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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Observation of Vibrational Relaxation Dynamics in X(sup 3)Sigma(sup -)(sub g) Oxygen Following Stimulated Raman Excitation to the v=1 Level: Implications for the RELIEF Flow Tagging Technique

The vibrational relaxation of ground-state molecular oxygen (O2, X(sup 3)Sigma(sup -)(sub g)) has been observed, following stimulated Raman excitation to the first excited vibrational level (v=1). Time delayed laser-induced fluorescence probing of the ro-vibrational population distribution was used to examine the temporal relaxation behavior. In the presence of water vapor, the relaxation process is rapid, and is dominated by near-resonant vibrational energy exchange between the v=1 level of O2 and the n2 bending mode of H2O. In the absence of H2O, reequilibration proceeds via homogeneous vibrational energy transfer, in which a collision between two v=1 O2 molecules leaves one molecule in the v=2 state and the other in the v=0 state. Subsequent collisions between molecules in v=1 and v>1 result in continued transfer of population up the vibrational ladder. The implications of these results for the RELIEF flow tagging technique are discussed.

Diskin, Glenn S.↗

Universal crossed beam imaging studies of polyatomic reaction dynamics

The marriage between high level quantum calculations and experimental advances in laser technology, quantum state control, and detection techniques have opened the door to the study of molecular collision dynamics at a new level of detail. However, one current challenge lies in adapting these powerful strategies to address questions beyond the scope of the small ground state systems that have largely been the focus of reaction dynamics investigations to-date. For molecules with intermediate or large size (more than 6 atoms), lack of spectroscopic information and spectral congestion limit quantum state preparation, control and detection for experiment, and the large number of degrees of freedom of the system makes accurate quantum dynamics calculations prohibitively expensive. Nevertheless, studies of the chemical dynamics of such systems can reveal novel aspects of reactivity not anticipated based upon the behavior of smaller model systems. This Perspective will highlight applications of soft vacuum ultraviolet photoionization at 157 nm as a universal probe in combination with crossed beams and DC slice velocity map ion imaging to study bimolecular reaction dynamics of molecules of intermediate or large size, illuminated with support of high-level ab initio calculations. In this work, we report on the chemical dynamics of atomic oxygen or chlorine reactions with organic compounds: propanol isomers, alkylamines (N(CH 3 ) 3 and NH(CH 3 ) 2 ), and isobutene ((CH 3 ) 2 CCH 2 ) studied using this approach. The polyatomic radical products from the hydrogen abstraction process have been detected by 157 nm photoionization and their slice ion images embody translational energy and angular information that directly reflect the underlying collision dynamics. Various reaction mechanisms (such as direct abstraction and addition–elimination) along with the involvement of roaming dynamics and novel intersystem crossing pathways are presented. These demonstrate the power of this technique to reveal fundamentally new aspects of reaction dynamics that arise in larger reaction systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cryogenic Laser Calorimetry for Impurity Analysis

The results of a one-year effort to determine the applicability of laser-calorimetric spectroscopy to the study of deep-level impurities in silicon are presented. Critical considerations for impurity analysis by laser-calorimetric spectroscopy are discussed, the design and performance of a cryogenic laser calorimeter is described, and measurements of background absorption in high-purity silicon are presented.

Swimm, R. T.↗

Scientific applications of frequency-stabilized laser technology in space

A synoptic investigation of the uses of frequency-stabilized lasers for scientific applications in space is presented. It begins by summarizing properties of lasers, characterizing their frequency stability, and describing limitations and techniques to achieve certain levels of frequency stability. Limits to precision set by laser frequency stability for various kinds of measurements are investigated and compared with other sources of error. These other sources include photon-counting statistics, scattered laser light, fluctuations in laser power, and intensity distribution across the beam, propagation effects, mechanical and thermal noise, and radiation pressure. Methods are explored to improve the sensitivity of laser-based interferometric and range-rate measurements. Several specific types of science experiments that rely on highly precise measurements made with lasers are analyzed, and anticipated errors and overall performance are discussed. Qualitative descriptions are given of a number of other possible science applications involving frequency-stabilized lasers and related laser technology in space. These applications will warrant more careful analysis as technology develops.

