Search NASA⌕ Search

SEARCH · Search NASA

Results for “kinetic distributions”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Quasilinear theory of general electromagnetic fluctuations including discrete particle effects for magnetized plasmas: General analysis

The general quasilinear Fokker–Planck kinetic equation for the gyrophase-averaged plasma particle distribution functions in magnetized plasmas is derived, making no restrictions on the energy of the particles and on the frequency of the electromagnetic fluctuations and avoiding the often made Coulomb approximation of the electromagnetic interactions. Here, the inclusion of discrete particle effects breaks the dichotomy of nonlinear kinetic plasma theory divided into the test particle and the test fluctuation approximation because it provides expression of both the non-collective and collective electromagnetic fluctuation spectra in terms of the plasma particle distribution functions. Within the validity of the quasilinear approach, the resulting full quasilinear transport equation can be regarded as a determining nonlinear equation for the time evolution of the plasma particle distribution functions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1992

Distribution of particles and fields in turbulent media

It is shown that fluctuations of kinetic coefficients can lead to the development of an instability that tends to increase the gradients of the distribution of particles and fields in turbulent media. It is found that high rank correlation functions of the cosmic medium turbulent velocity must be taken into account in most real cases. Turbulence in compressible media can lead to a decrease of the CR diffusion coefficient. In some cases the diffusion coefficient may become negative, which implies the development of an instability with respect to the formation of clusters of particles. A similar instability may exist for fields in turbulent media and in media with fluctuation parameters. It may lead to the bunching of magnetic field lines and to the fractal structure of waves propagating in the media.

Dolginov, A. Z.↗
NASA NTRS1977

Numerical prediction of aeroacoustic jet-flap flows

Turbulent boundary layer flows departing an aerodynamic surface are experimentally verified to be strong sources of noise. Analysis of the source tensor of the Lighthill equation identifies important gradients of mean and fluctuating velocity components. Transition distributions of mean flow and select fluctuating velocity correlations, within the region immediately downstream of a sharp edged flap terminus are established by finite element solution of a parabolized form of the time-averaged steady flow Navier-Stokes equations closed with a turbulence kinetic energy model. Numerical solutions are presented which quantize the localized large mean flow accelerations and resultant peaks in the distribution of turbulence kinetic energy in the near wake region. Results are verified by comparison to experiment.

Baker, A. J.↗
DOE OSTI2026

Pore-Scale Study on the Positive Feedback Between Stress and Porosity Caused by Pressure Solution in Porous Media

Pressure solution is an important process in the evolution of sedimentary rocks, which provide storage space for most of our petroleum resources. It directly influences the generation, migration, and storage of petroleum fluids in subsurface sedimentary rocks. Here, in this paper, we develop a pore-scale, mechanochemical model to demonstrate a possible positive feedback between the local porosity and pore surface stress, in which a higher local porosity causes a higher local pore surface stress, thus enhancing pressure solution and consequently further increasing the local porosity. Pore surface stress represents stress on a solid grain adjacent to a pore. Specifically, the pore-scale, mechanochemical model directly simulates the stress distribution over solid and pore surfaces using a finite element model. The dissolution of solids at the solid-pore interfaces under a far-from-equilibrium condition is simulated using a first-order kinetics model that accounts for the local stress distribution. The updated pore geometry, caused by pore surface dissolution, is then used in the stress simulation in the next numerical iteration. Two types of porous media, the Oriskany sandstone and an artificial porous medium with spherical pores, were tested in the mechanochemical simulation. The positive stress-porosity feedback during pressure solution was observed in both samples. In addition, the model quantitatively illustrated the distribution of local mineral dissolution rates on all pore surfaces, as well as its relation to the effective mineral dissolution rate of the entire sample. Based on the comparison between the two porous media, the local mineral dissolution was regulated by pore space distribution, geometry, and coalescence during pressure solution. This work is the first that uses direct, pore-scale numerical simulation to demonstrate the positive stress-porosity feedback during pressure solution, which has the potential to advance the understanding of the mechanical-chemical (MC) coupling in many geological processes that are relevant to subsurface energy systems, such as the recovery of petroleum hydrocarbons and geothermal energy.

