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At least 343 records · Page 19

Burning-to-violent-reaction transitions in explosions

In a program to study fragment initiation of cased propellants and explosives, it was found that one area of extreme importance is that of the cased reactive-material burning reactions triggered by the perforation of the case by an impacting fragment. Once the reaction is started, the importance of the impactor decreases, and the sequence of events is controlled by the burning properties of the reactive material, its physical condition, and the nature of the confinement. A brief history of the results obtained by previous investigators is presented along with a discussion of variations in experimental results caused by geometrical changes in the test configurations. Changes in interpretations of the results are discussed. Results of recent confined-burn tests with Composition B, PBXC-116, PBXC-117, and Destex are presented, including results of metallurgical examination of the confined fragments. These examinations indicate a transition to a violent reaction which is not a detonation, although it produces many effects that resemble a detonation.

Graham, K. J.↗

Selection of burn-resistant materials for oxygen-driven turbopumps

NASA goals for reusable space-based, high-performance orbit transfer vehicle propulsion systems have resulted in a need for oxygen/hydrogen engines which include lightweight, highly reliable, liquid oxygen pumps. The selection of ignition- and burn-resistant materials is a major factor in the design of a compact 75,000-rpm turbopump which can deliver 6 lbM/sec of liquid oxygen at 5,000 psia. The potential operational hazards of rubbing friction and impact of foreign particles at high velocity were investigated experimentally for a wide range of candidate materials, i.e., nickel, copper, monel, 316 Stainless Steel, Hastelloy-X, Invar-36, and silicon carbide. Test parameters included oxygen pressure and temperature up to 5,000 psia and 800 F, respectively. The effect of increasing the O2 pressure from 1000 to 5000 psi is discussed. The applicability of the candidate materials to oxygen pump design was ranked by comparing the experimental results among themselves and with an analytically determined parameter, i.e., the burn factor. Nickel and copper demonstrated superior resistance to ignition and burn in the friction rubbing and particle impact tests relative to monel, stainless steel, and nickel-iron base superalloys.

Schoenman, L.↗

Optimal low-thrust, three-burn orbit transfers with large plane changes

Optimal low-thrust, three-burn solutions have been obtained for orbit transfers between a 28.5-degree inclined low earth orbit and a series of 63.4-degree inclined circular orbits as well as a series of 63.4-degree inclined elliptical orbits with twelve hour periods. Solutions have also been obtained for orbit transfers between 97-degree inclined orbits and a 57-degree inclined low earth orbit. Thrust to weight ratios as low as 0.02 were considered. A hybrid nonlinear programming method was used to obtain the solutions. Analysis of the optimal steering during various burns reveals a natural division of the steering strategies into two categories based on whether a burn results in a change predominantly in semi-major axis or orbit plane. The similarity of these optimal steering strategies to previously obtained simple near-optimal steering strategies is discussed.

Zondervan, K. P.↗

Two-stage earth-to-orbit vehicles with series and parallel burn

Recent studies have indicated that a fully reusable earth-to-orbit vehicle system will be needed near the beginning of the next century. One likely concept is a two-stage, vertical takeoff system with liquid rocket propulsion. Such vehicles have been examined with series burn and parallel burn of the engines of each stage. The results indicate that the preferred concept will have parallel burn with crossfeed, the booster will have hydrocarbon engines, the Orbiter will have both hydrocarbon and hydrogen engines, and the staging velocity will be low enough to allow the booster to glide back to the launch site.

Martin, J. A.↗

The scaling of the threshold conditions for solid propellant erosive burning

The effects of the parameters that are considered to influence most strongly the scaling to larger rocket motor sizes of the transition or threshold conditions for erosive burning rate augmentation are measured and a scaling criterion for the threshold conditions for erosive burning is developed. The results are presented for a series of motor firings that were performed to measure the transition length threshold conditions (axial position at which deviation from nonerosive burning rate begins) while attempting to systematically vary the parameters that are considered to control the phenomena. The results of attempts to correlate the threshold conditions with several flow parameters are presented.

Strand, L. D.↗

Radiative surface temperatures of the burned and unburned areas in a tallgrass prairie

This study was conducted in a natural tallgrass prairie area in the Flint Hills of Kansas. The objective was to evaluate the surface radiative temperatures of burned and unburned treatments of the grassland as a means of delineating the areas covered by each treatment. Burning is used to remove the senescent vegetation resulting from the previous year's growth. Surface temperatures were obtained in situ and by an airborne scanner. Burned and unburned grass canopies had distinctly different diurnal surface radiative temperatures. Measurements of surface energy balance components revealed a difference in partitioning of the available energy between the two canopies, which resulted in the difference in their measured surface temperatures. The magnitude of this difference is dependent on the time of measurements and topographic conditions.

