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At least 343 records · Page 19

Improving Proton Conductivity by Navigating Proton Trapping in High Scandium-Doped Barium Zirconate Electrolytes

Proton-conducting oxides are used in intermediate-temperature (300 °C < T < 700 °C) applications of fuel cells, electrolyzers, membrane reactors, hydrogen pumps, and sensors. The proton conductivity of doped ABO 3 perovskites is partly dependent on the proton concentration and hence on the level of material hydration. However, how the material hydration ability is affected by differences in doping is not fully understood. Here, we show the prospect of proton trapping and detrapping that influences material hydration and dehydration. The proton-trapping influence is significant for Sc-doped BaZrO 3 compared to Y-doped BaZrO 3 . Here, our work offers a perspective to understand how defect interaction/associations influence the hydration ability of proton-conducting oxides. Furthermore, positron annihilation lifetime spectroscopy was revealed to be a valuable technique for studying the proton-trapping phenomena and the defect chemistry of dense proton conductors. Density functional theory calculations also showed that a high hydration level in Sc-doped BaZrO 3 boosts proton migration. In contrast, the effect of boosting the proton migration due to increased hydration is limited for Y-doped BaZrO 3 . This effect, in turn, might explain the trend of conductivity with dopant concentration in doped BaZrO 3 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Inner-zone energetic-electron repopulation by radial diffusion.

Quantitative study of the intrusion of natural electrons into the inner radiation zone during and after the geomagnetic storm of Sept. 2, 1966. It is shown that the transport is consistent with a radial-diffusion mechanism in which the first two invariants are conserved. Except for the three-day period of the storm main phase when data were missing, the radial-diffusion coefficient is found to have a value which could be produced by a variation of a large-scale electric field across the magnetosphere having an amplitude of 0.28 mV/m and a period of 1600 sec. Electric fields having approximately these characteristics have been inferred from previous observations of the motion of whistler ducts within the plasmapause. If fields of this amplitude and period exist throughout the magnetosphere, the radial diffusion of all geomagnetically trapped particles except the high-energy inner-zone protons is strongly influenced by electric-field variations. A comprehensive review of previously reported radial-diffusion coefficients shows reasonable agreement for L less than about 3.0, but serious discrepancies among reported values exist for determinations made in the outer zone. These discrepancies cannot be explained by the simple theory of radial diffusion due to variation of large-scale electric or magnetic fields.

Tomassian, A. D.↗

History and Future of Isotope Production

Operations at the IPF were initiated in October 1976. LAMPF was delivering 800 MeV protons at a current of 300 µA. Initially, only pure-metal targets were selected for irradiation. These included Mo, Ni, Ta, Si, V, Al and Cu, which ranged in mass from a few to several hundred g. One program required a multi-Ci quantity of 88 Y that necessitated the irradiation and processing of more than 5 kg of Mo metal. As experience was gained, it was learned that oxide and salt targets could safely be irradiated, and eventually the sweeping and cold trapping of radioxenon gas from a molten CsCl during irradiation. Operations ended in 1992.

07 ISOTOPE AND RADIATION SOURCES↗

In situ cryogenic characterization of proton damage in thick p-channel skipper CCDs

Skipper charge-coupled devices (CCDs) are an offshoot of standard silicon pixel detectors and are capable of performing repeated non-destructive charge measurements, enabling deeply sub-electron readout noise. This capability has opened the door to single-photon counting from the near-infrared ($\sim$1.1 $μ$m) to the soft X-ray (several keV), making these devices strong candidates for future astronomical instruments operating in the photon-starved limit. Furthermore, the p-channel architecture used to fabricate Skipper CCDs on n-type silicon has been demonstrated to have an increased hardness to the intense radiation environment of space. Building upon previous irradiation campaigns on room-temperature sensors, here we describe the first radiation-hardness tests of p-channel skipper CCDs at their cryogenic operating temperatures. We assess the performance of the floating-gate output stage and global CCD parameters (charge transfer inefficiency, dark current, hot pixels, and charge traps). We find that these devices maintain excellent performance after displacement damage doses equivalent to ${\sim}$10 years at the Earth/Sun L2 Lagrange point, demonstrating for the first time that these sensors remain radiation-hard in realistic deep-space thermal and radiation environments.

