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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2023

Cleaning up the Coasts: A System for the Removal of Marine Microplastics Using Semi-Autonomous Vehicles

In recent years, microplastic pollution has become an increasingly threatening problem for ocean ecosystems. With only 9% of plastics being successfully recycled, many end up in oceans where they break down into small particles less than 5 millimeters in length known as microplastics. These microplastics pose a threat to ocean wildlife, as many sea creatures are harmed by accidentally consuming them. Microplastics also end up contaminating human water and food supply. This report presents a system with the goal of identifying and collecting microplastics near coastlines in order to reduce the number of microplastics in the ocean that pose a threat to wildlife. The system consists of a combination of air and sea drones to locate and collect the microplastics, as well as charging stations to allow the drones to operate for extended periods of time. If implemented, this system will help combat microplastic pollution in oceans by preventing plastics from leaving the coastlines and going deeper where they could harm wildlife.

ocean cleanup↗
NASA NTRS2000

SeaWiFS Postlaunch Technical Report Series: Cumulative Index: Volumes 1-5 - Volume 6

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) is the follow-on ocean color instrument to the Coastal Zone Color Scanner (CZCS), which ceased operations in 1986, after an eight-year mission. SeaWiFS was launched on 1 August 1997, on the OrbView-2 satellite, built by Orbital Sciences Corporation (OSC). The SeaWiFS Project at the National Aeronautics and Space Administration (NASA) Goddard Space Flight Center (GSFC) undertook the responsibility of documenting all aspects of this mission, which is critical to the ocean color and marine science communities. The start of this documentation was titled the SeaWiFS Technical Report Series, which ended after 43 volumes were published. A follow-on series was started, titled the SeaWiFS Postlaunch Technical Report Series. This particular volume serves as a reference, or guidebook, to the previous five volumes and consists of four sections including an errata, an index to key words and phrases, a list of acronyms used, and a list of all references cited. The editors will publish a cumulative index of this type after every five volumes.

Firestone, Elaine R.↗
NASA NTRS2001

SeaWiFS Postlaunch Technical Report Series Cumulative Index

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) is the follow-on ocean color instrument to the Coastal Zone Color Scanner (CZCS), which ceased operations in 1986, after an eight-year mission. SeaWiFS was launched on 1 August 1997, onboard the OrbView-2 satellite, built by Orbital Sciences Corporation (OSC). The SeaWiFS Project at the National Aeronautics and Space Administration (NASA) Goddard Space Flight Center (GSFC), undertook the responsibility of documenting all aspects of this mission, which is critical to the ocean color and marine science communities. The start of this documentation was titled the SeaWiFS Technical Report Series, which ended after 43 volumes were published. A follow-on series was started, titled the SeaWiFS Postlaunch Technical Report Series. This particular volume of the so-called "Postlaunch Series" serves as a reference, or guidebook, to the previous 11 volumes and consists of 5 sections including an errata, an addendum, an index to key words and phrases, a list of acronyms used, and a list of all references cited. The editors will publish a cumulative index of this type after every five volumes.

Hooker, Stanford B.↗
NASA NTRS2003

SeaWiFS Postlaunch Technical Report Series Cumulative Index: Volumes 1-23

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) is the follow-on ocean color instrument to the Coastal Zone Color Scanner (CZCS), which ceased operations in 1986, after an eight-year mission. SeaWiFS was launched on 1 August 1997, onboard the OrbView-2 satellite, built by Orbital Sciences Corporation (OSC). The SeaWiFS Project at the National Aeronautics and Space Administration (NASA) Goddard Space Flight Center (GSFC), undertook the responsibility of documenting all aspects of this mission, which is critical to the ocean color and marine science communities. The start of this documentation was titled the SeaWiFS Technical Report Series, which ended after 43 volumes were published. A follow-on series was started, titled the Sea WiFS Postlaunch Technical Report Series. This particular volume of the so-called Postlaunch Series serves as a reference, or guidebook, to the previous 23 volumes and consists of 4 sections including an errata, an index to key words and phrases, a list of acronyms used, and a list of all references cited. The editors will publish a cumulative index of this type after every five volumes.