Asrar, G.↗

The scaling of the threshold conditions for solid propellant erosive burning

Rocket test firings were performed to measure the transition length threshold conditions while systematically varying various rocket motor parameters. These include the crossflow velocity, the chamber pressure, the propellant nonerosive burning rate, the propellant surface roughness, and the motor port diameter. The erosive burning trends with varying propellant burning rate, motor chamber pressure, and mass flow rate are consistent with published results.

Strand, L. D.↗

The hydrogen shell game - Pulsational instabilities in hydrogen shell-burning planetary nebula nuclei

Fully nonadiabatic g-mode pulsation calculations have been obtained for evolutionary models of planetary nebula nuclei (PNN) with active hydrogen-burning shells. Expressions have been developed for the phase delays which can develop between the temperature variations and the abundance variations of agents in the CN cycle. G-mode instabilities are noted that are driven by the epsilon mechanism at the position of the nuclear burning shells in standard PNN models. The results indicate that the central stars do not retain sufficient hydrogen to support nuclear burning following ejection of the planetary nebula.

Kawaler, Steven D.↗

Erosive burning threshold conditions in solid rocket motors

Erosive burning has been predicted to be enhanced by factors that increase the level of turbulence close to the propellant surface, such a high cross flow velocity, low surface blowing rate, propellant surface roughness, and adverse pressure gradient. A study is reported which was carried out with the objective of measuring the effects of these parameters on the scaling to larger rocket motor sizes of the transition to, or threshold conditions for, erosive burning rate augmentation. The results are used to develop a scaling criterion for the threshold conditions for erosive burning.

Strand, L. D.↗

An ultrasonic technique to measure the depth of burn wounds in humans

Whenever ultrasound encounters discontinuity in its medium of propagation, some energy is reflected from the interface. Such reflections or echoes occur when incident energy encounters the front skin, viable/necrotic, and dermis/fat skin tissue interfaces. It was shown that the most probable cause of the viable/necrotic interface is the uncoiling of collagen in the necrotic tissue, which can cause a reflection at the viable/necrotic interface of approximately 10 percent of the wave amplitude, and is approximately the same as that from the other two interfaces noted. The instrument, still in the prototype stage, was designed to detect the various reflections from within the skin layer. It is shown that, by studying the timing between the various echoes, one can use ultrasound as an aid in diagnosing the depth of burned skin tissue in humans. The instrument is a 60-MHz A-scan unit, modified to more easily identify the echoes occurring within the short time interval during which the reflections are received from the skin layers. A high frequency unit was selected so that various transducers could be utilized to optimize the system. Signal conditioning circuits were modified and added to provide an adequate display of the principle reflections expected. The unit was successful in studying burned tissue in pigs and was recently used to study burn wounds in humans. Measurement techniques and preliminary results are presented.

Yost, William T.↗

New estimates of nitrous oxide emissions from biomass burning

The recent discovery of an artifact producing increased levels of N2O in combustion gas samples collected and stored in grab bottles before chemical analysis has resulted in the downgrading of fossil-fuel combustion and the questioning of biomass burning as important sources of N2O. As almost all reported analyses of N2O produced from biomass burning have involved essentially the same collection and analysis protocols as used in the fossil-fuel studies, this source of N2O must also be reexamined. Here, measurements of N2O made over a large prescribed fire using a near real-time in situ measurement technique are reported and compared with measurements of N2O from simultaneously collected grab-bottle samples. The results from 27 small laboratory biomass test fires are also used to help clarify the validity of earlier assessments. It is concluded that biomass burning contributes about seven percent of atmospheric N2O, as opposed to earlier estimates of several times this value.

Cofer, W. R., III↗

Wolf-Rayet stars of type WN/WC and mixing processes during core helium burning of massive stars

Consequences of the recent finding that most WN/WC spectra probably originate from individual Wolf-Rayet stars for the internal structure of massive stars are discussed. Numerical models including the effect of slow-down or prevention of convective mixing due to molecular weight gradients are presented, in which a transition layer with a composition mixture of H- and He-burning ashes is formed above the convective He-burning core. These models are able to qualitatively account for the observed WN/WC frequency and agree quantitatively with the only WN/WC-composition determination so far. It is argued that the same transition layer may be responsible for the final blue loop which the SN 1987 A progenitor performed some 10,000 yr before explosion. These results indicate that composition barriers may be efficient in restricting convection during central helium burning, in contrast to computations relying on the Schwarzschild criterion for convection, with or without overshooting.

Langer, N.↗

Biomass burning - Combustion emissions, satellite imagery, and biogenic emissions

After detailing a technique for the estimation of the instantaneous emission of trace gases produced by biomass burning, using satellite imagery, attention is given to the recent discovery that burning results in significant enhancement of biogenic emissions of N2O, NO, and CH4. Biomass burning accordingly has an immediate and long-term impact on the production of atmospheric trace gases. It is presently demonstrated that satellite imagery of fires may be used to estimate combustion emissions, and could be used to estimate long-term postburn biogenic emission of trace gases to the atmosphere.

