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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Dilution Jet Experiments in Compact Combustor Configurations

The effects of cooling jets on the velocity and temperature fields in a compact reverse flow combustion are discussed. The work is motivated by the need to limit the temperature of past-combustion gases in jet engines to values within the endurance capabilities of turbine blades. The application requires not only that the temperature be kept sufficiently low but also that a suitably tailored temperature profile be provided at the combustor exit, with higher temperatures generally permissible at the blade tip than at the blade root because of higher centrifugal loads at the root. A single jet. As spacing is reduced, jet penetration is also reduced, and the cooling jets tend to remain close to the wall from which they are injected. Results suggest that cooling and temperature distribution tailoring can be accomplished without injecting cooling jets upstream of the turn, and thus it appears that combustors can be made smaller than current designs.

Greber, I.↗

Mechanisms of electromagnetic field control on mineral scaling in brackish water reverse osmosis: Combined homogenous and heterogeneous nucleation

Electromagnetic field (EMF) treatment has emerged as a promising approach for scaling control due to its cost-effectiveness, simplicity, and low energy consumption. However, there is a limited understanding of the mechanisms by which applied EMF impacts mineral scaling in reverse osmosis (RO) systems. This has led to inconclusive and varied results and uncertainties regarding its effectiveness. This study elucidates the impacts of EMF on homogenous and heterogeneous nucleation and membrane performance during RO desalination of different feedwaters. Our results reveal that EMF exhibits greater efficacy in treating near-saturated water (SI∼0), especially when coupled with extended hydraulic flushing (HF). For saturated brackish water desalination, heterogeneous scaling predominantly occurs on membrane surfaces, with the effectiveness of EMF in inhibiting scaling primarily attributed to the hydration effect. In supersaturated solutions, EMF promotes bulk precipitation due to the magnetohydrodynamic effect, quickly blocking membrane pores. Thus, when the saturation reaches a certain high level during RO desalination, magnetohydrodynamic EMF effects can accelerate flux decline caused by homogeneous scaling. In conclusion, this work provides an efficient method for predicting EMF efficiency, emphasizing the importance of saturation conditions and HF cleaning duration in determining membrane performance, suggesting these show promise for improving undersaturated or near-saturated feedwater desalination via RO.

42 ENGINEERING↗

Revealing the Defect‐Driven Ferroelectric Mechanisms of Aluminum Nitride

Wurtzite III-nitride compounds are CMOS-compatible with widespread industrial interest to exercise ferroelectricity, despite their polar structure being highly resistant to polarization reversal. Here, we induce and tune ferroelectric properties in w-AlN via direct-write ion-beam processing, using nanoscale patterned defect engineering as a post-growth alternative to conventional cation substitution. Nanometric piezoresponse spectroscopy of the focused He + beam patterned defect concentrations in ferroelectric Al 0.92 B 0.08 N measures a localized 10x enhancement in effective piezoresponse and 40% reduction in switching barrier. The irradiation-induced point defects convert piezoelectric AlN into a ferroelectric system with site-saturated nucleation and raise the dielectric susceptibility, switched polarization, and effective piezoelectric coefficient. Enhanced defect-lattice interactions in AlN increase carrier conduction and phonon scattering loss but preserve long-range crystallinity. Here, based on atomistic analysis of nudged elastic band density functional theory calculations and reactive force field simulations, both nitrogen vacancies and defect complexes disrupt bond ordering, facilitating a line-by-line low-barrier switching of pristine AlN.

36 MATERIALS SCIENCE↗

Wind tunnel tests of a 20 inch diameter 1.15 pressure ratio fan engine model

Aerodynamic and acoustic measurements at a typical STOL aircraft takeoff and landing velocity demonstrated that a 1.35 inlet lip area contraction ratio was superior to a 1.26 ratio at high nacelle incidence angles. Reverse thrust, obtained with a variable pitch rotor, was lower at the landing velocity, and the noise level higher, than at the static condition. High speed tests showed that, for the design cruise Mach number of 0.75, internal losses and external drag were 27 percent of the ideal fan net thrust, and propulsive efficiency was estimated to be 59 percent for an 85 percent efficient fan stage.

