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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

The Mars Environmental Compatibility Assessment (MECA) Abrasion Tool

The Mars Environmental Compatibility Assessment (MECA) experiment, an instrument suite to be flown on Mars Surveyor 2001, will include a tool for doing simple mineralogical scratch and streak tests on particles from the Martian regolith. The Abrasion Tool will be applied to particles that adhere themselves to highly polished substrates of various hardnesses. Granular soil components will be subjected to a compressive force of about 3 N using a leaf spring. The spring will be applied with a paraffin actuator capable of a 0.76 mm throw to achieve a maximum displacement of about 7.5 mm at the tip of the tool. The pressure per grain will be dependent on the grain size, the number of grains that adhere to the substrate and the number of grains in compression. The pressure per particle is expected to be on the order of 100 MPa - 1 GPa. The MECA sample wheel containing the substrates will be rotated after the particles are placed in compression to produce scratches or pits. A primary goal of the Abrasion Tool is to identify quartz (Mohs' hardness = 7) using substrates of varying hardnesses. Quartz is considered hazardous to future human explorers of Mars because it can cause silicosis of the lungs if it is of respirable size. It is also hazardous to machinery, structures, and space suits because of its ability to abrade and scratch surfaces. Since large quantities of minerals harder than quartz are not expected, any scratches produced on polished quartz substrates might be reasonably attributed to quartz particles, although there may be minerals such as impact metamorphic diamond in the soils. Careful calibration of the tool will be necessary to ensure that grains are not overloaded; for example, a steel ball pressed into glass will produce a Hertzian fracture, even though it is softer than glass. Other minerals, such as magnetite (Mohs' hardness = 6.5) have been shown to scratch glass ceramics such as Zerodur (Mohs' hardness = 6.5). Thus, minerals can be differentiated: note that regardless of the mineral species, if any particle is harder than 6.5 it will certainly be an interesting discovery for both planetary geology and human exploration concerns. The scratches will be identified using the 6X optical microscope and profiled with the atomic force microscope included in the MECA instrument suite. Analysis of the scratch morphology will yield evidence concerning the shape of the particle responsible for producing each scratch. For example, angular grains should leave vertical cracks with microconchoidal lateral chipping, while rounded grains might leave chatter marks, or nested partial Hertzian cracks. Particle shape can thus be inferred from these indentation modes, as well as material hardness. In addition, particle size information may also be available if pits caused by rolling particles can be identified. Converse to scratching, the minerals may be crushed at their contact points, and be smeared onto the target substrates to leave what geologists refer to as "streaks". These are cold-welded trails of mineral material that have structure and color indicative of mineral composition. The AFM will determine the morphology of these streaks, while the microscope will ascertain the color. On the harder substrates, we might expect streaking to dominate; on the softer substrates, scratching may dominate. Progressions of material interactions across the substrate selection will be a valuable source of data for mineral discrimination. It should also be noted that many minerals have coatings (such as iron oxides), and these will have to be differentiated from the host mineral grains; laboratory tests will establish the effects of such coatings on the scratch results. Finally, we note that the microscope will provide corroborative data regarding likely mineral species by grain shapes, fracture patterns, surface textures, color, and UV fluorescence reactions. Additional information is contained in the original extended abstract.

Kuhlman, K. R.↗

Interface markings in crystals experiment MA-060

Doped germanium single crystals with interface demarcation were successfully grown during the Apollo Soyuz Test Project mission. Interface demarcation permitted the determination of the microscopic growth behavior from the onset to the termination of solidification. Preliminary segregation analysis shows striking differences in segregation in the presence of gravity. The correlation between microscopic growth rate behavior and the composition of the solid on the microscale is being evaluated.