CT scanning↗
DOE OSTI2022

How the Hydrophobic Interface between a Perfluorosulfonic Acid Polymer and Water Vapor Controls Membrane Hydration

Stable hydration in perfluorinated polyelectrolyte membranes such as Nafion is essential to maintain good ion conductivity and manage permeation, especially in vapor-fed devices where water content depends on relative humidity in a gas stream. Extensive studies in the literature have shown that Nafion hydration in water vapor is controlled by its interfacial transport resistance. Nafion forms a fluorine-rich layer at the polymer-gas interface, and it has been proposed that this layer blocks water transport due to its hydrophobicity. To develop a molecular-level description of the physics underlying transport resistance in this system, we have performed a computational reaction-diffusion kinetics study of water evaporation from Nafion. Two distinct models are examined, one mimicking the blocking function proposed in the literature and the other assuming that there is no blocking, treating instead water evaporation as a dynamic balance between uptake from the gas and desorption from the polymer surface. Simulation results are compared to time-dependent infrared data over a range of 100-0% relative humidity from the literature. Only the dynamic model successfully reproduces experimental observations. This indicates that the physical nature of interfacial transport resistance is not slow diffusion across an interfacial layer; rather, it is due to the competition between dehydration and rehydration. The simulation data provide details on the accompanying water distributions throughout the membrane and on interfacial kinetics, showing that they are characterized by strong fluctuations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Controlling Complex Coacervation via Random Polyelectrolyte Sequences

The utilization of chemical sequence control in polymeric materials is key to enabling material design on par with biomacromolecular systems. One important avenue for scalable sequence-controlled polymers leverages the random copolymerization of distinct monomers, with the statistical distribution of the monomeric sequence arising from reaction kinetics following a first-order Markov process. Here we utilize the framework of the random phase approximation (RPA) to develop a theory for the phase behavior of symmetric polyelectrolyte coacervates whose chemical sequences are dictated by simple statistical distributions. We find that a high charge "blockiness" within the random sequences favors the formation of denser and more salt-resistant coacervates while simultaneously increasing the width of the two-phase region. Here, we trace these physical effects to the increased cooperativity of Coulomb interactions that results from increased charge blockiness in oppositely charged polyelectrolytes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1973

Energy distribution functions of kilovolt ions parallel and perpendicular to the magnetic field of a modified Penning discharge

The distribution function of ion energy parallel to the magnetic field of a modified Penning discharge has been measured with a retarding potential energy analyzer. These ions escaped through one of the throats of the magnetic mirror geometry. Simultaneous measurements of the ion energy distribution function perpendicular to the magnetic field have been made with a charge exchange neutral detector. The ion energy distribution functions are approximately Maxwellian, and the parallel and perpendicular kinetic temperatures are equal within experimental error. These results suggest that turbulent processes previously observed in this discharge Maxwellianize the velocity distribution along a radius in velocity space and cause an isotropic energy distribution. When the distributions depart from Maxwellian, they are enhanced above the Maxwellian tail.

Roth, R. J.↗
NASA NTRS1972

Energy distribution functions of kilovolt ions in a modified Penning discharge.

The distribution function of ion energy parallel to the magnetic field of a modified Penning discharge has been measured with a retarding potential energy analyzer. These ions escaped through one of the throats of the magnetic mirror geometry. Simultaneous measurements of the ion energy distribution function perpendicular to the magnetic field have been made with a charge-exchange neutral detector. The ion energy distribution functions are approximately Maxwellian, and the parallel and perpendicular kinetic temperatures are equal within experimental error. These results suggest that turbulent processes previously observed in this discharge Maxwellianize the velocity distribution along a radius in velocity space, and result in an isotropic energy distribution.

Roth, J. R.↗
NASA NTRS1973

Energy distribution functions of kilovolt ions in a modified Penning discharge.

The distribution function of ion energy parallel to the magnetic field of a modified Penning discharge has been measured with a retarding potential energy analyzer. These ions escaped through one of the throats of the magnetic mirror geometry. Simultaneous measurements of the ion energy distribution function perpendicular to the magnetic field have been made with a charge-exchange neutral detector. The ion energy distribution functions are approximately Maxwellian, and the parallel and perpendicular kinetic temperatures are equal within experimental error. These results suggest that turbulent processes previously observed in this discharge Maxwellianize the velocity distribution along a radius in velocity space, and result in an isotropic energy distribution.

