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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

A Sounding Rocket Experiment for the Chromospheric Lyman-Alpha Spectro-Polarimeter (CLASP)

A sounding-rocket experiment called the Chromospheric Lyman-Alpha Spectro-Polarimeter (CLASP) is presently under development to measure the linear polarization profiles caused by scattering processes and the Hanle effect in the hydrogen Lyman-alpha line (121.567nm). Accurate measurements of the linear polarization signals caused by scattering processes and the Hanle effect are essential to explore the strength and structures of weak magnetic fields. The primary target of future solar telescopes is to measure the weak magnetic field in outer solar atmospheres (from the chromosphere to the corona through the transition region). The hydrogen Lyman-alpha-line is one of the best lines for the diagnostics of magnetic fields in the outer solar atmospheres. CLASP is to be launched in 2015, and will provide, for the first time, the observations required for magnetic field measurements in the upper chromosphere and transition region. CLASP is designed to have a polarimetric sensitivity of 0.1% and a spectral resolution of 0.01nm for the Lyman-alpha line. CLASP will measure two orthogonal polarizations simultaneously for about 5-minute flight. Now the integration of flight mirrors and structures is in progress. In addition to our strategy to realize such a high-precision spectro-polarimetry in the UV, we will present a progress report on our pre-launch evaluation of optical and polarimetric performances of CLASP.

solar↗

Theoretical model of HZE particle fragmentation by hydrogen targets

The fragmenting of high energy, heavy ions (HZE particles) by hydrogen targets is an important, physical process in several areas of space radiation research. In this work quantum mechanical optical model methods for estimating cross sections for HZE particle fragmentation by hydrogen targets are presented. The cross sections are calculated using a modified abrasion-ablation collision formalism adapted from a nucleus-nucleus collision model. Elemental and isotopic production cross sections are estimated and compared with reported measurements for the breakup of neon, sulphur, and iron, nuclei at incident energies between 400 and 910 Mev/nucleon. Good agreement between theory and experiment is obtained.

Townsend, L.W.↗

Ground Test Stand Development for One-step Electrochemical Production of High-Pressure Oxygen

NASA designed a test rig, High-Pressure Oxygen Generation Assembly (HPOGA) to test a novel method of electrolysis as an alternative technology to the state-of-the-art Oxygen Generation Assembly (OGA) currently on the International Space Station (ISS). This approach involves utilizing a specialized electrolysis cell stack designed to both generate and compress high-pressure oxygen up to 3600 PSIG. The design eliminates the need for an external compressor and hydrogen separator, streamlining the oxygen generation process. HPOGA tests the viability of an electrolysis cell stack for extended life usage. Within the system, there are several key subsystems: nitrogen, high/low pressure oxygen, hydrogen, water recirculation, and water injection. The water injection subsystem supplies deionized (DI) water to a centralized reservoir for consumption. Subsequently, a water recirculation loop transfers the DI water across the cathode side of the electrolysis cell stack with constant flow rate. The result is a supply of hydrogen in the water loop and oxygen accumulation on the anode side of the cell stack. Hydrogen is evaporated out as part of the hydrogen sub-system which also measures hydrogen/oxygen concentration for safety. The oxygen subsystem is responsible for managing high pressure oxygen, O2 exhaust, and conducting hydrogen/oxygen concentration measurements. The nitrogen subsystem serves dual functions, purging the hydrogen/oxygen subsystems, and regulating pressure in both high/low-pressure O2 sections via pneumatic back pressure regulators. Various sensors monitor pressure, temperature, humidity, gas concentration and flow rate in each subsystem. This paper presents the design and testing of a comprehensive test stand, which serves to operate and functionally verify the performance of the electrolysis cell while offering valuable lessons learned.

