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At least 343 records · Page 19

Submm-Wave Radiometry for Cloud/Humidity/Precipitation Sciences

Although active sensors can provide cloud profiles at good vertical resolution, clouds are often coupled with dynamics to form fast and organized structures. Lack of understanding of these organized systems leads to great challenge for numerical models. The deficiency is partly reflected, for example, in poorly modeled intraseasonal variations (e.g., MJD). Remote sensing clouds in the middle and upper troposphere has been challenging from space. Vis/IR sensors are sensitive to the topmost cloud layers whereas low-frequency MW techniques are sensitivity to liquid and precipitation at the bottom of cloud layers. The middle-level clouds, mostly in the ice phase, require a sensor that has moderate penetration and sensitivity to cloud scattering, in order to measure cloud water content. Sensors at submm wavelengths provide promising sensitivity and coverage with the spatial resolution needed to measure cloud water content floating in the upper air. In addition, submm-wave sensors are able to provide better measurements of upper-tropospheric humidity than traditional microwave instruments.

Wu, Dong L.↗

Micro-Sensors for in-situ Meteorological Measurements

Improved in-situ meteorological measurements are needed for monitoring the weather and climate of the terrestrial and martian atmospheres. We have initiated a program to assess the feasibility and utility of micro-sensors for precise in-situ meteorological measurements in these environments. Sensors are being developed for measuring pressure, temperature, wind velocity, humidity, and aerosol amounts.

Micro-Sensors↗

Winter Lightning to the Lee of Lake Ontario: The Lake-Effect Electrification (LEE) Field Campaign

The National Science Foundation-sponsored Lake-Effect Electrification (LEE) field campaign intensive observation periods occurred between November and early February 2022-23 across the eastern Lake Ontario region. Project LEE documented, for the first time, the total lightning and electrical charge structures of lake-effect storms and the associated storm environment using a lightning mapping array (LMA), a mobile dual-polarization X-band radar, and balloon-based soundings that measured vertical profiles of temperature, humidity, wind, electric field, and hydrometeor types. LEE also observed abundant wind turbine-initiated lightning, which is climatologically more likely during the winter. The frequent occurrence of intense lake-effect storms and the proximity of a wind farm with nearly 300 turbines each more than 100 m tall to the lee of Lake Ontario provided an ideal laboratory for this study.

Scott M Steiger↗

Evaluating the Aerodynamic Impact of Circumferentially Grooved Fan Casing Treatments with Integrated Acoustic Liners on a Turbofan Rotor

NASA is investigating the potential of integrating acoustic liners into fan cases to reduce fan noise, while maintaining the fan's aerodynamic performance. An experiment was conducted to quantify the aerodynamic impact of circumferentially grooved fan cases with integrated acoustic liners on a 1.5 pressure ratio turbofan rotor. In order to improve the ability to measure small performance changes, fan performance calculations were updated to include real gas effects including the effect of humidity. For all fan cases tested, the measured difference in fan isentropic efficiency was found to be less than the measurement repeatability for a torque-based efficiency calculation (≈ 0.2%), however, an unintended tip clearance difference between configurations makes it difficult to determine if circumferentially grooved fan cases degraded fan performance. Fan exit turbulence measurements showed a 1.5% reduction in total turbulence intensity between hardwall and circumferentially grooved fan cases, which is attributed to the circumferential grooves modifying loading at the blade tips. The decrease in fan exit turbulence could potentially lead to a 1-2dB reduction in broadband rotor-stator interaction noise. Reduced aerodynamic performance losses associated with over-the-rotor liners could enable further fan noise reduction.

Bozak, Richard F.↗

Evaluating the Aerodynamic Impact of Circumferentially Grooved Fan Casing Treatments with Integrated Acoustic Liners on a Turbofan Rotor

NASA is investigating the potential of integrating acoustic liners into fan cases to reduce fan noise, while maintaining the fans aerodynamic performance. An experiment was conducted to quantify the aerodynamic impact of circumferentially grooved fan cases with integrated acoustic liners on a 1.5 pressure ratio turbofan rotor. In order to improve the ability to measure small performance changes, fan performance calculations were updated to include real gas effects including the effect of humidity. For all fan cases tested, the measured difference in fan isentropic efficiency was found to be less than the measurement repeatability for a torque-based efficiency calculation (approx. = 0.2%), however, an unintended tip clearance difference between configurations makes it difficult to determine if circumferentially grooved fan cases degraded fan performance. Fan exit turbulence measurements showed a 1.5% reduction in total turbulence intensity between hardwall and circumferentially grooved fan cases in the tip vortex region, which is attributed to a disruption in the formation of the tip leakage vortex. This decrease in fan exit turbulence could potentially lead to a 1-2dB reduction in broadband rotor-stator interaction noise. Reduced aerodynamic performance losses associated with over-the-rotor liners could enable further fan noise reduction.

