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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Measured Energy-Dependent Neutron Attenuation Through the Stacked Printed Circuit Boards

Engineers often stack printed circuit boards (PCBs), populated with semiconductor devices, one behind the other in neutron beams to improve the error statistics in radiation-effects tests. As the neutron beam traverses through the boards, the neutron flux is both attenuated and the energy spectrum changes, which may have a significant impact on the results of such tests. In this work, we have developed a technique to measure the energy-dependent neutron attenuation due to the PCBs and to determine the energy-dependent effective cross section of neutron interactions with a single PCB. With this effective cross section, engineers can calculate the change in the neutron energy spectrum and the total neutron attenuation after any number of identical PCBs in the stack. This information will allow test engineers to partially correct inaccuracies in soft error tests.

42 ENGINEERING↗

GEN3D Experimental and Numerical Development of GEN3 Durability Models

Understanding of the high temperature durability of particles and the materials that contain them is critical to next generation of concentrating solar power (CSP) technology. Here we studied the durability of particles and their containment materials under extreme UV cycling, thermal cycling, and in low-speed high temperature mechanical wear situations. The optical stability of seven candidate particles has been determined following exposure to the high temperature conditions present in a generation 3 particle-based CSP technology. Particle solar weighted absorptance and emittance measured periodically during 10,000 high solar irradiance exposure cycles and up to 400 hours of isothermal aging has been documented. The particle aging due to repeated exposure to concentrated solar flux represented the 30-year lifetime of a power plant. Models were fit to the absorptivity and emissivity data following the isothermal aging provides the projected optical degradation of the particles as a function of temperature. Mechanical wear was studied through the use of custom developed wear testing facilities for measuring high temperature impact wear, abrasion wear, and particle attrition. Additionally, a novel technique for measuring the high temperature mechanical properties of single particles was developed. Through these tests it was observed that high nickel alloys generally showed lower wear than comparable iron based steels, particularly at elevated temperatures of 800°C. Mechanical wear at these temperatures is a highly complex phenomenon combining both mechanical wear and oxidation. Additionally, the containment materials wear rates are influenced by the particles (both hardness and roundness), making the wear mechanisms complex. The initial wear test conducted in the abrasion test rig revealed a substantial amount of oxide materials in the particle bed after testing (in relative to later tests), and substantially more wear, likely indicating a need for concern in startup operation of particle facilities to not incur high wear from the presence of oxides. Particle attrition experiments have only been conducted for a single material but increase size distribution, reduction in circularity, and particle diameter is observed. Efforts to develop predictive models was limited due to a testing campaign that prioritized testing materials for particle pathway developers over building a comprehensive design of experiments. The results discussed in this report inform future CSP developers and researchers further de risking the technology and assisting in its future development. ParticleBased CSP development provides a path to dispatchable solar power generation with storage at a price competitive in the current energy market. Lowering the cost of CSP technology provides a carbon free power generation solution that can assist in the transition from fossil fuels to renewable sources of electricity.

14 SOLAR ENERGY↗

Rotating Disk Electrode Standardization and Best Practices in Acidic Oxygen Evolution for Low-Temperature Electrolysis

Efforts in oxygen evolution catalyst development have significantly increased and often use rotating disk electrode half-cells to evaluate intrinsic kinetics and screen materials for short-term durability. Standardizing rotating disk electrode test protocols is critical to experimental accuracy, to realistically assess their potential impact at a device level and to assess how different catalyst approaches and concepts are prioritized. The goal of this study is to provide standardized test protocols and suggest best practices to help reduce variability in ex situ materials characterization in the broader community. Specifically, these protocols focus on test cleanliness and materials choices, including how electrodes are prepared and tested, and the impact on activity observations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Stabilization of light-induced effects in Si modules for IEC 61215 design qualification

Standardized testing of commercial photovoltaic modules is widely used around the world and decreases risks of module failures. Such testing also reduces financial risks for module manufacturers and customers. This work examines the expected impact of certain defects in silicon (Si) modules during standardized accelerated testing. Specifically, the behavior of boron-oxygen (BO) light-induced degradation (LID) and light- and elevated temperature-induced degradation (LeTID) are simulated during some of the stress tests in IEC 61215. LID and LeTID reaction rates at qualification temperatures are estimated from earlier published data. It is demonstrated the BO-related LID may cause some false positives and false negatives when IEC 61215 tests are performed as prescribed in the 2016 published version. Possible stabilization steps to avoid these false results are suggested. State changes for the defects causing LeTID occur much more slowly than those causing BO LID, and therefore LeTID is predicted to have a lesser impact on the IEC 61215 stress tests results.