Schumaker, Bonny L.↗

Detection of the clock transition in thulium atoms by using repump laser radiation

A population transfer from the upper level of the clock transition in thulium atoms to the ground level is demonstrated by using radiation with a wavelength of 402 nm. The method for detecting the clock transition excitation that is not affected by technical fluctuations of the number of atoms in an optical lattice is investigated. The hyperfine splitting of the |4f{sup 12}({sup 3}F{sub 2})5d{sub 5/2} 6s{sup 2}; J = 7/2〉 level in the thulium atom is measured to be 1480(9) MHz. The suggested method for population transfer can be applied to both the hyperfine components of the clock transition intended for compensating Zeeman effect in a thulium optical clock. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Prototype Test Results for the Single Photon Detection SLR2000 Satellite Laser Ranging System

NASA's aging Satellite Laser Ranging (SLR) network is scheduled to be replaced over the next few years with a fully automated single photon detection system. A prototype of this new system, called SLR2000, is currently undergoing field trials at the Goddard Space Flight Center in Greenbelt, Maryland to evaluate photon counting techniques and determine system hardware, software, and control algorithm performance levels and limitations. Newly developed diode pumped microchip lasers and quadrant microchannel plate-based photomultiplier tubes have enabled the development of this high repetition rate single photon detection SLR system. The SLR2000 receiver threshold is set at the single photoelectron (pe) level but tracks satellites with an average signal level typically much less than 1 pe. The 2 kHz laser fire rate aids in satellite acquisition and tracking and will enable closed loop tracking by accumulating single photon count statistics in a quadrant detector and using this information to correct for pointing errors. Laser transmitter beamwidths of 10 arcseconds (FWHM) or less are currently being used to maintain an adequate signal level for tracking while the receiver field of view (FOV) has been opened to 40 arcseconds to accommodate point ahead/look behind angular offsets. In the near future, the laser transmitter point ahead will be controlled by a pair of Risley prisms. This will allow the telescope to point behind and enable closure of the receiver FOV to roughly match the transmitter beam divergence. Bandpass filters (BPF) are removed for night tracking operations while 0.2 nm or 1 nm filters are used during daylight operation. Both day and night laser tracking of Low Earth Orbit (LEO) satellites has been achieved with a laser transmitter energy of only 65 microjoules per pulse. Satellite tracking is presently limited to LEO satellites until the brassboard laser transmitter can be upgraded or replaced. Simultaneous tracks have also been observed with NASA s SLR standard, MOBLAS 7, for the purposes of data comparison and identification of biases. Work continues to optimize the receive optics; upgrade or replace the laser transmitter; calibrate the quadrant detector, the point ahead Risley prisms, and event timer verniers; and test normal point generation with SLR2000 data. This paper will report on the satellite tracking results to date, issues yet to be resolved, and future plans for the SLR2000 system.

Zagwodzki, Thomas W.↗

Quantification of Rare Earth Elements in the Parts Per Million Range: A Novel Approach in the Application of Laser-Induced Breakdown Spectroscopy

This work extends a previous percentage level concentration study of the optical emission spectra for six rare earth elements, europium (Eu), gadolinium (Gd), lanthanum (La), praseodymium (Pr), neodymium (Nd), and samarium (Sm), along with the transition metal, yttrium (Y) using laser-induced breakdown spectroscopy (LIBS). The concentration of these six rare earth elements and yttrium has been attempted for the first time systematically down to parts per million (ppm) concentration levels ranging from 30 to 300 ppm. In this study, the authors have developed multivariate models for each element capable of predicting concentration with acceptable to excellent levels of accuracy. Additionally, partial least squares regression coefficients were used to identify key spectral features able to be used in this lower concentration regime. This study has demonstrated that it is conceivable to quantify the six rare earth elements along with yttrium at low concentrations in the parts per million levels.

