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At least 343 records · Page 19

Assessment of Cold Spray Technology for Nuclear Power Applications

This report provides an overview of cold spray (CS) technology as it relates to repair and fabrication of metal alloys in the nuclear power industry. CS is a relatively new technology with applications established in other industries (e.g., aerospace, defense), and greater use of CS is anticipated within the nuclear power industry. This report is prepared in support of the United States Nuclear Regulatory Commission (NRC) Action Plan for Advanced Manufacturing Technologies (AMTs) Rev. 1, which includes objectives to identify the AMTs most likely to be used for nuclear power applications that require NRC approval, and to prepare NRC staff to review regulatory submittals containing components manufacturing using AMTs. In addition to providing an overview of CS technology, this report highlights engineering and scientific knowledge gaps of CS and rates the size of the knowledge gaps. It also assesses importance rankings of the knowledge gaps as they relate to several application categories. The application categories considered in this exercise include factory-applied CS for chloride induced stress corrosion cracking (CISCC) mitigation, field CISCC repair, light water reactor (LWR) factory structural fabrication, and LWR field dimensional restoration and corrosion protection. The combination of a knowledge gap size rating and importance ranking for an application can be used to prioritize additional data or information gathering efforts.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Offshore Wind Market Report: 2023 Edition

The Offshore Wind Market Report: 2023 Edition provides detailed information on the U.S. and global offshore wind energy industries to inform policymakers, researchers, and analysts about technology, economic, and market trends. The scope of the report covers the status of over 293 global operating offshore wind energy projects as well as the broader global pipeline of projects in various stages of development through December 31, 2022. To provide up-to-date information and discussion on this emerging industry in the United States, this report tracks the significant U.S. domestic industry progress and events from January 1, 2022, through May 31, 2023. The U.S. offshore wind energy project development pipeline has reached a potential generating capacity of over 52 gigawatts, and the industry has seen strong support from state and federal governments (such as from the Inflation Reduction Act of 2022 and the announced Floating Offshore Wind Shot to reduce the cost of floating wind by 70%). There are contracts for over 17 gigawatts of the electricity from these offshore wind projects and state policies are in place to procure over 42 gigawatts by 2040. Although some projects are facing economic headwinds due to rising costs and higher interest rates (corresponding to project cost increases of 11% - 30% in 2022), there has still been significant investment in a domestic supply chain (including manufacturing facilities, new vessels, and upgraded or planned ports). Technologies continue to evolve as offshore wind turbines in the 15-megawatt class advance towards commercial production. Key offshore wind energy market indicators, such as commercial leasing, state energy planning targets, procurement policies, offtake agreements, and federal support for U.S. jobs and supply chain development, point toward sustained market growth when viewed together, but the macroeconomic hurdles facing the first generation of commercial projects could significantly stunt that growth.

17 WIND ENERGY↗

Meteodrone data

The University of Nebraska-Lincoln (UNL) Meteodrone (model SSE MM-641) is a small (1.1 kg GTOW, ~40 cm across) hexcopter UAS manufactured by Meteomatics. Maximum endurance is approximately 30 min and estimated maximum operating altitude of 1500 m. Profiles can be executed at ascent/descent rates up to 10 m/s. The Meteodrone is capable of measuring temperature, relative humidity, wind velocity and GPS position time-stamped with GPS time. Temperature and dual relative humidity sensors are shielded from solar exposure by a housing with a vertically oriented air intake and hoirizontal exhaust. Sensor aspiration is driven by rotorwash across the horizontal exhaust. In its current configuration data are recorded only when executing vertical profiles. Attitude and position are updated at a data rate of 20 Hz while meteorological observations are updated at 10 Hz.

54 ENVIRONMENTAL SCIENCES↗

Influence of Coating Method on the Performance of Roll-to-Roll Coated PEM Fuel Cell Catalyst Layers

As production of fuel cell vehicles and power systems increases there is a need to understand the process science of fuel cell manufacturing. Industrial production of polymer electrolyte membrane fuel cell (PEMFC) electrodes will rely on continuous roll-to-roll (R2R) coating methods to meet the rates needed for mass production. There are a variety of coating methods that could be used to coat catalyst layers. The different physics of each method may result in different morphologies and performance. Here we present the results of a study comparing fuel cell catalyst layers coated using two R2R coating methods: slot-die and gravure. These two methods were selected because the physics of applying the liquid to the substrate is very different between the two cases. Pt/C catalysts layers were coated directly onto carbon-fiber gas diffusion media to create gas diffusion electrodes (GDEs), without the use of a decal transfer process. These GDEs were assembled into membrane electrode assemblies (MEAs) by hot pressing to Nafion membranes. In situ performance and other electrochemical diagnostics were used to determine the influence of coating method on catalyst layer electrochemical properties. Electron microscopy was utilized to understand the influence of coating method on electrode morphology and its influence on electrochemical properties. We also explored the influence of solvent ratio to understand the potential coupling between ink formulation and coating methodology.

