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At least 343 records · Page 19

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NASA NTRS1990

Role of the methylene amidogen (H2CN) radical in the atmospheres of Titan and Jupiter

The methylene amidogen (H2CN) radical can be shown to be an important intermediate in models for the formation of HCN (via N + CH3) and the recombination of H to H2 (via H + HCN) on Titan as well as in models for the formation of HCN (via NH2 + C2H3) in the atmosphere of Jupiter. Experiments in our laboratory in a discharge flow system with mass spectrometric detection of both reactants and products have established that the major product channel (90 percent for the reaction N + CH3 is that leading to H2CN + H. The same result was obtained for N + CD3 yields D2CN + D. The rate constant for the reaction D + D2CN yields DCN + D2 was measured for the first time and k(298 K) greater than 7 x 10(exp -11) cu cm/s was found. The same result was obtained for the H atom reaction. This is the final step in the reaction sequence leading to HCN on both Titan and Jupiter and to formation of H2 from H on Titan. The first measurement of the ionization potentials for H2CN and D2CN was also made. From electron impact studies I.P. = (9.6 + or - 1.0) eV was obtained for both radicals. An upperlimit of I.P. less than 11.6 eV came from observations of the H2CN radical by photoionization mass spectrometry using an Ar resonance lamp (106.7 nm). Further photoionization experiments are planned using synchrotron radiation plus monochromator as a tunable vacuum UV light source.

Nesbitt, F. L.↗

NASA NTRS1990

Titan and other icy satellites - Dielectric properties of constituent materials and implications for radar sounding

Radar sounding observations of Titan and the other outer solar system icy satellites have been conducted in order to ascertain the materials present, their dielectric properties, and the degree of radar signal penetration. Deep penetration is possible at long wavelengths, while strong reflections may occur due to pockets or layers of H2O-NH3 solution. Attention is given to the case of Titan, using models to calculate radar reflection S/N ratios; the models involve H2O ice covered by a 100-m thick layer of organic sediments that are overlain by an ocean of liquid CH4-C2H6-N2. At 13.6-cm wavelength, a greater-than-10 dB S/N is computed from the ocean-sediment and sediment-ice interfaces, suggesting that the geology of Titan may be investigated by such a sounding mode despite deep ocean coverage of the satellite.

Thompson, W. Reid↗

NASA NTRS1991

Nitrogen airglow sources - Comparison of Triton, Titan, and earth

The individual contributions of direct solar excitation, photoelectron excitation, and magnetospheric electron excitation of Triton and Titan airglow observed by the Voyager Ultraviolet Spectrometer (UVS) are quantified. The principal spectral features of Triton's airglow are shown to be consistent with precipitation of magnetospheric electrons with power dissipation about 500 million W. Solar excitation rates of the dominant N2 and N(+) emission features are factors of 2-7 weaker than magnetospheric electron excitation. On Titan, the calculated disk center and bright limb N(+) 1085 A intensities due to solar excitation agree with observed values, while the 970 A feature is mostly N21 c5 band emission. The calculated LBH intensity by photoelectrons suggests that magnetospheric electrons play a minor role in Titan's UV airglow. On earth, solar/photoelectron excitation explains the observed N(+) 1085 A and LBH intensites and accounts for only 40 percent of the N(+) 916 A intensity.

Strobel, Darrell F.↗

NASA NTRS1991

The greenhouse and antigreenhouse effects on Titan

The parallels between the atmospheric thermal structure of the Saturnian satellite Titan and the hypothesized terrestrial greenhouse effect can serve as bases for the evaluation of competing greenhouse theories. Attention is presently drawn to the similarity between the roles of H2 and CH4 on Titan and CO2 and H2O on earth. Titan also has an antigreenhouse effect due to a high-altitude haze layer which absorbs at solar wavelengths, while remaining transparent in the thermal IR; if this haze layer were removed, the antigreenhouse effect would be greatly reduced, exacerbating the greenhouse effect and raising surface temperature by over 20 K.

