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At least 343 records · Page 19

Unique Temperature Trend Pattern Associated With Internally Driven Global Cooling and Arctic Warming During 1980–2022

Abstract Diagnosing the role of internal variability over recent decades is critically important for both model validation and projections of future warming. Recent research suggests that for 1980–2022 internal variability manifested as Global Cooling and Arctic Warming (i‐GCAW), leading to enhanced Arctic Amplification (AA), and suppressed global warming over this period. Here we show that such an i‐GCAW is rare in CMIP6 large ensembles, but simulations that do produce similar i‐GCAW exhibit a unique and robust internally driven global surface air temperature (SAT) trend pattern. This unique SAT trend pattern features enhanced warming in the Barents and Kara Sea and cooling in the Tropical Eastern Pacific and Southern Ocean. Given that these features are imprinted in the observed record over recent decades, this work suggests that internal variability makes a crucial contribution to the discrepancy between observations and model‐simulated forced SAT trend patterns.

54 ENVIRONMENTAL SCIENCES↗

Modeling Spatial Asymmetries in Teleconnected Extreme Temperatures

Abstract Combining strengths from deep learning and extreme value theory can help describe complex relationships between variables where extreme events have significant impacts (e.g., environmental or financial applications). Neural networks learn complicated nonlinear relationships from large datasets under limited parametric assumptions. By definition, the number of occurrences of extreme events is small, which limits the ability of the data-hungry, nonparametric neural network to describe rare events. Inspired by recent extreme cold winter weather events in North America caused by atmospheric blocking, we examine several probabilistic generative models for the entire multivariate probability distribution of daily boreal winter surface air temperature. We propose metrics to measure spatial asymmetries, such as long-range anticorrelated patterns that commonly appear in temperature fields during blocking events. Compared to vine copulas, the statistical standard for multivariate copula modeling, deep learning methods show improved ability to reproduce complicated asymmetries in the spatial distribution of ERA5 temperature reanalysis, including the spatial extent of in-sample extreme events.

Krock, Mitchell L.↗

The short-term comprehensive impact of the phase-out of global coal combustion on air pollution and climate change

With the continuous intensification of global warming, the reduction and ultimate phase-out of coal combustion is an inevitable trend in the future global energy transformation. This study comprehensively analyzed the impact of phasing out coal combustion on global emissions and concentrations of air pollutants, radiative fluxes, meteorology and climate using Community Earth System Model 2 (CESM2). The results indicate that after the global phase-out of coal combustion, there is a marked decrease in the concentrations of sulfur dioxide (SO 2 ), nitrogen oxides (NO x ) and fine particulate matter (PM 2.5 ), with some regions experiencing a reduction of exceeding 50%. There is no significant change in global ozone (O 3 ) concentration. There are decreasing AOD and positive radiative fluxes globally in the short term, though the cloud contributes minor negative radiative fluxes. The global air temperature may increase by approximately (0.02 ± 0.15) °C on average with regional and seasonal variations, and the precipitation may potentially increase by approximately (2.7 ± 40.6) mm yr −1 globally and over 20% in equatorial regions in the short term. But combined with the decreasing trend of cloud water content in the Northern Hemisphere, it indicates a potential increase in the extremity of precipitation events. In conclusion, this study provides references for global control of air pollution, mitigation strategies of climate change, and transformation of energy structures under the objective of “carbon neutrality”, such as focusing on the negative climate impacts of exacerbating regional warming and increasing extreme precipitation resulting from the rapid reduction of aerosols in the short term.

01 COAL, LIGNITE, AND PEAT↗

Hyper‐Local Temperature Prediction Using Detailed Urban Climate Informatics

The accurate modeling of urban microclimate is a challenging task given the high surface heterogeneity of urban land cover and the vertical structure of street morphology. Recent years have witnessed significant efforts in numerical modeling and data collection of the urban environment. Nonetheless, it is difficult for the physical‐based models to fully utilize the high‐resolution data under the constraints of computing resources. The advancement in machine learning (ML) techniques offers the computational strength to handle the massive volume of data. In this study, we proposed a modeling framework that uses ML approach to estimate point‐scale street‐level air temperature from the urban‐resolving meso‐scale climate model and a suite of hyper‐resolution urban geospatial data sets, including three‐dimensional urban morphology, parcel‐level land use inventory, and weather observations from a sensor network. We implemented this approach in the City of Chicago as a case study to demonstrate the capability of the framework. The proposed approach vastly improves the resolution of temperature predictions in cities, which will help the city with walkability, drivability, and heat‐related behavioral studies. Moreover, we tested the model's reliability on out‐of‐sample locations to investigate the modeling uncertainties and the application potentials to the other areas. This study aims to gain insights into next‐gen urban climate modeling and guide the observation efforts in cities to build the strength for the holistic understanding of urban microclimate dynamics.

