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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Assimilation of scalar versus horizontal gradient information from the VAS into a mesoscale model

Comparisons are made between analyses and forecasts which incorporate VAS geopotential data as either scalar or horizontal gradient information for a case study on the AVE/VAS day of Mar. 6, 1982. On this day, incorporating the VAS information in analysis as a variational constraint on horizontal geopotential gradients significantly mitigated the effects of large data biases which made VAS assimilation by standard scalar methods very difficult. A subsequent forecast made from the gradient assimilation was superior to one made from the standard analysis and of comparable quality in geopotentials to a control forecast from synoptic data. Most impact was noted in the forecasts of vertical motion and precipitation in the gradient vs this control simulation.

Diak, George↗

Mesoscale structural gradients in human tooth enamel

The outstanding mechanical and chemical properties of dental enamel emerge from its complex hierarchical architecture. An accurate, detailed multiscale model of the structure and composition of enamel is important for understanding lesion formation in tooth decay (dental caries), enamel development (amelogenesis) and associated pathologies (e.g., amelogenesis imperfecta or molar hypomineralization), and minimally invasive dentistry. Although features at length scales smaller than 100 nm (individual crystallites) and greater than 50 µm (multiple rods) are well understood, competing field of view and sampling considerations have hindered exploration of mesoscale features, i.e., at the level of single enamel rods and the interrod enamel (1 to 10 µm). Here, we combine synchrotron X-ray diffraction at submicrometer resolution, analysis of crystallite orientation distribution, and unsupervised machine learning to show that crystallographic parameters differ between rod head and rod tail/interrod enamel. This variation strongly suggests that crystallites in different microarchitectural domains also differ in their composition. Thus, we use a dilute linear model to predict the concentrations of minority ions in hydroxylapatite (Mg 2+ and CO 3 2- /Na + ) that plausibly explain the observed lattice parameter variations. While differences within samples are highly significant and of similar magnitude, absolute values and the sign of the effect for some crystallographic parameters show interindividual variation that warrants further investigation. In conclusion, by revealing additional complexity at the rod/interrod level of human enamel and leaving open the possibility of modulation across larger length scales, these results inform future investigations into mechanisms governing amelogenesis and introduce another feature to consider when modeling the mechanical and chemical performance of enamel.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Data sets and products

Against background of spacecraft and in situ measurements, participants at the JPL workshops sought to review the sensor performance, understand the different SSt retrieval algorithms, evaluate the sensor SST accuracies, and discuss directions for future sensor development. The issue of utilization of satellite SSTs in climate, air sea interaction, and mesoscale oceanography studies was not the main focus of the workshops, but did have a bearing on the recommendations that arose from the discussions. More date were available for analysis with the acquisition of AVHRR (MCSST), HIRS/MSU, and VAS data sets. In Workshop 3 the acquisition and analysis fo data were completed, recommendations for future research and sensor development were discussed, and plans were made for eventual publication of results from the workshop series in the open literature.

Hilland, J. E.↗

A Comparison of the Diurnal Variation of Rainfall in the LBA Area Derived from Satellite Infrared Observations and Raingages

In this paper we will present results from the application of a satellite infrared (IR) technique for estimating rainfall over northern South America. Our main objectives are to examine the diurnal variability of rainfall and to investigate the relative contributions from the convective and stratiform components. Estimates for Jan-Apr. 1999 will be presented for a large (30 by 50 degree) area that includes the Amazon Basin and the LBA (Large Scale Biosphere Atmosphere Experiment in Amazonia) study area. An analysis of the LBA raingage has begun, and results from the analysis of the gage-derived diurnal cycle will be compared to the satellite estimates. Also, we hope to perform a comparison of results with LBA case studies of mesoscale convective systems using TOGA (Tropical Oceans and Global Atmosphere) and S-bands radars. Future calibration of the IR technique using rain estimates from TRMM (Tropical Rainfall Measuring Mission) is anticipated.