Mckay, Christopher P.↗

NASA NTRS1991

Cassini Titan Radar Mapper

The Cassini Titan Radar Mapper is a multimode radar instrument designed to probe the optically inaccessible surface of Titan, Saturn's largest moon. The instrument is to be included in the payload of the Cassini Saturn Mission, scheduled for launch in 1995. The individual modes of Cassini Radar Mapper will allow topographic mapping and surface imaging at few hundred meters resolution. The requirements that lay behind the design are briefly discussed, and the configuration and capability of the instrument are described. The present limited knowledge of Titan's surface and the measurement requirements imposed on the radar instrument are addressed. Also discussed are the Cassini mission and the projected orbits, which imposed another set of design constraints that led to the multitude of modes and to an unconventional antenna configuration. The antenna configuration and the different radar modes are described.

Elachi, Charles↗

NASA NTRS1991

Photochemical reactions of cyanoacetylene and dicyanoacetylene: Possible processes in Titan's atmosphere

Titan has an atmosphere which is subject to dramatic chemical evolution due mainly to the dramatic effect of the UV flux from the Sun. The energetic solar photons and other particles are converting the methane-nitrogen atmosphere into the unsaturated carbon compounds observed by the Voyager probes. These same solar photons are also converting some of these unsaturated reaction products into the aerosols observed in the atmosphere which obscure the view of the surface of Titan. In particular, the photochemical reactions of cyanoacetylene, dicyanoacetylene, acetylene and ethylene may result in the formation of the higher hydrocarbons and polymers which result in the aerosols observed in Titan's atmosphere. Polymers are the principal reaction products formed by irradiation of cyanoacetylene and dicyanoacetylene. Irradiation of cyanoacetylene with 185 nm of light also yields 1,3,5-tricyanobenzene while irradiation at 254 nm yields 1,2,4-tricyanobenzene and tetracyano cyclooctatetraenes. Photolyses of mixtures of cyanoacetylene and acetylene yields mono- and di- cyanobenzenes. The 1-Cyanocyclobutene is formed from the photochemical addition of cyanoacetylene with ethylene. The photolysis of dicyanoacetylene with acetylene yields 2,3-dicyano-1,3-butadiene and 1,2-dicyanobenzene. Tetracyano cyclooctatetraene products were also observed in the photolysis of mixtures of dicyanoacetylene and acetylene with 254 nm light. The 1,2-Dicyano cyclobutene is obtained from the photolysis dicyanoacetylene and ethylene. Reaction mechanisms will be proposed to explain the observed photoproducts.

Ferris, J. P.↗

NASA NTRS1991

Optimum data analysis procedures for Titan 4 and Space Shuttle payload acoustic measurements during lift-off

Analytical expressions have been derived to describe the mean square error in the estimation of the maximum rms value computed from a step-wise (or running) time average of a nonstationary random signal. These analytical expressions have been applied to the problem of selecting the optimum averaging times that will minimize the total mean square errors in estimates of the maximum sound pressure levels measured inside the Titan IV payload fairing (PLF) and the Space Shuttle payload bay (PLB) during lift-off. Based on evaluations of typical Titan IV and Space Shuttle launch data, it has been determined that the optimum averaging times for computing the maximum levels are (1) T (sub o) = 1.14 sec for the maximum overall level, and T(sub oi) = 4.88 f (sub i) (exp -0.2) sec for the maximum 1/3 octave band levels inside the Titan IV PLF, and (2) T (sub o) = 1.65 sec for the maximum overall level, and T (sub oi) = 7.10 f (sub i) (exp -0.2) sec for the maximum 1/3 octave band levels inside the Space Shuttle PLB, where f (sub i) is the 1/3 octave band center frequency. However, the results for both vehicles indicate that the total rms error in the maximum level estimates will be within 25 percent the minimum error for all averaging times within plus or minus 50 percent of the optimum averaging time, so a precise selection of the exact optimum averaging time is not critical. Based on these results, linear averaging times (T) are recommended for computing the maximum sound pressure level during lift-off.

Piersol, Allan G.↗

NASA NTRS1992

Ground-based observations of Titan's thermal spectrum

Past, present and future observations of Titan's thermal spectrum are discussed. Ground based observations of Titan's mid-infrared thermal spectrum gave the first indications of the temperature regime and the role of hydrocarbons in the chemical composition. Significant progress exploring Titan using ground based observations may be achieved by increasing the spectral resolution, exploring new spectral regions, and by searching for seasonal or time dependent changes of the spectrum.

