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At least 343 records · Page 19

A multi-criteria CCUS screening evaluation of the Gulf of Mexico, USA

Continued research into reservoir characterization along with offshore carbon dioxide (CO 2 ) transportation and infrastructure assets is needed to facilitate development of safe and successful carbon capture, utilization, and storage (CCUS) projects. This paper outlines a multi-criteria evaluation methodology that incorporates disparate sets of quantitative, spatially variable data into a decision-making framework for screening the Gulf of Mexico (GOM) outer continental shelf (OCS) for potentially viable CO 2 storage and enhanced oil recovery (EOR) sites. Criteria categories include favorable geologic characteristics, logistics, and potential risks. Data compiled for 14 criteria from several publicly available geographic information system (GIS) layers was aggregated over 2559 spatially balanced points across the study area using the National Energy Technology Laboratory (NETL)-developed Cumulative Spatial Impact Layers™ (CSIL) GIS tool. Criteria are weighted by qualitative expert opinion relative to their perceived importance to given scenarios— the output of combined criteria values and weights enables regional CO 2 storage suitability differentiation. The methodology considers both technical and non-technical factors impacting CCUS decision-making. The flexible methodology enables a systematic approach to regional ranking at high spatial resolution over a large study domain. Additionally, the framework enables high-grading of priority sites that warrant further characterization and follow-on analysis. Areas along the Louisiana coast and Mississippi River Delta consistently rank high for all scenarios largely a result of the favorable geology with the potential for stacked storage, as well as the density of existing pipelines and platforms, and proximity to several onshore CO 2 sources. High-graded regions for the CO 2 EOR-related scenarios are typically located further offshore towards the middle and edge of the OCS compared to higher priority regions for the geologic storage scenarios which fall closer to the Louisiana coastline.

54 ENVIRONMENTAL SCIENCES↗

The effect of spatial resolution upon cloud optical property retrievals. I - Optical thickness

High spectral and spatial resolution Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) imagery is used to study the effects of spatial resolution upon fair weather cumulus cloud optical thickness retrievals. As a preprocessing step, a variation of the Gao and Goetz three-band ratio technique is used to discriminate clouds from the background. The combination of the elimination of cloud shadow pixels and using the first derivative of the histogram allows for accurate cloud edge discrimination. The data are progressively degraded from 20 m to 960 m spatial resolution. The results show that retrieved cloud area increases with decreasing spatial resolution. The results also show that there is a monotonic decrease in retrieved cloud optical thickness with decreasing spatial resolution. It is also demonstrated that the use of a single, monospectral reflectance threshold is inadequate for identifying cloud pixels in fair weather cumulus scenes and presumably in any inhomogeneous cloud field. Cloud edges have a distribution of reflectance thresholds. The incorrect identification of cloud edges significantly impacts the accurate retrieval of cloud optical thickness values.

Feind, Rand E.↗

Keweenaw Bay Water Resources: Turbidity Data Decision Support for Shoreline Assessment and Management in Lake Superior'S Keweenaw Bay

The Keweenaw Bay Indian Community (KBIC) has shoreline along the south of Lake Superior that is contaminated with copper stamp sands from legacy mining. The stamp sands have been capped with sandy-loam soils and restored native species, but erosion and flooding threaten to re-deposit these stamp sands onto wetlands and into the bay. Erosion and flooding also threaten loss of beaches and shoreline, infrastructure, wetland restoration projects, and coastal highways, which has driven shoreline armoring. However, while shoreline armoring can be effective in protecting the intended areas, it can also exacerbate erosion in nearby unarmored areas, so its net impact on the shoreline is yet to be quantified. The DEVELOP team partnered with KBIC and the Environmental Protection Agency (EPA) to utilize imagery from Landsat 8 Operational Land Imager (OLI) and Sentinel-2 Multispectral Instrument (MSI) in order to analyze turbidity proxies. The results from these analyses showed that seasonal variation in study area was greatest during the season dominated by rain, but spatial variability across our study period did not show a clear trend. These results will be used to better inform future shoreline management efforts and support resilience in the face of more coastal erosion.