DIRECT ENERGY CONVERSION,MATERIALS SCIENCE↗

Manufacturing Supply Chain Development for Modular Solar-Thermochemical Conversion Platform [Abstract]

We will develop a tunable pulsed electron source capable of generating variable intensity highly-focused electron pulses at high repetition rates. Specifically, we need to demonstrate a high-speed variable electron gun capable of generating a variable intensity electron pulse containing between 102 and 105 electrons with an accelerating voltage of 1kV focused into a spot size <100nm in diameter at with a pulse rate >10MHz (with path to 300MHz). This combined performance cannot be achieved by commercially available electron sources. The primary technology path selected for this work will be to use a photocathode approach, where an easily modulated UV laser is used to stimulate electron emission. The approach utilizes the advances made in the development of the Dynamic TEM (DTEM), though this project will be simpler in that the pulse intensity is lower and there is no requirement for coherency. Alternate paths, including using a traditional electron beam modulated using a v-shaped slit and electrostatically deflecting the beam to adjust intensity; will also be considered for future capabilities. The electron source will then be used generate optically stimulated luminescence (OSL) in lithium fluoride (LiF) substrates to demonstrate the potential for OSL to serve as a basis technology for next generation data storage systems.

42 ENGINEERING↗

Predicting and Controlling Corrosion (Abbreviated Final Report)

Corrosion accumulates significant replacement costs in the transportation, utility, manufacturing, and infrastructure sectors. It also underpins several of LLNL’s core missions in stockpile stewardship, defense, and energy security. Whereas most corrosion and aging models are empirically parameterized to describe well-defined conditions late in the reaction, the factors that determine the early stages of corrosion—during which mitigation could be most impactful— are poorly understood. This project addressed the critical need for new approaches to predict the kinetics of corrosion initiation based on firm physical and chemical understanding. The activities encompassed degradation of relevant metals in both hydrogen-rich and environmental corrosion scenarios. The team integrated state-of-the-art multiscale simulation, in situ characterization, and data science within three technical thrusts: hydriding of Ti alloys; aqueous corrosion of Al and Ni-Cr alloys; and degradation of additively manufactured 316L stainless steel. In each case, novel capabilities were developed to identify and track the impacts of key atomistic, compositional, and microstructural features on the metal systems. For hydriding, protocols were developed to tightly integrate multiscale models, advanced multimodal characterization, and machine learning to determine how hydrogen interacts with native passivating surface oxides and nucleates new undesired phases, shedding new light on the critical role of grain boundaries, interfaces, and atomically disordered regions. For aqueous corrosion, the project demonstrated methods to predict dissolution rates of metal surfaces in corrosive solutions, to measure and understand microstructural and grain orientation effects on corrosion susceptibility, and to investigate competing growth and dissolution kinetics of surface oxides. For additively manufactured metals, analysis using state-of-the-art microscopy techniques revealed the role of specific heterogeneities invoked during laser processing, including cellular structure, dislocations, and precipitates, on corrosion susceptibility. In addition to new capabilities and understanding, the project provided an avenue for workforce development, as well as key partnerships with stakeholders in corrosion science.

08 HYDROGEN↗

Infusible thermoplastic resin based sandwich structures for wind blade applications and the influence of scrim on facesheet to core interface debonding

Infusible thermoplastic Elium® family of resins from Arkema have garnered much attention in recent years as a possible replacement for thermoset resins in laminate and sandwich composite manufacturing for wind blade applications due to its ease of recyclability and the ability to utilize existing manufacturing processes without imposing complicated variations. However, physical and mechanical properties of the proposed Elium® based thermoplastic composites must be comparable to existing epoxy (thermoset) based composites using manufacturing processes relevant for large wind turbine blades. A 13-meter-long demonstration blade was manufactured for that purpose and sandwich samples were obtained from that project for a detailed study. This paper details three-point flexural properties of unidirectional E-glass fiber reinforced acrylic and epoxy based sandwich panels with identical balsa wood core materials. In addition, to evaluate the relative merit considering debond failure mode, the interfacial critical strain energy release rate, predominantly in mode-1, was compared via single cantilever beam testing. In sandwich composites constructed with balsa wood core material, resin uptake by the balsa core is traditionally impeded via the insertion of a scrim material at the facesheet to core interface. Results revealed that inclusion of scrim mesh layer at the facesheet to core interface reduced flexural properties and strain energy release rates in panels infused with acrylic resin but did not significantly reduce these properties in epoxy infused facesheets.