electrolysis↗

Integrated lunar materials manufacturing process

A manufacturing plant and process for production of oxygen on the moon uses lunar minerals as feed and a minimum of earth-imported, process materials. Lunar feed stocks are hydrogen-reducible minerals, ilmenite and lunar agglutinates occurring in numerous, explored locations mixed with other minerals in the pulverized surface layer of lunar soil known as regolith. Ilmenite (FeTiO.sub.3) and agglutinates contain ferrous (Fe.sup.+2) iron reducible by hydrogen to yield H.sub.2 O and metallic Fe at about 700.degree.-1,200.degree. C. The H.sub.2 O is electrolyzed in gas phase to yield H.sub.2 for recycle and O.sub.2 for storage and use. Hydrogen losses to lunar vacuum are minimized, with no net hydrogen (or any other earth-derived reagent) consumption except for small leaks. Feed minerals are surface-mined by front shovels and transported in trucks to the processing area. The machines are manned or robotic. Ilmenite and agglutinates occur mixed with silicate minerals which are not hydrogen-reducible at 700.degree.-1,200.degree. C. and consequently are separated and concentrated before feeding to the oxygen generation process. Solids rejected from the separation step and reduced solids from the oxygen process are returned to the mine area. The plant is powered by nuclear or solar power generators. Vapor-phase water electrolysis, a staged, countercurrent, fluidized bed reduction reactor and a radio-frequency-driven ceramic gas heater are used to improve thermal efficiency.

Gibson, Michael A.↗

Apparatus for hydrogen and carbon production via carbon aerosol-catalyzed dissociation of hydrocarbons

A novel process and apparatus is disclosed for sustainable, continuous production of hydrogen and carbon by catalytic dissociation or decomposition of hydrocarbons at elevated temperatures using in-situ generated carbon particles. Carbon particles are produced by decomposition of carbonaceous materials in response to an energy input. The energy input can be provided by at least one of a non-oxidative and oxidative means. The non-oxidative means of the energy input includes a high temperature source, or different types of plasma, such as, thermal, non-thermal, microwave, corona discharge, glow discharge, dielectric barrier discharge, or radiation sources, such as, electron beam, gamma, ultraviolet (UV). The oxidative means of the energy input includes oxygen, air, ozone, nitrous oxide (NO.sub.2) and other oxidizing agents. The method, apparatus and process of the present invention is applicable to any gaseous or liquid hydrocarbon fuel and it produces no or significantly less CO.sub.2 emissions compared to conventional processes.

Muradov, Nazim Z.↗

Lyman-alpha fluorescence from hydrogen photofragments of CH4 and H2O

The process of H-Lyman-alpha fluorescence produced through photodissociation of CH4 and H2O provides an example for the usefulness of the detection of fluorescence of dissociation fragments as an aid in identifying some high lying Rydberg states. In the first experiment reported, an electron storage ring synchrotron radiation source was used. The fluorescence produced was detected with a solar blind photomultiplier and a Cs photocathode with a spectral sensitivity in the wavelength range from 1050 to 1950 A. In the second experiment considered, an intense atomic line source was employed.

Wu, C. Y. R.↗

A study of the efficiency of hydrogen liquefaction

The search for an environmentally acceptable fuel to eventually replace petroleum-based fuels for long-range jet aircraft has singled out liquid hydrogen as an outstanding candidate. Hydrogen liquefaction is discussed, along with the effect of several operating parameters on process efficiency. A feasible large-scale commercial hydrogen liquefaction facility based on the results of the efficiency study is described. Potential future improvements in hydrogen liquefaction are noted.

Baker, C. R.↗

Aqueous chloride stress corrosion cracking of titanium: A comparison with environmental hydrogen embrittlement

The physical characteristics of stress corrosion cracking of titanium in an aqueous chloride environment are compared with those of embrittlement of titanium by a gaseous hydrogen environment in an effort to help contribute to the understanding of the possible role of hydrogen in the complex stress corrosion cracking process. Based on previous studies, the two forms of embrittlement are shown to be similar at low hydrogen pressures (100 N/sqm) but dissimilar at higher hydrogen pressures. In an effort to quantify this comparison, tests were conducted in an aqueous chloride solution using the same material and test techniques as had previously been employed in a gaseous hydrogen environment. The results of these tests strongly support models based on hydrogen as the embrittling species in an aqueous chloride environment. Further, it is shown that if hydrogen is the causal species, the effective hydrogen fugacity at the surface of titanium exposed to an aqueous chloride environment is equivalent to a molecular hydrogen pressure of approximately 10 N/sqm.