Negril, Andrew J.↗

An equivalent potential vorticity theory applied to the analysis and prediction of severe storm dynamics

Potential vorticity theory is developed in a description of an equivalent potential temperature topography, and a new theory suited to the description of scale interaction is elaborated. Macroscale triggering of ageostrophic flow fields at the mesoscale, in turn leading to release of convective instability along narrow zones at the microscale, is examined. Correlation of appreciable decrease in potential vorticity with such phenomena as cumulonimbi, tornados, and duststorms is examined. The relevance of a multiscale energy-momentum cascade in numerical prediction of severe mesoscale and microscale phenomena from radiosonde data is reviewed. Hypotheses for mesoscale dynamics are constructed.

Paine, D. A.↗

Investigation of Mesoscale Variability in Convective Boundary Layer Development Using LASE

Throughout this research effort we have analyzed data collected from the Southern Great Plains 1997 (SGP) experiment to evaluate terms in the budget of water vapor in the atmospheric boundary layer (ABL). The analysis is centered on using data obtained from the Lidar Atmospheric Sensing Experiment (LASE) downward-looking differential absorption lidar (DIAL) that was flown on the NASA-P3 aircraft. The DIAL is able to measure vertical profiles of water vapor, as well as aerosol backscatter, throughout the ABL. Initial work on using the DIAL is summarized in the attached meeting preprint, which discusses results from a segment of the 12 July 1997 flight. Additional analysis has been carried out using both the DIAL data and in situ measurements to obtain more complete and detailed estimates of terms in the ABL water vapor budget. This includes data from the Canadian National Research Council Twin Otter aircraft, as well as from a spectrum of surface-based instruments. This work is expected to lead to a refereed article planned for submission to the Journal.

Lenschow, Donald H.↗

Thermal Conductivity Degradation in High Burnup U-Pu-Zr Fuel

Recent advancements in the characterization of irradiated U-Pu-Zr fuels have revealed complexities that challenge existing understanding of constituent redistribution. Traditionally, models have proposed three concentric regions within the fuel, each characterized by distinctive phases and porosity. However, through detailed analysis of high burnup U-Pu-Zr, we discovered the presence of four distinct constituent redistribution regions. Particularly novel is the observation of significant Pu redistribution, a previously unreported phenomenon that necessitates a reevaluation of current models. This work aims to delve deeper into these findings, seeking to correlate mesoscale measurements of thermal diffusivity and respective thermal conductivity with the phases present in each redistribution region. To achieve this objective, we employed mesoscale thermoreflectance methods using the unique, Idaho National Laboratory (INL) developed, Thermal Conductivity Microscope (TCM) at INL’s Irradiated Materials Characterization Laboratory. The TCM employs two tightly focused lasers: one for heating to generate periodic thermal waves in the substrate, and another spatially separated probe laser to detect changes in the optical reflectivity of the gold-coated substrate resulting from thermal wave diffusion. We conducted several thermal diffusivity measurements within each region of constituent redistribution of a U-19Pu-10Zr fuel pin cross section irradiated to 11 at. % burnup. The TCM measurement positions strategically aligned with transmission electron microscopy (TEM) lift-out locations previously collected from the fuel sample. Complementary microstructural analysis techniques such as optical and scanning electron microscopy (OM/SEM), electron probe microanalysis for chemical compositions, and TEM-based selective area electron diffraction (SAED) analysis for crystallographic insights into each phase were also utilized. This comprehensive approach allowed us to correlate local thermal diffusivity data with microstructural characteristics, enabling the computation of local thermal conductivity at each position. The significance of this contribution lies in its pioneering use of the TCM for ternary fuel mesoscale examination, shedding light on the previously overlooked effects of Pu redistribution on local thermal conductivity. By informing current models capturing constituent redistribution and heat transfer, our findings pave the way for more accurate predictions of metallic fuel performance. Moreover, this work sets the stage for future comparisons with similar TCM examinations on U-19Pu-10Zr fuels at ultra-low burnup, facilitating a comprehensive understanding of thermal property changes across different burnup levels. Ultimately, our study not only enriches our understanding of the thermophysical properties of individual redistribution regions within U-Pu-Zr fuel but also offers valuable insights for the design and operational parameters of proposed next-generation fast reactors.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Interactive initialization of heat flux parameters for numerical models using satellite temperature measurements

Day/night Heat Capacity Mapping Mission image pairs over Kansas and Indiana were used to examine the spatial variation of moisture availability on the mesoscale. Of particular concern was whether patterns of moisture availability and thermal inertia, as well as surface heat fluxes, respond to significant spatial variations in the rainfall pattern. A temperature analysis for the Indiana case is presented.