remote sensing↗

The Large UV/Optical/Infrared Surveyor (LUVOIR): Decadal Mission Study Update

NASA commissioned the study of four large mission concepts, including the Large Ultraviolet / Optical / Infrared (LUVOIR) Surveyor, to be evaluated by the 2020 Decadal Survey in Astrophysics. In response, the Science and Technology Definition Team (STDT) identified a broad range of science objectives for LUVOIR that include the direct imaging and spectral characterization of habitable exoplanets around sun-like stars, the study of galaxy formation and evolution, the exchange of matter between galaxies, star and planet formation, and the remote sensing of Solar System objects. To meet these objectives, the LUVOIR Study Office, located at NASA’s Goddard Space Flight Center (GSFC), completed the first design iteration of a 15-m segmented-aperture observatory that would be launched by the Space Launch System (SLS) Block 2 configuration. The observatory includes four serviceable instruments: the Extreme Coronagraph for Living Planetary Systems (ECLIPS), an optical / near-infrared coronagraph capable of delivering 10^-10contrast at inner working angles as small as 2 O/D; the LUVOIR UV Multi-object Spectrograph (LUMOS), which will provide low- and medium-resolution UV (100 – 400 nm) multi-object imaging spectroscopy in addition to far-UV imaging; the High Definition Imager (HDI), a high-resolution wide-field-of-view NUV-Optical-NIR imager; and Pollux, a high-resolution UV spectro-polarimeter being contributed by Centre National d’Etudes Spatiales (CNES).The study team has executed a second design iteration to further improve upon the 15-m concept, while simultaneously studying an 8-m concept. In these proceedings, we provide an update on these two architectures.

space telescopes↗

Analysis of RF Sheath-Driven Tungsten Erosion at RF Antenna in the WEST Tokamak

This study applies the newly developed STRIPE (Simulated Transport of RF Impurity Production and Emission) framework to analyze tungsten (W) erosion at RF antenna structures in the WEST tokamak. STRIPE integrates SolEdge3x for edge plasma backgrounds, COMSOL for 3D RF sheath potentials, RustBCA for sputtering yields, and GITR for impurity transport and ion energy–angle distributions. Building on prior work by Kumar et al. (2025) Nuclear Fusion, 65, 076039, which validated STRIPE for WEST ICRH discharge #57877, the present study provides a spatially resolved assessment of gross W erosion at both Q2 antenna limiters under ohmic and ICRH conditions. Simulations using 2D SolEdge3x profiles in COMSOL capture rectified sheath potentials exceeding 300 V, leading to strong upper-limiter localization. Both poloidal and toroidal asymmetries are observed and attributed to RF sheath effects, with modeled erosion patterns deviating from experiment—highlighting sensitivity to sheath geometry and plasma resolution. Erosion is driven primarily by high-charge-state oxygen ions (O6+–O8+), while D+ plays a negligible role. Assuming a plasma composition of 1% oxygen and 98% deuterium, STRIPE predicts a 30-fold increase in gross W erosion from ohmic to ICRH phases, consistent with a >25-fold rise in W-I (400.9 nm) brightness. Quantitative agreement is within 5% in the ohmic phase and 30% under ICRH, demonstrating predictive capability. Importantly, the study shows that the magnitude of ICRH-driven W erosion depends strongly on the concentration of light impurities (O, B, N, C), which drive sputtering through high charge states. Cleaner plasma conditions with reduced impurity content are therefore expected to substantially mitigate antenna W sources in WEST and other toroidal fusion devices. These findings establish STRIPE as a predictive framework for RF-induced plasma–material interactions and support its application to reactor-scale antenna design.