Gatos, H. C.↗

Automated Particle Analysis of Hanford Tank Wastes 241-AN-106, 241-AN-101, and 241-AW-105

This effort is involved in developing particle size and density distribution (PSDD) for the major phases within Hanford tank waste sludge. The object of this work has been to use automated particle analysis (APA) methods on the Scanning Electron Microscope (SEM) to provide PSDDs. The PSDD can be used to quantify the proportion of gibbsite particles likely to settle quickly and enable blending of wastes that may be prone to pipeline plugging such as the uranium phase, clarkeite with other wastes. The Hanford tank waste solids were analyzed with SEM combined with x-ray Energy Dispersive Spectroscopy (EDS) using APA. This method can allow thousands of individual particles to be characterized and so may provide a more representative view of the samples and information PSDDs. We characterized several as-received sludge samples and developed PSDD with APA. Sample preparation methods were found to impact the collected results, as it was more difficult to collect representative samples of the larger particles. Much of the material was also dried and cemented together that further impacted results.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analysis of infrared emission from thin adsorbates

Fuel and lubricant deposits on solid surfaces, though often of similar visual appearance, differ in composition, depending on the nature of the deposit formers and the circumstances of deposition. To help establish these relations an Infrared Emission Fourier Polarization Microspectrophotometer was constructed to record infrared spectra from the deposits on their original support. By focussing on small aggregates with a reflecting microscope objective and by discriminating against the randomly polarized blackbody radiation with a rotating polarizing filter phase-locked to an amplifier, excellent Fourier emission spectra of polarized bands could be obtained. In many instances, the microscope objective was adequate without the polarizer. The analysis was calibrated against a very thin film of polyethylene terephthalate attached to a highly reflective aluminum mirror on the sample positioner.

Lauer, J. L.↗

Controlling mechanical properties of laser powder bed fused AlSi10Mg through manipulation of laser scan rotation

The microstructure and mechanical properties of laser powder bed fused (LPBF) AlSi10Mg alloys can be controlled by many processing parameters. This study focuses on the scan rotation angle, α, between adjacent layers, and establishes the relationship between α and tensile behavior of the as-built LPBF-processed AlSi10Mg alloy. Near-full density cubic coupons were manufactured using the same processing parameters but with systematic variation of α from 0° to 90°. Microscopic observations and X-ray diffraction analysis showed that differences among various coupons mainly include orientations of the melt pools with respect to the build direction and development of the crystallographic texture. The α=0° coupon and α=30° coupon showed the highest and lowest texture index, although the overall crystallographic texture was mild. Tensile specimens were manufactured horizontally and vertically using either α=0° or α=30°, but with various first layer laser direction with respect to the build plate. Notably, the α=0° specimen that was tested along the laser scan direction showed the largest yield strength (283 MPa) and highest tensile ductility (10.1 %). Quantitative image analysis and fractography were performed on all specimens. Results showed that the melt pool orientation with respect to the tensile direction affected the tensile behavior across the different specimens. This was closely related to the localized strain distribution within the melt pool and along the melt pool boundary for the different melt pool orientations observed. Further, these results demonstrate that the laser scan rotation angle between layers can be used to fine tune the mechanical properties of LPBF AlSi10Mg alloy.

36 MATERIALS SCIENCE↗

The Frequency Shift and $Q$ of Disordered Superconducting RF Cavities

Niobium superconducting radio-frequency (SRF) cavities for high-energy accelerator applications have been greatly improved in terms of the quality factor $Q$ by techniques such as Nitrogen doping. However, the mechanisms leading to improvement in $Q$ are still not fully understood. Quite recently the SRF group at Fermilab measured anomalies in the frequency shift of N-doped SRF Niobium cavities near the transition temperature. Here we report our theoretical analysis of these results based on the microscopic theory of superconductivity that incorporates anisotropy of the superconducting gap and inhomogeneous disorder in the screening region of the SRF cavities. We are able to account for frequency shift anomalies very close to $T_c$ on the order of fractions of 1 kHz. Our results for the frequency shift and Q are in good agreement with the experimental data reported for all four N-doped Nb SRF cavities by Bafia et al. We also compare our theory with an earlier report on a Nb sample measured at 60 GHz. In addition, we show that the quality factor calculated theoretically has a peak of upper convexity with the largest $Q$ at intermediate levels of disorder. For strong disorder, i.e. the dirty limit, pair breaking in the presence of disorder and screening currents limits the $Q$.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

WizEM

The software provides a flexible pipeline for artificial intelligence (AI) assisted analysis of data collected from an electron microscope. This tool distinctly provides near real-time image quantification results during data collection, incorporating feedback from a user to tune performance.

Akers, Sarah [Pacific Northwest National Laborator↗

Sharp-Focus Composite Microscope Imaging by Computer

Enhanced depth of focus aids medical analysis. Computer image-processing system synthesizes sharply-focused composite picture from series of photomicrographs of same object taken at different depths. Computer rejects blured parts of each photomicrograph. Remaining in focus portions form focused composite. System used to study alveolar lung tissue and has applications in medicine and physical sciences.