Engineering↗

Additive Manufacture of Multi-Functional, Large-Scale Components

The poster summarizes the main results for a LDRD focused on developing a arc-based additive manufacturing (AM) system capable of fabricating large components with a composition gradient otherwise known as functionally graded materials (FGMs). FGMs are capable of addressing local extreme conditions in an optimal and cost-effective manner. The AM system (referred to as multi-Wire Arc Additive Manufacturing or m-WAAM) consisted of modifying a standard automated gas tungsten arc welding system to deliver multiple welding wires to the weld pool at controlled rates to deposit desired alloy compositions at critical locations. Numerous shapes and composition gradients were fabricated with the system and the effect of various deposition parameters on the nature of the composition profile were evaluated. Additionally, heat treatment of the FGM was performed to develop graded microstructures which should enhance dynamic impact performance of inexpensive steels. The project highlights the potential of m-WAAM to efficiently fabricate FGMs. However, this project only explored the science behind the technique and additional development work will be required to develop a fully-functional system that can build more complex components.

36 MATERIALS SCIENCE↗

Predicting industrial building energy consumption with statistical and machine-learning models informed by physical system parameters

The industrial sector consumes about one-third of global energy, making them a frequent target for energy use reduction. Variation in energy usage is observed with weather conditions, as space conditioning needs to change seasonally, and with production, energy-using equipment is directly tied to production rate. Previous models were based on engineering analyses of equipment and relied on site-specific details. Others consisted of single-variable regressors that did not capture all contributions to energy consumption. Further, new modeling techniques could be applied to rectify these weaknesses. Applying data from 45 different manufacturing plants obtained from industrial energy audits, a supervised machine-learning model is developed to create a general predictor for industrial building energy consumption. The model uses features of air enthalpy, solar radiation, and wind speed to predict weather-dependency; motor, steam, and compressed air system parameters to capture support equipment contributions; and operating schedule, production rate, number of employees, and floor area to determine production-dependency. Results showed that a model that used a linear regressor over a transformed feature space could outperform a support vector machine and utilize features more representative of physical systems. Using informed parameters to build a reliable predictor will more accurately characterize a manufacturing facility's energy savings opportunities.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Modeling batch melting: Roles of heat transfer and reaction kinetics

Development of mathematical models of heat and mass transfer in glass-melting furnaces began in the 1970s and progressed rapidly with advances in sophisticated experimental/numerical techniques and increasing computational power. Today, practically all newly built or rebuilt furnaces are optimized with these models to meet stringent quality requirements, reduce the unit costs of manufacturing, or control emissions. One remaining hurdle is to model the batch-to-glass conversion accurately enough to reliably assess the glass production rate. This article summarizes two key aspects of the batch-conversion modeling—the heat transfer and the kinetics of conversion—and reviews the current state-of-the-art approaches to simulating them. We critically examine the advantages of the commonly used heat transfer approach, but also explain that its predictive capabilities are significantly restricted by the dependence of batch thermal properties on the time-temperature history. We argue that kinetic approaches to the batch-conversion modeling would offer a significant improvement when coupled with the heat transfer approach. Finally, we summarize key areas requiring further research on the way toward a realistic model of the batch blanket.

Pokorny, Richard↗

Stress-strain and work hardening relationships of 304L AM alloy

A new approach to analytically derive constitutive stress-strain relationships from modeling the work hardening behavior of alloys was developed for assessing the strength and ductility of the Ti-6Al-4V alloy. This new approach is now successfully applied for assessing the quasi-static stress-strain behavior of an additively manufactured 304L sample. A predictive capability of this modelling approach may then be extended to model material stress-strain behavior at higher strain rates of loading.