Kumar, Atul [ORNL] (ORCID:0000000277475210)↗

The Large UV/Optical/Infrared Surveyor (LUVOIR): Decadal Mission Study Update

NASA commissioned the study of four large mission concepts, including the Large Ultraviolet / Optical / Infrared (LUVOIR) Surveyor, to be evaluated by the 2020 Decadal Survey in Astrophysics. In response, the Science and Technology Definition Team (STDT) identified a broad range of science objectives for LUVOIR that include the direct imaging and spectral characterization of habitable exoplanets around sun-like stars, the study of galaxy formation and evolution, the exchange of matter between galaxies, star and planet formation, and the remote sensing of Solar System objects. To meet these objectives, the LUVOIR Study Office, located at NASA's Goddard Space Flight Center (GSFC), completed the first design iteration of a 15-m segmented-aperture observatory that would be launched by the Space Launch System (SLS) Block 2 configuration. The observatory includes four serviceable instruments: the Extreme Coronagraph for Living Planetary Systems (ECLIPS), an optical / near-infrared coronagraph capable of delivering 10(exp -10) contrast at inner working angles as small as 2 lambda/D; the LUVOIR UV Multi-object Spectrograph (LUMOS), which will provide low- and medium-resolution UV (100 - 400 nm) multi-object imaging spectroscopy in addition to far-UV imaging; the High Definition Imager (HDI), a high-resolution wide-field-of-view NUV-Optical-NIR imager; and Pollux, a high-resolution UV spectro-polarimeter being contributed by Centre National d'Etudes Spatiales (CNES). The study team has executed a second design iteration to further improve upon the 15-m concept, while simultaneously studying an 8-m concept. In these proceedings, we provide an update on these two architectures.

cosmic origins↗

Dissolved Organic Carbon in Coastal Waters: Global Patterns, Stocks and Environmental Physical Controls

Abstract Dissolved organic carbon (DOC) in coastal waters is integral to biogeochemical cycling, but global and regional drivers of DOC are still uncertain. In this study we explored spatial and temporal differences in DOC concentrations and stocks across the global coastal ocean, and how these relate to temperature and salinity. We estimated a global median coastal DOC stock of 3.15 Pg C (interquartile range (IQR) = 0.85 Pg C), with median DOC concentrations being 2.2 times higher than in open ocean surface waters. Globally and seasonally, salinity was the main driver of DOC with concentrations correlated negatively with salinity, without a clear relationship to temperature. DOC concentrations and stocks varied with region and season and this pattern is likely driven by riverine inputs of DOC and nutrients that stimulate coastal phytoplankton production. Temporally, high DOC concentrations occurred mainly in months with high freshwater input, with some exceptions such as in Eastern Boundary Current margins where peaks are related to primary production stimulated by nutrients upwelled from the adjacent ocean. No spatial trend between DOC and temperature was apparent, but many regions (19 out of 25) had aligned peaks of seasonal temperature and DOC, related to increased phytoplankton production and vertical stratification at high temperatures. Links of coastal DOC with salinity and temperature highlight the potential for anthropogenic impacts to alter coastal DOC concentration and composition, and thereby ecosystem status.

Lønborg, Christian [Section for Marine Diversity a↗

Identification of Sea Surface Temperature and Sea Surface Salinity Fronts along the California Coast: Application Using Saildrone and Satellite Derived Products

Coastal upwelling regions are one of the most dynamic areas of the world’s oceans. The California and Baja California Coasts are impacted by both coastal upwelling and the California Current, leading to frontal activity that is captured by gradients in both Sea Surface Temperature (SST) and Sea Surface Salinity (SSS). Satellite data are a great source of spatial data to study fronts. However, biases near coastal areas and coarse resolutions can impair its usefulness in upwelling areas. In this work gradients in SST from NASA Multi-Scale Ultra-High Resolution (MUR) and in two SSS products derived from the Soil Moisture Active Passive (SMAP) NASA mission are compared directly with gradients derived from the Saildrone uncrewed vehicles to validate the gradients as well as to assess their ability to detect known frontal features. The three remotely sensed data sets (MURSST/JPL, SMAP SSS/RSS, SMAP SSS) were co-located with the Saildrone data prior to the calculation of the gradients. Wavelet analysis is used to determine how well the satellite derived SST and SSS products are reproducing the Saildrone derived gradients. Overall results indicate the remote sensing products are reproducing features of known areas of coastal upwelling. Differences between the SST and SSS gradients are mainly associated with the limitations of the microwave derived SSS coverage near land and its reduced spatial resolution. The results are promising for using remote sensing data sets to monitor frontal structure along the California Coast and the application to long term changes in coastal upwelling and dynamics.

