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At least 343 records · Page 19

Photochemical fractionation of O-16 in the space medium modeled by resonance excitation of CO by H-Lyman alpha

Analyses of meteorite matter, the present structure of the solar system, and the evolution of matter in stellar systems are used to provide inferences concerning the formation of primordial matter in the solar system. Results indicate that molecular excitation processes similar to those observed today in circumstellar regions and dark interstellar clouds were operating in the early solar nebula. It is suggested that resonance excitation of broad isotopic bands by strong UV line sources may have resulted in the anomalous isotopic compositions noted in meteorites.

Arrhenius, G.↗

Which stars have planets?

The question of predicting which stars have planetary systems is discussed, with special attention given to the work of Nakano (1988), who combined scaling arguments with his theory (Nakano, 1987) of formation of planets in the solar system to estimate planetary growth rates around stars of various masses. It is argued that, in addition to stellar mass, the process of planet formation depends on other parameters, such as angular momentum and collisions. The existence of binary and multiple star systems of varying type demonstrates that angular momentum variations can play a crucial role, while the fact that the solar system has four giant planets and four terrestrial planets is considered to be due to the effects of random impacts and scatterings. It is concluded that, at present, the concept of determining what types of planetary systems are to be expected about stars of varying masses cannot be resolved.

Lissauer, J. J.↗

Observations of comets and asteroids

All available ground-based observational techniques are used to study the chemical and physical properties of the small bodies of the solar system, primarily comets and secondarily asteroids. The ultimate goal is to use these bodies to understand the formation and evolution of the solar system. The analysis of charge coupled device (CCD) images of comet P/Halley continued. This included a mojor revision of a paper on the periodicities of CN jets in Halley showing that their periodicity is 7.3 days, not 2.2 days. It also included an analysis of the continuum images which showed that the dust in jets is much redder than in the ambient coma. Calculations with Mie theory suggest that the particles that show the strongest effects of radiation pressure. Much effort was expended devising methods to estimate the level of sky background of the many images in which comet extends to the edge of the chip. Examined images of comet Wilson were taken over many months in 1987. Wilson, a dynamically new comet, shows none of the short-term variability or jet structure (either dusty jets or jets of radicals seen in Halley. This is presumably due to the lack of a mantle or the nucleus. Median-imaging of sky was as a technique for removing residual flat-fielding errors in CCD images. A Monte Carlo model and a convolution model were developed for studying temporal variability of gaseous daughter products.

Ahearn, Michael F.↗

Observations of comets and asteroids

All available ground based observational techniques were used to study the chemical and physical properties of the small bodies of the solar system, primarily comets and next asteroids. The ultimate goal is to use these bodies to understand the formation and evolution of the solar system. Progress and accomplishments, and publications are given.

Ahearn, Michael F.↗

The Timing of Potential Last Nucleosynthetic Injections into the Protosolar Molecular Cloud Inferred from 41 Ca– 26 Al Systematics of Bulk CAIs

Short-lived radionuclides (SLRs) provide important information about the chronology of the early solar system. Among them, 41 Ca, due to its decay to 41 K with a half-life of only 0.1 Ma, is particularly valuable in constraining the timescales and origins of both SLRs and the formation of the oldest solar system materials, the Ca–Al-rich inclusions (CAIs). The initial abundance of 41Ca in the solar system, expressed as the ( 41 Ca/ 40 Ca)I ratio, is the key to unveiling the origin of this nuclide. Here, we report a new solar system ( 41 Ca/ 40 Ca)I ratio of 2.0 × 10 −8 derived from the K isotope compositions of two CAIs. This new ratio is about four times higher than the previous value inferred from a mineral isochron. Such a high ( 41 Ca/ 40 Ca)I ratio in the CAIs exceeds that expected for the protosolar molecular cloud by ∼1000×, implying very late injection of the 41 Ca (and possibly other SLRs) into the protosolar molecular cloud. The correlated enrichments of 41 Ca and 26 Al in the bulk CAI samples hint at a common stellar origin of both SLRs. The injection time estimated from our new data depends on the stellar source—it ranges from 0.6 Ma for a Wolf–Rayet wind to 1.0 Ma for a TP-AGB star ejecta.

79 ASTRONOMY AND ASTROPHYSICS↗

Surface ices in the outer solar system

Planetary volatile inventories are products of several factors: (1) condensation-accretion of pre-planetary material which determines the bulk volatile inventory; (2) energy history of a planet, including timing, causes, and mechanisms of degassing; (3) the volatile sinks, including temporary, long term, and permanent; and (4) external processes operating on the volatile inventory. Information regarding the current surface compositions provide insight into both internal and surface-atmosphere evolutionary history. Our discussion focuses upon the surface composition of outer solar system planets and satellites as determined by spacecraft and telescopic spectral observations. We provide a review and an update of the recent work by Cruikshank and Brown that includes more recent observations and interpretations. In the context of formation and evolution of solar system bodies, the interesting ices typically considered are simple molecules formed from elements having high cosmic abundances. These mainly include ices of H2O, NH3, SO2, H2S, CH4, CO, CO2, and N2. In the solid state, these ices have vibrational spectral features, analogous to their gaseous counterparts but rotational transitions are quenched, that lie in the near- and mid-infrared. The overtone and combination modes, occurring in the visible and near-IR region, are of particular importance as standard observational techniques used to identify these ices rely upon reflected solar energy. Table I summarizes the ices found on various bodies in the outer solar system. H2O is most abundant surface material in the inner and middle regions while more volatile species appear to dominate surfaces in the outermost edge of the outer solar system.