59 BASIC BIOLOGICAL SCIENCES↗

Misalignment in Gas Foil Journal Bearings: An Experimental Study

As gas foil journal bearings become more prevalent in production machines, such as small gas turbine propulsion systems and microturbines, system-level performance issues must be identified and quantified in order to provide for successful design practices. Several examples of system-level design parameters that are not fully understood in foil bearing systems are thermal management schemes, alignment requirements, balance requirements, thrust load balancing, and others. In order to address some of these deficiencies and begin to develop guidelines, this paper presents a preliminary experimental investigation of the misalignment tolerance of gas foil journal bearing systems. Using a notional gas foil bearing supported rotor and a laser-based shaft alignment system, increasing levels of misalignment are imparted to the bearing supports while monitoring temperature at the bearing edges. The amount of misalignment that induces bearing failure is identified and compared to other conventional bearing types such as cylindrical roller bearings and angular contact ball bearings. Additionally, the dynamic response of the rotor indicates that the gas foil bearing force coefficients may be affected by misalignment.

Howard, Samuel A.↗

State-resolved ultrafast charge and spin dynamics in [Co/Pd] multilayers

We use transient absorption spectroscopy with circularly polarized x rays to detect laser-excited hole states below the Fermi level and compare their dynamics with that of unoccupied states above the Fermi level in ferromagnetic [Co/Pd] multilayers. While below the Fermi level, an instantaneous and significantly stronger demagnetization is observed, above the Fermi level, the demagnetization is delayed by 35 ± 10 fs. This provides a direct visualization of how ultrafast demagnetization proceeds via initial spin-flip scattering of laser-excited holes to the subsequent formation of spin waves.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Flashlamp Driver for Quasi-CW Laser Pumping

Circuit maintains constant high-current level through lamp while lighted and a low simmer current through lamp while not lighted. Lamp current is switched between these two modes by transistor; transistor is therefore called current-mode switch. Stable light pulses are emitted from flashlamp when monostable multivibrator goes high, in part because unsaturated transistor switch has negative feedback control that keeps lamp current constant.

Logan, K. E.↗

Laser Ablation Cleaning of Self-Reacting Friction Stir Weld Seam Surfaces: A Preliminary Evaluation

Anodized aluminum panels were cleaned by three lasers at three separate sites with a view to determining whether more economical laser cleaning might supplant current manual cleaning methods for preparation of surfaces to be welded by the self-reacting friction stir process. Uncleaned panels yielded welds exhibiting residual oxide defect (ROD) and failing at very low stresses along the trace of the weld seam. Manually cleaned panels yielded welds without ROD; these welds failed at nominal stress levels along an angled fracture surface not following the weld seam trace. Laser cleaned panels yielded welds failing at intermediate stress levels. The inadequacy of the laser cleaning processes leaves questions: Was the anodized aluminum test too stringent to represent actual cleaning requirements? Were the wrong laser cleaning techniques/parameters used for the study? Is the laser cleaning mechanism inadequate for effective preweld surface cleaning?

Nunes, A. C., Jr.↗

Comparing plasma conditions in short-pulse-heated foils via fine-structure x-ray emission

Fine-structure x-ray spectra have been measured from foils with embedded tracer layers at two laser facilities. In this work, a suite of layered foils with thin Ti tracers under varied tamper layers was studied at both the Titan and the ALEPH 400 nm laser facilities, where Ti Heα emission was recorded using a high-resolution Bragg crystal spectrometer. Several indicators of plasma parameters are examined in the spectra, including temperature- and density-dependent line ratios and line broadening from Stark and opacity effects. Spectra indicate that (1) the plasma density at ALEPH is significantly higher than at Titan and (2) the electron temperature is high for near-surface layers at both facilities but drops more quickly with depth at ALEPH. These inferences of plasma conditions are consistent with differing levels of temporal contrast at each laser facility.