36 MATERIALS SCIENCE↗

A Software/Hardware Framework for Efficient and Safe Emergency Response in Post-Crash Scenarios of Battery Electric Vehicles

The adoption rate of battery electric vehicles (EVs) is rapidly increasing. Electric vehicles differ significantly from conventional internal combustion engine vehicles and vary widely across different manufacturers. Emergency responders (ERs) and recovery personnel may have less experience with EVs and lack timely access to critical information such as the extent of the stranded energy present, high-voltage safety hazards, and post-crash handling procedures in a user-friendly manner. This paper presents a software/hardware interactive tool named Electric Vehicle Information for Incident Response Solutions (EVIRS) to aid in the quick access to emergency response and recovery information. The current prototype of EVIRS identifies EVs using the VIN or Make, Model, and Year, and offers several useful features for ERs and recovery personnel. These features include integration and easy access to emergency response procedures tailored to an identified EV, vehicle structural schematics, the quick identification of battery pack specifications, and more. For EVs that are not severely damaged, EVIRS can perform calculations to estimate stranded energy in the EV’s battery and discharge time for various power loads using either EV dashboard information or operational data accessed through the CAN interface. Knowledge of this information may be helpful in the post-crash handling, management, and storage of an EV. The functionality and accuracy of EVIRS were demonstrated through laboratory tests using a 2021 Ford Mach-E and associated data acquisition system. The results indicated that when the remaining driving range was used as an input, EVIRS was able to estimate the pack voltage with an error of less than 3 V. Conversely, when pack voltage was used as an input, the estimated state of charge (SOC) error was less than 5% within the range of 30–90% SOC. Additionally, other features, such as retrieving emergency response guides for identified EVs and accessing lessons learned from archived incidents, have been successfully demonstrated through EVIRS for quick access. EVIRS can be a valuable tool for emergency responders and recovery personnel, both in action and during offline training, by providing crucial information related to assessing EV/battery safety risks, appropriate handling, de-energizing, transport, and storage in an integrated and user-friendly manner.

25 ENERGY STORAGE↗

Public – Private Partnership to Promote Efficient Manufacturing and Workforce Development (IAC Final Technical Report)

Through delivering ninety (90) energy assessments to small- and medium-sized manufacturing facilities in and around Tennessee, significant understandings were gained through providing detailed energy assessment reports to manufacturers and training seventy-seven (77) engineering students in which thirty-five (35) certified IAC students were recognized by DOE. The robust involvement of Tennessee Valley Authority (TVA), local utility and Tennessee Tech’s Cybersecurity Education, Research, and Outreach Center (CEROC) in majority of assessments made the technical operation very effective where leaded to 40.5% implementation rate of energy recommendations. Other benefits of the award to the public are a dynamic modeling tool capable of analyzing existing cooling towers for energy use optimization was developed and presented to DOE IAC, providing technical assistance to non-participating manufacturers in the form of workshop and training, publishing fifteen (15) peer-reviewed conference and journal papers as well as a book chapter in the area of industrial energy efficiency field, assisting the TVA Magnolia Combined Cycle Power Plant to become the First 50001 Ready Certified Power Plant in the U.S. through briefing them on ISO 50001 and 50001 Ready as well as providing an energy assessment to the plant, assisted the new IAC center at Clemson University with on-site and remote support, and provided assessment and training in unique areas of water, waste water, cyber security and smart manufacturing to our clients, students and community.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Comparing the deformation mechanism in 316 L stainless steel fabricated by hybrid and additive manufacturing

This study rationalizes the relatively higher elongation with minimal strength drop of 316L stainless steel (316LSS) manufactured using the hybrid approach in comparison to a fully additive approach followed by machining. It was found that twinning was the dominant deformation mechanism in 316LSS produced by both additive and hybrid approaches. Additionally, the relatively lower fraction of twins in the as-fabricated state of hybrid approach compared to a fully additive approach resulted in delaying the onset of steady-state strain hardening rate to higher strain levels, thereby resulting in an overall increase in elongation to failure.

36 MATERIALS SCIENCE↗

Additively Manufactured Intensified Device for Enhanced Carbon Capture

Additively manufactured packed bed devices for the enhancement of carbon capture were successfully developed, built, characterized, and tested in this project. The objective was to demonstrate that in situ cooling of chemical absorption could have beneficial effects on the absorption rate of CO 2 . This was achieved in two stages, divided between FY 2018 and FY 2019. First, the feasibility of printing conventional packing elements was investigated, and the core hydrodynamic metrics were experimentally validated. The data obtained in those studies informed the operating conditions set for the next stage, which was to validate the efficacy of in situ cooling provided by an additively manufactured packed bed element, referred to as the intensified device. The intensified device is designed to enable heat exchange between an internally flowing coolant and the gas-liquid system flowing on the external corrugated surface of the packing. Polymer and metal were both considered as the base materials for the device, and comparative studies on hydrodynamic properties were performed. These considerations, as well as thermal properties and leak tests led to aluminum being chosen as the base material for experimental validation of capture enhancement. The experimental validation was first conducted under non-reactive conditions, and after establishing heat-exchange capabilities, was subsequently conducted under reactive conditions. These studies demonstrated that in situ cooling can benefit absorption given the appropriate operating conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Part-scale evolution of fine-scale microstructural heterogeneity in solid-state additive manufacturing