Roach, Brandon M. [Chicago U., KICP] (ORCID:000000↗

Overview of Results from the Cassini Magnetospheric Imaging Instrument (MIMI) During the First Year of Operations

The MIMI investigation comprises three sensors covering the indicated energy ranges: the Ion and Neutral Camera (INCA) -- 7 keV/nuc 3 Mev) and protons (1.6 < E < 160 Mev) from the back end of the dual field-of-view telescope. The Saturn observation sequences began in January, 2004 and culminated in Saturn Orbit Insertion on July 1, 2004. The MIMI sensors observed substantial activity in interplanetary space for several months prior to SOI, including several interplanetary shocks associated with corotating interaction regions, numerous increases most likely originating from particle streams in the vicinity of the Saturnian bow shock and energetic neutral atoms (ENA) emanating from Saturn s magnetosphere. Results following SOI revealed: a dynamical magnetosphere with a day-night asymmetry and an 11-hour periodicity; several water-product ions (O+, OH+, H2O+), but little N+; inferred quantities of neutral gas sufficient to cause major losses in the trapped ions and electrons in the middle and inner magnetosphere; a Titan exosphere that is a copious source of ENA; INCA imaging through ENA has also revealed a previously unknown radiation belt residing inward of the D-ring that is most likely the result of double charge-exchange between the main radiation belt and the upper layers of Saturn s exosphere. Finally, there is ample evidence for the presence of substorm-like injections of plasma that subsequently corotates for a number of days before dissipating on the night-side magnetotail. The observations will be presented and discussed in the context of current theoretical models.

Krimigis, S. M.↗

Decreasing Proton Single Event Effects in CubeSats with Shielding

Shields-1, NORAD ID 43850,has been operating in polar low earth orbit since December 2018. The shielding has resulted in a lower total ionizing dose over time than typical aluminum thin-walled CubeSat structures. The reduced ionizing dosage caused by Shields-1 increases the reliability of commercial parts and reduces internal charging. Furthermore, the Shields-1 shielding reduces the ionizing particle fluence inside the spacecraft that contributes to the ionizing dose. NOVICE Sigma shielding software, using the (Aerospace Proton) AP8 –(Aerospace Electron) AE8 solar minimum trapped belt environment for a 1-year mission, estimates a 21.3 g/cm2 aluminum effective shielding for the Shields-1 electronics enclosure. This high areal density reduces not only the total number of energetic protons, but also reduces the number of ionizing particles over all modeled energies from the estimated shielded fluence for a 1-year mission. NOVICE Adjoint CAD modeling of the Shields-1 structure, with the detector located within the electronics enclosure, estimates that the total number of particles is reduced from 2.20x 10exp9 protons/cm2 to 1.52x 10exp8 protons/cm2, which represents 6.90% of the remaining particles(figure 1). By slowing down approximations of the integral proton fluence, a minimum proton threshold is estimated at 151 MeV. In comparison, a 0.204-cm aluminum thin-walled 3-unit (U) structure, with a 0.907 g/cm2 effective shielding, has 25.0% remaining particles and a minimum proton threshold of 36.2 MeV(figure 1). Proton energies that contribute to single event effects in radiation tolerant or higher semiconductor hardness are typically 100 MeV and higher. The Shields-1 electronics enclosure is estimated to attenuate energies: 100 MeV by 76.5%, 200 MeV by 61.7%, and 500 MeV by 63.0%(figure 2), when comparing the space environment proton differential fluence with the shielded differential fluence. The aluminum thin-walled structure is estimated to attenuate proton energies: 100 MeV by 13.7%, 200 MeV by 12.4%, and 500 MeV by 12.6%(figure 2), which are lower than for the Shields-1 electronics enclosure. The significant differences in attenuation between the Shields-1 electronics enclosure and aluminum thin-walled 3U structure show the additional utility of increasing shielding effectiveness for reducing the numbers of energetic protons that contribute to single event effects.