47 OTHER INSTRUMENTATION↗

Simultaneous Convective and Radiative Heating of Materials with the 200 kW Laser Enhanced Arc Jet Facility (LEAF)

Recent installation of the 200-kW Laser Enhanced Arc Jet Facility (LEAF) at the Interaction Heating Facility (IHF) arc jet at NASA Ames Research Center has enabled combined heating of material samples. The LEAF system is permanently located adjacent to IHF. During LEAF operation, IHF can convectively heat material samples with heat fluxes up to 0.16 kW/cm 2 using the 22.86-cm nozzle or up to 0.07 kW/cm 2 using the truncated semi-elliptic nozzle. LEAF can deliver radiant heating with various profiles and sizes to a material sample. In flat-top square configuration, irradiance levels of nearly 0.1 kW/cm 2 have been demonstrated over a 43.2 x 43.2 cm area, and irradiance levels up to 0.39 kW/cm 2 have been demonstrated over a 15.2 x 15.2 cm area. LEAF can also be configured to deliver a super-Gaussian profile over a variety of beam diameters (1.8 to 5.6 cm). This configuration has been demonstrated up to peak irradiance levels of 25.7 kW/cm 2 per laser at the smallest, 1.8 cm, diameter setting. The LEAF system is composed of four 50-kW lasers, so it can also be configured to simultaneously deliver two different beam shapes (e.g., one square beam and one super-Gaussian beam).

Megan MacDonald↗

Using Laser Altimetry to Detect Topographic Change in Long Valley Caldera, California

Long Valley caldera California, is a site of extensive volcanism, persistent seismicity, and uplift of a resurgent dome, currently at a rate of about 3 cm/year. Airborne laser altimetry was used to determine the surface topography of the region in 1993. A repeat mission occurred in 1995. Three different laser altimeters were flown, dubbed ATLAS, SLICER and RASCAL. Data processing consists of the combination of the aircraft trajectory and attitude data with the laser range, the determination of an atmospheric delay, laser pulse timing errors, laser system biases, and data geolocation to obtain the position of the laser spot on the ground. Results showed that using the ATLAS and SLICER instruments, the elevation of an overflown lake is determined to precisions of 3.3 cm and 2.9 cm from altitudes of 500 m and 3 km above the ground, and about 10 cm using the RASCAL instrument from 500 m above ground. Comparison with tide gauge data showed the laser measurements are able to resolve centimeter-level changes in the lake elevation over time. Repeat pass analysis of tracks over flat surfaces indicate no systematic biases affect the measurement procedure of the ATLAS and SLICER instruments. Comparison of GPS and laser-derived elevations of easily-identifiable features in the caldera confirm the horizontal accuracy of the measurement is within the diameter of the laser footprint, and vertical accuracy is within the error inherent in the measurement. Crossover analysis shows that the standard error of the means at track intersection points within the caldera, and dome (i.e., where zero and close to the maximum amount of uplift is expected) are about I cm, indicating elevation change at the 3 cm/year level should be detectable. We demonstrate one of the powerful advantages of scanning laser altimetry over other remote sensing techniques; the straightforward creation of precise digital elevation maps of overflown terrain. Initial comparison of the 1993-1995 data indicates uplift occurred, but filtering is required to remove vegetation effects. Although research continues to utilize the full potential of laser altimetry data, the results constitute a successful demonstration that the technique may be used to perform geodetic monitoring of surface topographic change.

Hofton, M. A.↗

Using Laser Altimetry to Detect Topographic Change at Long Valley Caldera, California