14 SOLAR ENERGY↗

Mechanistic Insights Into Fatigue Life Enhancement of High‐Strength Steel via Ultrasonic Impact Treatment

In this work we explore the impact of Ultrasonic Impact Treatment (UIT) on the fatigue performance of high‐strength microalloyed steel commonly used in crankshaft applications. Building on prior observations of fatigue life improvement with UIT, this work focuses on unraveling the process–structure–performance relationships underpinning these enhancements. Microstructural analysis revealed significant grain refinement in the near‐surface layers, with deformation depth increasing at higher impact energies. This led to increased surface hardness and the development of deeper compressive residual stresses, particularly in samples treated with higher impact energy. Rotating bending fatigue testing showed a substantial improvement in fatigue life for UIT‐treated samples, with the endurance limit nearly doubling compared with untreated specimens. Fractographic analysis revealed a transition in crack initiation from surface defects in untreated samples to interior regions in UIT‐treated samples, characterized by the formation of noninclusion‐induced granular bright facets (GBFs). The observed fatigue enhancement is attributed to the synergistic effects of strain hardening and compressive residual stresses, which increase the surface crack threshold and promote interior crack initiation. This study provides new mechanistic insight into UIT‐induced fatigue resistance and interior failure behavior in high‐strength steels.

36 MATERIALS SCIENCE↗

Bentonite buffer under high temperature: laboratory experiments and coupled process modeling

Abstract. Bentonite buffer in a geological repository will be simultaneously heated from decaying radioactive waste and hydrated from the surrounding host rock, triggering complex and coupled THMC (thermal–hydrological–mechanical–chemical) processes. Understanding the THMC behavior of bentonite-based engineered barrier system (EBS) is key to the evaluation and prediction of its long-term performance. Studies on the THMC process have been focused on conditions under 100 ∘C, as most design concepts impose a thermal limit of 100 ∘C in bentonite. Recently, studies under high-temperature conditions have been conducted to evaluate the possibility of raising the thermal limit and expanding the data/knowledge base to increase the confidence level. In this abstract, we present a series of bench-scale laboratory experiments at high temperatures (up to 200 ∘C) and the corresponding modeling work. Two sets of column tests were conducted, and each set consisted of two test columns: a control column undergoing only hydration (non-heated) and an experiment column experiencing both heating and hydration (heated). During the experiment, frequent X-ray computed tomography (CT) images were collected to provide a 3D visualization of the density distribution and present the spatiotemporal evolution of (1) hydration/dehydration, (2) clay swelling/shrinkage, (3) displacement, and (4) mineral precipitation. The two sets of tests differ with respect to several experimental conditions, such as bentonite type, compacted density and water content, water chemistry, and hydration pressure, but the important difference is that the first set used bentonite powder with a dry density of 1.28 g cm−3, whereas the second set used granulated bentonite (mixture of pellets and powder) with a dry density of 1.45–1.5 g cm−3. In both sets of experiments, a comprehensive post-dismantling characterization of bentonite samples was carried out after the column tests had been running for 1.5 years. Comparing non-heated and heated columns, the temperature gradient led to lower degree of homogenization of bentonite after bentonite became fully saturated; comparing the first and second sets, granulated and powdered bentonite exhibited drastically different hydration behavior. A THM model with a 2D axisymmetric grid system was used to interpret the data from the first set of tests. The model considers the combined impact of saturation, fluid pressure, and porosity change due to swelling/compression on the spatiotemporal distribution of bulk density and movement of the thermocouple modules. Observations from the tests help us understand the early perturbation of bentonite buffer under high temperature, and data from these tests improve the calibration of key constitutive hydrological and mechanical models and, therefore, enhance the modeling capability with respect to calculating the long-term evolution of bentonite buffer.

Zheng, Liange↗

Ionization Yield in Silicon for eV-Scale Electron-Recoil Processes

The development of single charge resolving, macroscopic silicon detectors has opened a window into rare processes at the O(eV) scale. In order to reconstruct the energy of a given event, or model the charge signal obtained for a given amount of energy absorbed by the electrons in a detector, an accurate charge yield model is needed. In this paper we review existing measurements of charge yield in Silicon, focusing in particular on the region below 1 keV. We highlight a calibration gap between 12-50 eV (referred to as the "UV-gap") and employ a phenomenological model of impact ionization to explore the likely charge yield in this energy regime. Finally, we explore the impact of variations in this model on a test case, that of dark matter scattering off electrons, to illustrate the scientific impact of uncertainties in charge yield.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Visual Systems Mapping to Define and Compare Woody Biomass LCAs for Sustainable Systems