54 ENVIRONMENTAL SCIENCES↗

Assessment of peak power demand reduction available via modulation of building ventilation systems.

Peak power demand strains electrical grids and increases cost of electricity generation, transmission and distribution infrastructure. Many studies have examined ways of reducing peak power demand, including modification of room air temperature setpoints or reduction of lighting levels. However, very few or no studies have examined the peak power reduction resource offered by temporary curtailment of building ventilation systems. For this reason, we conducted a simulation campaign in which we examined the resource offered by temporary ventilation curtailment in commercial buildings of different use types across the United States and in residences in the state of California, with the essential constraint that any changes resulted in air quality acceptable to occupants through additional ventilation to compensate for the curtailment. To do this, we employed previously validated building models implemented in the airflow and contaminant transport tool CONTAM and building thermal and systems modeling tool EnergyPlus, in some cases co-simulated. Overall, results show savings are highly dependent on building type and climate but range from 0–2 W/ft 2 and up to 40% of total peak building power demand. Depending on building type, this power shed can be conducted for 1.5–8 h before acute exposure or odor concerns are expected, assuming a safety factor of 2. This reduction is of the same magnitude as that offered by thermal control strategies such as setpoint increase, or from lighting reduction strategies.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Impacts of Wildfire Aerosols on Global Energy Budget and Climate: The Role of Climate Feedbacks

Aerosols emitted from wildfires could significantly affect global climate through perturbing global radiation balance. In this study, the Community Earth System Model with prescribed daily fire aerosol emissions is used to investigate fire aerosols’ impacts on global climate with emphasis on the role of climate feedbacks. The total global fire aerosol radiative effect (RE) is estimated to be -0.78 ± 0.29 W m -2 , which is mostly from shortwave RE due to aerosol–cloud interactions (REaci; -0.70 ± 0.20 W m -2 ). The associated global annual-mean surface air temperature (SAT) change ΔT is -0.64 ± 0.16 K with the largest reduction in the Arctic regions where the shortwave REaci is strong. Associated with the cooling, the Arctic sea ice is increased, which acts to reamplify the Arctic cooling through a positive ice-albedo feedback. The fast response (irrelevant to ΔT) tends to decrease surface latent heat flux into atmosphere in the tropics to balance strong atmospheric fire black carbon absorption, which reduces the precipitation in the tropical land regions (southern Africa and South America). The climate feedback processes (associated with ΔT) lead to a significant surface latent heat flux reduction over global ocean areas, which could explain most (~80%) of the global precipitation reduction. The precipitation significantly decreases in deep tropical regions (5°N) but increases in the Southern Hemisphere tropical ocean, which is associated with the southward shift of the intertropical convergence zone and the weakening of Southern Hemisphere Hadley cell. Such changes could partly compensate the interhemispheric temperature asymmetry induced by boreal forest fire aerosol indirect effects, through intensifying the cross-equator atmospheric heat transport.

