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At least 343 records · Page 19

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NASA NTRS1988

Planetary Fabry-Perot spectroscopy

Application of high spectral resolution, Earth-based Fabry-Perot spectroscopy to the study of planetary atmospheres, for which current topics are outer planet HD and H2 spectra (atmospheric structure, D/H ratio), Mars CO2, CO, O2, and H2O spectra (atomspheric photochemistry), Venus H2O and HDO, associated laboratory spectroscopy (especially H2 overtone bands, HDO) was accomplished. Monochromatic charge coupled device (CCD) imaging photometry of the Jovian nebula, with images taken in rapid sequence among the diagnostic spectral lines of ionized sulfur species, provided self-supporting snapshots of the Jupiter/Io plasma conditions (spatially resolved electron and ion densities and temperatures), covering the post-Voyager period from 1981 and leading up to the Galileo tour in the early 1990s. High spectral resolution Fabry-Perot/charge coupled device (CCD) imaging of comets (OI, CI, and H2O(+) velocity maps and spatial distriubtions), and Io's charge exchanged neutral jet was studied.

Trauger, J. T.↗

NASA NTRS1988

The ATMOS (Atmospheric Trace Molecule Spectroscopy) experiment - An overview

The objective of the ATMOS experiment is to measure the concentrations and distributions of gases in the middle and upper atmosphere (10 to 120 km) by IR absorption spectroscopy. In 1985 high resolution (0.01/cm) IR occultation spectra of the atmosphere were recorded using a modified Michelson interferometer orbiting onboard the Space Shuttle. With the sun as the radiation source, a single spectrum was obtained every 2.2 seconds with S/N ratios of 100:1 or better. An overview of the data analysis techniques, implications for malecular spectroscopy, and results obtained from the mission is presented.

Brown, L. R.↗

NASA NTRS1990

Terrestrial-Imaging Spectroscopy

Report reviews history and state of art of terrestrial imaging spectroscopy. Discusses history, design, and performance of Airborne Imaging Spectrometer (AIS), which is pioneering sensor for terrestrial high-resolution remote sensing. Also discusses recent developments described in literature of imaging spectroscopy from three points of view: techniques for handling and analysis of spectral-image data, geological research, and botanical research. This field encompasses use of airborne and spaceborne imaging spectrometers to generate specialized maps for use in agriculture, geology, ecology, and related disciplines.

Vane, Gregg A.↗

NASA NTRS1990

Positron annihilation induced Auger electron spectroscopy

Recently, Weiss et al. have demonstrated that it is possible to excite Auger transitions by annihilating core electrons using a low energy (less than 30eV) beam of positrons. This mechanism makes possible a new electron spectroscopy, Positron annihilation induced Auger Electron Spectroscopy (PAES). The probability of exciting an Auger transition is proportional to the overlap of the positron wavefunction with atomic core levels. Since the Auger electron energy provides a signature of the atomic species making the transition, PAES makes it possible to determine the overlap of the positron wavefunction with a particular element. PAES may therefore provide a means of detecting positron-atom complexes. Measurements of PAES intensities from clean and adsorbate covered Cu surfaces are presented which indicate that approx. 5 percent of positrons injected into CU at 25eV produce core annihilations that result in Auger transitions.

Weiss, Alex↗

NASA NTRS1990

Monitoring of catalyst performance in CO2 lasers using frequency modulation spectroscopy with diode lasers

Closed-cycle CO2 laser operation with removal of O2 and regeneration of CO2 can be achieved by catalytic CO-O2 recombination. Both parametric studies of the optimum catalyst formulation and long-term performance tests require on line monitoring of CO, O2 and CO2 concentrations. There are several existing methods for molecular oxygen detection. These methods are either intrusive (such as electrochemical method or mass spectrometry) or very expensive (such as CARS, UV laser absorption). Researchers demonstrated a high-sensitivity spectroscopic measurement of O2 using the two-tone frequency modulation spectroscopy (FMS) technique with a near infrared GaAlAs diode laser. Besides its inexpensive cost, fast response time, nonintrusive measurements and high sensitivity, this technique may also be used to differentiate between isotopes due to its high spectroscopic resolution. This frequency modulation spectroscopy technique could also be applied for the on-line monitoring of CO and CO2 using InGaAsP diode lasers operation in the 1.55 microns region and H2O in the 1.3 microns region. The existence of single mode optical fibers at the near infrared region makes it possible to combine FMS with optical fiber technology. Optical fiber FMS is particularly suitable for making point-measurements at one or more locations in the CO2 laser/catalyst system.