Hooker, Stanford B.↗
DOE OSTI2025

A real-time search for Type Ia Supernovae with late-time interactions with circumstellar material in ZTF data

While it is generally accepted that Type Ia supernovae (SNe Ia) are the terminal explosions of white dwarfs (WDs), the nature of their progenitor systems and the mechanisms that lead up to these explosions remain widely debated. In rare cases, the SN ejecta interact with circumstellar material (CSM) that had previously been ejected from the progenitor system. The longer the delay between the creation of the CSM and the SN explosion, the greater the distance between the SN explosion site and the CSM and the later the onset of the interaction. The unknown distance between the CSM and SN explosion site makes it impossible to predict when the interaction will start. If the time between the SN explosion and the onset of the CSM interaction is of the order of several months to years, the SN has generally faded and it is no longer actively followed up on. This makes it even more difficult to detect the interaction while it is happening. In this work, we report on a real-time monitoring programme running between 13 November 2023 and 9 July 2024. It monitored 6914 SNe Ia for signs of late-time rebrightening using the Zwicky Transient Facility (ZTF). Flagged candidates were rapidly followed up on with photometry and spectroscopy to confirm the late-time excess and its position. We report the discovery of a ∼50 day rebrightening event in SN 2020qxz around 1200 rest-frame days after the peak of its light curve. SN 2020qxz exhibited signs of an early CSM interaction, but had faded from view over two years before its reappearance. Initial follow-up spectroscopy revealed the presence of four emission lines, while later follow-up spectroscopy showed that these had faded shortly after the end of the ZTF-detected rebrightening event. Our best match for these emission lines are H β (blueshifted by ∼5900 km s −1 ) and Ca II λ8542 , N I λ8567 , and K I λλ8763, 8767 (all blueshifted by 5100 km s −1 ; although we note that the line identifications are uncertain). This shows that catching and following up on late-time interactions as they occur can offer new clues on the nature of the progenitor systems that produce these SNe by putting constraints on the possible type of donor star. The only way to do this systematically is to use large sky surveys such as ZTF and the upcoming Vera C. Rubin Observatory’s Legacy Survey of Space and Time (LSST) to monitor a large sample of objects for the rare events that reappear long after the object has faded from view.

circumstellar matter↗
NASA NTRS1993

Investigation of air transportation technology at Princeton University, 1991-1992

The Air Transportation Research Program at Princeton University proceeded along six avenues during the past year: (1) intelligent flight control; (2) computer-aided control system design; (3) neural networks for flight control; (4) stochastic robustness of flight control systems; (5) microburst hazards to aircraft; and (6) fundamental dynamics of atmospheric flight. This research has resulted in a number of publications, including archival papers and conference papers. An annotated bibliography of publications that appeared between June 1991 and June 1992 appears at the end of this report. The research that these papers describe was supported in whole or in part by the Joint University Program, including work that was completed prior to the reporting period.

Stengel, Robert F.↗
NASA NTRS1993

Dynamics Explorer 2: Continued FPI and NACS instrument data analysis and associated scientific activity at the University of Michigan

The grant entitled 'Dynamics Explorer 2 - continued FPI and NACS instrument data analysis and associated scientific activity at the University of Michigan' is a continuation of a grant that began with instrument development for the Dynamics Explorer 2 (DE 2) satellite. Over the years, many publications and presentations at scientific meetings have occurred under the aegis of this grant. This present report details the progress that has been made in the final three years of the grant. In these last 4 years of the grant 26 papers have been published or are in press and about 10 more are in preparation or have been submitted. A large number of presentations have been made in the same time span: 36 are listed in Appendix 2. Evidence of the high educational utility of this research is indicated by the list of Ph. D. and M. S. theses that have been completed in the last 3 years that have involved work connected with NAG5-465. The structure of this report is as follows: a brief synopsis of the aims of the grant NAG5-465 is given in the next section; then there is a summary of the scientific accomplishments that have occurred over the grant period; last, we make some brief concluding remarks. Reprints of articles that have recently appeared in refereed journals are appended to the end of this document.