The challenge addressed in this research centres on the need to choose between several biomass sources and energy production processes, while supporting rural economies and resilience of forest systems. A key barrier to effective decision-making for strategies using biomass is the lack of standardized and transparent life cycle assessment (LCA) baselines. These baselines are critical for assessing the impacts of biomass strategies but often vary due to regional factors and chosen simplifying assumptions of the LCAs. However, omitting key variables can mean the LCA omits key feedback and balancing loops relevant to fully assessing impacts of the change or test scenario. To address these complexities, this project employs a systems engineering approach: visual systems mapping. This technique is used to define the boundaries and dynamic behaviours of LCA baselines, enhancing transparency. By examining five literature sources and their documented baseline scenarios, the systems mapping case-studies demonstrates an approach to documenting and archiving these baselines. Recommendations are that visual systems mapping should be used to document key assumptions, such as baselines, of LCAs. Further, where possible open data repositories should hold key information about LCA baselines and reproducible workflows (e.g., using open-source tools) should be used to improve transparency and comparability in LCAs. Given the consensus within the broader scientific community on the importance of replicable data practices, this research reinforces the need for standardized frameworks and systems engineering tools in LCAs. This research demonstrates a pathway to more transparent, standardized, and comparable LCAs, that may bolster decisions for biomass systems.

Davis, Maggie [ORNL] (ORCID:0000000181319328)↗

A high-order, localized-artificial-diffusivity method for Eulerian simulation of multi-material elastic-plastic deformation with strain hardening

A high-order method for Eulerian simulation of material undergoing large elastic–plastic deformation is developed. Thermodynamically consistent hyperelastic constitutive relations are assumed, facilitating the treatment of solids, liquids, and gases in a unified manner. Here, the method enables the simulation of multi-material interactions using a diffuse interface approach. Numerical capturing of material interfaces, shock waves, contact surfaces, and elastic-plastic strain discontinuities using high-order compact-difference schemes is assisted by Localized Artificial Diffusivity (LAD). In the new setting involving elastic–plastic deformation, the previously established terms for the artificial properties are verified to effectively regularize normal shocks. Additional LAD terms are introduced to the elastic and plastic kinematic equations to regularize shear shocks and other strain discontinuities, improving solution stability. Other important features of the method that improve robustness include the numerical treatment of compatibility terms in the kinematic equations, and the treatment of rotation. Particular emphasis is focused toward new advancements of the methods for plastic-deformation integration and the associated strain hardening of the material, including rate-dependent plasticity. The method is demonstrated on a variety of test problems, including 1-D impacts, a variant of the Shu-Osher problem, a Taylor impact, and a Richtmyer-Meshkov instability between two elastic–plastic solids with strain hardening.

42 ENGINEERING↗

Production of desensitized, ultrafine PETN powder

Pentaerythritol tetranitrate (PETN) is a widely studied high explosive (HE), most commonly used in detonator applications. In this work, we use a spray drying technique to manufacture a new “nano-powder” morphology of PETN. The spray dried PETN is several orders of magnitude smaller in particle size than traditionally prepared PETN powders. The spray dried PETN has a mostly spherical and smooth morphology, while traditional crystalline PETN typically has sharp edges and crystal facets. Small-scale sensitivity tests including drop-weight impact, friction, and electrostatic discharge (ESD) indicate the spray dried PETN is less sensitive than traditionally used forms of PETN powders. Furthermore, we also observed no changes in chemical properties (melt temperature and onset of decomposition) after spray drying, and the material remains in the tetragonal, crystalline phase.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Local and Global Sensitivity Analysis of a Reactive Transport Model Simulating Floodplain Redox Cycling

Reactive transport models (RTMs) are essential tools that simulate the coupling of advective, diffusive, and reactive processes in the subsurface, but their complexity makes them difficult to understand, develop and improve without accompanying statistical analyses. Although global sensitivity analysis (SA) can address these issues, the computational cost associated with most global SA techniques limits their use with RTMs. In this study, we apply distance-based generalized sensitivity analysis (DGSA), a novel and computationally efficient method of global SA, to a floodplain-scale RTM and compare DGSA results to those from local SA. Our test case focuses on the impact of 17 uncertain environmental parameters on spatially and temporally variable redox conditions within a floodplain aquifer. The input parameters considered include flow and diffusion rates, geochemical reaction rates, and the spatial distribution of sediment facies. Sensitivity was evaluated for three distinct components of the model response, encompassing both multidimensional and categorical output. Parameter rankings differ between local SA and DGSA, due to nonlinear effects of individual parameters and interaction effects between parameters. DGSA results show that fluid residence time, which is controlled by aquifer permeability, generally exerts a stronger control on redox conditions than do geochemical reaction rates. Sensitivity indices also demonstrate that sulfate reduction is key for establishing and maintaining reducing conditions throughout the aquifer. Furthermore, these results provide insights into the key drivers of heterogeneous redox processes within floodplain aquifers, as well as the main sources of uncertainty when modeling complex subsurface systems.