Wall, R. J.↗

Radiative transfer in a sphere illuminated by a parallel beam - An integral equation approach

The problem of multiple scattering of nonpolarized light in a planetary body of arbitrary shape illuminated by a parallel beam is formulated using the integral equation approach. There exists a simple functional whose stationarity condition is equivalent to solving the equation of radiative transfer and whose value at the stationary point is proportional to the differential cross section. The analysis reveals a direct relation between the microscopic symmetry of the phase function for each scattering event and the macroscopic symmetry of the differential cross section for the entire planetary body, and the interconnection of these symmetry relations and the variational principle. The case of a homogeneous sphere containing isotropic scatterers is investigated in detail. It is shown that the solution can be expanded in a multipole series such that the general spherical problem is reduced to solving a set of decoupled integral equations in one dimension. Computations have been performed for a range of parameters of interest, and illustrative examples of applications to planetary problems as provided.

Shia, R.-L.↗

Evaluation, development, and characterization of superconducting materials for space application

Results are reported of low magnetic field studies of dc magnetic susceptibility and ac magnetic susceptibility of bulk samples and powders. These data are analyzed and compared with the microstructures and compositions of the samples as determined by scanning electron microscopic micrographs, X-ray and chemical analysis. Particular emphasis is given to the interpretation of the ac magnetic susceptibility data which were obtained as function of the magnitude and frequency of the ac measuring field, and low values of an applied dc magnetic field. Two general conclusions are given and briefly discussed.

Thorpe, A. N.↗

Thermoplastic coating of carbon fibers

A continuous powder coating system was developed for coating carbon fiber with LaRC-TPI (Langley Research Center-Thermoplastic Polyimide), a high-temperature thermoplastic polymide invented by NASA-Langley. The coating line developed used a pneumatic fiber spreader to separate the individual fibers. The polymer was applied within a recirculating powder coating chamber then melted using a combination of direct electrical resistance and convective heating to make it adhere to the fiber tow. The tension and speed of the line were controlled with a dancer arm and an electrically driven fiber wind-up and wind-off. The effects of heating during the coating process on the flexibility of the prepreg produced were investigated. The uniformity with which the fiber tow could be coated with polymer also was examined. Composite specimens were fabricated from the prepreg and tested to determine optimum process conditions. The study showed that a very uniform and flexible prepeg with up to 50 percent by volume polymer could be produced with this powder coating system. The coating line minimized powder loss and produced prepeg in lengths of up to 300 m. The fiber spreading was found to have a major effect on the coating uniformity and flexibility. Though test results showed low composite tensile strengths, analysis of fracture surfaces under scanning electron microscope indicated that fiber/matrix adhesion was adequate.

Edie, D. D.↗

The Influence of Sound Cues on the Maintenance of Temporal Organization in the Sprague-Dawley Rat

Temporal organization is a fundamental property of living matter. From single cells to complex animals including man, most physiological systems undergo daily periodic changes in concert with environmental cues (e.g., light, temperature etc.). It is known that pulsed Environmental synchronizers, zeitgebers, (e.g. light) can modify rhythm parameters. Rhythm stability is a necessary requirement for most animal experiments. The extent to which sound can influence the circadian system of laboratory rats is poorly understood. This has implications to animal habitats in the novel environments of the Space-Laboratory or Space Station. A series of three white noise (88+/-0.82 db) zeitgeber experiments were conducted (n=6/experiment).The sound cue was introduced in the circadian free-running phase (DD-NQ) and in one additional case sound was added to the usual photoperiod (12L:12D) to determine masking effects. Circadian rhythm parameters of drinking frequency, feeding frequency, and gross locomotor activity were continuously monitored. Data analysis for these studies included macroscopic and microscopic methods. Raster plots to visually detect entrainment versus free-running period, were plotted for each animal, for all three parameters, during all sound perturbation tested. These data were processed through a series of detrending (robust locally weighted regression analyses) and complex demodulation analyses. In summary, these findings show that periodic "white" noise "influences" the rats circadian system but does not "entrain" the feeding, drinking or locomotor activity rhythms.