Burns, Alan↗
NASA NTRS2014

Satellite Ocean Color Sensor Design Concepts and Performance Requirements

In late 1978, the National Aeronautics and Space Administration (NASA) launched the Nimbus-7 satellite with the Coastal Zone Color Scanner (CZCS) and several other sensors, all of which provided major advances in Earth remote sensing. The inspiration for the CZCS is usually attributed to an article in Science by Clarke et al. who demonstrated that large changes in open ocean spectral reflectance are correlated to chlorophyll-a concentrations. Chlorophyll-a is the primary photosynthetic pigment in green plants (marine and terrestrial) and is used in estimating primary production, i.e., the amount of carbon fixed into organic matter during photosynthesis. Thus, accurate estimates of global and regional primary production are key to studies of the earth's carbon cycle. Because the investigators used an airborne radiometer, they were able to demonstrate the increased radiance contribution of the atmosphere with altitude that would be a major issue for spaceborne measurements. Since 1978, there has been much progress in satellite ocean color remote sensing such that the technique is well established and is used for climate change science and routine operational environmental monitoring. Also, the science objectives and accompanying methodologies have expanded and evolved through a succession of global missions, e.g., the Ocean Color and Temperature Sensor (OCTS), the Seaviewing Wide Field-of-view Sensor (SeaWiFS), the Moderate Resolution Imaging Spectroradiometer (MODIS), the Medium Resolution Imaging Spectrometer (MERIS), and the Global Imager (GLI). With each advance in science objectives, new and more stringent requirements for sensor capabilities (e.g., spectral coverage) and performance (e.g., signal-to-noise ratio, SNR) are established. The CZCS had four bands for chlorophyll and aerosol corrections. The Ocean Color Imager (OCI) recommended for the NASA Pre-Aerosol, Cloud, and Ocean Ecosystems (PACE) mission includes 5 nanometers hyperspectral coverage from 350 to 800 nanometers with three additional discrete near infrared (NIR) and shortwave infrared (SWIR) ocean aerosol correction bands. Also, to avoid drift in sensor sensitivity from being interpreted as environmental change, climate change research requires rigorous monitoring of sensor stability. For SeaWiFS, monthly lunar imaging accurately tracked stability at an accuracy of approximately 0.1% that allowed the data to be used for climate studies [2]. It is now acknowledged by the international community that future missions and sensor designs need to accommodate lunar calibrations. An overview of ocean color remote sensing and a review of the progress made in ocean color remote sensing and the variety of research applications derived from global satellite ocean color data are provided. The purpose of this chapter is to discuss the design options for ocean color satellite radiometers, performance and testing criteria, and sensor components (optics, detectors, electronics, etc.) that must be integrated into an instrument concept. These ultimately dictate the quality and quantity of data that can be delivered as a trade against mission cost. Historically, science and sensor technology have advanced in a "leap-frog" manner in that sensor design requirements for a mission are defined many years before a sensor is launched and by the end of the mission, perhaps 15-20 years later, science applications and requirements are well beyond the capabilities of the sensor. Section 3 provides a summary of historical mission science objectives and sensor requirements. This progression is expected to continue in the future as long as sensor costs can be constrained to affordable levels and still allow the incorporation of new technologies without incurring unacceptable risk to mission success. The IOCCG Report Number 13 discusses future ocean biology mission Level-1 requirements in depth.

Ocean Color↗
NASA NTRS2022

9- by 15-Foot Low-Speed Wind Tunnel Acoustic Upgrade Part 1: Supporting Studies

The 9- by 15-Foot Low Speed Wind Tunnel at NASA Glenn Research Center was refurbished in a major construction project starting in June 2017 and ending in March 2019, with some interruptions. Studies supporting this effort started years earlier and continued through the end of construction. The focus of the refurbishment project was to reduce the background noise in the test section during operation. The major focus of the supporting studies was the wind tunnel flow surface. These studies included roughness noise testing of samples, impedance measurements, computational simulations and analysis. NASA Langley and Ames Research Centers both contributed, as did Virginia Polytechnic Institute and State University. This report describes the major efforts and findings of the supporting studies.