Wesoky, H. L.↗

Wind tunnel tests of a 20 inch diameter 1.15 pressure ratio fan engine model

Aerodynamic and acoustic measurements at a typical STOL aircraft takeoff and landing velocity demonstrated that a 1.35 inlet lip area contraction ratio was superior to a 1.26 ratio at high nacelle incidence angles. Reverse thrust, obtained with a variable pitch rotor, was lower at the landing velocity, and the noise level higher, than at the static condition. High speed tests showed that, for the design cruise Mach number of 0.75, internal losses and external drag were 27 per cent of the ideal fan net thrust, and propulsive efficiency was estimated to be 59 per cent for an 85 per cent efficient fan stage. For comparison, a similar 1.55 pressure ratio fan system would have a propulsive efficiency of 62 per cent.

Wesoky, H. L.↗

The Prediction Properties of Inverse and Reverse Regression for the Simple Linear Calibration Problem

The calibration of measurement systems is a fundamental but under-studied problem within industrial statistics. The origins of this problem go back to basic chemical analysis based on NIST standards. In today's world these issues extend to mechanical, electrical, and materials engineering. Often, these new scenarios do not provide "gold standards" such as the standard weights provided by NIST. This paper considers the classic "forward regression followed by inverse regression" approach. In this approach the initial experiment treats the "standards" as the regressor and the observed values as the response to calibrate the instrument. The analyst then must invert the resulting regression model in order to use the instrument to make actual measurements in practice. This paper compares this classical approach to "reverse regression," which treats the standards as the response and the observed measurements as the regressor in the calibration experiment. Such an approach is intuitively appealing because it avoids the need for the inverse regression. However, it also violates some of the basic regression assumptions.

Parker, Peter A.↗

Kinetic Control over Disproportionation Stabilizes Wurster’s Blue Catholyte for Nonaqueous Redox Flow Batteries

Redoxmers are organic molecules that serve as charge carriers in redox flow batteries. While these materials are affordable and easy to source, insufficient stability of their charged states (radical ions) remains a challenge. A common reaction of these species is their disproportionation. Furthermore, this reversible reaction yields unstable multiply charged states, shifting the overall charge transfer equilibrium toward the decomposition products. Here we show how kinetic controls can be engineered into a redoxmer molecule to suppress these unwanted charge transfer reactions. This approach is used to transform Wurster's blue, which is historically the first example of a stable radical ion in organic chemistry, into an exceptionally durable redoxmer molecule that persists over thousands of electrochemical cycles.

Cations↗

Domain-wall-mediated polarization switching in ferroelectric AlScN: Strain relief and field-dependent dynamics

While scandium-doped aluminum nitride (AlScN) exhibits robust ferroelectricity and excellent thermal stability, its utility is limited by an exceptionally high coercive field (𝐸 𝑐 ) for polarization switching. Unraveling the atomistic switching dynamics is therefore critical for tailoring 𝐸 𝑐 . Here, in this study, we combine density functional theory and machine-learning molecular dynamics to elucidate the polarization switching mechanisms in AlScN over various Sc concentrations and applied electric fields. We find that excessive lattice strain strictly prohibits collective polarization switching, but the preexisting domain walls relieve strain and lead to a distinct switching dynamics—dictating a field-dependent switching mechanism. At low electric fields, switching occurs via gradual domain-wall propagation consistent with the Kolmogorov-Avrami-Ishibashi model. In contrast, high fields stimulate additional nucleation, driving a rapid, homogeneous reversal process described by the simultaneous nonlinear nucleation and growth model. These findings highlight the critical role of domain-wall dynamics and suggest domain engineering as a viable strategy to tailor coercive fields in AlScN and related ferroelectrics.

36 MATERIALS SCIENCE↗

Small gas turbine combustor experimental study: Compliant metal/ceramic liner and performance evaluation

Combustor research relating to the development of fuel efficient small gas turbine engines capable of meeting future commercial and military aviation needs is currently underway at NASA Lewis. As part of this combustor research, a basic reverse-flow combustor has been used to investigate advanced liner wall cooling techniques. Liner temperature, performance, and exhaust emissions of the experimental combustor utilizing compliant metal/ceramic liners were determined and compared with three previously reported combustors that featured: (1) splash film-cooled liner walls; (2) transpiration cooled liner walls; and (3) counter-flow film cooled panels.