Carlson, T. N.↗

HIS - A high resolution atmospheric sounder

This paper describes the High-Resolution Interferometer Sounder (HIS), which is the first of a new generation of passive remote sensors for achieving high vertical resolution sounding information, with special attention given to the sounding retrieval procedure. Examples of mesoscale temperature and moisture profiles obtained with airborne HIS during field programs held in 1986 are presented. A spacecraft version of the instrument, to be used in advanced global weather analysis and forecasting, is under development.

Smith, W. L.↗

Ocean-Atmosphere Coupled Model Simulations of Precipitation in the Central Andes

The meridional extent and complex orography of the South American continent contributes to a wide diversity of climate regimes ranging from hyper-arid deserts to tropical rainforests to sub-polar highland regions. In addition, South American meteorology and climate are also made further complicated by ENSO, a powerful coupled ocean-atmosphere phenomenon. Modelling studies in this region have typically resorted to either atmospheric mesoscale or atmosphere-ocean coupled global climate models. The latter offers full physics and high spatial resolution, but it is computationally inefficient typically lack an interactive ocean, whereas the former offers high computational efficiency and ocean-atmosphere coupling, but it lacks adequate spatial and temporal resolution to adequate resolve the complex orography and explicitly simulate precipitation. Explicit simulation of precipitation is vital in the Central Andes where rainfall rates are light (0.5-5 mm hr-1), there is strong seasonality, and most precipitation is associated with weak mesoscale-organized convection. Recent increases in both computational power and model development have led to the advent of coupled ocean-atmosphere mesoscale models for both weather and climate study applications. These modelling systems, while computationally expensive, include two-way ocean-atmosphere coupling, high resolution, and explicit simulation of precipitation. In this study, we use the Coupled Ocean-Atmosphere-Wave-Sediment Transport (COAWST), a fully-coupled mesoscale atmosphere-ocean modeling system. Previous work has shown COAWST to reasonably simulate the entire 2003-2004 wet season (Dec-Feb) as validated against both satellite and model analysis data when ECMWF interim analysis data were used for boundary conditions on a 27-9-km grid configuration (Outer grid extent: 60.4S to 17.7N and 118.6W to 17.4W).

Regional Climate Model↗

Verification of mesoscale objective analyses of VAS and rawinsonde data using the March 1982 AVE/VAS special network data

Various combinations of VAS (Visible and Infrared Spin Scan Radiometer Atmospheric Sounder) data, conventional rawinsonde data, and gridded data from the National Weather Service's (NWS) global analysis, were used in successive-correction and variational objective-analysis procedures. Analyses are produced for 0000 GMT 7 March 1982, when the VAS sounding distribution was not greatly limited by the existence of cloud cover. The successive-correction (SC) procedure was used with VAS data alone, rawinsonde data alone, and both VAS and rawinsonde data. Variational techniques were applied in three ways. Each of these techniques was discussed.

Doyle, James D.↗

Verification of mesoscale objective analyses of VAS and rawinsode data using the March 1982 AVE/VAS special network data

Various combinations of VAS (Visible and Infrared Spin Scan Radiometer Atmospheric Sounder) data, conventional rawinsonde data, and gridded data from the National Weather Service's (NWS) global analysis, were used in successive-correction and variational objective-analysis procedures. Analyses are produced for 0000 GMT 7 March 1982, when the VAS sounding distribution was not greatly limited by the existence of cloud cover. The successive-correction (SC) Procedure was used with VAS data alone, rawinsonde data alone, and both VAS and rawinsonde data. Variational techniques were applied in three ways. Each of these techniques was discussed.