Wang, Liang-Guo↗

NASA NTRS1989

Characterization of the surfaces of platinum/tin oxide based catalysts by Fourier transform spectroscopy (FTIR)

The Laser Atmospheric Wind Sounder (LAWS) Program has as one of its goals the development of a satellite based carbon dioxide laser for making wind velocity measurements. The specifications for this laser include the requirement that the laser operate at a repetition rate of 10 Hertz continuously for three years. Earth-based carbon dioxide lasers can operate for only a short time on a single charge of gas because the lasing action causes the CO2 to break down into CO and O2. Therefore, earth-based CO2 lasers are generally operated in a flow through mode in which the spent gas is continually exhausted and fresh gas is continually added. For a satellite based system, however, a recirculation system is desired because it is not practical to send up extra tanks of CO2. A catalyst which could enable a recirculating CO2 laser to function continuously for three years needs to be developed. In the development of a catalyst system there are many variables. Obviously, not all possible formulations can be tested for three years, therefore, an accurate model which is based on the reaction mechanism is needed. The construction of a multistep reaction mechanism is similar to the construction of a jigsaw puzzle. Different techniques each supply a piece of the puzzle and the researcher must put the pieces together. Transmission infrared spectroscopy was shown to be very useful in supplying some of the information needed to elucidate reaction mechanisms. The purpose was to see what kind of information might be obtained about the NASA catalyst using infrared absorption spectroscopy. Approximately 200 infrared spectra of the prototype Pt/tin oxide catalyst and its precursor components are observed under a variety of different conditions. The most significant observations are summarized.

Keiser, Joseph T.↗

NASA NTRS1990

High resolution spectroscopy in the microwave and far infrared

High resolution rotational spectroscopy has long been central to remote sensing techniques in atmospheric sciences and astronomy. As such, laboratory measurements must supply the required data to make direct interpretation of data for instruments which sense atmospheres using rotational spectra. Spectral measurements in the microwave and far infrared regions are also very powerful tools when combined with infrared measurements for characterizing the rotational structure of vibrational spectra. In the past decade new techniques were developed which have pushed high resolution spectroscopy into the wavelength region between 25 micrometers and 2 mm. Techniques to be described include: (1) harmonic generation of microwave sources, (2) infrared laser difference frequency generation, (3) laser sideband generation, and (4) ultrahigh resolution interferometers.

Pickett, Herbert M.↗

NASA NTRS1990

Electron-impact spectroscopy

The methods of electron impact spectroscopy and cross section measurements are discussed and compared to optical spectroscopy. A brief summary of the status of this field and the available data is given.

Trajmar, S.↗

NASA NTRS1989

Optical fringe reduction technique for FM laser spectroscopy

A simple fringe reduction method for FM diode laser spectroscopy is discussed. The fringes can be effectively suppressed by using a modulation frequency that is an integral multiple of the free spectral range of the fringes. The technique is experimentally confirmed by two-tone FM spectroscopy of water vapor absorption lines. A factor of 20 fringe reduction is observed.

Chou, Nee-Yin↗

NASA NTRS1988

Wavelength-precise slit spectroscopy with optical fiber image scramblers

The application of optical-fiber image scramblers in wavelength-precise slit spectroscopy is discussed together with the design strategy for the optimal instrument configuration incorporating an optical-fiber image scrambler. Particular attention is given to the aspects of data analysis and interpretation techniques which must be specially designed for high-precision spectroscopy. In a specific application to an existing coude spectrograph, the instrumentation and data reduction techniques described in this paper demonstrate an achievable precision corresponding to a systematic radial velocity error of about 30 m/sec.

Heacox, William D.↗

NASA NTRS1990

Uses of Auger and x ray photoelectron spectroscopy in the study of adhesion and friction

Three studies are described characterizing the possible contributions of surface science to tribology. These include surface contamination formed by the interaction of a surface with the environment, contaminants obtained with diffusion of compounds, and surface chemical changes resulting from selective thermal evaporation. Surface analytical tools such as Auger electron spectroscopy (AES) and x ray photoelectron spectroscopy (XPS) incorporated directly into adhesion and friction systems are primarily used to define the nature of tribological surfaces before and after tribological experimentation and to characterize the mechanism of solid-to-solid interaction. Emphasis is on fundamental studies involving the role of surfaces in controlling the adhesion and friction properties of materials emerging as a result of the surface analyses. The materials which were studied include metals and ceramics such as elemental metals, amorphous alloys (metallic glasses), and silicon-based ceramics.

Miyoshi, Kazuhisa↗

NASA NTRS1991

Reflectance spectroscopy of palagonite and iron-rich montmorillonite clay mixtures: Implications for the surface composition of Mars

Because of the power of remote sensing reflectance spectroscopy in determining mineralogy, it was used as the major method of identifying possible mineral analogs of the Martian surface. A summary of proposed Martian surface compositions from reflectance spectroscopy before 1979 was presented. Since that time, iron-rich montmorillonite clay, nanocrystalline or nanophase hematite, and palagonite were suggested as Mars soil analog materials.