54 ENVIRONMENTAL SCIENCES↗

Seasonality and Albedo Dependence of Cloud Radiative Forcing in the Upper Colorado River Basin

Mountains create and enhance their own clouds, which both scatter and absorb shortwave radiation from the sun and absorb and re-emit land surface and atmospheric longwave radiation. However, the impacts of clouds on the surface radiation balance in high elevation snowy mountain terrain are poorly explored. In this study, we use data collected by the SAIL field campaign and partner organizations in the upper elevations (2,880 m.a.s.l) of the Upper Colorado River Basin (UCRB) over a 21-month period from September 2021 to June 2023 to estimate Cloud Radiative Forcing (CRF) in the shortwave, longwave, and the net effect. Longwave warming effects dominate during the winter when snow albedos are high (0.8–0.9) and the background atmospheric precipitable water vapor is low (<0.5 cm), yielding a maximum monthly average net CRF of +34.7 W·m -2 , meaning that clouds increase the net radiation relative to clear skies during this time period. The sign of net CRF switches in the warm season as snow recedes, sun-angles increase, and the North American monsoon arrives, yielding a minimum monthly average net CRF of -47.6 W·m -2 with hourly minima of -600 W·m -2 . The sign of net CRF is typically positive, even at solar noon, when the surface is snow covered, except for a brief period over melting, low-albedo snow (0.5–0.6) impacted by dust impurities. Sensitivity tests elucidate the role of the surface albedo on the net CRF. The results suggest that net CRF will increase in magnitude and lead to a more persistent cooling effect on the surface net radiation budget as the snow cover declines.

54 ENVIRONMENTAL SCIENCES↗

Threadsafe Dynamic Neighbor Lists for Monte Carlo Ray Tracing

Monte Carlo (MC) transport codes offer high-fidelity modeling of particle transport physics, but their high computational cost makes them impractical for many applications. For some applications such as multiphysics and depletion that use finely discretized geometries, a large portion of this computational cost is attributable to ray tracing. Neighbor lists are a well-known method for accelerating ray-tracing calculations in a MC code, but despite their prevalence, little work has been published on the details of their implementation. The fine details can have a significant impact on performance, particularly when using shared-memory parallelism. This paper addresses these details of implementation with a discussion of different neighbor list schemes and their impact on software runtime. Performance tests were run by using OpenMC on a pin-cell problem discretized with up to 200 axial regions. The results demonstrate that switching from surface-based to cell-based neighbor lists leads to a 10 faster calculation rate for the most fine discretization. Finally, using a threadsafe shared-memory data structure results in a 20% faster calculation rate versus simple threadprivate neighbor lists. Results here show that a data structure that is contiguous in memory improves performance by only 1% to 2% over noncontiguous linked lists.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Power-to-Gas Systems for Active Load Management at EV Charging Sites with High DER Penetration

Intermittent renewable systems and increasing electric vehicle (EV) penetrations increase load intermittency—and will require expensive distribution system infrastructure upgrades. Power-to-gas (P2G) systems are highly controllable loads that can be modulated to regulate the net load behind the meter. In this work, we present an active load management approach using P2G systems to regulate the net load for an EV charging station with high penetrations of renewable generation. The system also validates the feasibility of the proposed approach using a 750-kW electrolyzer operated with the distribution system in a real-time power-hardware-in-the-loop test. Finally, we evaluate the impact of the size of the P2G system on its ability to regulate the net load.

ADVANCED PROPULSION SYSTEMS,POWER TRANSMISSION AND↗

Investigation of Surface Skidding Response of PBX 9501 and PBX 9502

Introduction: Assess the hazards of handling polymer bonder explosives(PBX) for the case of skidding with grit particles in the frictional interface. High explosive (HE) materials tested: PBX 9501 and 9502. High melting point materials at the skidding interface between HE and a substrate is known to increase the probability of ignition by creating hot spots not subject to reduced heating from the melting of HE material. Skidding occurred at peak forces of 6-26 kN normal force, and 0.6-3.4 kN of frictional force. Velocities for skidding range from 5-30 m/s, see figure 7. Sparse amounts of 300 μm silica grit is applied loosely to the HE surface before testing. Previous works have tested ignition by grit. Testing parameters include angle of impact, drop height, grit size, grit density, substrate material. This study focuses on pre ignition conditions and detailed thermal imaging of the frictional interface. Conclusions: Temperature hot spots were observed at high points in HE surface topology. These high points may be created by grit particles. Since these points impact first high frictional work is concentrated and quickly increases temperature. Small amounts of grit do not affect the overall frictional force but do concentrate the frictional work to create hot spots.