Roth, J. R.↗
NASA NTRS1991

A self-consistent model for the particles and fields upstream of an outgassing comet. I - Gyrotropic and isotropic ion distributions

The magnetic field and solar wind flow parameters in the vicinity of a weakly outgassing comet are determined using a self-consistent model which treats the cometary ions kinetically. Two different assumptions are made concerning the cometary ion distribution function; the pickup cometary ions from either a velocity space gyrotropic ring distribution or a velocity space isotropic shell distribution in the solar wind frame of reference. The individual currents due to the solar wind and cometary ions, which determine the magnetic field, are calculated in each case. Using theoretically determined parameters which reflect the conditions expected to comet Kopff (a typical short-period comet and one possible target for the future CRAF/Cassini mission) for various heliocentric distances, the way in which global field and flow characteristics are influenced by the nature of the cometary ion distribution function is determined.

Flammer, K. R.↗
DOE OSTI2023

Effect of material properties on batch‐to‐glass conversion kinetics

Abstract A recently developed model of the cold cap—the reacting glass batch (melter feeds) floating on molten glass in an electric glass melter—couples heat transfer with the feed‐to‐glass conversion kinetics. The model allows for determining the distributions of temperature and various properties within the cold cap. In the present study, this model is applied to four melter feeds designed for high‐level and low‐activity nuclear wastes. Profiles of temperature, conversion degree, cold cap porosity and density, condensed matter velocity, and heating rate were determined using the material properties of the cold cap. Effects of vigorous foaming at the cold cap bottom were considered. Density, thermal conductivity, and glass production rate strongly affect the cold cap thickness and the fraction of undissolved silica entering the melt under the cold cap. The heating rate profile in the cold cap is highly nonlinear, with high heating rates observed in the foam layer.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1993

Comparison of hydrodynamic and semi-kinetic treatments for plasma flow along closed field lines

Hydrodynamic and semi-kinetic treatments of plasma flow along closed geomagnetic field lines are compared. The hydrodynamic treatment is based on a simplified 16-moment set of transport equations as the equations for the heat flows are not solved; the heat flows are treated heuristically. The semi-kinetic treatment is based on a particle code. The comparison deals with the distributions of the plasma density, flow velocity, and parallel and perpendicular temperatures as obtained from the two treatments during the various stages of the flow. In the kinetic treatment, the appropriate boundary condition is the prescription of the velocity distribution functions for the particles entering the flux tubes at the ionospheric boundaries; those particles leaving the system are determined by the processes occurring in the flux tube. The prescribed distributions are half-Maxwellian with temperature T(sub 0) and density n(sub 0). In the hydrodynamic model, the prescribed boundary conditions are on density (n(sub 0)), flow velocity (V(sub 0)) and temperature (T(sub 0). It was found that results from the hydrodynamic treatment critically depend on V(sub 0); for early stages of the flow this treatment yields results in good agreement with those from the kinetic treatment, when V(sub 0) = square root of (kT(sub 0)/2 (pi)m), which is the average velocity of particles moving in a given direction for a Maxwellian distribution. During this early stage, the flows developing form the conjugate ionospheres show some distinct transitions. For the first hour or so, the flows are highly supersonic and penetrate deep into the opposite hemispheres, and both hydrodynamics and kinetic treatments yield almost similar features. It is found that during this period heatflow effects are negligibly small. When a flow penetrates deep into the opposite hemisphere, the kinetic treatment predicts reflection and setting up of counterstreaming. In contrast, the hydrodynamic treatment yields a shock in the flow. The reasons for this difference in the two treatments is discussed, showing that in view of the relatively warm ions, the coupling of ion beams and the consequent shock formation in the offequatorial region are not likely due to the enhancements in the beam temperatures. The counterstreaming in the kinetic treatment and the shock in the hydrodynamic treatment first advance upward to the equator and then downward to the ionospheric boundary from where the flow originated. The transit time for this advancement is found to be about 1 hour for the respective models. After 2 hours or so, both models predict that the flows from the ionospheric boundaries are generally subsonic with respect to the local ion-sound speed. At late stages of the flow, when a substantial fraction of ions entering the flux tube begin to return back in the kinetic treatment, the hydrodynamic treatment with the boundary condition V(sub 0) = square root of (kT(sub 0)/2(pi)m) yields an over-refilling, and the choice of V(sub 0) becomes uncertain.