Orton, Glenn↗

NASA NTRS1992

The meteorology of Titan

Current knowledge of Titan's meteorology is reviewed, including diagnostic inferences of the large scale wind field and prognostic studies of thermal and momentum balances. Titan's winds were largely inferred from temperature maps whose spatial coverage is incomplete. The inferred winds are cyclostrophic, approximately 75 m/s in the upper stratosphere. The direction of the winds is ambiguous from the temperature data, but arguments based on the spin up of a planetary atmosphere from an initial state of rest strongly suggest that Titan's winds blow predominantly in the direction of the planetary rotation. Stratospheric temperatures exhibit a north-south asymmetry, suggesting that seasonal variations are controlled by a dynamical inertia associated with the need to transport angular momentum as well as heat. A consideration of the global angular momentum balance indicates that the zonally averaged winds near the surface are approximately 0.3 m/s.

Flasar, F. M.↗

NASA NTRS1992

Titan's organic chemistry: Results of simulation experiments

Recent low pressure continuous low plasma discharge simulations of the auroral electron driven organic chemistry in Titan's mesosphere are reviewed. These simulations yielded results in good accord with Voyager observations of gas phase organic species. Optical constants of the brownish solid tholins produced in similar experiments are in good accord with Voyager observations of the Titan haze. Titan tholins are rich in prebiotic organic constituents; the Huygens entry probe may shed light on some of the processes that led to the origin of life on Earth.

Sagan, Carl↗

NASA NTRS1992

VIMS/Cassini mission at Titan: Scientific objectives and observational scenarios

The scientific objectives and observational scenarios of the Cassini/Visual Infrared Mapping Spectrometer (VIMS) Mission at Titan are addressed. The VIMS represents a powerful and effective means to both investigate, in four dimensions (latitude, longitude, altitude, and time), Titan's atmospheric structure and to map the near infrared spectral character of Titan's surface. Its broad spectral coverage from 0.35 to 5.1 micrometers together with its significant spectral resolution allows it to determine minor constituent distributions and cloud optical/microphysical properties from the surface to several hundred km. A promising means of obtaining high vertical resolution stratospheric profiles of hydrocarbons, oxides, and hazes via stellar occultation observations is discussed.

Baines, Kevin H.↗

NASA NTRS1992

The ionosphere of Titan and its interaction with Saturnian magnetospheric electrons

The interaction of superthermal electrons, including both magnetospheric electrons and photoelectrons, with the upper atmosphere and ionosphere of Titan, is studied using a two stream electron transport code. Ionization rates, electron heating rates, and airglow emission rates are calculated. Results of a one dimensional model of the ionosphere of Titan, which includes both photoionization and ionization by magnetospheric electrons, are presented. Preliminary calculations of ionospheric ion outflow down the wake (or tail) of Titan, for time periods when the wake region is illuminated by the Sun, are made.

Cravens, Thomas E.↗

NASA NTRS1992

A model of the ionosphere of Titan

A 1D model is developed to study both the composition and density of Titan's structure. Ionization rates due both to photoionization by solar EUV flux and to electron impact ionization by photoelectrons and Saturnian magnetospheric electrons are included. The major neutral species (nitrogen and methane) are ionized to produce N2(+), N(+), CH4(+), CH3(+), CH2(+), and CH(+) ions. The total external pressure upstream of Titan at the time of the Voyager encounter is of the order of the maximum ionospheric thermal pressure. It is argued that the solar wind interaction with Venus during periods of high solar wind dynamic pressure might provide a good analogy for the interaction of Titan with the Saturnian magnetospheric plasma.

Keller, C. N.↗

NASA NTRS1992

Titan

The following topics are discussed with respect to Titan: observations of the atmosphere; laboratory simulations and theoretical models of Titan's atmosphere; endpoints of atmospheric chemistry - aerosols and oceans; exobiology; and the next steps in understanding Titan.

Owen, Tobias↗

NASA NTRS1993

Phase transition studies in barium and strontium titanates at microwave frequencies

The objectives were the following: to understand the phase transformations in barium and strontium titanates as the crystals go from one temperature to the other; and to study the dielectric behavior of barium and strontium titanate crystals at a microwave frequency of 9.12 GHz and as a function of temperature. Phase transition studies in barium and strontium titanate are conducted using a cylindrical microwave resonant cavity as a probe. The cavity technique is quite successful in establishing the phase changes in these crystals. It appears that dipole relaxation plays an important role in the behavior of the dielectric response of the medium loading the cavity as phase change takes place within the sample. The method of a loaded resonant microwave cavity as applied in this work has proven to be sensitive enough to monitor small phase changes of the cavity medium.