Current solid-state additive manufacturing methods, refined through costly and time-consuming trial and error, have spurred interest in computational models that replicate material behavior under typical thermomechanical conditions (e.g., strain-rate ~ 102 s−1). These models, however, struggle to capture time-dependent microstructural evolution. In this work, Additive Friction-Stir Deposition (AFSD) is used as a representative case study for part-scale quantification of microstructure evolution at a fine spatial resolution (200 μm) by examining a liquid-nitrogen-cooled stop-action build via energy-dispersive X-ray diffraction coupled with a multi-channel detector. These results inform modeling efforts by linking process asymmetry to stored plastic strain, residual elastic strain, and texture development, and unlike current state-of-the-art characterization methods (e.g., EBSD or neutron diffraction), this approach provides both the spatial resolution and collection efficiency necessary to quantify fine-scale microstructural heterogeneity over large component volumes. As such, this technique provides essential validation data for computational models, e.g., crystal plasticity, enabling future prediction of heterogeneous behavior in AFSD and other additive manufacturing processes.

Franz, Cole [ORNL] (ORCID:0000000213465881)↗

Crack mitigation in additively manufactured AlCrFe 2 Ni 2 high-entropy alloys through engineering phase transformation pathway

The far-from-equilibrium solidification during additive manufacturing often creates large residual stresses that induce solid-state cracking. Here we present a strategy to suppress solid-state cracking in an additively manufactured AlCrFe 2 Ni 2 high-entropy alloy via engineering phase transformation pathway. We investigate the solidification microstructures formed during laser powder-bed fusion and directed energy deposition, encompassing a broad range of cooling rates. At high cooling rates (10 4 –10 6 K/s), we observe a single-phase BCC/B2 microstructure that is susceptible to solid-state cracking. At low cooling rates (10 2 –10 4 K/s), FCC phase precipitates out from the BCC/B2 matrix, resulting in enhanced ductility (~10 %) and resistance to solid-state cracking. Site-specific residual stress/strain analysis reveals that the ductile FCC phase can largely accommodate residual stresses, a feature which helps relieve residual strains within the BCC/B2 phase to prevent cracking. Our work underscores the value of exploiting the toolbox of phase transformation pathway engineering for material design during additive manufacturing.

36 MATERIALS SCIENCE↗

Low-Cost Radiant Heater for Rapid Response, High-Temperature Heating

High-temperature processing has an irreplaceable role in many research and industrial applications. Despite remarkable development spanning over a century, the pursuit of even higher thermal flux density and more rapid thermal transients has not slowed down. As part of the ongoing energy evolution, many industrial applications are transitioning from direct combustion of fossil fuels as primary energy sources to increasing electrification, capable of adapting to renewable power grids. Thus, there is an emerging need for electrical heaters that can replace burners and supply the heat demand, especially at the highest temperatures. In this study, we report on a radiant heater design that can achieve cyclic heating/cooling rates of up to 400 K min –1 and a temperature range in excess of 1,800 K, comparable to those of commercial infrared gold image furnaces, at high surface and volumetric power densities. The heater consists of a modular unit of incandescent tungsten filament and is enclosed in an evacuated ceramic envelope, chemically inert, tolerant of thermal shock, and impervious to gasses. The material and manufacture cost of such heaters, which is estimated at ~$0.05/W, is less than 0.03% of that for infrared gold image furnaces, which is at >$2/W. Tests of more than 10,000 demanding cycles (high temperature and high heating/cooling rate) over 350 h of total operational time and in different temperature ranges confirm the robust performance of radiant heater prototypes. The design is widely applicable to high-temperature reactor and furnace designs. In thermochemistry research and practice, these radiant heaters could offer multiple benefits compared to solar simulators, lasers, infrared gold furnaces, ceramic heaters, or direct concentration of solar input.

99 GENERAL AND MISCELLANEOUS↗