waveforms from nearby events (< 5 km) in quick succession (< 5 min) and data with nonviable waveforms. These 200 samples per second data are filtered at 0.5-25 Hz and must have signal-tonoise ratios (SNRs) of 2.5+. Peak ground acceleration (PGA) and peak ground velocity (PGV) are derived individually from the maximum absolute values of each of the 3-component waveforms (vertical, northsouth, and east-west). Five of the seven arrays traverse the San Jacinto fault, and two do not. Ground motion observations are compared with theoretical estimates from Abrahamson et al., 2014. On average, arrays deployed within and across fault zones consistently record ground motions above theoretical expectations, whereas off-fault arrays record ground motions at or slightly below theoretical expectations. We attribute these differences to site conditions because these trends prevail for the full data suites. For each network and each individual channel, the coefficient of variation indicates that the standard deviations are ~30±6% of the mean. Exploring relative ground motion contributions from all three channels (ternary plots), as expected, most data show that vertical ground motions are attenuated compared to horizontal ones. However, this is not always the case for RA array data, where vertical motions can be ~2-3 times larger than horizontal motions for select events near Cahuilla, CA. These anomalously high vertical motions are focal mechanism-related. These results suggest that ternary plots created using only a small amount of data can be used as a data quality metric and a tool to find anomalous features in three-component data.

58 GEOSCIENCES↗

The Updated Umkehr Ozone Retrieval Algorithm and its Validation against Satellite Data

Improvements to the Umkehr ozone profile retrieval algorithm have been developed and are now being evaluated. The updated algorithm is able to simulate observations more accurately and provides data output that is easier to analyze. Among the new diagnostic capabilities that the updated algorithm provides is the averaging kernel (AK) method. The AK approach allows studying how the algorithm responds when a small perturbation is made in a particular layer of the atmosphere [Rodgers 1976, 1990]. We will use the AK method to define precisely what Umkehr should measure given a set of profiles measured by other platforms. This method allows us to compare trends and offsets in data more accurately than it has been done in the past. The updated Umkehr retrievals will be validated against SAGE II ozone profiles as well as SSBUV ozone profile data. We will discuss possible reasons for offset between data and differences in derived ozone profile trends. Considerable variability of the ozone profile within the 10-degree latitude envelope creates noise in the SAGE matching dataset and makes comparisons difficult. To eliminate this problem, the SAGE and Umkehr data had been previously de-seasonalized by subtracting the latitude/season dependent ozone climatology. However, the remaining noise in the ozone residuals was still considerably high for trend analysis and was attributed to longitude variability of SAGE sampling. The new ozone climatology (Labow, NASA) that has longitude dependent ozone variability will be used to minimize contribution of sampling noise in comparisons of satellite and ground station. The comparison of zenith-sky radiances (Umkehr N-value measurements) synthesized for a given set of SAGE profiles will be used to determine whether SAGE-derived N-values agree with the Umkehr-measured N-values. The instrumental effects will be discussed. Both the Umkehr data and SAGE II measurements will be analyzed for their information about ozone variability and loss and recovery rates at the mid- and upper (40 km) levels. The updated long-term Umkehr dataset can be used to provide high quality information for identifying signs of ozone recovery. The long Umkehr historical record can provide additional information for separating the dynamic and chemical mechanisms of depletion, and can help the community better understand climate change effects.