Singh, Nagendra↗
NASA NTRS2006

Development of Comprehensive Reduced Kinetic Models for Supersonic Reacting Shear Layer Simulations

Large-scale simulations of multi-dimensional unsteady turbulent reacting flows with detailed chemistry and transport can be computationally extremely intensive even on distributed computing architectures. With the development of suitable reduced chemical kinetic models, the number of scalar variables to be integrated can be decreased, leading to a significant reduction in the computational time required for the simulation with limited loss of accuracy in the results. A general MATLAB-based automated mechanism reduction procedure is presented to reduce any complex starting mechanism (detailed or skeletal) with minimal human intervention. Based on the application of the quasi steady-state (QSS) approximation for certain chemical species and on the elimination of the fast reaction rates in the mechanism, several comprehensive reduced models, capable of handling different fuels such as C2H4, CH4 and H2, have been developed and thoroughly tested for several combustion problems (ignition, propagation and extinction) and physical conditions (reactant compositions, temperatures, and pressures). A key feature of the present reduction procedure is the explicit solution of the concentrations of the QSS species, needed for the evaluation of the elementary reaction rates. In contrast, previous approaches relied on an implicit solution due to the strong coupling between QSS species, requiring computationally expensive inner iterations. A novel algorithm, based on the definition of a QSS species coupling matrix, is presented to (i) introduce appropriate truncations to the QSS algebraic relations and (ii) identify the optimal sequence for the explicit solution of the concentration of the QSS species. With the automatic generation of the relevant source code, the resulting reduced models can be readily implemented into numerical codes.

Zambon, A. C.↗
NASA NTRS1999

Experiments on Nucleation in Different Flow Regimes

The vast majority of metallic engineering materials are solidified from the liquid phase. Understanding the solidification process is essential to control microstructure, which in turn, determines the properties of materials. The genesis of solidification is nucleation, where the first stable solid forms from the liquid phase. Nucleation kinetics determine the degree of undercooling and phase selection. As such, it is important to understand nucleation phenomena in order to control solidification or glass formation in metals and alloys. Early experiments in nucleation kinetics were accomplished by droplet dispersion methods. Dilatometry was used by Turnbull and others, and more recently differential thermal analysis and differential scanning calorimetry have been used for kinetic studies. These techniques have enjoyed success; however, there are difficulties with these experiments. Since materials are dispersed in a medium, the character of the emulsion/metal interface affects the nucleation behavior. Statistics are derived from the large number of particles observed in a single experiment, but dispersions have a finite size distribution which adds to the uncertainty of the kinetic determinations. Even though temperature can be controlled quite well before the onset of nucleation, the release of the latent heat of fusion during nucleation of particles complicates the assumption of isothermality during these experiments. Containerless processing has enabled another approach to the study of nucleation kinetics. With levitation techniques it is possible to undercool one sample to nucleation repeatedly in a controlled manner, such that the statistics of the nucleation process can be derived from multiple experiments on a single sample. The authors have fully developed the analysis of nucleation experiments on single samples following the suggestions of Skripov. The advantage of these experiments is that the samples are directly observable. The nucleation temperature can be measured by noncontact optical pyrometry, the mass of the sample is known, and post processing analysis can be conducted on the sample. The disadvantages are that temperature measurement must have exceptionally high precision, and it is not possible to isolate specific heterogeneous sites as in droplet dispersions.