Roush, Ted L.↗

Dust That's Worth Keeping

Images taken of interstellar space often display a colorful canvas of portions of the electromagnetic spectrum. Dispersed throughout the images are interstellar clouds of dust and gas--remnants ejected from stars and supernovae over billions and billions of years. For more than 40 years, astronomers have observed that interstellar dust exhibits a consistent effect at a spectral wavelength of 2,175 angstroms, the equivalent of 5.7 electronvolts in energy on the electromagnetic spectrum. At this wavelength, light from stars is absorbed by dust in the interstellar medium, blocking the stars light from reaching Earth. The 2,175-angstrom feature, which looks like a bump on spectra, is the strongest ultraviolet-visible light spectral signature of interstellar dust and is visible along nearly every observational line of sight. Scientists have sought to solve the mystery of what causes the 2,175-angstrom feature by reproducing the effect in the laboratory. They speculated a number of possibilities, including fullerenes (buckyballs), nanodiamonds, and even interstellar organisms. However, none of these materials fits the data for the unique spectral feature. Limitations in the energy and spatial resolution achievable with electron microscopes and ion microprobes--the two main instruments used to study samples of dust--have also prevented scientists from finding the answer. A collaborative effort led by Livermore physicist John Bradley and funded by the National Aeronautics and Space Administration (NASA) has used a new-generation transmission electron microscope (TEM) and nanoscale ion microprobe to unlock the mystery. The Livermore group includes physicists Zu Rong Dai, Ian Hutcheon, Peter Weber, and Sasa Bajt and postdoctoral researchers Hope Ishii, Giles Graham, and Julie Smith. They collaborated with the University of California at Davis (UCD), Lawrence Berkeley National Laboratory, Washington University's Laboratory for Space Sciences in St. Louis, and NASA's Ames Research Center for their discovery. The team analyzed micrometer-size interplanetary dust particles (IDPs), each about one-tenth the diameter of a human hair. Within the particles, they found carriers of the 2,175-angstrom feature: organic carbon mixed with amorphous silicates (glass with embedded metals and sulfides, GEMS), two of the most common materials in interstellar space. Ishii says, 'Organic carbon and amorphous silicates are abundant in interstellar dust clouds, and abundant carriers are needed to account for the frequent astronomical observation of the 2,175-angstrom feature. It makes sense that this ubiquitous feature would come from common materials in interstellar space'. The group's results increase scientific understanding of the starting materials for the formation of the Sun, solar system, and life on Earth.

Interstellar matter↗

Extinct radioactivities - A three-phase mixing model

A new class of models is advanced for interpreting the relationship of radioactive abundances in the early solar system to their average concentration in the interstellar medium. The model assumes that fresh radioactivities are ejected from supernovae into the hot interstellar medium, and that the time scales for changes of phase into molecular clouds determine how much survives for formation therein of the solar system. A more realistic and physically motivated understanding of the low observed concentrations of I-129, Pu-244, and Pd-107 may result.

Clayton, D. D.↗

The Initial W-182/W-183 and Hf-182/Hf-180 of the Solar System and a Consistent Chronology with Pb-Pb Ages

The utility of the Hf-182 (bar-tau ==13 x 10(exp 6) yr) -W-182 chronometer for early solar system processes is now well established. At the 2002 LPSC meeting we first reported new Hf-W data for chondritic meteorites showing that some crucial data as well as interpretations of Lee and Halliday for chondrites were incorrect. Our results were confirmed by reports of two other groups. This new data imply a much-shorter timescale for the early Solar System evolution and the formation of the Earth s core more consistent with the original conclusions of Harper and Jacobsen. Thus, the chondritic Hf-W evolution is now well established as beginning with epsilon(sub W)(0) = -3.45 +/- 0.25 at the time of origin of the solar system and evolving to -2.2 by 20 Myr and -1.9 +/- 0.20 at present. However, there are a number of iron meteorite data that suggest the existence of initial W lower than those measured for chondrites. If the low epsilon(sub W)(0) of -4 to -5 are correct then we face an embarrassing dilemma of differentiated iron meteorites being older than the primitive chondrites, or we would have to conclude that there is an additional pre-history of 5-10 Myr in primitive chondritic meteorites prior to the closure of the Hf-182 - W-182 system. Such a prolonged early time does not seem reasonable to us. We have therefore initiated a study to resolve this issue.