Larry Thomsen↗

The ONR-602 experiment and investigation of particle precipitation near the equator

The global precipitation of radiation belt particles at low altitude was investigated, using the ONR-602 experiment on board U.S. Air Force mission S81-1. A combination of a main telescope, beginning analysis at a few MeV/nucleon, and a monitor system, giving results below 1 MeV/nucleon, was designed for measuring particle phenomena characterized by almost any energy spectrum. The monitor provides an indication of the presence of the particles at low energy, while the main telescope gives detailed flux and composition data for the higher energy events. Results of the instrument performance analysis indicate that, at the equator, the monitor telescope has the peak efficiency for particles of about 90 deg pitch angles. The large opening angle of 75 deg makes it possible to detect omnidirectional flux of quasi-trapped particles. The high-energy cosmic-ray background count is found to be very insignificant. It is demonstrated that the particle counting rates for the low-energy threshold have been almost entirely due to protons.

Miah, M. A.↗

Dynamics of Solar Energetic Particles in Geospace

Solar energetic particles (SEPs) penetrate deep into the geospace and the Earth's atmosphere, initiating nuclear and chemical reactions. These reactions produce secondary hadrons, leptons, and photons, posing radiation hazards at commercial aviation altitudes, particularly during high-latitude flights. During solar particle events, protons with energies above 10 MeV can reach below 100 km altitude, causing ionization that disrupts HF communication and navigation in polar regions. Galactic Cosmic Rays (GCRs) and Solar Energetic Particles (SEPs) pose radiation risks to satellites, astronauts, and ground infrastructure. High-energy particles can lead to single-event effects in spacecraft electronics, such as upsets, latch-ups, and burnouts. These particles also interact with the Earth's atmosphere, generating ionization and secondary particles like hadrons, leptons, and photons, creating hazards for astronauts, especially during extravehicular activities. The work presented in the paper is focused on characterizing the SEP population in geospace in the altitude range starting from that of LEO through MEO and GEO, and up to the magnetopause accounting for the realistic geomagnetic field. The dynamics of SEPs are studied during quiet and geomagnetically active times using Monte Carlo simulations. The paper discusses the variability of the SEP population in geospace in response to geomagnetic activity. The former manifests in the temporal trapping of SEPs in geospace and the suppression of rigidity cutoff during geomagnetic storms.

Valeriy Tenishev↗

Precision mass measurement of lightweight self-conjugate nucleus 80 Zr

Protons and neutrons in the atomic nucleus move in shells analogous to the electronic shell structures of atoms. The nuclear shell structure varies due to changes of the nuclear mean field with the number of neutrons N and protons Z, and these variations can be probed by measuring mass differences between nuclei. The N=Z=40 self-conjugate nucleus 80 Zr is of particular interest as its proton and neutron shell structures are expected to be very similar, and its ground state is highly deformed. Here, we provide evidence for the existence of a deformed double shell closure in 80Zr through high precision Penning trap mass measurements of 80-83 Zr. Our mass values show that 80Zr is significantly lighter, and thus more strongly bound than predicted. This can be attributed to the deformed shell closure at N=Z=40 and the large Wigner energy. A statistical Bayesian model mixing analysis employing several global nuclear mass models demonstrates difficulties with reproducing the observed mass anomaly using current theory.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Complex Organics from Laboratory Simulated Interstellar Ices

Many of the volatiles in interstellar dense clouds exist in ices surrounding dust grains. The low temperatures of these ices (T < 50 K) preclude most chemical reactions, but photolysis can drive reactions that produce a suite of new species, many of which are complex organics. We study the UV and proton radiation processing of interstellar ice analogs to explore links between interstellar chemistry, the organics in comets and meteorites, and the origin of life on Earth. The high D/H ratios in some interstellar species, and the knowledge that many of the organics in primitive meteorites are D-enriched, suggest that such links are plausible. Once identified, these species may serve as markers of interstellar heritage of cometary dust and meteorites. Of particular interest are our findings that UV photolysis of interstellar ice analogs produce molecules of importance in current living organisms, including quinones, amphiphiles, and amino acids. Quinones are essential in vital metabolic roles such as electron transport. Studies show that quinones should be made wherever polycyclic aromatic hydrocarbons are photolyzed in interstellar ices. In the case of anthracene-containing ices, we have observed the production of 9-anthrone and 9,10 anthraquinone, both of which have been observed in the Murchison meteorite. Amphiphiles are also made when mixed molecular ices are photolyzed. These amphiphiles self-assemble into fluorescent vesicles when placed in liquid water, as do Murchison extracts. Both have the ability to trap an ionic dye. Photolysis of plausible ices can also produce alanine, serine, and glycine as well as a number of small alcohols and amines. Flash heating of the room temperature residue generated by such experiments generates mass spectral distributions similar to those of IDPs. The detection of high D/H ratios in some interstellar molecular species, and the knowledge that many of the organics, such as hydroxy and amino acids, in primitive meteorites are D-enriched provides evidence for a connection between intact organic material in the interstellar medium and in meteorites. Thus, some of the oxidized aromatics, amphiphiles, amino acids, hydroxy acids, and other compounds found in meteorites may have had an interstellar ancestry and not solely a product of parent body aqueous alteration. Such compounds should also be targeted for searches of organics in cometary dust.