Petropavlovskikh, I.↗

Advanced Life Systems for Extreme Environments: An Arctic Application

The problems of obtaining adequate pure drinking water and disposing of liquid and solid waste in the U.S. Arctic, a region where virtually all water is frozen solid for much of the year, has led to unsanitary solutions (U.S. Arctic Research Commission). These solutions are also damaging to the environment. Sanitation and a safe water supply are particularly problems in rural villages. About one-fourth of Alaska's 86.000 Native residents live in these communities. They are without running water and use plastic buckets for toilets. The outbreak of diseases is believed to be partially attributable to exposure to human waste. Villages with the most frequent outbreaks of disease are those in which running water is difficult to obtain (Office of Technology Assessment, 1994). Waste is emptied into open lagoons, rivers, or onto the sea coast. It does not degrade rapidly and in addition to affecting human health, can be harmful to the fragile ecology of the Arctic and the indigenous wildlife and fish populations. Advanced Life Systems for Extreme Environments (ALSEE) provides a solution to sanitation and safe water problems. The system uses an advanced integrated technology developed for Antarctic and space applications. ALSEE uses the systems approach to address more than waste and water problems. By incorporating hydroponic horticulture and aquaculture into the waste treatment system, ALSEE addresses the quality and quantity of fresh foods available to Arctic residents. A temperate climate is required for year-round plant growth. ALSEE facilities can be designed to include a climate controlled area within the structure. This type of environment is a change from the long periods of darkness and cold found in the Arctic and can help alleviate stress so often associated with these extremes. While the overall concept of ALSEE projects is advanced, system facilities can be operated by village residents with appropriate training. ALSEE provides continuing training and education as a part of the project. Not only is this desirable but necessary. There is ample evidence in "gravoyard" throughout rural Alaska of technologies which failed not because they were not applic4tble, but because they were not integrated and could not be operated or repaired by village residents. Waste streams in villages will vary depending on the human diet and the non-food waste stream. ALSEE units can be adapted to different village situations once the content of the waste stream is known. Units located in population hubs can serve as research, education. and demonstration centers. Appropriate modifications can be determined at these centers to transfer technology to more remote locations where waste stream conditions may differ.

Lewis, Carol E.↗

Premature Deaths in Africa Due to Particulate Matter Under High and Low Warming Scenarios

Sustainable development and climate change mitigation can provide enormous public health benefits via improved air quality, especially in polluted areas. We use the latest state-of-the-art composition-climate model simulations to contrast human exposure to fine particulate matter in Africa under a “baseline” scenario with high material consumption, population growth, and warming to that projected under a sustainability scenario with lower consumption, population growth, and warming. Evaluating the mortality impacts of these exposures, we find that under the low warming scenario annual premature deaths due to PM2.5 are reduced by roughly 515,000 by 2050 relative to the high warming scenario (100,000, 175,000, 55,000, 140,000, and 45,000 in Northern, West, Central, East, and Southern Africa, respectively). This reduction rises to ∼800,000 by the 2090s, though by that time much of the difference is attributable to the projected differences in population. By contrast, during the first half of the century benefits are driven predominantly by emissions changes. Depending on the region, we find large intermodel spreads of ∼25%–50% in projected future exposures owing to different physics across the ensemble of 6 global models. The spread of projected deaths attributable to exposure to fine particulate matter, including uncertainty in the exposure-response function, are reduced in every region to ∼20%–35% by the non-linear exposure-response function. Differences between the scenarios have an even narrower spread of ∼5%–25% and are highly statistically significant in all regions for all models. These results provide valuable information for policy-makers to consider when working toward climate change mitigation and sustainable development goals.

PM2.5↗

STS-113/11A: Assessment of Air Quality in the International Space Station (ISS) and Space Shuttle Based on Samples Returned in December 2002 and in May 2003 aboard Soyuz 5

The toxicological assessments of grab sample canisters (GSCs) returned aboard STS-l13 and Soyuz 5 are reported. Analytical methods have not changed from earlier reports. Surrogate standard recoveries from the GSCs were 79-120% except as noted in the table. One sample was returned with the valve opened. The two general criteria used to assess air quality are the total-non-methane-volatile organic hydrocarbons (NMVOCs) and the total T-value (minus the CO2 and formaldehyde contributions). Control of atmospheric alcohols is important to the water recovery system engineers, hence total alcohols (including acetone) are also shown for each sample. Octafluoropropane (OFP) has leaked from heat-exchange units in large quantities, so its concentration is tracked separately. Because formaldehyde is quantified from sorbent badges, its concentration is also listed separately. The table shows that the air quality in general was acceptable for crew respiration through the middle of December 2002. No conclusions can be made about the air quality after that date due to NASA's inability to return air samples from the ISS . Alcohols are not being controlled to the recently lowered guideline of 5 mg/m3, which was recommended to protect the water recovery systems. The airlock sample was taken during the regeneration of Met ox canisters in the adjacent Node. The trace pollutants were not increased above background; however, inspection of table 1 in the appendix shows a CO2 concentration of 17,000 mg/cu m, which is a relatively high concentration, but still below the 24-hour SMAC of23,000 mg/cu m. The control of OFP continues to be adequate at least through December 2002. Formaldehyde concentrations suggest that the high levels that were being found in the Lab atmosphere have subsided. This is probably attributable to the restoration of IMV in early February 2003 . Before the obstructing material was removed from ducts the Lab formaldehyde concentrations approached 0.06 mg/cu m, whereas after the repair the levels were near 0.04 mg/m3 . This does not mean that local sources in the Lab have been reduced, only that the excess of formaldehyde produced in the Lab is distributed into the whole volume of the ISS.