turbofan↗

New Thermochemical Salt Hydrate System for Energy Storage in Buildings

This paper introduces an innovative design for an “inorganic salt-expanded graphite” composite thermochemical system. The storage unit is made of a perforated, compressed, expanded graphite block impregnated with molten CaCl 2 ∙6H 2 O; the humid air passes through the holes that allow the moisture to diffuse and react with the salt. The prepared block underwent 90 hydration-dehydration cycles. Although most of the performed cycles were carried out with salt overhydration and deliquescence, the treated samples have remained mechanically and thermally stable with no drop in energy density. The volumetric energy density of the composite ranged from 135.5 to 277.6 kWh/m 3 , depending on airflow rate and absolute humidity. To ensure composite material cycling stability, the energy density of the block was measured during hydration at similar conditions of absolute humidity, inlet temperature, and airflow rate (0.01 kg water /kg air , 20 °C, 400 l/min). The average energy density at these conditions was sustained at 219 kWh/m 3 . The block integrity was monitored by visual inspection after removing it from the reactor chamber every few cycles. Both the composite material and its manufacturing process are simple and easy to scale up for future commercialization.

25 ENERGY STORAGE↗

BOREAS TE-4 Gas Exchange Data from Boreal Tree Species

The BOREAS TE-4 team collected steady-state gas exchange and reflectance data from several species in the BOREAS SSA during 1994 and in the NSA during 1996. Measurements of light, CO2, temperature, and humidity response curves were made by the BOREAS TE-4 team during the summers of 1994 and 1996 using intact attached leaves of boreal forest species located in the BOREAS SSA and NSA. These measurements were conducted to calibrate models used to predict photosynthesis, stomatal conductance, and leaf respiration. The 1994 and 1996 data can be used to construct plots of response functions or for parameterizing models. Parameter values are suitable for application in SiB2 (Sellers et al., 1996) or the leaf model of Collatz et al. (1991), and programs can be obtained from the investigators. The data are stored in tabular ASCII files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC).

Hall, Forrest G.↗

Humidity and particle fields around some small cumulus clouds

Aircraft-borne measurements showed that five small cumulus clouds were surrounded by regions of high humidity out to distances of several cloud radii from their centers. Total particle concentrations in the regions of high humidity were about twice those in the air at the same level but well removed from the cloud boundaries. The regions of high humidity and particle concentrations also coincided with regions of high turbulence surrounding the clouds. In addition to affecting particle production, regions of high humidity surrounding clouds can be expected to affect chemical process and atmospheric radiation transfer.

Radke, Lawrence F.↗

Design, Development, and Testing of a Water Vapor Exchanger for Spacecraft Life Support Systems

Thermal and environmental control systems for future exploration spacecraft must meet challenging requirements for efficient operation and conservation of resources. Maximizing the use of regenerative systems and conserving water are critical considerations. This paper describes the design, development, and testing of an innovative water vapor exchanger (WVX) that can minimize the amount of water absorbed in, and vented from, regenerative CO2 removal systems. Key design requirements for the WVX are high air flow capacity (suitable for a crew of six), very high water recovery, and very low pressure losses. We developed fabrication and assembly methods that enable high-efficiency mass transfer in a uniform and stable array of Nafion tubes. We also developed analysis and design methods to compute mass transfer and pressure losses. We built and tested subscale units sized for flow rates of 2 and 5 cu ft/min (3.4–8.5 cu m/hr). Durability testing demonstrated that a stable core geometry was sustained over many humid/dry cycles. Pressure losses were very low (less than 0.5 in. H2O (125 Pa) total) and met requirements at prototypical flow rates. We measured water recovery efficiency across a range of flow rates and humidity levels that simulate the range of possible cabin conditions. We measured water recovery efficiencies in the range of 80 to 90%, with the best efficiency at lower flow rates and higher cabin humidity levels. We compared performance of the WVX with similar units built using an unstructured Nafion tube bundle. The WVX achieves higher water recovery efficiency with nearly an order of magnitude lower pressure drop than unstructured tube bundles. These results show that the WVX provides uniform flow through flow channels for both the humid and dry streams and can meet requirements for service on future exploration spacecraft. The WVX technology will be best suited for long-duration exploration vehicles that require regenerative CO2 removal systems while needing to conserve water.

