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At least 343 records · Page 19

Optical phase distortion due to compressible flow over laser turrets

Analytical models for optical phase distortion due to compressible flow over a laser turret are developed. Phase distortion is calculated for both blunt and small perturbation turrets. For the blunt turret, the Janzen-Rayleigh technique is used to determine the flow field. Phase distortions of 2.2 wavelengths at 3.8 microns are calculated for the blunt turret. For small perturbation turrets, a versatile analytical model is developed for a turret on a fuselage with circular cross section. With a two dimensional Fourier series representation of the turret, any shape can be considered. Both subsonic and supersonic flows can be calculated. Phase distortions of 1.2 wavelengths at 3.8 microns are calculated for one turret at high subsonic Mach number. In addition to being of value for laser turrets, the methods are applicable to reconnaissance aircraft using photographic equipment and cruise missiles using celestial navigation.

Fuhs, A. E.↗

Measuring molecular flows with high-resolution stimulated Raman spectroscopy

It is proposed to use high-resolution stimulated Raman spectroscopy to directly measure high-speed molecular flow velocities in wind tunnels and in combustive chambers. A feasibility study indicates that flow speeds from Mach 0.04 up may be measured with the proposed method using available laser systems. It is pointed out that the success of the proposed technique will make it possible to measure all interesting flow parameters, i.e., species concentration, temperature, and velocity, in a time of less than 1 microsecond at a repetition rate of 10,000/s using a single experimental arrangement.

She, C. Y.↗

Modeling of photodegradation in solar cell modules of substrate and superstrate design made with ethylene-vinyl acetate as pottant material

The rates of hydrogen abstraction by peroxy radicals were proven to be too slow for significant oxidation of the alkane substrate to be important. The numerical procedure, independent of our particular data base was verified by reproducing concentration time profiles for a model reaction set describing the cesium flare system in the upper atmosphere. Simulation was identical to that given in the literature. Experimental verification of the data base is to be attempted by weatherometry studies in the coming year. Work on the new diagnostic techniques was completed. The adapted automated viscometer was demonstrated to be an efficient and reliable tool for routine measurements of viscosity (molecular weight) changes in solid samples after batch solutions have been made up. The laser photolysis GC method for monitoring extremely low levels of oxidation in polymers proved to be impractical because the yields of carbon monoxide were too low for quantification. Much progress was made with the computer model. The reaction matrix was completely revised, resulting in a new scheme of 31 reactions and time, lifetimes in excess of ten years. The results to date lead us to some tentative observations.

Somersall, A. C.↗

Gravito-inertial sensitivity of the spider - Araneus sericatus

The gravito-inertial transfer function of the orb-weaving spider was evaluated by changes in the cardiac reflex. A non-intrusive method, using a laser system recorded the cardiac pulse. Between 1.001 and 1.5 Gz the data are 'best-fit' by a log function (r-squared 0.92). The response of the neurogenic heart is seen to be a good dependent variable for invetebrate research. The arachnid lyriform organ has those qualities which complement the obtained gravity function. It is hypothesized that the cardiac pump maintains the spiders equilibrium in the gravito-inertial field.

Finck, A.↗

Supersonic-nitrogen flow-field measurements with the resonant Doppler velocimeter

The application of the resonant Doppler velocimeter (RDV) for obtaining the mean velocity, temperature, and pressure measurements and flow-field visualization in a supersonic free nitrogen jet is reported. This method utilizes laser-induced fluorescence to determine the spectral absorption of an atomic or molecular species seeded into the flow. A narrow linewidth tunable laser is directed into the flow and the total fluorescence from any point is obtained as the laser is tuned. The velocity of the flow is obtained from the Doppler shifted absorption frequency, and the temperature and pressure of the gas are determined from line broadening measurements. Results are presented for the use of this technique to determine the velocity, temperature, and pressure of the flow of sodium atoms seeded into a supersonic nitrogen jet. It is concluded that the visible signal is sufficiently intense for spatially resolved flow visualization purposes.

Cheng, S.↗

Elemental composition of arctic particulate matter

Measurements were made of the elemental composition of particulate matter collected in flights in the Arctic in spring 1983 as part of the Arctic Gas and Aerosol Sampling Program (AGASP). Ten samples of size-selected particles were analyzed by four nondestructive techniques at Davis. Concentrations were determined for H, C, N, and O by Forward Alpha Scattering Techniques (FAST) and for elements heavier than fluorine by Particle Induced X-ray Emission (PIXE). Total mass was measured gravimetrically, and optical absorption was measured using the Laser Integrating Plate Method (LIPM). Results of the analyses show dramatic differences in concentrations and elemental ratios from the Alaskan Arctic to the Norwegian Arctic, with indications of wood smoke and sulfuric acid in the arctic atmosphere.