54 ENVIRONMENTAL SCIENCES↗

Microwave-Assisted Reactive CO 2 Capture with the SrCO 3 -Graphite System

This study details the initial development of a microwave heat-driven reactive CO 2 capture (RCC) process using the SrO/SrCO 3 cycle and graphitic carbon to absorb ppm-levels of CO 2 from humidified room temperature air and selectively convert it into CO. By combining first-principles density functional theory (DFT) simulations with thermogravimetric analysis (TGA) and X-ray diffraction (XRD) verification, it is demonstrated that SrO spontaneously absorbs moisture to generate Sr(OH) 2 followed by Sr(OH) 2 *1H 2 O, which then can spontaneously react with atmospheric levels of CO 2 to form SrCO 3 . The resulting SrCO 3 can then react with solid carbon at elevated temperatures to selectively produce CO and regenerate SrO. Graphitic carbon is an excellent microwave absorber that can quickly generate temperatures approaching 1000 °C and then cool to room temperature within minutes, potentially allowing for integration with intermittent electricity. It is shown that using microwaves to selectively heat a mixture of graphitic carbon and SrCO 3 produced CO with 85 ± 3% selectivity and stable performance over ten cycles. The rapid heating for release and room temperature CO 2 uptake processes appeared to prevent performance loss from particle sintering typically observed with traditional thermal systems. In conclusion, these results demonstrate a new RCC approach that adds to the growing number of potential technologies available for converting CO 2 to useful chemicals.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Limited thermal acclimation of photosynthesis in tropical montane tree species

Abstract The temperature sensitivity of physiological processes and growth of tropical trees remains a key uncertainty in predicting how tropical forests will adjust to future climates. In particular, our knowledge regarding warming responses of photosynthesis, and its underlying biochemical mechanisms, is very limited. We grew seedlings of two tropical montane rainforest tree species, the early‐successional species Harungana montana and the late‐successional species Syzygium guineense , at three different sites along an elevation gradient, differing by 6.8℃ in daytime ambient air temperature. Their physiological and growth performance was investigated at each site. The optimum temperature of net photosynthesis ( T optA ) did not significantly increase in warm‐grown trees in either species. Similarly, the thermal optima ( T optV and T optJ ) and activation energies ( E aV and E aJ ) of maximum Rubisco carboxylation capacity ( V cmax ) and maximum electron transport rate ( J max ) were largely unaffected by warming. However, V cmax , J max and foliar dark respiration ( R d ) at 25℃ were significantly reduced by warming in both species, and this decline was partly associated with concomitant reduction in total leaf nitrogen content. The ratio of J max / V cmax decreased with increasing leaf temperature for both species, but the ratio at 25℃ was constant across sites. Furthermore, in H . montana , stomatal conductance at 25℃ remained constant across the different temperature treatments, while in S . guineense it increased with warming. Total dry biomass increased with warming in H . montana but remained constant in S . guineense . The biomass allocated to roots, stem and leaves was not affected by warming in H . montana , whereas the biomass allocated to roots significantly increased in S . guineense . Overall, our findings show that in these two tropical montane rainforest tree species, the capacity to acclimate the thermal optimum of photosynthesis is limited while warming‐induced reductions in respiration and photosynthetic capacity rates are tightly coupled and linked to responses of leaf nitrogen.

54 ENVIRONMENTAL SCIENCES↗

Performance Results from DOE Cold Climate Heat Pump Challenge Field Validation

Space conditioning and water heating consume over 40% of the nation’s primary energy use and represent a significant component of many homeowners’ monthly energy bill. However, in cold climates, performance of heat pumps has traditionally suffered as the units have been unable to efficiently transfer heat from colder outdoor air temperatures to warm the interior space of homes. Optimizing heat pumps for cold climates (5 °F and below) requires coordinated effort to ensure heat pump technologies can be enjoyed by Americans living in these regions. The DOE Cold Climate Heat Pump (CCHP) Challenge sought to address this challenge by partnering with industry to develop, test, and validate the performance of new, highly efficient heat pumps in real homes. The Challenge, launched in 2021, brought together leading heating, ventilation, and air conditioning (HVAC) manufacturers to develop prototype units optimized for performance at cold climates. This report summarizes results from the field validation that occurred 2022-2024.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Role of the Terrestrial Biosphere in Atmospheric Chemistry and Climate