Dworkin, J. P.↗

A new moment-based general-relativistic neutrino-radiation transport code: Methods and first applications to neutron star mergers

ABSTRACT We present a new moment-based energy-integrated neutrino transport code for neutron star merger simulations in general relativity. In the merger context, ours is the first code to include Doppler effects at all orders in υ/c, retaining all non-linear neutrino–matter coupling terms. The code is validated with a stringent series of tests. We show that the inclusion of full neutrino–matter coupling terms is necessary to correctly capture the trapping of neutrinos in relativistically moving media, such as in differentially rotating merger remnants. We perform preliminary simulations proving the robustness of the scheme in simulating ab-initio mergers to black hole collapse and long-term neutron star remnants up to ${\sim }70\,$ ms. The latter is the longest dynamical space-time, 3D, general relativistic simulations with full neutrino transport to date. We compare results obtained at different resolutions and using two different closures for the moment scheme. We do not find evidences of significant out-of-thermodynamic equilibrium effects, such as bulk viscosity, on the post-merger dynamics or gravitational wave emission. Neutrino luminosities and average energies are in good agreement with theory expectations and previous simulations by other groups using similar schemes. We compare dynamical and early wind ejecta properties obtained with M1 and with our older neutrino treatment. We find that the M1 results have systematically larger proton fractions. However, the differences in the nucleosynthesis yields are modest. This work sets the basis for future detailed studies spanning a wider set of neutrino reactions, binaries, and equations of state.

79 ASTRONOMY AND ASTROPHYSICS↗

Uncertainties in Estimates of the Risks of Late Effects from Space Radiation

The health risks faced by astronauts from space radiation include cancer, cataracts, hereditary effects, and non-cancer morbidity and mortality risks related to the diseases of the old age. Methods used to project risks in low-Earth orbit are of questionable merit for exploration missions because of the limited radiobiology data and knowledge of galactic cosmic ray (GCR) heavy ions, which causes estimates of the risk of late effects to be highly uncertain. Risk projections involve a product of many biological and physical factors, each of which has a differential range of uncertainty due to lack of data and knowledge. Within the linear-additivity model, we use Monte-Carlo sampling from subjective uncertainty distributions in each factor to obtain a Maximum Likelihood estimate of the overall uncertainty in risk projections. The resulting methodology is applied to several human space exploration mission scenarios including ISS, lunar station, deep space outpost, and Mar's missions of duration of 360, 660, and 1000 days. The major results are the quantification of the uncertainties in current risk estimates, the identification of factors that dominate risk projection uncertainties, and the development of a method to quantify candidate approaches to reduce uncertainties or mitigate risks. The large uncertainties in GCR risk projections lead to probability distributions of risk that mask any potential risk reduction using the "optimization" of shielding materials or configurations. In contrast, the design of shielding optimization approaches for solar particle events and trapped protons can be made at this time, and promising technologies can be shown to have merit using our approach. The methods used also make it possible to express risk management objectives in terms of quantitative objective's, i.e., the number of days in space without exceeding a given risk level within well defined confidence limits.