Cahill, T. A.↗

Rate constant for the OH + CO reaction - Pressure dependence and the effect of oxygen

The effect of pressure on the rate constant of the OH + CO reaction has been measured for Ar, N2, and SF6 over the pressure range 200-730 torr. All experiments were at room temperature. The method involved laser-induced fluorescence to measure steady-state OH concentrations in the 184.9 nm photolysis of H2O-CO mixtures in the three carrier gases, combined with supplementary measurements of the CO depletion in these same carrier gases in the presence and absence of competing reference reactants. The effect of O2 on the pressure effect was determined. A pressure enhancement of the rate constant was observed for N2 and SF6, but not for Ar, within an experimental error of about 10 percent. The pressure effect for N2 was somewhat lower than previous literature reports, being about 40 percent at 730 torr. For SF6 a factor of two enhancement was seen at 730 torr. In each case it was found that O2 had no effect on the pressure enhancement. The roles of the radical species HCO and HOCO were evaluated.

Demore, W. B.↗

An intercomparison of carbon monoxide measurement techniques

Results from an intercomparison of techniques to measure tropospheric levels of carbon monoxide (CO) are discussed. The intercomparison was conducted as part of the National Aeronautics and Space Administration's Global Tropospheric Experiment (GTE) and was held at Wallops Island, VA, in July 1983. Instruments intercompared included a laser differential absorption method and three grab sample/gas chromatograph methods. The intercomparison consisted of simultaneous measurements of ambient levels of CO and controlled injections of CO from a common manifold. Results from the techniques exhibited a high degree of correlation among themselves and with changes in the CO mixing ratio. The results suggested a level of agreement among the techniques of about 15 percent. However, a day-to-day bias between the techniques was observed, which resulted in differences between techniques as large as 38 percent.

Hoell, J. M., Jr.↗

Rotational inelastic cross sections for OCS-Ar, OCS-He, OCS-H2 collisions - A comparison between theory and experiment

The experimental determination of absorption line profiles for OCS nu3 vibrational transitions broadened by collisions with Ar, He, and H3 buffer gases is reported. The experimental method using diode laser spectroscopy in the five micron region is described. The data are compared with theoretical values obtained using intermolecular potentials previously suggested for these systems and infinite order sudden approximation molecular scattering calculations.

Broquier, M.↗

The role of photographic parameters in laser speckle or particle image displacement velocimetry

The parameters involved in obtaining the multiple exposure photographs in the laser speckle velocimetry method (to record the light scattering by the seeding particles) were optimized. The effects of the type, concentration, and dimensions of the tracer, the exposure conditions (time between exposures, exposure time, and number of exposures), and the sensitivity and resolution of the film on the quality of the final results were investigated, photographing an experimental flow behind an impulsively started circular cylinder. The velocity data were acquired by digital processing of Young's fringes, produced by point-by-point scanning of a photographic negative. Using the optimal photographing conditions, the errors involved in the estimation of the fringe angle and spacing were of the order of 1 percent for the spacing and +/1 deg for the fringe orientation. The resulting accuracy in the velocity was of the order of 2-3 percent of the maximum velocity in the field.

Lourenco, L.↗

Airborne intercomparisons of carbon monoxide measurement techniques

Results from an airborne intercomparison of techniques to measure tropospheric levels of carbon monoxide (CO) are discussed. The intercomparison was conducted as part of the National Aeronautics and Space Administration's Global Tropospheric Experiment and included a laser differential absorption method and two grab sample/gas chromatograph methods. Measurements were obtained during approximately 90 flight hours, during which the CO mixing ratios ranged from about 60 to 140 ppbv. The level of agreement observed for the ensemble of measurements was well within the overall accuracy stated for each instrument. The correlation observed between the measurements from the respective pairs of instruments ranged from 0.85 to 0.98, with no evidence for the presence of either a constant or proportional bias between any of the instruments.

Hoell, James M., Jr.↗

Response function of a tunable diode laser spectrometer from an iterative deconvolution procedure

A deconvolution procedure commonly used for resolution enhancement of spectra has been applied to the determination of the response function of a tunable diode laser spectrometer. The method is sufficiently fast and simple for routine application when correcting for nonnegligible instrumental broadening. Absolute linestrengths of CH4 in the 1327/cm region and line positions of HNO3 in the 1335/cm region, measured with the aid of the deconvolution technique, are reported here.