The terrestrial biosphere–atmosphere interface provides a key chemical, biological, and physical lower boundary for the atmosphere. The presence of vegetation itself modifies the physical boundary, or the biogeophysical aspects of the system, by controlling important climate drivers such as soil moisture, light environment, and temperature. The leaf surface area of the terrestrial biosphere provides additional surface area for emissions, and it can be up to 55% of the total Earth’s surface area during the boreal summer. Vegetation also influences the biogeochemical aspects of the system by emitting a broad suite of reactive trace gases such as biogenic volatile organic compound (BVOC) emissions and climate-relevant primary biological aerosol particles (PBAP). Many of these emissions are a function of meteorological and climatological conditions at the surface, including temperature, light environment, soil moisture, and winds. Once emitted, they can be processed in the troposphere through a suite of chemical reactions. BVOC can contribute to the formation of ozone and secondary organic aerosols (SOA), and PBAP can rupture to form smaller particles with climatic relevance. These emissions and subsequent aerosol products can influence atmospheric processes that affect the surface climate, such as the attenuation of radiation, the formation of greenhouse gases such as ozone that can feedback to surface air temperature, and the alteration of clouds and subsequent precipitation. These atmospheric changes can then feedback to the land surface and emissions themselves, creating positive or negative feedback loops that can dampen or amplify the emission response. For the dominant BVOC isoprene, the feedback response to temperature can be positive or negative depending on ambient temperatures that drive isoprene emissions. The feedback response to soil moisture and precipitation can be positive, negative, or uncoupled depending on the moisture content of the soil and the total atmospheric aerosol loading. For light, the isoprene response can be positive or negative depending on the role of diffuse light. Overall, these feedbacks highlight the dynamical response of the biosphere to changing atmospheric conditions across a range of time scales, from minutes for trace gases and aerosols, to months for phenological changes, to years for land cover and land use change. Here, the dynamic aspect of this system requires us to understand, simulate, and predict the complex feedbacks between the biosphere and atmosphere and understand their role in the simulation and understanding of climate and global change. From the observational perspective, these feedbacks are challenging to identify in observations, and predictive modeling tools provide a crucial link for understanding how these feedbacks will change under warming climate scenarios.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Advancing the Understanding of Snow Accumulation, Melting, and Associated Thermal Insulation Using Spatially Dense Snow Depth and Temperature Time Series

Snow thermal insulation is a critical factor influencing ground thermal dynamics and associated biogeochemical processes. We analyzed the spatiotemporal variability of snow accumulation, melting, and thermal insulation dynamics using spatially dense, collocated snow depth and ground interface temperature time series over two consecutive years. We demonstrated that considering late‐winter snow depth alone was insufficient to fully capture the complexity in snow and insulation dynamics. The influence of vegetation and topography on snow depth distribution varied over the season, across sites and years. We found that deep snow with a long melting period had a substantial impact on thawing n‐factors. To better predict snow insulation effects, we proposed a new weighted snow depth metric that integrates mean daily snow depth and air temperature throughout the cold season. Our results provide insights for developing space‐time remote sensing products and evaluating the representation of snow and permafrost processes in Earth system models.