Wind Tunnel↗
DOE OSTI2019

Integrated Solutions for Optimized Performance (ISOP) Final Technical Report

The goal of this project was to demonstrate technical feasibility of an integrated approach for deep energy retrofits by packaging innovative technologies with smart communicating controls that represent the next generation of energy efficiency. The integrated solutions for optimized performance (ISOP) package integrates (i) advanced lighting and plug load controls; (ii) intelligent daylight harvesting through automated self-powered shades and window films; (iii) advanced HVAC controls sequences (ASHRAE Guideline (GDL) 36); and (iv) fault detection and diagnosis (FDD) and continuous commissioning (CCx) using advanced analytics. These technologies address energy use across multiple building end uses that represent more than 60% of the energy consumption in all commercial buildings. The project was structured to be implemented over three budget periods: Budget Period 1 scope included site selection, project design, site-specific customization of technology packages, procurement of technologies, initiation of installation of technologies, the development of a measurement and verification plan and collection of pre-retrofit data collection. The first year go/no-go decision was based on securing host sites representing 250,000 sq. ft. of occupied operational spaces, savings analysis, technology procurement and initiation of installation. Budget Period 2 planned to complete technology installations and initiate data collection of post-retrofit performance data. The second year go/no-go was to be the completion of technology installations and commissioning, metering and data collecting to support the requirements laid out in site specific M&V plans. Budget Period 3 planned to collect and analyze post-retrofit performance data and provide data and reporting to support energy efficiency rebate programs. After the team completed activities planned for Budget Period 1, the team reached a Go/No-Go Decision Point. At that point, TRC recommended that DOE discontinue the project without prejudice due to challenges with securing demonstration sites to meet the full 250,000 sf of occupied operational spaces and DOE concurred. In Budget Period 1, the TRC team developed criteria to recruit and evaluate potential demonstration host sites. TRC worked with Princeton University, the project demonstration partner, to identify buildings on their campus as potential candidates for the demonstration. Following the selection of demonstration sites, the TRC team customized energy technology packages according to the needs and characteristics of each site. TRC defined technology specifications, identified vendors, and conducted analysis to estimate energy and cost savings potential. The project team then developed schedules for technology procurement processes and scheduled for installation at all selected demonstration sites. The project team worked with Princeton University and DOE to develop an approach to verify energy savings achieved through measurement and verification (M&V) 2.0 methods. Princeton University initiated open bids to procure the necessary materials and installation contractors. Bid results came back higher than estimates due to a couple of factors – lack of familiarity of the bidders with the proposed technologies and lack of local trained installers to execute the installation of these new measures. Due to the higher bids, projects no longer met the internal cost-effectiveness criteria used by Princeton to proceed with procurement of the full suite of technologies as proposed in ISOP. Princeton had already procured parts of the ISOP package as part of a campus-wide initiative for FDD and lighting retrofits, but with the higher costs for other ISOP components, Princeton could no longer commit to the full ISOP package on the selected sites. Based on this, the team reached the Go/No-Go decision point, where they decided not to proceed with the project. Princeton is separately installing portions of the ISOP package where they individually meet Princeton’s payback criteria but on a different schedule than would have been needed for the DOE ISOP project. The team has learned several lessons from project progress in the first budget period. The team will utilize these lessons in future projects, as should any team which proceeds with a project around the ISOP technology. The first lesson is that more information about the proposed sites is required earlier in the process (perhaps even at the proposal stage) in order to have a successful demonstration. Technical details not evident earlier in the process (such as the TLED limitations for ALCS) can derail project execution. The second lesson is that pricing of emerging technologies is highly variable due to lack of familiarity of local installers and distributor with the proposed technologies as well as alternate bids using products they were more familiar with, but that cost more than the ones proposed by TRC. Finally, the last major lesson is that the host site’s internal project criteria is of critical importance. Based on these higher installed costs and lack of an informed installer base for the products proposed for this project, the project does not meet Princeton’s simple payback goals of five years.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Machine learning surrogate of physics-based building-stock simulator for end-use load forecasting

Building energy models are used to simulate heat and mass transfer and estimate end-use load in buildings. With the proliferation of solar photovoltaics on residential and commercial buildings, increasingly, buildings are expected to provide grid services, for which accurate and computationally efficient building energy simulations and end-use load prediction are imperative. Existing building energy simulation tools, however, have significant computational overhead that make them less practical in real-time deployment for optimization, design, uncertainty quantification and control in building energy management systems. Here this article presents a data-driven machine learning model based on light gradient boosting method (LightGBM) as a surrogate for a physics-based simulator for residential buildings to predict end-use load. The machine learning based surrogate model accounts for time-series related variables, seasonality and trend component of end-use load, and history of end-use load. The accuracy of the surrogate model is assessed on the prediction of the load profiles of 100 different houses in Cook County, Illinois, USA. The LightGBM surrogate model is shown to reduce the root-mean-squared error by 53% relative to a reference decision tree (DT) based model reported previously in the literature. Moreover, the model predicts the load spikes and high-ramp rate events throughout the year which are often the Achilles heel of other models in the literature. The machine learning based surrogate model is demonstrated to be computationally efficient, with a ten-fold reduction in the computational time compared to a physics-based building energy simulation, and suitable for uncertainty analysis and real-time control of building characteristics in response to uncertainty.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