Doyle, James D.↗

Global energy spectrum of the general oceanic circulation

Abstract Advent of satellite altimetry brought into focus the pervasiveness of mesoscale eddies $${{{{{{{\bf{{{{{{{{\mathcal{O}}}}}}}}}}}}}}}}({100})$$ O ( 100 ) km in size, which are the ocean’s analogue of weather systems and are often regarded as the spectral peak of kinetic energy (KE). Yet, understanding of the ocean’s spatial scales has been derived mostly from Fourier analysis in small "representative” regions that cannot capture the vast dynamic range at planetary scales. Here, we use a coarse-graining method to analyze scales much larger than what had been possible before. Spectra spanning over three decades of length-scales reveal the Antarctic Circumpolar Current as the spectral peak of the global extra-tropical circulation, at ≈ 10 4 km, and a previously unobserved power-law scaling over scales larger than 10 3 km. A smaller spectral peak exists at ≈ 300 km associated with mesoscales, which, due to their wider spread in wavenumber space, account for more than 50% of resolved surface KE globally. Seasonal cycles of length-scales exhibit a characteristic lag-time of ≈ 40 days per octave of length-scales such that in both hemispheres, KE at 10 2 km peaks in spring while KE at 10 3 km peaks in late summer. These results provide a new window for understanding the multiscale oceanic circulation within Earth’s climate system, including the largest planetary scales.

54 ENVIRONMENTAL SCIENCES↗

Replication Data for: Neural network assisted analysis of bimetallic nanocatalysts using X-ray absorption near edge structure spectroscopy

The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Satellite microwave observations of a storm complex: A comparative analysis

The hypothesis that cold events correspond to a particular stage in a class of thunderstorms was tested. That class is a storms class which updrafts are: (1) strong, broad and moist, and (2) extend well above the freezing level. Condition (1) implies strong mesoscale forcing. Condition (2) implies a tall updraft or a relatively low freezing level. Such storms should have big, intense radar echoes and cold, fast-growing anvils. The thunderstorm events were analyzed by radar, rain gauge and GOES infrared observations. Radar was the starting point for detection and definition of the hypothesized thunderstorms. The radar signature is compared to the signature of the storm in rain gauge observations, satellite infrared images and satellite microwave images.

Martin, D. W.↗

Mesoscale temperature and moisture fields from satellite infrared soundings

The combined use of radiosonde and satellite infrared soundings can provide mesoscale temperature and moisture fields at the time of satellite coverage. Radiance data from the vertical temperature profile radiometer on NOAA polar-orbiting satellites can be used along with a radiosonde sounding as an initial guess in an iterative retrieval algorithm. The mesoscale temperature and moisture fields at local 9 - 10 a.m., which are produced by retrieving temperature profiles at each scan spot for the BTPR (every 70 km), can be used for analysis or as a forecasting tool for subsequent weather events during the day. The advantage of better horizontal resolution of satellite soundings can be coupled with the radiosonde temperature and moisture profile both as a best initial guess profile and as a means of eliminating problems due to the limited vertical resolution of satellite soundings.

Hillger, D. W.↗

Integrated Modeling of Aerosol, Cloud, Precipitation and Land Processes at Satellite-Resolved Scales

In this talk, I will present recent results from a project led at NASA/GSFC, in collaboration with NASA/MSFC and JHU, focused on the development and application of an observation-driven integrated modeling system that represents aerosol, cloud, precipitation and land processes at satellite-resolved scales. The project, known as the NASA Unified WRF (NU-WRF), is funded by NASA's Modeling and Analysis Program, and leverages prior investments from the Air Force Weather Agency and NASA's Earth Science Technology Office (ESTO). We define "satellite-resolved" scales as being within a typical mesoscale atmospheric modeling grid (roughly 1-25 km), although this work is designed to bridge the continuum between local (microscale), regional (mesoscale) and global (synoptic) processes. NU-WRF is a superset of the standard NCAR Advanced Research WRF model, achieved by fully integrating the GSFC Land Information System (LIS, already coupled to WRF), the WRF/Chem enabled version of the Goddard Chemistry Aerosols Radiation Transport (GOCART) model, the Goddard Satellite Data Simulation Unit (SDSU), and boundary/initial condition preprocessors for MERRA and GEOS-5 into a single software release (with source code available by agreement with NASA/GSFC). I will show examples where the full coupling between aerosol, cloud, precipitation and land processes is critical for predicting local, regional, and global water and energy cycles, including some high-impact phenomena such as floods, hurricanes, mesoscale convective systems, droughts, and monsoons.

Peters-Lidard, Christa↗