Sea Surface Salinity↗

Enhancing Autonomous Control of Microreactors Using Multi-Agent Reinforcement Learning

In order for microreactors to be economically competitive, operation costs will need to be minimized through some degree of autonomous control. Previous work has demonstrated the effectiveness of reinforcement learning (RL) for load-following control in a drum-controlled microreactor. This study extends that work by exploring the potential of RL to independently control each of the reactor’s drums. We compare a single-agent RL approach with a multi-agent RL (MARL) framework, testing them for generalization across different load-following power profiles and control timescales, and for robustness in cases of randomly disabled control drums. Since the point kinetics simulation environment used in this study cannot resolve spatial effects, we assume that in the absence of spatially localized disturbances, optimal drum movements should be symmetrical. We demonstrate that single-agent RL is able to achieve accurate performance only when symmetric actions are ignored; otherwise, it fails to train a useful controller. Meanwhile, the MARL framework performs symmetric actions by design and trains a robust, accurate agent, as evidenced by mean absolute errors in power matching of 0.41% for the training power profile, 0.68% for a profile with half the drums disabled, and 0.21% for a profile on a realistic load-following time horizon.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Weekly Gridded Aquarius L-band Radiometer-Scatterometer Observations and Salinity Retrievals over the Polar Regions - Part 2: Initial Product Analysis

Following the development and availability of Aquarius weekly polar-gridded products, this study presents the spatial and temporal radiometer and scatterometer observations at L band (frequency1.4 GHz) over the cryosphere including the Greenland and Antarctic ice sheets, sea ice in both hemispheres, and over sub-Arctic land for monitoring the soil freeze-thaw state. We provide multiple examples of scientific applications for the L-band data over the cryosphere. For example, we show that over the Greenland Ice Sheet, the unusual 2012 melt event lead to an L-band brightness temperature (TB) sustained decrease of 5 K at horizontal polarization. Over the Antarctic ice sheet, normalized radar cross section (NRCS) observations recorded during ascending and descending orbits are significantly different, highlighting the anisotropy of the ice cover. Over sub-Arctic land, both passive and active observations show distinct values depending on the soil physical state (freeze-thaw). Aquarius sea surface salinity (SSS) retrievals in the polar waters are also presented. SSS variations could serve as an indicator of fresh water input to the ocean from the cryosphere, however the presence of sea ice often contaminates the SSS retrievals, hindering the analysis. The weekly grided Aquarius L-band products used a redistributed by the US Snow and Ice Data Center at http:nsidc.orgdataaquariusindex.html, and show potential for cryospheric studies.

Aquarius↗

Global Assessment of the SMAP Level-4 Soil Moisture Product Using Assimilation Diagnostics

The Soil Moisture Active Passive (SMAP) mission Level-4 Soil Moisture (L4_SM) product provides 3-hourly, 9-km resolution, global estimates of surface (0-5 cm) and root-zone (0-100 cm) soil moisture and related land surface variables from 31 March 2015 to present with approx. 2.5-day latency. The ensemble-based L4_SM algorithm assimilates SMAP brightness temperature (Tb) observations into the Catchment land surface model. This study describes the spatially distributed L4_SM analysis and assesses the observation-minus-forecast (O-F) Tb residuals and the soil moisture and temperature analysis increments. Owing to the climatological rescaling of the Tb observations prior to assimilation, the analysis is essentially unbiased, with global mean values of approx. 0.37 K for the O-F Tb residuals and practically zero for the soil moisture and temperature increments. There are, however, modest regional (absolute) biases in the O-F residuals (under approx. 3 K), the soil moisture increments (under approx. 0.01 cu m/cu m), and the surface soil temperature increments (under approx. 1 K). Typical instantaneous values are approx. 6 K for O-F residuals, approx. 0.01 (approx. 0.003) cu m/cu m for surface (root-zone) soil moisture increments, and approx. 0.6 K for surface soil temperature increments. The O-F diagnostics indicate that the actual errors in the system are overestimated in deserts and densely vegetated regions and underestimated in agricultural regions and transition zones between dry and wet climates. The O-F auto-correlations suggest that the SMAP observations are used efficiently in western North America, the Sahel, and Australia, but not in many forested regions and the high northern latitudes. A case study in Australia demonstrates that assimilating SMAP observations successfully corrects short-term errors in the L4_SM rainfall forcing.