FY22 NCSP accomplishments for U and Pu Evaluations [Slides]

This presentation covers fiscal year 2022 for Nuclear Criticality Safety Program (NCSP) accomplishments for Uranium (U) and Plutonium (Pu) evaluations. This presentation includes an overview on plutonium and uranium. Additionally, this presentation covers the inclusion of sub-thermal data for 235 U and the inclusion of LANL ratio capture-to-fission data for 233 U and 235 Pu. The presentation ends with a discussion on 239 Pu Primary fit of Mosby's data as reported and a look at the uncertainty quantification.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

End-Use Load Profiles for the U.S. Building Stock

The United States is embarking on an ambitious transition to a 100% clean energy economy by 2050, which will require improving the flexibility of electric grids. One way to achieve grid flexibility is to shed or shift demand to align with changing grid needs. To facilitate this, it is critical to understand how and when energy is used. High quality end-use load profiles (EULPs) provide this information, and can help cities, states, and utilities understand the time-sensitive value of energy efficiency, demand response, and distributed energy resources. Publicly available EULPs have traditionally had limited application because of age and incomplete geographic representation. To help fill this gap, the U.S. Department of Energy (DOE) funded a three-year project, End-Use Load Profiles for the U.S. Building Stock, that culminated in this publicly available dataset of calibrated and validated 15-minute resolution load profiles for all major residential and commercial building types and end uses, across all climate regions in the United States. These EULPs were created by calibrating the ResStock and ComStock physics-based building stock models using many different measured datasets, as described in the "Technical Report Documenting Methodology" linked in the submission.

Array↗
NASA NTRS1983

Test program to demonstrate the stability of hydrazine in propellant tanks

A 24-month coupon test program to evaluate the decomposition of propellant tanks is reported. The propellant fuel evaluated was monopropellant-grade hydrazine (N2H4), which is normally a colorless, fuming, corrosive, strongly reducing liquid. The degree of hydrazine decomposition was determined by means of chemical analyses of the liquid and evolved gases at the end of the test program. The experimental rates of hydrazine decomposition were determined to be within acceptable limits. The propellant tank materials and material combinations were not degraded by a 2-year exposure to hydrazine propellant. This was verified using change-of-weight determinations and microscopic examination of the specimen surface before and after exposure, and by posttest chemical analyses of hydrazine liquid for residual metal content.

Moran, C. M.↗
NASA NTRS1993

Long-term microparticle flux variability indicated by comparison of Interplanetary Dust Experiment (IDE) timed impacts for LDEF's first year in orbit with impact data for the entire 5.77-year orbital lifetime

The electronic sensors of the Interplanetary Dust Experiment (IDE) recorded precise impact times and approximate directions for submicron to approximately 100 micron size particles on all six primary sides of the spacecraft for the first 346 days of the LDEF orbital mission. Previously-reported analyses of the timed impact data have established their spatio-temporal features, including the demonstration that a preponderance of the particles in this regime are orbital debris and that a large fraction of the debris particles are encountered in megameter-size clouds. Short-term fluxes within such clouds can rise several orders of magnitude above the long-term average. These unexpectedly large short-term variations in debris flux raise the question of how representative an indication of the multi-year average flux is given by the nearly one year of timed data. One of the goals of the IDE was to conduct an optical survey of impact sites on detectors that remained active during the entire LDEF mission, to obtain full-mission fluxes. We present here the comparisons and contrasts among the new IDE optical survey impact data, the IDE first-year timed impact data, and impact data from other LDEF micrometeoroid and debris experiments. The following observations are reported: (1) the 5.77 year long-term integrated microparticle impact fluxes recorded by IDE detectors matched the integrated impact fluxes measured by other LDEF investigators for the same period; (2) IDE integrated microparticle impact fluxes varied by factors from 0.5 to 8.3 for LDEF days 1-346, 347-2106 and 1-2106 (5.77 years) on rows 3 (trailing edge, or West), 6 (South side), 12 (North side), and the Earth and Space ends; and (3) IDE integrated microparticle impact fluxes varied less than 3 percent for LDEF days 1-346, 347-2106 and 1-2106 (5.77 years) on row 9 (leading edge, or East). These results give further evidence of the accuracy and internal consistency of the recorded IDE impact data. This leads to the further conclusion that the utility of long-term ratios for impacts on various sides of a stabilized satellite in low Earth orbit (LEO) is extremely limited. These observations and their consequences highlight the need for continuous, real time monitoring of the dynamic microparticle environment in LEO.