54 ENVIRONMENTAL SCIENCES↗

AmeriFlux US-GL1 Stannard Rock

This is the AmeriFlux version of the carbon flux data for the site US-GL1 Stannard Rock. Site Description - Stannard Rock is located 39 km from the nearest shore (Keweenaw Peninsula) in Lake Superior, 44 miles NNE of Marquette, Michigan, and 24 miles ESE of Manitou Island. The site is located on the historic Stannard Rock Lighthouse, which was completed in 1882. Eddy covariance instrumentation was installed in 2008 by a network of scientists from both US and Canada, eventually to be called the Great Lakes Evaporation Network (GLEN). The intent of GLEN has been to provide observations of over-lake meteorology and evaporation, improve forecasting of Great Lakes water levels, and support a wide variety of stakeholders, including the National Weather Service (NWS), Environment and Climate Change Canada, National Oceanic and Atmospheric Administration, U.S. Coast Guard, recreational boaters and commercial shipping, emergency management officials, and the Great Lakes research community. The eddy covariance station along with other ancillary meteorological instrumentation is located at an approximate elevation of 39.2 meters above mean lake water level. Meteorological data from the lighthouse are sent to the National Data Buoy Center, where they can be viewed in real-time at http://www.ndbc.noaa.gov/station_page.php?station=stdm4 Uncorrected half-hour fluxes were computed directly on the logger using a 30-minute block averaging period as high-frequency data were not available. The half hour flux measurements downloaded from the datalogger were post-processed with the following filters and corrections. Latent and sensible heat and carbon dioxide fluxes were corrected with 2-D coordinate rotation. Although the primary objective of data collection at Stannard Rock was to quantify the evaporative flux, additional preliminary measurements of the carbon dioxide concentration and flux from the LI-7500 are also included in this dataset but it is advised to use the carbon data with caution. Carbon data reported in this dataset includes turbulent fluxes of CO2 with no storage correction (FC, µmol m-2 s-1) and CO2 density in mole fraction of wet air (CO2), which was originally output on the datalogger as average CO2 density (mg m-2 s-1) and converted into µmol mol-1 using air temperature and pressure in post-processing. Webb, Pearman, and Leuning terms were applied to account for density fluctuations for water vapor and CO2. Sonic path length, high-frequency attenuation and sensor separation were accounted for according to Horst and Massman, and the oxygen absorption correction for the KH2O hygrometer was also applied. Latent and sensible heat fluxes were assumed to be unrealistic above an absolute value of 1000 W m-2 and were removed. Both carbon flux (FC) and carbon dioxide mole fraction in wet air (CO2) and were assumed to be unrealistic above 1000 µmol m-2 s-1 and 1000 µmol mol-1 respectively. Spikes in latent and sensible heat and carbon fluxes and densities (often due to periods of precipitation) were identified by computing the mean and standard deviation over a moving, overlapping window of 336 half-hours (7 days), similar to Shao et al., and were removed when the flux was more than 1.5 standard deviations from the moving window’s mean. While Vickers and Mahrt use a threshold of 3.5 standard deviations from the mean, a conservative value of 1.5 was chosen due to the noisy nature of over-lake data at this particular site. This process was repeated twice for latent and sensible heat, and carbon dioxide fluxes and densities and therefore it is possible that some real, realistic data was filtered out in this process. No detrending was performed. As per AmeriFlux standards, no friction velocity (USTAR, m s-1) filtering was performed.

Spence, Chris↗

AmeriFlux FLUXNET-1F US-GL1 Stannard Rock

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-GL1 Stannard Rock. This is the FLUXNET version of the carbon flux data for the site US-GL1 Stannard Rock produced by applying the standard ONEFlux (1F) software. Site Description - Stannard Rock is located 39 km from the nearest shore (Keweenaw Peninsula) in Lake Superior, 44 miles NNE of Marquette, Michigan, and 24 miles ESE of Manitou Island. The site is located on the historic Stannard Rock Lighthouse, which was completed in 1882. Eddy covariance instrumentation was installed in 2008 by a network of scientists from both US and Canada, eventually to be called the Great Lakes Evaporation Network (GLEN). The intent of GLEN has been to provide observations of over-lake meteorology and evaporation, improve forecasting of Great Lakes water levels, and support a wide variety of stakeholders, including the National Weather Service (NWS), Environment and Climate Change Canada, National Oceanic and Atmospheric Administration, U.S. Coast Guard, recreational boaters and commercial shipping, emergency management officials, and the Great Lakes research community. The eddy covariance station along with other ancillary meteorological instrumentation is located at an approximate elevation of 39.2 meters above mean lake water level. Meteorological data from the lighthouse are sent to the National Data Buoy Center, where they can be viewed in real-time at http://www.ndbc.noaa.gov/station_page.php?station=stdm4 Uncorrected half-hour fluxes were computed directly on the logger using a 30-minute block averaging period as high-frequency data were not available. The half hour flux measurements downloaded from the datalogger were post-processed with the following filters and corrections. Latent and sensible heat and carbon dioxide fluxes were corrected with 2-D coordinate rotation. Although the primary objective of data collection at Stannard Rock was to quantify the evaporative flux, additional preliminary measurements of the carbon dioxide concentration and flux from the LI-7500 are also included in this dataset but it is advised to use the carbon data with caution. Carbon data reported in this dataset includes turbulent fluxes of CO2 with no storage correction (FC, µmol m-2 s-1) and CO2 density in mole fraction of wet air (CO2), which was originally output on the datalogger as average CO2 density (mg m-2 s-1) and converted into µmol mol-1 using air temperature and pressure in post-processing. Webb, Pearman, and Leuning terms were applied to account for density fluctuations for water vapor and CO2. Sonic path length, high-frequency attenuation and sensor separation were accounted for according to Horst and Massman, and the oxygen absorption correction for the KH2O hygrometer was also applied. Latent and sensible heat fluxes were assumed to be unrealistic above an absolute value of 1000 W m-2 and were removed. Both carbon flux (FC) and carbon dioxide mole fraction in wet air (CO2) and were assumed to be unrealistic above 1000 µmol m-2 s-1 and 1000 µmol mol-1 respectively. Spikes in latent and sensible heat and carbon fluxes and densities (often due to periods of precipitation) were identified by computing the mean and standard deviation over a moving, overlapping window of 336 half-hours (7 days), similar to Shao et al., and were removed when the flux was more than 1.5 standard deviations from the moving window’s mean. While Vickers and Mahrt use a threshold of 3.5 standard deviations from the mean, a conservative value of 1.5 was chosen due to the noisy nature of over-lake data at this particular site. This process was repeated twice for latent and sensible heat, and carbon dioxide fluxes and densities and therefore it is possible that some real, realistic data was filtered out in this process. No detrending was performed. As per AmeriFlux standards, no friction velocity (USTAR, m s-1) filtering was performed.

