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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Rapid simulations of hyperspectral near-field images of three-dimensional heterogeneous surfaces

The scattering-type scanning near-field optical microscope (s-SNOM) has emerged as a powerful tool for resolving nanoscale inhomogeneities in laterally heterogeneous samples. However, most analytical models used to predict the scattering near-field signals are assuming homogenous landscapes (bulk materials), resulting in inconsistencies when applied to samples with more complex configurations. In this work, we combine the point-dipole model (PDM) to the finite-element method (FEM) to account for the lateral and vertical heterogeneities while keeping the computation time manageable. Full images, spectra, or hyperspectral line profiles can be simulated by calculating the self-consistent dipole radiation demodulated at higher harmonics of the tip oscillation, mimicking real experimental procedures. Using this formalism, we clarify several important yet puzzling experimental observations in near-field images on samples with rich typography and complex material compositions, heterostructures of two-dimensional material flakes, and plasmonic antennas. The developed method serves as a basis for future investigations of nano-systems with nontrivial topography.

36 MATERIALS SCIENCE↗

Testing to Evaluate Processes Expected to Occur during MSR Salt Spill Accidents

Obtaining a license for a new nuclear reactor requires the identification and assessment of the potential consequences of specified accident scenarios, which are achieved using accident progression models. Those models need to be parameterized and validated using experimental data, but existing experimental data addressing processes relevant to molten salt reactor accidents are sparse. Specifically, experimental data that quantify the sensitives of important processes to the initial conditions of the spill, the ambient environment, and the containment features are needed to parameterize individual process models. Integrated experiments that simulate accident scenarios are also needed to provide data for model validation, but these experiments will require the use of proven methods to quantify the processes under evaluation. The overarching objectives of this work are to develop the methods for simulating the targeted processes, to determine the effectiveness of the methods in producing the data required for model development, to generate data that can be used to parameterize individual process models, and to provide key insights into the behavior of spilled molten salt that should be considered in models. Experimental methods were designed to quantify aspects of individual processes expected to occur during or after a molten salt spill accident that will affect the fate of spilled molten salt and the radionuclides within. These processes include 1) molten salt spreading and heat transfer, 2) molten salt flowing and freezing in tubing, 3) stainless steel corrosion kinetics in molten salt, and 4) molten salt splashing and aerosol generation. The initial tests described in this report were conducted using eutectic FLiNaK to demonstrate the test methods, the data that are generated, and the analyses of the data to derive values needed for modeling. The primary variables that were tested include initial salt temperature and the presence of volatile surrogate fission products (e.g., cesium and iodine). The developed methods are shown to be effective in quantifying the desired processes and can be applied to study more complex salt compositions of interest to molten salt reactor developers, a wide range of environmental conditions of interest to modelers, and additional variables relevant to salt spill accidents. The developed methods and insights gained from laboratory tests can also be incorporated in future large-scale integrated tests used to simulate molten salt spill accidents.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Analysis Report for Determination of pH Correction Factors for Brines under AP-157 Rev.1

This Analysis Report (AR) documents the determination of pH correction factors for the observed pH readings. The correction factor converts the observed pH reading recorded from the brines used in geochemical studies in support of the Waste Isolation Pilot Plant (WIPP) to a corrected pH value. The data analysis in this AR falls under AP-157 Rev. 1 Analysis Plan for Determination of pH Correction Factors in Brines (Kirkes et al, 2021). Measurement of pH in some solutions can be challenging due to numerous factors such as high ionic strength, elevated or lowered temperature, complex matrix composition, etc. (Knauss et al., 1990; and Rai et al., 1995). The measured pH can be corrected by applying the correction factor, empirically obtained from a specific test solution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Assessing Critical Conditions for Scour Near Obstructions using Bed Shear, Particle Onset of Motion Balances, and CFD-DEM Modeling of Granular Beds