Reichle, Rolf↗

Using Data Assimilation Diagnostics to Assess the SMAP Level-4 Soil Moisture Product

The Soil Moisture Active Passive (SMAP) mission Level-4 Soil Moisture (L4_SM) product provides 3-hourly, 9-km resolution, global estimates of surface (0-5 cm) and root-zone (0-100 cm) soil moisture and related land surface variables from 31 March 2015 to present with approx.2.5-day latency. The ensemble-based L4_SM algorithm assimilates SMAP brightness temperature (Tb) observations into the Catchment land surface model. This study describes the spatially distributed L4_SM analysis and assesses the observation-minus-forecast (O-F) Tb residuals and the soil moisture and temperature analysis increments. Owing to the climatological rescaling of the Tb observations prior to assimilation, the analysis is essentially unbiased, with global mean values of approx. 0.37 K for the O-F Tb residuals and practically zero for the soil moisture and temperature increments. There are, however, modest regional (absolute) biases in the O-F residuals (under approx. 3 K), the soil moisture increments (under approx. 0.01 cu m/cu m), and the surface soil temperature increments (under approx. 1 K). Typical instantaneous values are approx. 6 K for O-F residuals, approx. 0.01 (approx. 0.003) cu m/cu m for surface (root-zone) soil moisture increments, and approx. 0.6 K for surface soil temperature increments. The O-F diagnostics indicate that the actual errors in the system are overestimated in deserts and densely vegetated regions and underestimated in agricultural regions and transition zones between dry and wet climates. The O-F auto-correlations suggest that the SMAP observations are used efficiently in western North America, the Sahel, and Australia, but not in many forested regions and the high northern latitudes. A case study in Australia demonstrates that assimilating SMAP observations successfully corrects short-term errors in the L4_SM rainfall forcing.

SMAP↗

Influences of the South American Low-Level Jet on the Convective Environment in Central Argentina Using a Convection-Permitting Simulation

This study documents the spatial and temporal distribution of the South American low-level jet (SALLJ) and quantifies its impact on the convective environment using a 6.5-month convection-permitting simulation during the Remote Sensing of Electrification, Lightning, And Mesoscale/Microscale Processes with Adaptive Ground Observations and Clouds, Aerosols, and Complex Terrain Interactions (RELAMPAGO-CACTI) campaigns. Overall, the simulation reproduces the observed SALLJ characteristics in central Argentina near the Sierras de Córdoba (SDC), a focal point for terrain-focused upscale growth. SALLJs most frequently occur in the summer with maxima to the northwest and east of the SDC and minima over the higher terrain. The shallower SALLJs (<1750 m) have a strong overnight skew, while the elevated jets are more equally spread throughout the day. SALLJ periods often have higher amounts of low-level moisture and instability compared to non-SALLJ periods, with these impacts increasing over time when the SALLJ is present and decreasing afterward. The SALLJ may enhance low-level wind shear magnitudes (particularly when accounting for the jet height); however, enhancement is somewhat limited due to the presence of speed shear in most situations. SALLJ periods are associated with low-level directional shear favorable for organized convection and an orientation of cloud-layer wind shear parallel to the terrain, which could favor upscale growth. A case study is shown in which the SALLJ influenced both the magnitude and direction of wind shear concurrent with convective upscale growth near the SDC. This study highlights the complex relationship between the SALLJ and its impacts during periods of widespread convection.