Bayuzick, R. J.↗
NASA NTRS1999

Experiments on Nucleation in Different Flow Regimes

The vast majority of metallic engineering materials are solidified from the liquid phase. Understanding the solidification process is essential to control microstructure, which in turn, determines the properties of materials. The genesis of solidification is nucleation, where the first stable solid forms from the liquid phase. Nucleation kinetics determine the degree of undercooling and phase selection. As such, it is important to understand nucleation phenomena in order to control solidification or glass formation in metals and alloys. Early experiments in nucleation kinetics were accomplished by droplet dispersion methods [1-6]. Dilitometry was used by Turnbull and others, and more recently differential thermal analysis and differential scanning calorimetry have been used for kinetic studies. These techniques have enjoyed success; however, there are difficulties with these experiments. Since materials are dispersed in a medium, the character of the emulsion/metal interface affects the nucleation behavior. Statistics are derived from the large number of particles observed in a single experiment, but dispersions have a finite size distribution which adds to the uncertainty of the kinetic determinations. Even though temperature can be controlled quite well before the onset of nucleation, the release of the latent heat of fusion during nucleation of particles complicates the assumption of isothermality during these experiments. Containerless processing has enabled another approach to the study of nucleation kinetics [7]. With levitation techniques it is possible to undercool one sample to nucleation repeatedly in a controlled manner, such that the statistics of the nucleation process can be derived from multiple experiments on a single sample. The authors have fully developed the analysis of nucleation experiments on single samples following the suggestions of Skripov [8]. The advantage of these experiments is that the samples are directly observable. The nucleation temperature can be measured by noncontact optical pyrometry, the mass of the sample is known, and post processing analysis can be conducted on the sample. The disadvantages are that temperature measurement must have exceptionally high precision, and it is not possible to isolate specific heterogeneous sites as in droplet dispersions.

Bayuzick, Robert J.↗
NASA NTRS1998

Experiments on Nucleation in Different Flow Regimes

The vast majority of metallic engineering materials are solidified from the liquid phase. Understanding the solidification process is essential to control microstructure, which in turn, determines the properties of materials. The genesis of solidification is nucleation, where the first stable solid forms from the liquid phase. Nucleation kinetics determine the degree of undercooling and phase selection. As such, it is important to understand nucleation phenomena in order to control solidification or glass formation in metals and alloys. Early experiments in nucleation kinetics were accomplished by droplet dispersion methods. Dilitometry was used by Turnbull and others, and more recently differential thermal analysis and differential scanning calorimetry have been used for kinetic studies. These techniques have enjoyed success; however, there are difficulties with these experiments. Since materials are dispersed in a medium, the character of the emulsion/metal interface affects the nucleation behavior. Statistics are derived from the large number of particles observed in a single experiment, but dispersions have a finite size distribution which adds to the uncertainty of the kinetic determinations. Even though temperature can be controlled quite well before the onset of nucleation, the release of the latent heat of fusion during nucleation of particles complicates the assumption of isothermality during these experiments. Containerless processing has enabled another approach to the study of nucleation kinetics. With levitation techniques it is possible to undercool one sample to nucleation repeatedly in a controlled manner, such that the statistics of the nucleation process can be derived from multiple experiments on a single sample. The authors have fully developed the analysis of nucleation experiments on single samples following the suggestions of Skripov. The advantage of these experiments is that the samples are directly observable. The nucleation temperature can be measured by noncontact optical pyrometry, the mass of the sample is known, and post-processing analysis can be conducted on the sample. The disadvantages are that temperature measurement must have exceptionally high precision, and it is not possible to isolate specific heterogeneous sites as in droplet dispersions. Levitation processing of refractory materials in ultra high vacuum provides an avenue to conduct these kinetic studies on single samples. Two experimental methods have been identified where ultra high vacuum experiments are possible; electrostatic levitation in ground-based experiments and electromagnetic processing in low earth orbit on TEMPUS. Such experiments, reported here, were conducted on zirconium. Liquid zirconium is an excellent solvent and has a high solubility for contaminants contained in the bulk material as well as those contaminants found in the vacuum environment. Oxides, nitrides, and carbides do not exist in the melt, and do not form on the surface of molten zirconium, for the materials and vacuum levels used in this study. Ground-based experiments with electrostatic levitation have shown that the statistical nucleation kinetic experiments are viable and yield results which are consistent with classical nucleation theory. The advantage of low earth orbit experiments is the ability to vary the flow conditions in the liquid prior to nucleation. The put-pose of nucleation experiments in TEMPUS was to examine.

Bayuzick, R. J.↗