Computational Fluid Dynamics combined with a Discrete Element Method is one of the computational methods that can be used to model multiphase flows. In this method various phases, gas and liquid or solid, are present in the same computational domain. The local averaged Navier–Stokes equations determine the flow of the continuous phase fluid and are solved using the traditional CFD finite volume approach. DEM is based on a Lagrangian formulation, which solves the equations of motion, expressed in ordinary differential equations, for representative particles as they move in space and time. The interactions between the continuous fluid phase and discrete solid phase are modeled with the use of Newton’s laws of motion via drag force. The particles interact with each other and with the boundaries of the fluid continuum, and the resulting contact forces are included in the equations of motion. The properties of solid particles and boundaries are treated as elastic bodies, with specified density, elastic modulus, and Poisson’s ratio. Particle shapes may vary from single spherical particles to more complex-shaped composite particles. The particles may be introduced into the domain by random or structured injection at a point, surface, or volume, depending on the application. More details on the formulation can be found in the Simcenter STAR-CCM+ User’s Manual and OpenFOAM website.

97 MATHEMATICS AND COMPUTING↗

Novel Zwitterionic Chromatography to Separate Lithium from Unconventional Resources

Since lithium (Li) is a key element for clean energy technologies, the global lithium demand is anticipated to increase rapidly. As a result, efficient lithium extraction technologies that allow the exploitation of unconventional lithium resources, such as geothermal brines and inland brine streams, are essentially needed to meet the Li demand and keep supply chains stable. However, because of low Li concentration, low ratio of Li/Mg or Li/Ca, and complex feed compositions in these feedstocks, using conventional hydrometallurgy or current Direct Lithium Extraction (DLE) processes are often chemical-intensive, requiring substantial amounts of reagent chemicals to recover Li at scale, resulting in large chemical footprints. Therefore, we developed a novel Zwitterionic Chromatography (ZIC) process to separate Li from these resources. Because Li can be partitioned from divalent salts on ZIC under water elution without using chemicals, exploiting the unconventional resources via a ZIC approach can be environmentally benign and sustainable. In this work, we will present the development of the ZIC process for DLE applications. Simulation studies for the Li separation mechanism in ZIC and the demonstration of a continuous ZIC process to separate Li from domestic inland brine and mining wastewater will be presented. Finally, the chemical and energy footprints of ZIC in comparison to other DLE processes will be discussed.

09 BIOMASS FUELS↗

Acclimation and Compensating Metabolite Responses to UV-B Radiation in Natural and Transgenic Populus spp. Defective in Lignin Biosynthesis

Plants have evolved to protect leaf mesophyll tissue from damage caused by UV-B radiation by producing an array of UV-absorbing secondary metabolites. Flavonoids (phenolic glycosides) and sinapate esters (hydroxycinnamates) have been implicated as UV-B protective compounds because of the accumulation in the leaf epidermis and the strong absorption in the wavelengths corresponding to UV. Environmental adaptations by plants also generate a suite of responses for protection against damage caused by UV-B radiation, with plants from high elevations or low latitudes generally displaying greater adaptation or tolerance to UV-B radiation. In an effort to explore the relationships between plant lignin levels and composition, the origin of growth elevation, and the hierarchical synthesis of UV-screening compounds, a collection of natural variants as well as transgenic Populus spp. were examined for sensitivity or acclimation to UV-B radiation under greenhouse and laboratory conditions. Noninvasive, ecophysiological measurements using epidermal transmittance and chlorophyll fluorescence as well as metabolite measurements using UPLC-MS generally revealed that the synthesis of anthocyanins, flavonoids, and lignin precursors are increased in Populus upon moderate to high UV-B treatment. However, poplar plants with genetic modifications that affect lignin biosynthesis, or natural variants with altered lignin levels and compositions, displayed complex changes in phenylpropanoid metabolites. A balance between elevated metabolic precursors to protective phenylpropanoids and increased biosynthesis of these anthocyanins, flavonoids, and lignin is proposed to play a role in the acclimation of Populus to UV-B radiation and may provide a useful tool in engineering plants as improved bioenergy feedstocks.