Long Valley caldera, California, is a site of extensive volcanism, persistent seismicity, and uplift of a resurgent dome, currently at a rate of approximately 3 cm/year. Airborne laser altimetry was used to determine the surface topography of the region in 1993. A repeat mission occurred in 1995. Three different laser altimeters were flown, dubbed ATLAS, SLICER and RASCAL. Data processing consists of the combination of the aircraft trajectory and attitude data with the laser range, the determination of an atmospheric delay, laser pulse timing errors, laser system biases, and data geolocation to obtain the position of the laser spot on the ground. Results showed that using the ATLAS and SLICER instruments, the elevation of an overflown lake is determined to precisions of 3.3 cm and 2.9 cm from altitudes of 500 m and 3 km above the ground, and approximately 10 cm using the RASCAL instrument from 500 m above ground. Comparison with tide gauge data showed the laser measurements are able to resolve centimeter-level changes in the lake elevation over time. Repeat pass analysis of tracks over flat surfaces indicate no systematic biases affect the measurement procedure of the ATLAS and SLICER instruments. Comparison of GPS and laser-derived elevations of easily-identifiable features in the caldera confirm the horizontal accuracy of the measurement is within the diameter of the laser footprint, and vertical accuracy is within the error inherent in the measurement. Crossover analysis shows that the standard error of the means at track intersection points within the caldera and dome (i.e., where zero and close to the maximum amount of uplift is expected) are about 1 cm, indicating elevation change at the 3 cm/year level should be detectable. We demonstrate one of the powerful advantages of scanning laser altimetry over other remote sensing techniques; the straightforward creation of precise digital elevation maps of overflown terrain. Initial comparison of the 1993-1995 data indicates uplift occurred, but filtering is required to remove vegetation effects. Although research continues to utilize the full potential of laser altimetry data, the results constitute a successful demonstration that the technique may be used to perform geodetic monitoring of surface topographic change.

Hofton, M. A.↗

Determination of station coordinates from Lageos

Laser tracking of Lageos by the NASA and SAO laser tracking systems from its launch in May 1976 until December 1976 has been used to derive the coordinates of the tracking stations. The NASA tracking data from four systems in the United States had a precision of 10 to 15 cm and the SAO stations in North America, South America and Australia had precisions between 0.8 meters and 1.3 meters. Nearly 90,000 observations of Lageos were used in this analysis. Thirty-one orbital arcs, each five days in length, were derived which had orbital fits of 25 cm for the NASA data and at about 1 meter level for the SAO data. The coordinates of all eight stations were derived from this data set and the preliminary estimate of the overall accuracy of 50 cm in each coordinate. These results are in general agreement at about the 30 cm level with other results obtained from laser tracking of Beacon Explorer C.

Smith, D. E.↗

Laser action in far-infrared astrophysical sources

Employing new atomic data and a 15 level collisional-radiative model, it is shown that population inversion, and consequent laser action, can be achieved in far-infrared (FIR) lines (C II) 157 micrometer, (N III) 58 micrometer, (O IV) 26 micrometer, (Ne VI) 7.6 micrometer, and (Mg VIII) 3 micrometer. Coupling of the lasting transition 2s(sup 2)2p((sup 2)P(sup o sub 3/2)-(sup 2)P(sup o sub 1/2)) to higher energy levels of the 2s2p(sup 2) configuration in boron-like ions provides the dominant pumping flux. Lasing column lengths are found to be l approximately equal 10(exp -4)-1.0 pcs, at T(sub e) approximately equal 10(exp 4)-10(exp 6) K, N(sub e) approximately equal 10(exp 4)-10(exp 10)/cu cm, conditions and sizes prevalent in broad-line regions of active-galactic nuclei and novae. Detectable emission fluxes are estimated. Lasing activity in the source could significantly affect abundance determinations. The FIR line emission should be readily observable with the upcoming Infrared Space Observatory.

Peng, Jianfang↗

Linewidth narrowing in self-injection locked lasers: Effects of quantum confinement

This paper explores the impact of gain medium on linewidth narrowing in integrated self-injection locked III–V/SiN lasers, theoretically and experimentally. We focus on the effects of carrier densities of states in zero- and two-dimensional structures due to quantum-dot and quantum-well confinement. The theoretical approach includes (a) multimode laser interaction to treat mode competition and wave mixing, (b) quantum-optical contributions from spontaneous emission, and (c) composite laser/free-space eigenmodes to describe outcoupling and coupling among components within an extended cavity. For single-cavity lasers, such as distributed feedback lasers, the model reproduces the experimentally observed better linewidth performance of quantum-dot active regions over quantum-well ones. When applied to integrated III–V/SiN lasers, our analysis indicates Hz-level linewidth performance for both quantum-dot and quantum-well gain media due to overcoming the difference in carrier-induced refractive index by incorporating a high-Q SiN passive resonator. Trade-offs are also explored between linewidth, output power, and threshold current.

Cavity quantum electrodynamics↗