Yin, Qingzhu↗

Small grains of truth

The evidence concerning the formation of the solar nebula from preexisting clouds found in the chemical composition of solar system grains is discussed. Evidence for sequential star formation in the grains is examined. It is argued that there is no model for the origin of the solar system which can account for the increasing complexity of the evidence.

Nuth, Joe↗

Chemical and Isotopic Analysis of Trace Organic Matter on Meteorites and Interstellar Dust Using a Laser Microprobe Instrument

Polycyclic Aromatic Hydrocarbons (PAHs) are of considerable interest today because they are ubiquitous on Earth and in the interstellar medium (ISM). In fact, about 20% of cosmic carbon in the galaxy is estimated to be in the form of PAHs. Investigation of these species has obvious uses for determining the cosmochemistry of the solar system. Work in this laboratory has focused on four main areas: 1) Mapping the spatial distribution of PAHs in a variety of meteoritic samples and comparing this distribution with mineralogical features of the meteorite to determine whether a correlation exists between the two. 2) Developing a method for detection of fullerenes in extraterrestrial samples using microprobe Laser Desorption Ionization Mass Spectroscopy and utilizing this technique to investigate fullerene presence, while exploring the possibility of spatially mapping the fullerene distribution in these samples through in situ detection. 3) Investigating a possible formation pathway for meteoritic and ancient terrestrial kerogen involving the photochemical reactions of PAHs with alkanes under prebiotic and astrophysically relevant conditions. 4) Studying reaction pathways and identifying the photoproducts generated during the photochemical evolution of PAH-containing interstellar ice analogs as part of an ongoing collaboration with researchers at the Astrochemistry Lab at NASA Ames. All areas involve elucidation of the solar system formation and chemistry using microprobe Laser Desorption Laser Ionization Mass Spectrometry. A brief description of microprobe Laser Desorption Ionization Mass Spectroscopy, which allows selective investigation of subattomole levels of organic species on the surface of a sample at 10-40 micrometer spatial resolution, is given.

Zare, Richard N.↗

Estimation of the reaction rate for the formation of CH3O from H + H2CO - Implications for chemistry in the solar system

Troe's (1977) approximate theory is presently used in conjunction with transition state theory to estimate the rate coefficient of the reaction by which CO is reduced to CH4; attention is given to the role that may be played in the reduction process by the formation of the CH3O radical from H + H2CO. Attention is given to the implications of such a reaction (1) for the CO chemistry on Jupiter and within the solar nebula, (2) for the interpretation of such experimental results as those of Bar-Nun and Shaviv (1975) and Bar-Nun and Chang (1983), and (3) for organic synthesis in the prebiotic terrestrial atmosphere.

Yung, Yuk L.↗

A possible mechanism for the capture of microparticles by the earth and other planets of the solar system

By application of Lyttleton's theory for the formation of comets, it is shown that a possible mechanism for the origin and formation of a concentration of cosmic particles around the earth and the other planets of the solar system exists. In the vicinity of the neutral point, where the velocity of colliding particles is not greater than 6 km/s, it is found that if the solid particles after collision must remain in a solid state, there can be no possibility of accretion for Mercury, Mars, and the Moon, where the maximum value of the distance of the center of the planet to the asymptotic trajectory is less than the radius of the planet. On the other hand, the capture radii of microparticles in solid form varies from a minimum of 2.95 planetary radii for Venus and 3.47 for the Earth, to about 986 for Jupiter.

Dibenedetto, F.↗

Accretion of the earliest inner Solar System planetesimals beyond the water snowline

How and where the first generation of inner Solar System planetesimals formed remains poorly understood. Potential formation regions are the silicate condensation line and water snowline of the solar protoplanetary disk. Whether the chemical compositions of these planetesimals align with accretion at the silicate condensation line (water-free and reduced) or water snowline (water-bearing and oxidized) is, however, unknown. Here we use the Fe/Ni and Fe/Co ratios of magmatic iron meteorites to quantify the oxidation states of the earliest planetesimals associated with non-carbonaceous (NC) and carbonaceous (CC) reservoirs, representing the inner and outer Solar System, respectively. Our results show that the earliest NC planetesimals contained substantial amounts of oxidized Fe in their mantles (3–19 wt% FeO). In turn, we argue that this required the accretion of water-bearing materials into these NC planetesimals. The presence of substantial quantities of moderately and highly volatile elements in their parent cores is also inconsistent with their accretion at the silicate condensation line and favours, instead, their formation at or beyond the water snowline. Similar oxidation states in the early formed parent bodies of NC iron meteorites and those of NC achondrites and chondrites with diverse accretion ages suggest that the formation of oxidized planetesimals from water-bearing materials was widespread in the early history of the inner Solar System.

Damanveer S. Grewal↗