59 BASIC BIOLOGICAL SCIENCES↗

Uranium Retardation Capacity of Lithologies from the Negev Desert, Israel—Rock Characterization and Sorption Experiments

A series of batch experiments were performed to assess the uranium sorption capacity of four mineralogically distinct lithologies from the Negev Desert, Israel, to evaluate the suitability of a potential site for subsurface radioactive waste disposal. The rock specimens consisted of an organic-rich phosphorite, a bituminous marl, a chalk, and a sandstone. The sorption data for each lithology were fitted using a general composite surface complexation model (GC SCM) implemented in PHREEQC. Sorption data were also fitted by a non-mechanistic Langmuir sorption isotherm, which can be used as an alternative to the GC SCM to provide a more computationally efficient method for uranium sorption. This is because all the rocks tested have high pH/alkalinity/calcium buffering capacities that restrict groundwater chemistry variations, so that the use of a GC SCM is not advantageous. The mineralogy of the rocks points to several dominant sorption phases for uranyl (UO 2 2+ ), including apatite, organic carbon, clays, and iron-bearing phases. The surface complexation parameters based on literature values for the minerals identified overestimate the uranium sorption capacities, so that for our application, an empirical approach that makes direct use of the experimental data to estimate mineral-specific sorption parameters appears to be more practical for predicting uranium sorption.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Computer program determines chemical composition of physical system at equilibrium

FORTRAN 4 digital computer program calculates equilibrium composition of complex, multiphase chemical systems. This is a free energy minimization method with solution of the problem reduced to mathematical operations, without concern for the chemistry involved. Also certain thermodynamic properties are determined as byproducts of the main calculations.

Kwong, S. S.↗

Experiment M409: Bremsstrahlung spectrometer

Spectrometric data were used to gain information for computation of the flux-energy spectra of bremsstrahlung inside the Gemini spacecraft and to determine if energetic electrons are able to penetrate the vehicle walls. The spectra were compared with computer predicted bremsstrahlung spectra by the use of data from beta spectrometers flown on Gemini 10 and 12 missions. The calculations of bremsstrahlung radiation involved uncertainties because of the small amount of information available on cross-section interaction and because of the complex, heterogeneous composition of the spacecraft. The bremsstrahlung detector was designed for time-differentiated measurement of the electron-induced gamma rays over a large section of the vehicle. Preliminary analysis of the data obtained during the missions was indicative that electrons did penetrate the spacecraft wall.

Lindsey, R. S., Jr.↗

Chemical composition of sawdust from lunar rock 12013 and comparison of a Java tektite with the rock.

Abundances of 11 major and minor elements and 11 trace elements have been determined by instrumental neutron activation analysis of two Apollo 12013 rock fragments, a sample of rock 12013,17 sawdust, and a Java tektite (J2). Although the abundances of major elements in tektite J2 are similar to those of rock 12013, comparison of the minor and trace elements shows that no fragment of sawdust or rock 12013 that has been analyzed to date is chemically similar to tektite glass. Rock sawdust is representative of ?whole rock' composition only if the amount of contamination from the sawing process is known. After appropriate correction for saw wire contamination, analyses of sawdust yield fairly accurate averaged elemental compositions of complex clastic lunar and other rocks.

Showalter, D. L.↗

Investigation of chemical vapor deposition of garnet films for bubble domain memories

The important process parameters and control required to grow reproducible device quality ferrimagnetic films by chemical vapor deposition (CVD) were studied. The investigation of the critical parameters in the CVD growth process led to the conclusion that the required reproducibility of film properties cannot be achieved with individually controlled separate metal halide sources. Therefore, the CVD growth effort was directed toward replacement of the halide sources with metallic sources with the ultimate goal being the reproducible growth of complex garnet compositions utilizing a single metal alloy source. The characterization of the YGdGaIG films showed that certain characteristics of this material, primarily the low domain wall energy and the large temperature sensitivity, severely limited its potential as a useful material for bubble domain devices. Consequently, at the time of the change from halide to metallic sources, the target film compositions were shifted to more useful materials such as YGdTmGaIG, YEuGaIG and YSmGaIG.

Besser, P. J.↗

An analysis of aircrew procedural compliance

This research examines the relationships between aircrew compliance with procedures and operator errors. The data for this analysis were generated by reexamination of a 1976 experiment in full mission simulation conducted by Dr. H. P. Ruffell Smith (1979) for the NASA-Ames Research Center. The character of individual operators, the chemistry of crew composition, and complex aspects of the operational environment affected procedural compliance by crew members. Associations between enumerated operator errors and several objective indicators of crew coordination were investigated. The correspondence among high operator error counts and infrequent compliance with specific crew coordination requirements was most notable when copilots were accountable for control of flight parameters.