May, Randy D.↗

Fluorescence spectroscopy and thermometry for hypersonic flight research

The present study, which has demonstrated the feasibility of using time-resolved laser-induced fluorescence methods to ascertain boundary layer temperature distributions in real time for hypersonic vehicles in atmospheric flight, employs conventional optics in combination with novel time-resolved spectroscopy. The radiative lifetime and signal intensity involved, both of which are reduced by quenching, are adequate for measurement with state-of-the-art time-resolved fluorescence techniques, except for certain conditions associated with both the highest speeds and the lowest altitudes.

Thompson, B. E.↗

Chemical analyses of provided samples

Two batches of samples were received and chemical analysis was performed of the surface and near surface regions of the samples by the surface analysis by laser ionization (SALI) method. The samples included four one-inch optics and several paint samples. The analyses emphasized surface contamination or modification. In these studies, pulsed sputtering by 7 keV Ar+ and primarily single-photon ionization (SPI) by coherent 118 nm radiation (at approximately 5 x 10(exp 5) W/cm(sup 2) were used. For two of the samples, also multiphoton ionization (MPI) at 266 nm (approximately 5 x 10(exp 11) W/cm(sup 2) was used. Most notable among the results was the silicone contamination on Mg2 mirror 28-92, and that the Long Duration Exposure Facility (LDEF) paint sample had been enriched in K and Na and depleted in Zn, Si, B, and organic compounds relative to the control paint.

Becker, Christopher H.↗

Laser/Spectroscopic Determination Of Mass Flows

Mass flow rates of air and other gases computed from absorption-spectroscopic measurements of light generated by tunable diode lasers. Rates of flow measured nonintrusively. Method implemented with rugged, compact, economical lasers and optical fibers to guide laser light to and from measurement locations.

Hanson, R. K.↗

Characterization of polymer decomposition products by laser desorption mass spectrometry

Laser desorption mass spectrometry has been used to characterize the ash-like substances formed on the surfaces of polymer matrix composites (PMC's) during exposure on LDEF. In an effort to minimize fragmentation, material was removed from the sample surfaces by laser desorption and desorbed neutrals were ionized by electron impact. Ions were detected in a time-of-flight mass analyzer which allows the entire mass spectrum to be collected for each laser shot. The method is ideal for these studies because only a small amount of ash is available for analysis. Three sets of samples were studied including C/polysulfone, C/polyimide and C/phenolic. Each set contains leading and trailing edge LDEF samples and their respective controls. In each case, the mass spectrum of the ash shows a number of high mass peaks which can be assigned to fragments of the associated polymer. These high mass peaks are not observed in the spectra of the control samples. In general, the results indicate that the ash is formed from decomposition of the polymer matrix.

Pallix, Joan B.↗

Anticipated uncertainty budgets of PRARETIME and T2L2 techniques as applied to ExTRAS

The Experiment on Timing Ranging and Atmospheric Soundings, ExTRAS, was conceived jointly by the European Space Agency, ESA, and the Russian Space Agency, RSA. It is also designated the 'Hydrogen-maser in Space/Meteor-3M project'. The launch of the satellite is scheduled for early 1997. The package, to be flown on board a Russian meteorological satellite includes ultra-stable frequency and time sources, namely two active and auto-tuned hydrogen masers. Communication between the on-board hydrogen masers and the ground station clocks is effected by means of a microwave link using the modified version for time transfer of the Precise Range And Range-rate Equipment, PRARETIME, technique, and an optical link which uses the Time Transfer by Laser Link, T2L2, method. Both the PRARETIME and T2L2 techniques operate in a two-directional mode, which makes it possible to carry out accurate transmissions without precise knowledge of the satellite and station positions. Due to the exceptional quality of the on-board clocks and to the high performance of the communication techniques with the satellite, satellite clock monitoring and ground clocks synchronization are anticipated to be performed with uncertainties below 0.5 ns (1 sigma). Uncertainty budgets and related comments are presented.

Thomas, Claudine↗

Experimental Space Weathering of Ordinary Chondrites by Nanopulse Laser: TEM Results

A set of ordinary chondrite meteorites has been subjected to artificial space weathering by nanopulse laser to simulate the effects of micrometeorite bombardment. Three meteorites, an H (Ehole), L (Chateau Renard - CR), and LL (Appley Bridge - AB) were lasered following the method of Sasaki et al [1]. Near IR spectra were taken before and after exposure to examine the optical changes induced and the samples were examined by scanning and transmission electron microscopy (SEM and TEM) to understand the physical changes.

Noble, S. K.↗