Acosta, W. A.↗

Small gas turbine combustor experimental study - Compliant metal/ceramic liner and performance evaluation

Combustor research relating to the development of fuel efficient small gas turbine engines capable of meeting future commercial and military aviation needs is currently underway at NASA Lewis. As part of this combustor research, a basic reverse-flow combustor has been used to investigate advanced liner wall cooling techniques. Liner temperature, performance, and exhaust emissions of the experimental combustor utilizing compliant metal/ceramic liners were determined and compared with three previously reported combustors that featured: (1)splash film-cooled liner walls; (2) transpiration cooled liner walls; and (3) counter-flow film cooled panels.

Acosta, W. A.↗

Excitation of slosh waves associated with low frequency impulsive reverse gravity acceleration of geyser initiation

The objective of the cryogenic fluid management of the spacecraft propulsion system is to develop the technology necessary for acquisition or positioning of liquid and vapor within a tank in reduced gravity to enable liquid outflow or vapor venting. The requirement to settle or to position liquid fuel over the outlet end of the spacecraft propellant tank prior to main engine restart poses a microgravity fluid behavior problem. The purpose of the present study is to investigate the stability of the most efficient technique for propellant resettling through the minimization of propellant usage and weight penalties. In this study slosh wave excitation induced by the resettling flow field activated by 0.1 Hz low frequency, impulsive reverse gravity acceleration, during reorientation with the initiation of geyser for liquid fill levels of 30, 50, 65, 70 and 80 percent, have been studied. Characteristics of slosh waves with various frequencies excited are discussed. Slosh wave excitation shift the fluid mass distribution in the container which impose time dependent variations in spacecraft moment of inertia. This information is important for the spacecraft control during the course of liquid reorientation.

Hung, R. J.↗

Cryogenic Cooling for Myriad Applications-A STAR Is Born

Cryogenics, the science of generating extremely low temperatures, has wide applicability throughout NASA. The Agency employs cryogenics for rocket propulsion, high-pressure gas supply, breathable air in space, life support equipment, electricity, water, food preservation and packaging, medicine, imaging devices, and electronics. Cryogenic liquid oxygen and liquid hydrogen systems are also replacing solid rocket motor propulsion systems in most of the proposed launch systems, a reversion to old-style liquid propellants. In the late 1980s, NASA wanted a compact linear alternator/motor with reduced size and mass, as well as high efficiency, that had unlimited service life for use in a thermally driven power generator for space power applications. Prior development work with free-piston Stirling converters (a Stirling engine integrated with a linear actuator that produces electrical power output) had shown the promise of that technology for high-power space applications. A dual use for terrestrial applications exists for compact Stirling converters for onsite combined heat and power units. The Stirling cycle is also usable in reverse as a refrigeration cycle suitable for cryogenic cooling, so this Stirling converter work promised double benefits as well as dual uses. The uses for cryogenic coolers within NASA abound; commercial applications are similarly wide-ranging, from cooling liquid oxygen and nitrogen, to cryobiology and bio-storage, cryosurgery, instrument and detector cooling, semiconductor manufacturing, and support service for cooled superconducting power systems.