Simon, Charles G.↗
DOE OSTI2022

Supply chain optimization of sustainable aviation fuel from carinata in the Southeastern United States

We report carinata is a purpose-grown oilseed feedstock for renewable fuels, including sustainable aviation fuel (SAF) that can replace conventional aviation fuel (CAF). Given carinata is a new crop in the Southeastern United States, it is crucial to analyze its sustainability from a supply chain perspective. This study developed a mixed-integer linear programming (MILP) model and simulated it for 20 years, starting from a farm (county-level data) and ending at the airport. About 2.06 million ha in Alabama, Florida, and Georgia combined were found suitable for carinata production. Given the three-year rotation period, about 0.69 million hectares can be cultivated annually, approximately 65% of which was in Georgia. About 2.4% of the combined SAF annual demand of four major airports (about 210 thousand t) in the study area is satisfied at that level of carinata cultivation. However, all available SAF was supplied to the Atlanta airport as this decision minimizes the supply chain cost. A total of 1343 storage units, one oil extraction mill, and one biorefinery were needed to meet the overall demand. We found that SW Georgia is the top supplier of carinata seeds. The unit cost of production and carbon intensity were estimated to be $\$$0.89 L -1 (or $\$$26.79 GJ -1 ) and 0.91 kg CO 2 e L -1 (or 27.28 kg CO 2 e GJ -1 ), respectively. This carbon intensity of carinata-based SAF was 67.8% lower than that of CAF. With variations included in SAF demand, yield, and soil carbon sequestration, carbon savings remained between 66.5% and 67.8%. Given the GHG advantage of SAF over CAF, there is justification for subsidies required to make SAF competitive.

10 SYNTHETIC FUELS↗
DOE OSTI2026

Commercial and Residential Hourly Load Profiles for All Typical Meteorological Year 3 (TMY3) Locations in the United States

One way to achieve grid flexibility is to shed or shift demand to align with changing grid needs. To facilitate this, it is critical to understand how and when energy is used. High-quality end-use load profiles (EULPs) provide this information and can help cities, states, and utilities understand the time-sensitive value of energy efficiency, demand response, and distributed energy resources. Publicly available EULPs have traditionally had limited application because of age and incomplete geographic representation. To help fill this gap, the U.S. Department of Energy funded a 3-year project, End-Use Load Profiles for the U.S. Building Stock, that culminated in this publicly available dataset of calibrated and validated 15-minute-resolution load profiles for all major residential and commercial building types and end uses across all climate regions in the United States. These EULPs were created by calibrating the ResStock and ComStock physics-based building stock models using many different measured datasets, as described in the "Technical Report Documenting Methodology" linked in the submission.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2022

Quantify Contaminant Partitioning in Advanced Chlorination Process

Chlorination of the zirconium in spent fuel cladding has been identified as a significant means of Zr recovery and purification, enabling a 25% (wt.) or greater reduction in waste requiring geologic disposition. Several chlorinating agents have been identified over the last few years, including gases and liquids. In particular, the interactions of sulfur-chloride solvents with zirconium may allow the separation of zirconium from uranium with the selective formation of ZrCl 4 . This report reviews what is known about reactions between chlorinating agents, uranium metal and oxide, Zircaloy and its alloying elements, and fission plus activation products. Plans for testing the feasibility of applying advanced chlorination methods developed for zirconium recycling to the front end of the recycling of spent nuclear fuel are also included.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