Levine, Joel S.↗

Biomass Burning Airborne and Spaceborne Experiment in the Amazonas (BASE-A)

Results are presented on measurements of the trace gas and particulate matter emissions due to biomass burning during deforestation and grassland fires in South America, conducted as part of the Biomass Burning Airborne and Spaceborne Experiment in the Amazonas in September 1989. Field observations by an instrumented aircraft were used to estimate concentrations of O3, CO2, CO, CH4, and particulate matter. Fires were observed from satellite imagery, and the smoke optical thickness, particle size, and profiles of the extinction coefficient were measured from the aircraft and from the ground. Four smoke plumes were sampled, three vertical profiles were measured, and extensive ground measurements of smoke optical characteristics were carried out for different smoke types. The simultaneous measurements of the trace gases, smoke particles, and the distribution of fires were used to correlate biomass burning with the elevated levels of ozone.

Kaufman, Y. J.↗

Biomass burning and the production of greenhouse gases

The present discussion of related aspects of biomass burning describes a technique for estimating the instantaneous emission of trace gases generated by such fires on the basis of satellite imagery, and notes that burning results in significantly enhanced biogenic emissions of N2O, NO, and CH4. Biomass burning therefore has both immediate and long-term impacts on the trace-gas content of the atmosphere. The effects of Kuwait's oil fires, which encompass both combustion gases and particulates, are compared with those of the more general problem.

Levine, Joel S.↗

A trajectory modeling investigation of the biomass burning-tropical ozone relationship

The hypothesis that tropical total O3 maxima seen by the TOMS satellite derive from African biomass burning has been tested using isentropic trajectory analyses with global meteorological data fields. Two case studies from the 1989 biomass burning season demonstrate that a large fraction of the air arriving at the location of TOMS O3 maxima passed over regions of intense burning. Other trajectories initiated at a series of points over Africa and the Atlantic suggest flight strategies for field studies to be conducted in September 1992.

Pickering, Kenneth E.↗

Trace gas emissions to the atmosphere by biomass burning in the west African savannas

Savanna fires and atmospheric carbon dioxide (CO2) detection and estimating burned area using Advanced Very High Resolution Radiometer_(AVHRR) reflectance data are investigated in this two part research project. The first part involves carbon dioxide flux estimates and a three-dimensional transport model to quantify the effect of north African savanna fires on atmospheric CO2 concentration, including CO2 spatial and temporal variability patterns and their significance to global emissions. The second article describes two methods used to determine burned area from AVHRR data. The article discusses the relationship between the percentage of burned area and AVHRR channel 2 reflectance (the linear method) and Normalized Difference Vegetation Index (NDVI) (the nonlinear method). A comparative performance analysis of each method is described.

Frouin, Robert J.↗

Effects of biomass burning on summertime nonmethane hydrocarbon concentrations in the Canadian wetlands

Approximately 900 whole air samples were collected and assayed for selected C2-C10 hydrocarbons and seven halocarbons during the 5-week Arctic Boundary Layer Expedition (ABLE) 3B conducted in eastern Canadian wetland areas. In more than half of the 46 vertical profiles flown, enhanced nonmethane hydrocarbon (NMHC) concentrations attributable to plumes from Canadian forest fires were observed. Urban plumes, also enhanced in many NMHCs, were separately identified by their high correlation with elevated levels of perchloroethene. Emission factors relative to ethane were determined for 21 hydrocarbons released from Canadian biomass burning. Using these data for ethane, ethyne, propane, n-butane, and carbon monoxide enhancements from the literature, global emissions of these four NMHCs were estimated. Because of its very short atmospheric lifetime and its below detection limit background mixing ratio, 1,3-butadiene is an excellent indicator of recent combustion. No statistically significant emissions of nitrous oxide, isoprene, or CFC 12 were observed in the biomass-burning plumes encountered during ABLE 3B. The presence of the short-lived biogenically emitted isoprene at altitudes as high as 3000 m implies that mixing within the planetary boundary layer (PBL) was rapid. Although background levels of the longer-lived NMHCs in this Canadian region increase during the fire season, isoprene still dominated local hydroxyl radical photochemistry within the PBL except in the immediate vicinity of active fires. The average biomass-burning emission ratios for hydrocarbons from an active fire sampled within minutes of combustion were, relative to ethane, ethene, 2.45; ethyne 0.57; propane, 0.25; propene, 0.73; propyne, 0.06; n-butane, 0.09; i-butane, 0.01; 1-butene, 0.14; cis-2-butene, 0.02; trans-2-butene, 0.03; i-butylene, 0.07; 1,3-butadiene, 0.12; n-pentane, 0.05; i-pentane, 0.03; 1-pentene, 0.06; n-hexane, 0.05; 1-hexene, 0.07; benzene, 0.37; toluene, 0.16.

Blake, D. R.↗