Cucinotta, F. A.↗

Characterizing hole trap production due to proton irradiation in germanium cross-strip detectors

We present an investigation into the effects of high-energy proton damage on charge trapping in germanium cross-strip detectors with the goal of accomplishing three important measurements. First, we calibrated and characterized the spectral resolution of a spare COSI-balloon detector in order to determine the effects of intrinsic trapping, finding that electron trapping due to impurities dominates over hole trapping in the undamaged detector. Second, we performed two rounds of proton irradiation of the detector in order to quantify, for the first time, the rate at which charge traps are produced by proton irradiation. We find that the product of the hole trap density and cross-sectional area, [nσ] h , follows a linear relationship with the proton fluence, F p , with a slope of (5.4 ± 0.4) x 10 -11 cm/p + . Third, by utilizing our measurements of physical trapping parameters, we performed calibrations which corrected for the effects of trapping and mitigated degradation to the spectral resolution of the detector.

79 ASTRONOMY AND ASTROPHYSICS↗

Radiation Environment and Surface Radiolytic Interactions at Mimas

Saturn's innermost principal moon Mimas shares the distinction with Europa at Jupiter of being the most irradiated icy moon in its respective planetary system, although the energetic electron energy flux at Mimas is forty times smaller than at Europa. High energy (> 10 MeV) proton fluxes are low in this moon's orbital corridor, likely since slowly diffusing protons from the weak but steady source of cosmic ray albedo neutron decay (CRAND) cannot accumulate without impacting the moon surface. Lower energy proton fluxes are also evidently suppressed in this orbital region. Plasma ion and electron fluxes are also low apparently due to cooling by interaction with E-ring dust and neutral gas from Enceladus. Due to energy-dependent effects of longitudinal gradient-curvature drift for the electrons, the trailing hemisphere is mainly irradiated by electrons at energies below 1 MeV that drift relative to Mimas in the prograde direction of orbital motion around Saturn, while higher energy electrons primarily impact the leading hemisphere. Plasma ions in the inner magnetosphere of Saturn are mainly pickup ions forming from the dissociation products of Enceladus plume water molecules, additionally including some contribution from photosputtering of the main rings, and do not introduce new elemental materials at Mimas via surface implantation from the corotating plasma. Thus the primary interaction at the surface is radiolytic chemistry induced in pure water ice by relatively deep penetration of the energetic electrons to millimeter and greater depths, as compared to the micron depths impacted by the corotating plasma ions. If surface erosion by sputtering from relatively low fluxes of the plasma and more energetic ions is indeed ineffective, then molecular products (OH, H2O2, 02, 03) of the radiolytic interactions may accumulate in the meters-deep impact regolith of the surface ices. An effect of regolith trapped gas accumulation could be to increase porosity and reduce thermal conductivity of the ice, potentially contributing to reported thermal anomalies from Cassini infrared map observations. Low amplitude of trailing-leading asymmetry in optical albedo and color maps at Mimas is suggestive of relative weakness of asymmetrical effects from low-energy ions. Greater induced asymmetries are expected and observed for the moons beyond Enceladus in the middle magnetospheric region of hot plasma ions at much greater fluxes than at Mimas. Low density (1.15 g/cc) of this moon indicates paucity of mineral salts and radiogenic heating to maintain subsurface liquids, so Enceladus-like cryovolcanism as a resurfacing process is unlikely despite closer proximity to Saturn, greater tidal forcing, and more intense surface irradiation than for Enceladus.

Cooper, J. F.↗

Fill and dump measurement of the neutron lifetime using an asymmetric magneto-gravitational trap

The past two decades have yielded several new measurements and reanalysis of older measurements of the neutron lifetime. These have led to a 4.4 standard deviation discrepancy between the most precise measurements of the neutron decay rate producing protons in cold neutron beams and the most precise lifetime measured in neutron storage experiments. Measurements using different techniques are important for investigating whether there are unidentified systematic effects in any of the measurements. In this paper we report a new measurement using the Los Alamos asymmetric magneto-gravitational trap where the surviving neutrons are counted external to the trap using the fill and dump method. In this work, the new measurement gives a free neutron lifetime of $τ_n$ = 876.3(2.4) stat (0.8) syst . Although this measurement is not as precise, it is in statistical agreement with previous results using in situ counting in the same apparatus.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Bulk viscosity of nuclear matter with pions in the neutrino-trapped regime