Nelson, H. G.↗

Aqueous chloride stress corrosion cracking of titanium - A comparison with environmental hydrogen embrittlement

The physical characteristics of stress corrosion cracking of titanium in an aqueous chloride environment are compared with those of embrittlement of titanium by a gaseous hydrogen environment in an effort to help contribute to the understanding of the possible role of hydrogen in the complex stress corrosion cracking process. Based on previous studies, the two forms of embrittlement are shown to be similar at low hydrogen pressures (100 N/sq m) but dissimilar at higher hydrogen pressures. In an effort to quantify this comparison, tests were conducted in an aqueous chloride solution using the same material and test techniques as had previously been employed in a gaseous hydrogen environment. The results of these tests strongly support models based on hydrogen as the embrittling species in an aqueous chloride environment.

Nelson, H. G.↗

Post-treatment of reclaimed waste water based on an electrochemical advanced oxidation process

The purification of reclaimed water is essential to water reclamation technology life-support systems in lunar/Mars habitats. An electrochemical UV reactor is being developed which generates oxidants, operates at low temperatures, and requires no chemical expendables. The reactor is the basis for an advanced oxidation process in which electrochemically generated ozone and hydrogen peroxide are used in combination with ultraviolet light irradiation to produce hydroxyl radicals. Results from this process are presented which demonstrate concept feasibility for removal of organic impurities and disinfection of water for potable and hygiene reuse. Power, size requirements, Faradaic efficiency, and process reaction kinetics are discussed. At the completion of this development effort the reactor system will be installed in JSC's regenerative water recovery test facility for evaluation to compare this technique with other candidate processes.

Verostko, Charles E.↗

Effects of hydrogen on metals

Several rules to guide choice of materials, and methods of welding, electroplating, and heat treatment will provide a method for minimizing failures in storage tanks and related hardware. Failures are caused by high-pressure hydrogen effects, the formation of hydrides in titanium, and hydrogen absorption through various metals processing techniques.

Cataldo, C. E.↗

Photochemistry and lifetimes of interstellar molecules.

Quantitative discussion of the photochemistry and lifetime against photodecomposition of five interstellar molecules: H2CO, NH3, H2O, CH4, and CO. For the first four molecules, primary photochemical decomposition processes yielding atomic and molecular hydrogen are considered in addition to photoionization. The quantum yield for decomposition of these molecules is unity. For CO, only decomposition to ground-state carbon and oxygen atoms occur, but the quantum yield is not known and may be considerably less than unity. The radiation field in obscuring clouds is estimated, using an interstellar extinction curve for the Perseus region.

Stief, L. J.↗

Photochemical synthesis of simple organic free radicals on simulated planetary surfaces - An ESR study

Electron spin resonance (ESR) spectroscopy provided evidence for formation of hydroxyl radicals during ultraviolet photolysis (254 nm) at -170 C of H2O adsorbed on silica gel or of silica gel alone. The carboxyl radical was observed when CO or CO2 or a mixture of CO and CO2 adsorbed on silica gel at -170 C was irradiated. The ESR signals of these radicals slowly disappeared when the irradiated samples were warmed to room temperature. However, reirradiation of CO or CO2, or the mixture CO and CO2 on silica gel at room temperature then produced a new species, the carbon dioxide anion radical, which slowly decayed and was identical with that produced by direct photolysis of formic acid adsorbed on silica gel. The primary photochemical process may involve formation of hydrogen and hydroxyl radicals. Subsequent reactions of these radicals with adsorbed CO or CO2 or both yield carboxyl radicals, CO2H, the precursors of formic acid. These results confirm the formation of formic acid under simulated Martian conditions and provide a mechanistic basis for gauging the potential importance of gas-solid photochemistry for chemical evolution on other extraterrestrial bodies, on the primitive earth, and on dust grains in the interstellar medium.