Dahiya, Jai N.↗

NASA NTRS1993

Monte Carlo analysis of the Titan III/Transfer Orbit Stage guidance system for the Mars Observer mission

An important part of space launch vehicle mission planning for a planetary mission is the integrated analysis of guidance and performance dispersions for both booster and upper stage vehicles. For the Mars Observer mission, an integrated trajectory analysis was used to maximize the scientific payload and to minimize injection errors by optimizing the energy management of both vehicles. This was accomplished by designing the Titan III booster vehicle to inject into a hyperbolic departure plane, and the Transfer Orbit Stage (TOS) to correct any booster dispersions. An integrated Monte Carlo analysis of the performance and guidance dispersions of both vehicles provided sensitivities, an evaluation of their guidance schemes and an injection error covariance matrix. The polynomial guidance schemes used for the Titan III variable flight azimuth computations and the TOS solid rocket motor ignition time and burn direction derivations accounted for a wide variation of launch times, performance dispersions, and target conditions. The Mars Observer spacecraft was launched on 25 September 1992 on the Titan III/TOS vehicle. The post flight analysis indicated that a near perfect park orbit injection was achieved, followed by a trans-Mars injection with less than 2sigma errors.

Bell, Stephen C.↗

NASA NTRS1994

The energetics of Titan's ionosphere

We have developed a comprehensive model to study the dynamics and energetics of the ionosphere of Titan. We solved the one-dimensional, time-dependent, coupled continuity and momentum equations for several ion species, together with single ion and electron energy equations, in order to calculate density, velocity, and temperature profiles. Calculations were carried out for several cases corresponding to different local times and configurations of the Titan-Saturn system. In our model the effects of horizontal magnetic fields were assumed to be negligible, except for their effect on reducing the electron and ion thermal conductivities and inhibiting vertical transport in the subram region. The ionospheric density peak was found to be at an altitude of about 1100 km, in accordance with earlier model calculations. The ionosphere is chemically controlled below an altitude of about 1500 km. Above this level, ion densities differ significantly from their chemical equilibrium values due to strong upward ion velocities. Heat is deposited in a narrow region around the ionospheric peak, resulting in temperature profiles increasing sharply and reaching nearly constant values of 800-1000 deg K for electrons and 300 deg K for ions in the topside, assuming conditions appropriate for the wake region. In the subram region magnetic correction factors make the electron heat conductivities negligible, resulting in electron temperatures increasing strongly with altitude and reaching values in the order of 5000 deg K at our upper boundary located at 2200 km. Ion chemical heating is found to play an important role in shaping the ion energy balance in Titan's ionosphere.

Roboz, A.↗

NASA NTRS1994

Gravity waves in Titan's atmosphere

Scintillations (high frequency variations) observed in the radio signal during the occultation of Voyager 1 by Titan (Hinson and Tyler, 1983) provide information concerning neutral atmospheric density fluctuations on scales on hundreds of meters to a few kilometers. Those seen at altitudes higher than 25 km above the surface were interpreted by Hinson and Tyler as being caused by linear, freely propagating (energy-conserving) gravity waves, but this interpretation was found to be inconsistent with the scintillation data below the 25-km altitude level. Here an attempt is made to interpret the entire scintillation profile between the surface and the 90-km altitude level in terms of gravity waves generated at the surface. Numerical calculations of the density fluctuations caused by two-dimensional, nonhydrostatic, finite-amplitude gravity waves propagating vertically through Titan's atmosphere are performed to produce synthetic scintillation profiles for comparison with the observations. The numerical model accurately treats the effects of wave transience, nonlinearity, and breakdown due to convective instability in the overturned part of the wave. The high-altitude scintillation data were accurately recovered with a freely propagating wave solution, confirming the analytic model of Hinson and Tyler. It is found that the low-altitude scintillation data can be fit by a model where a component of the gravity waves becomes convectively unstable and breaks near the 15 km level. The large-scale structure of the observed scintillation profile in the entire altitude range between 5 and 85 km can be simulated by a model where the freely propagating and breaking waves are forced at the surface simultaneously. Further analysis of the Voyager 1 Titan low-altitude scintillation data, using inversion theory appropriate for strong scattering, could potentially remove some of the ambiguities remaining in this analysis and allow a better determination of the strength and source of the waves.

Friedson, A. James↗