54 ENVIRONMENTAL SCIENCES↗

Novel Cell-Type-Specific Drought-Responsive Proteins in Root Tips of Field-Grown Perennial Switchgrass

The root-tip region of plants, including the root cap, forms the most basal terminal of the root and exhibits a high degree of cellular complexity in terms of morphology, cytological function, and interaction with environmental cues in the soil. Cells in this region follow a developmental trajectory, transitioning from stem cells to meristematic cells, and ultimately to fully differentiated cell types. However, our understanding of root-tip cell-type specific proteomic responses to abiotic stresses, such as drought, particularly under field conditions, remains limited. This study aimed to identify spatially resolved, cell type-specific proteomes in switchgrass (Panicum virgatum) root tips under drought stress. Root tips were collected from seven-year-old, field-grown switchgrass ‘Alamo’ plants excavated under both well-watered and long-term drought conditions. Cell type-specific proteins were identified using laser capture microdissection (LCM) coupled with nanoPOTS (Nanodroplet Processing in One Pot for Trace Samples) and nano-LC-MS proteomics analysis. Five distinct cell types were targeted: (1) cells in the quiescent center and stem cell niche (QuC), (2) protodermal epidermal cells (PEC) in the meristematic zone, (3) epidermal cells in the transition and elongation zones above the root cap (Epi), (4) peripheral root cap cells (PRC), forming 2–3 layers below the PEC and 1–2 layers above the root border cells, and (5) columella root cap cells (Col) comprising of the columella initials and a single underlying layer of cells undergoing active growth. Principal component analysis (PCA) revealed clear separation among the five targeted cell types, confirming distinct proteomic profiles. Proteins predominantly enriched in each cell type were linked to distinct cellular functions, with QuC cells showing involvement in chromosomal behavior, DNA replication, and mitosis—key processes for stem cell niche regulation. Drought stress resulted in alterations of proteostasis, as evidenced by significant decreases in ribosomal proteins and increases in protein synthesis inhibitors. Moreover, drought stress induced unique cell-type–specific proteins involved in phytohormone biosynthesis and signaling pathways, including auxin, cytokinin, and jasmonic acid. In particular, QuC cells were more highly enriched in proteins associated with DNA repair and mitotic processes. Metabolic pathways related to amino acids, carbohydrates, and lipids were differentially affected in a cell-type–dependent manner, whereas general stress-responsive proteins exhibited consistent changes across all five cell types. Overall, this study provides unique spatially resolved, cell-type-specific proteomic profiles in root tips, representing a significant advancement in our understanding of the cellular mechanisms underlying plant responses to drought stress in natural field conditions.

perennial grass↗

Inviscid spatial stability of a compressible mixing layer. III - Effect of thermodynamics

The results of a comprehensive comparative study of the inviscid spatial stability of a parallel compressible mixing layer using various models for the mean flow are reported. The models are: (1) the hyperbolic tangent profile for the mean speed and the Crocco relation for the mean temperature, with the Chapman viscosity-temperature relation and a Prandtl number of one; (2) the Lock profile for the mean speed and the Crocco relation for the mean temperature, with the Chapman viscosity-temperature relation and a Prandtl number of one; and (3) the similarity solution for the coupled velocity and temperature equations using the Sutherland viscosity temperature relation and arbitrary but constant Prandtl number. The purpose was to determine the sensitivity of the stability characteristics of the compressible mixing layer to the assumed thermodynamic properties of the fluid. It is shown that the quantitative features of the stability characteristics are quite similar for all models but that there are quantitative differences resulting from the difference in the thermodynamic models. In particular, it is shown that the stability characteristics are sensitive to the value of the Prandtl number.