Spence, Chris [Environment and Climate Change Cana↗

Sensitivity and vulnerability to summer heat extremes in major cities of the United States

Many cities are experiencing increases in extreme heat because of global temperature rise combined with the urban heat island effect. The heterogeneity of urban morphology also leads to fine-scale variability in potential for heat exposure. Yet, how this rise in temperature and local variability together impacts urban residents differently at exposure-relevant scales is still not clear. Here we map the Universal Thermal Climate Index, a more complete indicator of human heat stress at an unprecedentedly fine spatial resolution (1 m), for 14 major cities in the United States using urban microclimate modeling. We examined the different heat exposure levels across different socioeconomic and racial/ethnic groups in these cities, finding that income level is most consistently associated with heat stress. We further conducted scenario simulations for a hypothetical 1 °C increase of air temperature in all cities. Results show that a 1 °C increase would have a substantial impact on human heat stress, with impacts that differ across cities. The results of this study can help us better evaluate the impact of extreme heat on urban residents at decision-relevant scales.

54 ENVIRONMENTAL SCIENCES↗

Extreme Wet-Bulb Temperatures in China: The Significant Role of Moisture

This paper investigates the extreme wet bulb temperatures (TWs) in China, with a focus on understanding the relative contributions of temperature and moisture to the extremes. Analysis of station observations shows that daily extreme temperatures (T), specific humidity (q) and TWs generally co-occur in southeastern China while extreme TW and T rarely overlap in the arid and semi-arid North and Northwest China. Overall, q contributes more than T to extreme TWs, especially in North and Northwest China. Based on the relative contributions of q and T, regional extreme TW events are classified as q-dominated and T-dominated, respectively, to study their large-scale environment. Cluster analysis of global reanalysis data shows that extreme TWs are generally accompanied by increased surface air temperature and humidity, concomitant with anomalous high-pressure and notable water vapor flux convergence. However, important differences are also seen in the large-scale environment during q-dominated and T-dominated extreme TWs. During q-dominated extreme TWs, the large-scale environment favors convection, as indicated by ascending motions, decreased downward solar radiation (DSR) as well as increased precipitable water and near surface relative humidity. In contrast, during T-dominated extreme TWs, convection is inhibited by the large-scale environment that features descending motion and increased DSR, decreased precipitable water as well as decreased relative humidity. Consistent with the contrasting environments, we demonstrate that T-dominated extreme TWs tend to last longer than q-dominated extremes. Given the significant role of moisture in extreme TWs, more research is needed to understand its impacts on heat stress now and in the future.

extreme wet bulb temperatures, Moisture, synoptic ↗

A physiological signal derived from sun-induced chlorophyll fluorescence quantifies crop physiological response to environmental stresses in the U.S. Corn Belt