36 MATERIALS SCIENCE↗

Chemical durability assessment of enhanced low-activity waste glasses through EPA method 1313

In this work, we report the progress of the Glass Leaching Assessment for Durability (GLAD) program on the implementation of the United States Environmental Protection Agency (EPA) Leaching Environmental Assessment Framework pH-dependent leach test (EPA Method 1313) to low-activity nuclear waste (LAW) glasses. The GLAD program seeks to develop new strategies to understand the chemical durability of nuclear waste glasses for the disposal in near-surface conditions. A series of 16 high-waste loading LAW glasses, currently under development, were selected using machine learning methods to study the corrosion behavior using EPA Method 1313. Reacted glass powders were examined using scanning electron microscopy and the eluate compositions were examined using inductively coupled plasma-optical emission spectroscopy. Compositional modeling was used to fit the measured elemental releases from EPA Method 1313. The compositional models demonstrated that elements such as Si reduce elemental release while B can increase elemental release (consistent with elemental modeling of the Product Consistency Test and Vapor Hydration Test) while other elements, such as Fe, exhibit pH-dependent behavior. The amount of acid added during the EPA testing was found to significantly impact the observed result, which was only apparent after preforming the present matrix study. The overall titration curves were able to be compositionally modeled for future process optimization.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Sensitivity of meteorological-forcing resolution on hydrologic variables

Projecting the spatiotemporal changes in water resources under a no-analog future climate requires physically based integrated hydrologic models which simulate the transfer of water and energy across the earth's surface. These models show promise in the context of unprecedented climate extremes given their reliance on the underlying physics of the system as opposed to empirical relationships. However, these techniques are plagued by several sources of uncertainty, including the inaccuracy of input datasets such as meteorological forcing. These datasets, usually derived from climate models or satellite-based products, are typically only resolved on the order of tens to hundreds of kilometers, while hydrologic variables of interest (e.g., discharge and groundwater levels) require a resolution at much smaller scales. In this work, a high-resolution hydrologic model is forced with various resolutions of meteorological forcing (0.5 to 40.5 km) generated by a dynamical downscaling analysis from the regional climate model Weather Research and Forecasting (WRF). The Cosumnes watershed, which spans the Sierra Nevada and Central Valley interface of California (USA), exhibits semi-natural flow conditions due to its rare undammed river basin and is used here as a test bed to illustrate potential impacts of various resolutions of meteorological forcing on snow accumulation and snowmelt, surface runoff, infiltration, evapotranspiration, and groundwater levels. Results show that the errors in spatial distribution patterns impact land surface processes and can be delayed in time. Localized biases in groundwater levels can be as large as 5–10 m and 3 m in surface water. Most hydrologic variables reveal that biases are seasonally and spatially dependent, which can have serious implications for model calibration and ultimately water management decisions.

54 ENVIRONMENTAL SCIENCES↗

Wake steering optimization under uncertainty

Turbines in wind power plants experience significant power losses when wakes from upstream turbines affect the energy production of downstream turbines. A promising plant-level control strategy to reduce these losses is wake steering, where upstream turbines are yawed to direct wakes away from downstream turbines. However, there are significant uncertainties in many aspects of the wake steering problem. For example, infield sensors do not give perfect information, and inflow to the plant is complex and difficult to forecast with available information, even over short time periods. Here, we formulate and solve an optimization under uncertainty (OUU) problem for determining optimal plant-level wake steering strategies in the presence of independent uncertainties in the direction, speed, turbulence intensity, and shear of the incoming wind, as well as in turbine yaw positions. The OUU wake steering strategy is first examined for a two-turbine test case to explore the impacts of different types of inflow uncertainties, and it is then demonstrated for a more realistic 11-turbine wind power plant. Of the sources of uncertainty considered, we find that wake steering strategies are most sensitive to uncertainties in the wind speed and direction. When maximizing expected power production, the OUU strategy also tends to favor smaller yaw angles, which have been shown in previous work to reduce turbine loading. Ultimately, the plant-level wake steering strategy formulated using an OUU approach yields 0.48?% more expected annual energy production for the 11-turbine wind plant than a strategy that neglects uncertainty when considering stochastic inputs. Thus, not only does the present OUU strategy produce more power in realistic conditions, but it also reduces risk by prescribing strategies that call for less extreme yaw angles.

17 WIND ENERGY↗