Jackson, T. L.↗

Impact of Grazing Duration and Environment on Soil Carbon in Reclaimed Uranium Mines Tailings: A Region Specific Study

ABSTRACT Grassland ecosystems, which cover over one‐third of the Earth's land area, store 10%–30% of global soil carbon (C). However, these ecosystems face substantial impacts from human activities, including mining. This study investigates the spatial distribution of soil C and related environmental factors in reclaimed grasslands on former uranium mine sites in Wyoming. We hypothesized that grazing duration and environmental factors would influence soil C levels. Interactions between topography, vegetation diversity, soil properties, and soil C in the context of grazing management in both natural and reclaimed grasslands from a wide range of periods from 1 year to 100 years were analyzed using geographically weighted regression models. Data collected from 2022 to 2023 showed that total carbon was consistently higher in natural grasslands (1.2%–4.9%) than in reclaimed grasslands (0.8%–1.3%). Additionally, soil C was significantly higher in natural grasslands grazed for 1 year compared to those grazed for 100 years. In contrast, reclaimed grasslands had lower soil C in areas grazed for 1 year compared to those grazed for 7 or 14 years. The absolute values of coefficients from environmental covariates indicated that areas grazed for a shorter duration (~1 year) were more influenced by biotic and abiotic factors than areas grazed for longer periods (> 7 years). Our findings show moderate grazing increases the resiliency of grassland ecosystems when grazed 7 years or longer and acknowledge the roles of topographic, soil, and vegetative factors in enhancing soil C concentration and developing sustainable land management practices in rangeland conditions.

Shilpakar, Chandan [Department of Plant Sciences U↗

Answering old questions with new techniques: Understanding performance-limiting factors in transition metal dichalcogenide photoelectrochemical solar cells

In the late 1970s and early 1980s, several research groups reported high-efficiency and stable photoelectrochemical solar cells based on transition metal dichalcogenides (TMDS; e.g., MoS 2 , WSe 2 , and MoSe 2 ) immersed in iodide/tri-iodide electrolytes. A consensus emerged that smooth crystals were necessary for high efficiency based on significant evidence that rough crystals with exposed edge sites produced lower photocurrents and fill factors. However, anecdotal observations in the literature hinted at significant performance variation among apparently smooth crystals with the possibility of highly active “hot” edge sites. Furthermore, this mini-review article is a case study on how spatially resolved photoelectrochemical techniques developed in the 2020s are answering old questions regarding the origin of performance variation in high efficiency n-type TMD|I – ,I 3 – |Pt photoelectrochemical solar cells.

14 SOLAR ENERGY↗

Rapid Coal-Ash Characterization using Geophysical Methods & Machine Learning

Coal combustion products (CCP) are challenging to delineate in heterogeneous field settings. Conventional methods (test pits, coring, and laboratory analyses) are labor-intensive, slow, invasive, and provide sparse spatial coverage. This study evaluates whether rapid non-invasive geophysical screening methods—induced polarization (IP), magnetic susceptibility, and nuclear magnetic resonance (NMR) —combined with surface colorimetry (RGB_24), can discriminate CCP-soil mixtures and provide reliable estimates of CCP content. Laboratory measurements were collected on five CCP-soil mixtures (series) and modeled using (i) a linear baseline, (ii) a calibrated non-linear (power-mean) model, and (iii) a machine-learning (ML) Random Forest approach, with validation via leave-one-series-out and site-specific tests. Across the five series, individual signals—particularly IP and magnetic susceptibility—were strongly predictive of ash content but were consistently outperformed by combined models. The pooled calibrated non-linear and ML models captured the observed non-linearity and achieved high accuracy and precision, improving on linear fits. Colorimetry showed the weakest direct relationship with ash content for the tested samples but improved performance when included in multi-signal models. At pre-selected 3.5% decision threshold, calibrated and ML approaches yielded near-perfect classification (Matthews correlation coefficient ˜ 1), suggesting strong practical operability for field screening. Additionally, field-analog tests highlighted the role of endmembers—accuracy declined without access to end-member measurements but was largely recovered by collecting a minimal labeled pair for local recalibration. With end members, accuracy remained high. Globally trained models performed well on three operational unknowns; however, series-specific refits provided the most accurate predictions. Overall, these results highlight the potential of combining rapid geophysics and minimal local calibration for improved coal-ash delineation.

Peshtani, Klaudio↗