Orenberg, J. B.↗

NASA NTRS1991

Preliminary results of imaging spectroscopy of the Humorum Basin region of the moon

Imaging spectroscopy of the lunar surface was carried out using a CCD spectrograph employed as an imaging spectrometer at the University of Hawaii 2.24-m telescope at Mauna Kea Observatory. A portion of the Humorum multiringed impact basin was observed, yielding an imaging spectroscopic dataset consisting of approximately 400,000 spectra covering the wavelength region 0.7-0.98 microns at a spectral resolution of 200 (lambda/Delta-lambda). Results of this analysis included (1) identifying craters and other explosures of highland material within the bounds of Mare Humorum, (2) identifying craters in the highlands adjacents to Mare Humorum that excavate buried mare basalt, and (3) identifying two spectral units in the highlands that likely represent compositional units. The region is shown to be extremely diverse spectrally and demonstrates the ability of imaging spectroscopy to enable a qualitative improvement in the ability to identify and map compositional units.

Lucey, P. G.↗

NASA NTRS1990

The goals of gamma-ray spectroscopy in high energy astrophysics

The use of high resolution gamma-ray spectroscopy in astrophysics is discussed with specific attention given to the application of the Nuclear Astrophysics Explorer (NAE). The gamma-ray lines from nuclear transitions in radionucleic decay and positron annihilation permits the study of current sites, rates and models of nucleosynthesis, and galactic structure. Diffuse galactic emission is discussed, and the high-resolution observations of gamma-ray lines from discrete sites are also described. Interstellar mixing and elemental abundances can also be inferred from high-resolution gamma-ray spectroscopy of nucleosynthetic products. Compact objects can also be examined by means of gamma-ray emissions, allowing better understanding of neutron stars and the accreting black hole near the galactic center. Solar physics can also be investigated by examining such features as solar-flare particle acceleration and atmospheric abundances.

Lingenfelter, Richard E.↗

NASA NTRS1991

Theory of the resonance line shape in velocity-modulation spectroscopy

Velocity-modulation spectroscopy is often used to obtain absorption spectra of ions in discharges. However, there have been few studies of the line shape. The resonance line shape in velocity-modulation spectroscopy is derived in the present work. Both sinusoidal modulation and square-wave modulation are treated, and the differences in the resulting line shapes are emphasized. The results are relevant to measurements of ion mobilities, resolved with respect to the internal state of the ion.

Farley, John W.↗

NASA NTRS1992

Liquid-Arc/Spark-Excitation Atomic-Emission Spectroscopy

Constituents of solutions identified in situ. Liquid-arc/spark-excitation atomic-emission spectroscopy (LAES) is experimental variant of atomic-emission spectroscopy in which electric arc or spark established in liquid and spectrum of light from arc or spark analyzed to identify chemical elements in liquid. Observations encourage development of LAES equipment for online monitoring of process streams in such industries as metal plating, electronics, and steel, and for online monitoring of streams affecting environment.

Schlagen, Kenneth J.↗

NASA NTRS1992

BATSE spectroscopy analysis system

The Burst and Transient Source Experiment (BATSE) Spectroscopy Analysis System (BSAS) is the software system which is the primary tool for the analysis of spectral data from BATSE. As such, Guest Investigators and the community as a whole need to know its basic properties and characteristics. Described here are the characteristics of the BATSE spectroscopy detectors and the BSAS.

Schaefer, Bradley E.↗

NASA NTRS1992

How well is Martian ozone inferred with reflectance spectroscopy?

The Mariner 9 UV spectrometer scanned from 2100 to 3500 Angstroms in one of its two spectral channels every 3 seconds with a spectral resolution of 15 Angstroms and an effective field-of-view of approximately 300 km(exp 2). The only gaseous absorption in the 2000 to 3000 Angstrom region was assumed to come from the Hartley band system of ozone, and therefore the amount of ozone was inferred by fitting this absorption feature with laboratory data of ozone absorption. Mars O3 as inferred from these spectra shows strong seasonal and latitudinal variation, with column abundances ranging from 0.2 microns at equatorial latitudes to 60 microns over the northern winter polar latitudes. The detectability limit of the spectrometer was approximately 3 microns. I use a radiative transfer model based on the discrete ordinate method to calculate synthetic radiance spectra. When typical amounts of dust and cloud are present, significant underestimation of O3 occurs. A factor of 3 times as much O3 is needed to generate the same spectrum for cloudy, dusty atmospheres as for a clear atmosphere. If the scattering properties of Martian clouds and dust were well known, then their appearance would not be a problem, as a model would be capable of retrieving the O3 abundance. However, these properties are not well known, which raises doubts about the effectiveness of the current UV spectroscopy technique used to measure O3. Spatial and temporal variability in temperature and water vapor have been claimed to account for the scatter of the data points. However, water vapor is a small source of odd hydrogen in the winter polar atmosphere, and may not account for most of the variability. Masking by clouds and dust may also account for some of the observed O3 variability, because the nature and opacity of the clouds and dust in the polar hood change dramatically in latitude and even on a day-to-day basis. As the maximum O3 abundance resides near the surface, spacecraft must be able to observe through the entire cloud and dust abundance in order to actually see the total O3 column abundance. If reflectance spectroscopy is used, as on Mariner 9, then the cloud and the airborne dust must be traversed twice; first by the incoming solar flux down to the surface, and then once again upon reflection from the surface out to the spacecraft.

Lindner, Bernhard Lee↗