Izenson, Michael G.↗

Drying model of a high salt content cementitious waste form: Effect of capillary forces and salt solution

Highlights: • Drying model for a high salt content cementitious waste form is developed. • Water vapor diffusion and capillary liquid flow are distinguished. • Capillary and salt solution effects are considered in vapor-liquid equilibrium. A water transport model coupling capillary liquid flow with vapor diffusion is developed to describe the drying process for a cementitious waste form with high salinity porewater. Vapor-liquid equilibrium is formulated as the driving force for vapor diffusion and the model accounts for pore capillary and high salinity effects on water thermodynamic activity. Pore filling and porewater surface tension as a function of pore size distribution and water saturation have been quantified for the material. Geochemical speciation modeling is used to simulate porewater activity as a function of composition over the range of saturation. The theoretical relationship between relative humidity and water saturation generally agrees with experimental measurement, and the developed model is capable of predicting drying rates under various external relative humidity conditions. The model was developed to be incorporated into reactive transport models considering the effects of drying such as salt redistribution and efflorescence.

36 MATERIALS SCIENCE↗

Sensible and latent heat flux estimates in Antarctica

The assumption has been made that the net annual contribution of water by the processes of deposition and sublimation to the Antarctic Ice Sheet is zero. The U.S. Antarctic Program started installing reliable automatic weather stations on the Antarctic Continent in 1980. The initial units were equipped to measure wind speed, wind direction, air pressure, and air temperature. During the 1983-1984 field season in Antarctica, three units were installed that measured a vertical air temperature difference between the nominal heights of 0.5 m and 3.0 m and relative humidity at a nominal height of 3 m. The measurements of the vertical air temperature difference and the relative humidity are the minimum required to estimate the sensible and latent heat fluxes to the air, while not exceeding the available energy requirements for the weather stations. The estimates of the net annual sublimation and deposition on the Ross Ice Shelf amount to 20 to 80 percent of the annual accumulation. We conclude that the assumption that annual sublimation and deposition are zero is not valid under Antarctic conditions.

Stearns, Charles R.↗

Fluidic device for measuring constituent masses of a flowing binary gas mixture

Device consists of fluidic humidity sensor and specially designed flow calorimeter. Calorimeter provides readings of gas stream temperature rise produced by measured amount of heat that is dissipated into gas stream, and humidity sensor is used to obtain continuous calculation of specific heat capacity of gas mixture.

Prokopius, P. R.↗

An Induced Environment Contamination Monitor for the Space Shuttle

The Induced Environment Contamination Monitor (IECM), a set of ten instruments integrated into a self-contained unit and scheduled to fly on shuttle Orbital Flight Tests 1 through 6 and on Spacelabs 1 and 2, is described. The IECM is designed to measure the actual environment to determine whether the strict controls placed on the shuttle system have solved the contamination problem. Measurements are taken during prelaunch, ascent, on-orbit, descent, and postlanding. The on-orbit measurements are molecular return flux, background spectral intensity, molecular deposition, and optical surface effects. During the other mission phases dew point, humidity, aerosol content, and trace gas are measured as well as optical surface effects and molecular deposition. The IECM systems and thermal design are discussed. Preflight and ground operations are presented together with associated ground support equipment. Flight operations and data reduction plans are given.

Miller, E. R.↗

Propagation of sound through the Earth's atmosphere

The data collected at a pressure of one atmosphere for the different temperatures and relative humidities of the air-water vapor mixtures is summarized. The dew point hygrometer used in these measurements did not give reliable results for dew points much above the ambient room temperature. For this reason measurements were not attempted at the higher temperatures and humidities. Viscous wall losses in the resonant tube at 0 C so dominate the molecular relaxation of nitrogen, in the air-water vapor mixture, that reliable data could not be obtained using the free decay method in a resonant tube at one atmosphere. In an effort to obtain viable data at these temperatures, measurements were performed at a pressure of 10 atmospheres. Since the molecular relaxation peak is proportional to the pressure and the viscous losses are proportional to the inverse square root of the pressure the peak height should be measurable at the higher pressure. The tradeoff here is that at 10 atmospheres; the highest relative humidity attainable is 10 percent. The data collected at 10 atmospheres is also summarized.