James, John T.↗

Transient nucleate pool boiling in microgravity: Some initial results

Variable gravity provides an opportunity to test the understanding of phenomena which are considered to depend on buoyancy, such as nucleate pool boiling. The active fundamental research in nucleate boiling has sought to determine the mechanisms or physical processes responsible for its high effectiveness, manifested by the high heat flux levels possible with relatively low temperature differences. Earlier research on nucleate pool boiling at high gravity levels under steady conditions demonstrated quantitatively that the heat transfer is degraded as the buoyancy normal to the heater surfaced increases. Correspondingly, it was later shown, qualitatively for short periods of time only, that nucleate boiling heat transfer is enhanced as the buoyancy normal to the heater surface is reduced. It can be deduced that nucleate pool boiling can be sustained as a quasi-steady process provided that some means is available to remove the vapor generated from the immediate vicinity of the heater surface. One of the objectives of the research, the initial results of which are presented here, is to quantify the heat transfer associated with boiling in microgravity. Some quantitative results of nucleate pool boiling in high quality microgravity (a/g approximately 10(exp -5)) of 5s duration, obtained in an evacuated drop tower, are presented here. These experiments were conducted as precursors of longer term space experiments. A transient heating technique is used, in which the heater surface is a transparent gold film sputtered on a qua rtz substrate, simultaneously providing the mean surface temperature from resistance thermometry and viewing of the boiling process both from beneath and across the surface. The measurement of the transient mean heater surface temperature permits the computation, by numerical means, of the transient mean heat transfer coefficient. The preliminary data obtained demonstrates that a quasi-steady boiling process can occur in microgravity if the bulk liquid subcooling is sufficiently high and if the imposed heat flux is sufficiently low. This is attributed to suface tension effects at the liquid-vapor-solid junction causing rewetting to take place, sustaining the nucleate boiling. Otherwise, dryout at the heater surface will occur, as observed.

Merte, Herman, Jr.↗

Thermal Properties of Lunar Regolith Simulants

Various high temperature chemical processes have been developed to extract oxygen and metals from lunar regolith. These processes are tested using terrestrial analogues of the regolith. But all practical terrestrial analogs contain H2O and/or OH(-), the presence of which has substantial impact on important system behaviors. We have undertaken studies of lunar regolith simulants to determine the limits of the simulants to validate key components for human survivability during sustained presence on the moon. Differential Thermal Analysis (DTA) yields information on phase transitions and melting temperatures. Themo-Gravimetric Analysis (TGA) with mass spectrometric (MS) determination of evolved gas species yields chemical information on various oxygenated volatiles (water, carbon dioxide, sulfur oxides, nitrogen oxides and phosphorus oxides) and their evolution temperature profiles. The DTA and TGAMS studies included JSC-1A fine, NU-LHT-2M and its proposed feed stocks: anorthosite; dunite; HQ (high quality) glass and the norite from which HQ glass is produced. Fig 1 is a data profile for anorthosite. The DTA (Fig 1a) indicates exothermic transitions at 355 and 490 C and endothermic transitions at 970 and 1235 C. Below the 355 C transition, water (Molecular Weight, MW, 18 in Fig 1c) is lost accounting for approximately 0.1% mass loss due to water removal (Fig 1b). Just above 490 C a second type of water is lost, presumably bound in lattices of secondary minerals. Between 490 and the 970 transition other volatile oxides are lost including those of hydrogen (third water type), carbon (MW = 44), sulfur (MW = 64 and 80), nitrogen (MW 30 and 46) and possibly phosphorus (MW = 79, 95 or 142). Peaks at MW = 35 and 19 may be attributable to loss of chlorine and fluorine respectively. Negative peaks in the NO (MW = 30) and oxygen (MW = 32) MS profiles may indicate the production of NO2 (MW = 46). Because so many compounds are volatilized in this temperature range quantification of the mass loss associated with individual species is difficult. Similar information will be presented for the other materials studied in this investigation.