Sun-induced chlorophyll fluorescence (SIF) measurements have shown unique potential for quantifying plant physiological stress. However, recent investigations found canopy structure and radiation largely control SIF, and physiological relevance of SIF remains yet to be fully understood. This study aims to evaluate whether the SIF-derived physiological signal improves quantification of crop responses to environmental stresses, by analyzing data at three different spatial scales within the U.S. Corn Belt, i.e. experiment plot, field, and regional scales, where ground-based portable, stationary and space-borne hyperspectral sensing systems are used, respectively. We found that, when controlling for variations in incoming radiation and canopy structure, crop SIF signals can be decomposed into non-physiological (i.e. canopy structure and radiation, 60% ~ 82%) and physiological information (i.e. physiological SIF yield, Φ F , 17% ~ 31%), which confirms the contribution of physiological variation to SIF. We further evaluated whether Φ F indicated plant responses under high-temperature and high vapor pressure deficit (VPD) stresses. The plot-scale data showed that Φ F responded to the proxy for physiological stress (partial correlation coefficient, r p = 0.40, p < 0.001) while non-physiological signals of SIF did not respond ( p > 0.1). The field-scale Φ F data showed water deficit stress from the comparison between irrigated and rainfed fields, and Φ F was positively correlated with canopy-scale stomatal conductance, a reliable indicator of plant physiological condition (correlation coefficient r = 0.60 and 0.56 for an irrigated and rainfed sites, respectively). The regional-scale data showed Φ F was more strongly correlated spatially with air temperature and VPD ( r = 0.23 and 0.39) than SIF ( r = 0.11 and 0.34) for the U.S. Corn Belt. The lines of evidence suggested that Φ F reflects crop physiological responses to environmental stresses with greater sensitivity to stress factors than SIF, and the stress quantification capability of Φ F is spatially scalable. Utilizing Φ F for physiological investigations will contribute to improve our understanding of vegetation responses to high-temperature and high-VPD stresses.

54 ENVIRONMENTAL SCIENCES↗

Dryness controls temperature-optimized gross primary productivity across vegetation types

Temperature response of gross primary productivity (GPP) is a well-known property of ecosystem, but GPP at the optimum temperature (GPP_T opt ) has not been fully discussed. Our understanding of how GPP_T opt responds to warming and water availability is highly limited. Here, in this study, we analyzed data at 326 globally distributed eddy covariance sites (79°N-37°S), to identify controlling factors of GPP_T opt . Although GPP_T opt was significantly influenced by soil moisture, global solar radiation, mean annual temperature, and vapor pressure deficit in a non-linear pattern (R 2 = 0.47), the direction and magnitude of these climate variables’ effects on GPP_T opt depend on the dryness index (DI), a ratio of potential evapotranspiration to precipitation. The spatial pattern showed that soil moisture did not affect GPP_T opt across energy-limited sites with DI < 1 while dominated GPP_T opt across water-limited sites with DI >1. The temporal pattern showed that GPP_T opt was lowered by warming or low precipitation in water-limited sites while energy-limited sites tended to maintain a stable GPP_T opt regardless of changes in air temperature. Vegetation types in humid climates tended to have higher GPP_T opt and were more likely to benefit from a warmer climate since it was not restricted by water conditions. This study highlights that the response of GPP_T opt to global warming depends on the dryness conditions, which explains the nonlinear control of water and temperature over GPP_T opt . Our finding is essential to realistic prediction of terrestrial carbon uptake under future climate and vegetation conditions.

54 ENVIRONMENTAL SCIENCES↗

Simulation-based assessment of ASHRAE Guideline 36, considering energy performance, indoor air quality, and control stability

This study assesses American Society of Heating, Refrigerating and Air-Conditioning Engineers Guideline 36 (G36) with a typical medium office building. Specifically, this study employed a Modelica model of a variable air volume (VAV) system that serves this building, which includes components for representing indoor virus transmission and filtration. It then implemented the G36 control sequences for both water-side and air-side equipment in Python. After that, this study conducted the assessment by co-simulating G36 and the Modelica model using the Building Operations Testing Framework. Unlike existing works, this work has three unique features: (1) It considers the interactions between control sequences for water-side and air-side equipment of the studied VAV system. (2) It assesses the performance of G36 from the perspective of IAQ. (3) It examines the short-term behaviors of the studied building under G36 to understand the control stability. This assessment confirms significant energy savings from G36, largely because of the interaction between supply air temperature and hot water controls. It also reveals a trade-off between the ability to slow the spread of virus and the energy performance via demand controlled ventilation. Lastly, it emphasizes the necessity of tuning local feedback control when implementing G36.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