Source record↗

Propellant-Flow-Actuated Rocket Engine Igniter

A rocket engine igniter has been created that uses a pneumatically driven hammer that, by specialized geometry, is induced into an oscillatory state that can be used to either repeatedly impact a piezoelectric crystal with sufficient force to generate a spark capable of initiating combustion, or can be used with any other system capable of generating a spark from direct oscillatory motion. This innovation uses the energy of flowing gaseous propellant, which by means of pressure differentials and kinetic motion, causes a hammer object to oscillate. The concept works by mass flows being induced through orifices on both sides of a cylindrical tube with one or more vent paths. As the mass flow enters the chamber, the pressure differential is caused because the hammer object is supplied with flow on one side and the other side is opened with access to the vent path. The object then crosses the vent opening and begins to slow because the pressure differential across the ball reverses due to the geometry in the tube. Eventually, the object stops because of the increasing pressure differential on the object until all of the kinetic energy has been transferred to the gas via compression. This is the point where the object reverses direction because of the pressure differential. This behavior excites a piezoelectric crystal via direct impact from the hammer object. The hammer strikes a piezoelectric crystal, then reverses direction, and the resultant high voltage created from the crystal is transferred via an electrode to a spark gap in the ignition zone, thereby providing a spark to ignite the engine. Magnets, or other retention methods, might be employed to favorably position the hammer object prior to start, but are not necessary to maintain the oscillatory behavior. Various manifestations of the igniter have been developed and tested to improve device efficiency, and some improved designs are capable of operation at gas flow rates of a fraction of a gram per second (0.001 lb/s) and pressure drops on the order of 30 to 50 kilopascal (a few psi). An analytical model has been created and tested in conjunction with a precisely calibrated reference model. The analytical model accurately captures the overall behavior of this innovation. The model is a simple "volume-orifice" concept, with each chamber considered a single temperature and pressure "node" connected to adjacent nodes, or to vent paths through flow control orifices. Mass and energy balances are applied to each node, with gas flow predicted using simple compressible flow equations.

Wollen, Mark↗

Synergistic Combination of Living Ring-Opening Metathesis Polymerization and Atom Transfer Radical Polymerization to Synthesize Structurally Tailored and Engineered Macromolecular Networks

Structurally tailored and engineered macromolecular (STEM) networks are attractive materials for soft robotics, stretchable electronics, tissue engineering, and 3D printing due to their tunable properties. To date, STEM networks have been synthesized by atom transfer radical polymerization (ATRP) or the combination of reversible addition–fragmentation chain-transfer (RAFT) polymerization and ATRP. RAFT polymerization could have limited selectivity with ATRP inimer sites that can participate in radical-transfer processes. On the other hand, living ring-opening metathesis polymerization (ROMP) can produce a polymeric network with latent ATRP initiator sites in high selectivity. Herein, for the first time, we report the syntheses of STEM zero-generation (STEM-0) networks using a monomer, a cross-linker, and an ATRP/ROMP inimer via living ROMP, followed by their modification using a second monomer via ATRP to synthesize STEM first-generation (STEM-1) networks. The mechanical property and swelling capacity analyses of these networks were carried out. A change in mechanical properties and swelling capacity of these networks was observed due to their structural modification.

Absorption↗

In situ atomic-resolution imaging of water vapor–driven multistep oxidation dynamics in strontium cobaltite

Understanding how water vapor interacts with transition metal oxides (TMOs) is critical for tailoring material properties to improve performance and enable new technologies. Despite extensive research efforts, atomic-scale mechanisms underpinning dynamic reactions and reaction-induced phase transitions remain elusive. Here, we use in situ environmental transmission electron microscopy to investigate how water vapor oxidizes vacancy-ordered SrCoO 2.5 at moderately elevated temperatures, demonstrating that water molecules can initiate oxidation more effectively than oxygen under comparable conditions. We discover a distinct “staging” behavior during the oxidation process: A fully ordered intermediate phase, SrCoO 2.75 , forms before transitioning into a near-perovskite SrCoO 3−δ . In addition, antiphase boundaries, originating at step terraces of SrTiO 3 , alleviate strain by creating reversible nanoscale “gaps” during lattice contraction under oxidation, providing a pathway for preserving structural integrity throughout redox cycling. This work provides atomic-level guidance for engineering TMOs by leveraging water vapor to control their redox behavior and tailor functional properties.

Science & Technology - Other Topics↗

The influence of engine/transmission/governor on tilting proprotor aircraft dynamics

An analytical model is developed for the dynamics of a tilting proprotor aircraft engine and drive train, including a rotor speed governor and interconnect shaft. The dynamic stability of a proprotor and cantilever wing is calculated, including the engine-transmission-governor model. It is concluded that the rotor behaves much as if windmilling as far as its dynamic behavior is concerned, with some influence of the turboshaft engine inertia and damping. The interconnect shaft has a significant influence on the antisymmetric dynamics of proprotor aircraft. The proprotor aerodynamics model is extended to include reverse flow, and a refinement on the method used to calculate the kinematic pitch-bending coupling of the blade is developed.

Johnson, W.↗