Meredith, R. W.↗

Disentangling Oxygen and Water Vapor Effects on Optoelectronic Properties of Monolayer Tungsten Disulfide

By understanding how the environmental composition impacts the optoelectronic properties of transition metal dichalcogenide monolayers, we demonstrate that simple photoluminescence (PL) measurements of tungsten disulfide (WS 2 ) monolayers can differentiate relative humidity environments. In this paper, we examine the PL and photoconductivity of chemical vapor deposition grown WS 2 monolayers under three carefully controlled environments: inert gas (N 2 ), dry air (O 2 in N 2 ), and humid nitrogen (H 2 O vapor in N 2 ). The WS 2 PL is measured as a function of 532 nm laser power and exposure time and can be decomposed into the exciton, trion, and lower energy state(s) contributions. Under continuous illumination in either O 2 or H 2 O vapor environment, we find dramatic (and reversible) increases in PL intensity relative to the PL in an inert environment. The PL bathochromically shifts in an O 2 environment and is dominated by increased trion emission and diminished exciton emission. In contrast, the WS 2 PL increase in a H 2 O environment results from an overall increase in emission from all spectral components where the exciton contribution dominates. The drastic increases in PL are anticorrelated with corresponding decreases in photoconductivity, as measured by time-resolved microwave conductivity. The results suggest that both O 2 and H 2 O react photochemically with the WS 2 monolayer surface, modifying the optoelectronic properties, but do so via distinct pathways. Thus, we use these optoelectronic differences to differentiate the amount of humidity in the air, which we show with 0%, 40%, and 80% relative humidity environments. This deeper understanding of how ambient conditions impact WS 2 monolayers enables novel humidity sensors as well as a better understanding of the correlation between TMDC surface chemistry, light emission, and photoconductivity. Moreover, these WS 2 measurements highlight the importance of considering the impact of the local environment on reported results.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Application of Aerosol Hygroscopicity Measured at the Atmospheric Radiation Measurement Program's Southern Great Plains Site to Examine Composition and Evolution

A Differential Mobility Analyzer/Tandem Differential Mobility Analyzer (DMA/TDMA) was used to measure submicron aerosol size distributions, hygroscopicity, and occasionally volatility during the May 2003 Aerosol Intensive Operational Period (IOP) at the Central Facility of the Atmospheric Radiation Measurement Program's Southern Great Plains (ARM SGP) site. Hygroscopic growth factor distributions for particles at eight dry diameters ranging from 0.012 micrometers to 0.600 micrometers were measured throughout the study. For a subset of particle sizes, more detailed measurements were occasionally made in which the relative humidity or temperature to which the aerosol was exposed was varied over a wide range. These measurements, in conjunction with backtrajectory clustering, were used to infer aerosol composition and to gain insight into the processes responsible for evolution. The hygroscopic growth of both the smallest and largest particles analyzed was typically less than that of particles with dry diameters of about 0.100 micrometers. It is speculated that condensation of secondary organic aerosol on nucleation mode particles is largely responsible for the minimal hygroscopic growth observed at the smallest sizes considered. Growth factor distributions of the largest particles characterized typically contained a nonhygroscopic mode believed to be composed primarily of dust. A model was developed to characterize the hygroscopic properties of particles within a size distribution mode through analysis of the fixed size hygroscopic growth measurements. The performance of this model was quantified through comparison of the measured fixed size hygroscopic growth factor distributions with those simulated through convolution of the size-resolved concentration contributed by each of the size modes and the mode-resolved hygroscopicity. This transformation from sizeresolved hygroscopicity to mode-resolved hygroscopicity facilitated examination of changes in the hygroscopic properties of particles within a size distribution mode that accompanied changes in the sizes of those particles. This model was used to examine three specific cases in which the sampled aerosol evolved slowly over a period of hours or days.

Gasparini, Roberto↗

Hydration of α-UO 3 following storage under controlled conditions of temperature and relative humidity

Changes in chemical speciation of uranium oxides following storage under varied conditions of temperature and relative humidity are valuable for characterizing material provenance. In this study, subsamples of high purity α-UO 3 were stored under four sets of controlled conditions of temperature and relative humidity over several years, and then measured periodically for chemical speciation. Powder X-ray diffraction (XRD) analysis and extended X-ray absorption fine structure spectroscopy confirm hydration of α-UO 3 to a schoepite-like end product following storage under each of the varied storage conditions, but the species formed during exposure to the lower relative humidity and lower temperature condition follows different trends from those formed under the other three storage conditions (high relative humidity with high or low temperatures, and low relative humidity with a high temperature). Thermogravimetry coupled with XRD analysis was carried out to distinguish desorption pathways of water from the hydrated end products. Density functional theory calculations discern changes in the structure of α-UO 3 following incorporation of 1, 2 or 3 H 2 O molecules or 1, 2 or 3 OH groups into the orthorhombic lattice, revealing differences in lattice constants, U–O bond lengths, and U–U distances. The collective results from this analysis are in contrast to analogous studies that report that U 3 O 8 is oxidized and hydrated in air during storage under high relative humidity conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