Tseng, S.-S.↗

A molecular model for ice nucleation and growth, attachment 2

The central field empirical pair potential model is applied to studying the effects of kinks, ledges, and vacancies on the absorption of water molecules from the vapor. Molecular dynamics simulations indicate that cluster and/or surface modes play a primary role in the absorption process, the flexibility of the hydrogen bond serves to decrease the energy required for structural interconversion, and the rapid distribution of added energy in a hydrogen bonded system lead to aggregate stability which greatly exceeds that predicted by static energy calculations.

Hale, B. N.↗

On the maximum luminosity in X-ray bursts

A qualitative model is proposed which relates the burst behavior of 1608-52 observed by Murakami et al (1980) to the composition of the envelope in which the X-ray bursts occur. The model provides an explanation for the large scatter in the peak fluxes when the accretion rate is high. A flux would be transported outward at the top of the convective region which equals 1.5 to 2 times the Eddington limit appropriate to a helium-rich gas. Upon traversing the outer part of the accreted layer, which is not affected by the nuclear processes and is therefore hydrogen-rich, this flux is about a factor of 3 to 4 higher than the local value of the Eddington luminosity.

Van Paradijs, J.↗

Plasma waves produced by the xenon ion beam experiment on the Porcupine sounding rocket

The production of electrostatic ion cyclotron waves by a perpendicular ion beam in the F-region ionosphere is described. The ion beam experiment was part of the Porcupine program and produced electrostatic hydrogen cyclotron waves just above harmonics of the hydrogen cyclotron frequency. The plasma process may be thought of as a magnetized background ionosphere through which an unmagnetized beam is flowing. The dispersion equation for this hypothesis is constructed and solved. Preliminary solutions agree well with the observed plasma waves.

Kintner, P. M.↗

On the origin of the 6.1-ms pulsar

A quantitative model is presented to account for the observed features of the binary pulsar PSR1953+53. A lower giant branch star is suggested to have evolved on a nuclear time scale while orbiting a neutron star, with mass transfer to the neutron star commencing when the giant attained its Roche lobe. A radius-core mass relationship was used to examined the processes that occurred after the hydrogen atmosphere was drained off to the neutron star. Tidal dissipation has circularized the orbit of the companion during mass transfer, while the orbit expanded. Accretion torques caused spin-up of the neutron star, which had a magnetic moment of no more than 3 x 10 to the 27th G/cu cm. The drained star became a degenerate dwarf with very faint luminosity, which accounts for no visual companion having been observed to date.

Joss, P. C.↗

SSME fuel preburner phase 1/phase 2+ comparison

An analytical comparison of the predicted combustion flowfields for the Phase 1 and Phase 2+ fuel preburner configurations using an advanced CFD combustion code is currently underway at Rocketdyne. The Phase 2+ injector has a modified element design. The redesigned element provides for improved atomization through a shift in the injector element/face bleed flow split while maintaining an acceptable pressure drop. Cold-flow tests of the new design have been encouraging. As a complement to those tests, the Advanced Rocket Injector Combustor Code (ARICC) was selected to conduct a detailed combustion flowfield simulation. ARICC models two-dimensional (or axisymmetric), transient, turbulent, two-phase mixing and combustion flowfields. It is derived from a member of the Los Alamos ICEd-ALE family of codes. Unique features of ARICC include explicit representation of the coaxial LOX jet and hydrogen gas flows, distributed atomization processes, droplet breakup, and supercritical vaporation processes. Predictions of temperature and OH concentration profiles for the Phase 1 and Phase 2+ injector flowfields indicate a trend toward more uniform temperature distributions and shorter flame lengths with the Phase 2+ design.

Jensen, R. J.↗