Recent work has shown that a population of thermal pions could modify the equation of state and transport properties of hot and dense neutron-rich matter and introduce new reaction pathways to change the proton fraction. In this article we study their impact on the bulk viscosity of dense matter, focusing on the neutrino-trapped regime that would be realized in neutron star mergers and supernovae. We find that the presence of a thermal population of pions alters the bulk viscosity by modifying the EoS (via the susceptibilities) and by providing new reaction pathways to achieve beta equilibrium. In neutron star merger conditions, the bulk viscosity in neutrino-trapped npeμ matter (without pions) has its peak at temperatures of at most a couple MeV and is quite small at temperatures of tens of MeV. We find that thermal pions enhance the low-temperature peak of the bulk viscosity by a factor of a few and shift it to slightly lower temperatures. At higher temperatures, where the pion abundance is large but the bulk viscosity is traditionally small, pions can increase the bulk viscosity by an order of magnitude or more, although it is still orders of magnitude smaller than its peak value.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Measurements of LET distribution and dose equivalent onboard the Space Shuttle IML-2 (STS-65) and S/MM#4 (STS-79)

Space radiation dosimetry measurements have been made onboard the Space Shuttle STS-65 in the Second International Microgravity Laboratory (IML-2: 28.5 degrees x 300 km: 14.68 days) and the STS-79 in the 4th Shuttle MIR mission (S/MM#4: 51.6 degrees x 300-400km: 10.2 days). In these measurements, three kinds of detectors were used; one is a newly developed active detector telescope called "Real-time Radiation Monitoring Device (RRMD-I for IML-2 and RRMD-II with improved triggering system for S/MM#4)" utilizing silicon semi-conductor detectors and the other detectors are conventional passive detectors of thermoluminescence dosimeters (TLDs) and CR-39 plastic track detectors. The main contribution to dose equivalent for particles with LET > 5.0 keV/micrometer (IML-2) and LET > 3.5 keV/micrometer (S/MM#4) is seen to be due to galactic cosmic rays (GCRs) and the contribution of the South Atlantic Anomaly (SAA) is less than 5% (IML-2: 28.5 degrees x 300 km) and 15% (S/MM#4: 51.6 degrees x 400 km) in the above RRMD LET detection conditions. For the whole LET range (> 0.2 kev/micrometer) obtained by TLDs and CR-39 in these two typical orbits (a small inclination x low altitude and a large inclination x high altitude), absorbed dose rates range from 94 to 114 microGy/day, dose equivalent rates from 186 to 207 microSv/day and average quality factors from 1.82 to 2.00 depending on the locations and directions of detectors inside the Spacelab at the highly protected IML-2 orbit (28.5 degrees x 300 km), and also, absorbed dose rates range from 290 to 367 microGy/day, dose equivalent rates from 582 to 651 microSv/day and average quality factors from 1.78 to 2.01 depending on the dosimeter packages around the RRMD-II "Detector Unit" at the S/MM#4 orbit (5l.6 degrees x 400km). In general, it is seen that absorbed doses depend on the orbit altitude (SAA trapped particles contribution dominant) and dose equivalents on the orbit inclination (GCR contribution dominant). The LET distributions obtained by two different types of active and passive detectors, RRMDs and CR-39, are in good agreement for LET of 15 - 200 kev/micrometer and difference of these distributions in the regions of LET < 15 kev/micrometer and LET > 200 kev/micrometer can be explained by considering characteristics of CR-39 etched track formation especially for the low LET tracks and chemical etching conditions.

manned↗

Fill and dump measurement of the neutron lifetime using an asymmetric magneto-gravitational trap

The past two decades have yielded several new measurements and reanalysis of older measurements of the neutron lifetime. These have led to a 4.4 standard deviation discrepancy between the most precise measurements of the neutron decay rate producing protons in cold neutron beams and the most precise lifetime measured in neutron storage experiments. Measurements using different techniques are important for investigating whether there are unidentified systematic effects in any of the measurements. In this paper we report a new measurement using the Los Alamos asymmetric magnetogravitational trap where the surviving neutrons are counted external to the trap using the fill and dump method. The new measurement gives a free neutron lifetime of $τ_n$ = 876.3(2.4) stat (0.8) syst . Although this measurement is not as precise, it is in statistical agreement with previous results using in situ counting in the same apparatus.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