Schofield, J. E.↗

Scaling violation in fragmentation region at energies above 10-15 eV based on the data on cosmic ray hadron component

The ratio of intensity of energetic hadrons, having no visible accompaniment, to the total flux of hadrons of the same energy at 4380m above sea level is given. The ratio is much more than expected for scaling model with proton primaries. This result could not be explained by complex chemical composition of primary cosmic ray and indicates the scaling violation in fragmentation region.

Source record↗

Design of Fiber Composites for Structural Durability

Hygrothermomechanical effects analyzed by computers. Computational methodology developed and available at NASA Lewis Research Center to design and analyze fiber-composite structures subjected to complex hygrothermomechanical environments. Includes composite mechanics and advanced finited-element structural-analysis methods. Methodology applied to such problems as progressive fracture of composite material, design of composite material for cycle fatigue combined with hot and wet conditions, and general composite-laminate configurations.

Chamis, Christos C.↗

The Petrogenetic significance of Plagioclase megacrysts in Archean rocks

The petrogenetic significance of plagioclase megacryst-bearing Archean rocks was considered. It was suggested that these developed in mid-to upper-crustal magma chambers that were repeatedly replenished. Crystallization of megacrysts from a primitive liquid that evolves to an Fe-rich tholeiite (with LREE enrichment) is nearly isothermal and is an equilibrium process. Cumulates probably form near the margins of the chambers and liquids with megacrysts are periodically extracted and can appear as volcanics. Some flows and intrusives are found in arc-like settings in greenstone belts. Megacrystic dikes represent large volumes of melt and dike swarms such as the Metachawan swarm of Ontario suggest multiple sources of similar compositions. A complex series of melt ponding and migration are probable and involve large amounts of liquid.

Morrison, D. A.↗

A reexamination of luminosity sources in T Tauri stars. I - Taurus-Auriga

An analysis is presented of 72 T Tau stars identified by IRAS in the Tau-Aur complex. The composite energy distributions of the stars are constructed to define bolometric luminosities and the luminosity components in different spectral regimes are separated. The near- to far-IR spectral indices of these stars are analyzed. It is shown that 2/3 of typical T Tau stars have a bolometric to stellar luminosity ratio of about 1.0, which implies no appreciable disks. The distribution is bimodal, however, with a second peak at about 2.0, suggesting that 1/3 of the stars have disks. The bolometric luminosities of the north and south components of T Tau are found to be in the range of 9-21 solar luminosities and 1.5-14 solar luminosities for T Tau N and T Tau S, respectively.

Cohen, Martin↗

Ultrasonic nondestructive characterization of composites with 3-dimensional architectures

The development and implementation of advanced composite material systems and their associated technologies are critical for success in the highly competitive world aerospace market. Acceptance of advance production methods and field support of structures made with these new materials require the development of quantitative, cost-effective, inspection methods. The results of quantitative ultrasonic through-transmission imaging of composites with complex three-dimensional architecture using phase-insensitive and phase-sensitive techniques are presented.

Miller, James G.↗

High-resolution study of luminous infrared galaxies. I - The composite nature of the Seyfert 1 galaxy IRAS 20044-6114 (NGC 6860)

The physical conditions in the ionized gas, the stellar population, and the kinematics of the Seyfert 1 galaxy IRAS 20044-6114 (NGC 6860) are studied by high spatial resolution optical imaging and optical and near-IR spectroscopy of this luminous IR source. The broadband images show a compact nucleus, two weak spiral arms, a bar, a bulge, an inner ring, and a possible outer ring. The I-alpha image reveals bright emission-line regions associated with the Seyfert nucleus and an inner ring of intense star formation. The forbidden O III 5007-A image shows that the high-excitation gas is elongated perpendicularly to the direction of the bar, and reveals a bright compact object at about 40 arcsec NE of the nucleus which is undetectable in the broadband images. This object is interpreted as a dwarf young H II galaxy. The optical, near-IR, and FIR results show clear evidence that the nuclear and circumnuclear regions have composite and complex structure: a variable Seyfert 1 nucleus embedded in an intense and dusty star formation. environment.

Lipari, Sebastian↗