Street, Kenneth↗

Thermal Properties of Lunar Regolith Simulants

Various high temperature chemical processes have been developed to extract oxygen and metals from lunar regolith. These processes are tested using terrestrial analogues of the regolith. But all practical terrestrial analogs contain H2O and/or OH-, the presence of which has substantial impact on important system behaviors. We have undertaken studies of lunar regolith simulants to determine the limits of the simulants to validate key components for human survivability during sustained presence on the moon. Differential Thermal Analysis (DTA) yields information on phase transitions and melting temperatures. Themo-Gravimetric Analysis (TGA) with mass spectrometric (MS) determination of evolved gas species yields chemical information on various oxygenated volatiles (water, carbon dioxide, sulfur oxides, nitrogen oxides and phosphorus oxides) and their evolution temperature profiles. The DTA and TGAMS studies included JSC-1A fine, NU-LHT-2M and its proposed feed stocks: anorthosite; dunite; HQ (high quality) glass and the norite from which HQ glass is produced. Fig 1 is a data profile for anorthosite. The DTA (Fig 1a) indicates exothermic transitions at 355 and 490 C and endothermic transitions at 970 and 1235 C. Below the 355 C transition, water (Molecular Weight, MW, 18 in Fig 1c) is lost accounting for approximately 0.1% mass loss due to water removal (Fig 1b). Just above 490 C a second type of water is lost, presumably bound in lattices of secondary minerals. Between 490 and the 970 transition other volatile oxides are lost including those of hydrogen (third water type), carbon (MW = 44), sulfur (MW = 64 and 80), nitrogen (MW 30 and 46) and possibly phosphorus (MW = 79, 95 or 142). Peaks at MW = 35 and 19 may be attributable to loss of chlorine and fluorine respectively. Negative peaks in the NO (MW = 30) and oxygen (MW = 32) MS profiles may indicate the production of NO2 (MW = 46). Because so many compounds are volatilized in this temperature range quantification of the mass loss associated with individual species is difficult. Similar information will be presented for the other materials studied in this investigation.

Street, Kenneth↗

Correction Technique for Raman Water Vapor Lidar Signal-Dependent Bias and Suitability for Water Wapor Trend Monitoring in the Upper Troposphere

The MOHAVE-2009 campaign brought together diverse instrumentation for measuring atmospheric water vapor. We report on the participation of the ALVICE (Atmospheric Laboratory for Validation, Interagency Collaboration and Education) mobile laboratory in the MOHAVE-2009 campaign. In appendices we also report on the performance of the corrected Vaisala RS92 radiosonde measurements during the campaign, on a new radiosonde based calibration algorithm that reduces the influence of atmospheric variability on the derived calibration constant, and on other results of the ALVICE deployment. The MOHAVE-2009 campaign permitted the Raman lidar systems participating to discover and address measurement biases in the upper troposphere and lower stratosphere. The ALVICE lidar system was found to possess a wet bias which was attributed to fluorescence of insect material that was deposited on the telescope early in the mission. Other sources of wet biases are discussed and data from other Raman lidar systems are investigated, revealing that wet biases in upper tropospheric (UT) and lower stratospheric (LS) water vapor measurements appear to be quite common in Raman lidar systems. Lower stratospheric climatology of water vapor is investigated both as a means to check for the existence of these wet biases in Raman lidar data and as a source of correction for the bias. A correction technique is derived and applied to the ALVICE lidar water vapor profiles. Good agreement is found between corrected ALVICE lidar measurments and those of RS92, frost point hygrometer and total column water. The correction is offered as a general method to both quality control Raman water vapor lidar data and to correct those data that have signal-dependent bias. The influence of the correction is shown to be small at regions in the upper troposphere where recent work indicates detection of trends in atmospheric water vapor may be most robust. The correction shown here holds promise for permitting useful upper tropospheric water vapor profiles to be consistently measured by Raman lidar within NDACC (Network for the Detection of Atmospheric Composition Change) and elsewhere, despite the prevalence of instrumental and atmospheric effects that can contaminate the very low signal to noise measurements in the UT.

MOHAVE-2009↗