Winget, C. M.↗

Particle Morphology and Size Results from the Smoke Aerosol Measurement Experiment-2

Results are presented from the Reflight of the Smoke Aerosol Measurement Experiment (SAME-2) which was conducted during Expedition 24 (July-September 2010). The reflight experiment built upon the results of the original flight during Expedition 15 by adding diagnostic measurements and expanding the test matrix. Five different materials representative of those found in spacecraft (Teflon, Kapton, cotton, silicone rubber and Pyrell) were heated to temperatures below the ignition point with conditions controlled to provide repeatable sample surface temperatures and air flow. The air flow past the sample during the heating period ranged from quiescent to 8 cm/s. The smoke was initially collected in an aging chamber to simulate the transport time from the smoke source to the detector. This effective transport time was varied by holding the smoke in the aging chamber for times ranging from 11 to 1800 s. Smoke particle samples were collected on Transmission Electron Microscope (TEM) grids for post-flight analysis. The TEM grids were analyzed to observe the particle morphology and size parameters. The diagnostics included a prototype two-moment smoke detector and three different measures of moments of the particle size distribution. These moment diagnostics were used to determine the particle number concentration (zeroth moment), the diameter concentration (first moment), and the mass concentration (third moment). These statistics were combined to determine the diameter of average mass and the count mean diameter and, by assuming a log-normal distribution, the geometric mean diameter and the geometric standard deviations can also be calculated. Overall the majority of the average smoke particle sizes were found to be in the 200 nm to 400 nm range with the quiescent cases producing some cases with substantially larger particles.

Urban, David L.↗

Automated Energy-Dispersive X-ray Spectroscopy Analysis for Multi-Modal Few-Shot Learning

Scanning transmission electron microscopy (STEM) is a powerful tool that allows for the atomic-scale analysis of a materials’ structure, chemistry, and defect domains (Akers et al. 2021). The current generation of microscopes generate vast amounts of data, surpassing the limits of effective manual analysis traditionally performed by domain experts (Spurgeon et al. 2021). While recent strides in machine learning have significantly enhanced the processing of large and intricate datasets acquired through electron microscopy, the prevalent use of proprietary software packages for initial data collection poses a challenge. In many cases, these software packages act as a ‘black box’, constraining user functionality and hindering the output of data in a format that is conducive to seamless integration into machine learning models. This work addresses these challenges by adapting HyperSpy, an open-source Python library, for the analysis and quantification of raw energy dispersive spectroscopy (EDS) data acquired through STEM. The modified HyperSpy code successfully facilitates user-defined segmentation of the data, enabling the integration of atomic %, weight %, and raw EDS spectra for each segmented region into an existing few-shot machine learning model. While initial results reveal discrepancies in quantified atomic and weight percentages when compared to proprietary software, ongoing efforts aim to rectify this issue by refining the fit of the HyperSpy model to the EDS spectra. Overall, this research underscores the potential of open-source tools like HyperSpy to enhance the accessibility of analytical tools, fostering a transparent and user-friendly environment for seamlessly incorporating electron microscopy data into machine learning models.

36 MATERIALS SCIENCE↗

SIMS analysis of extended impact features on LDEF experiment

Discussed here are the first Secondary Ion Mass Spectroscopy (SIMS) analysis of projectile material deposited in extended impact features on Ge wafers from the trailing edge. Although most capture cells lost their plastic film covers, they contain extended impact features that apparently were produced by high velocity impacts when the plastic foils were still intact. Detailed optical scanning of all bare capture cells from the trailing edge revealed more than 100 impacts. Fifty-eight were selected by scanning electron microscope (SEM) inspection as prime candidates for SIMS analysis. Preliminary SIMS measurements were made on 15 impacts. More than half showed substantial enhancements of Mg, Al, Si, Ca, and Fe in the impact region, indicating micrometeorites as the projectiles.

Amari, S.↗

Effect of Microscopic Damage Events on Static and Ballistic Impact Strength of Triaxial Braid Composites

In previous work, the ballistic impact resistance of triaxial braided carbon/epoxy composites made with large flat tows (12k and 24k) was examined by impacting 2 X2 X0.125" composite panels with gelatin projectiles. Several high strength, intermediate modulus carbon fibers were used in combination with both untoughened and toughened matrix materials. A wide range of penetration thresholds were measured for the various fiber/matrix combinations. However, there was no clear relationship between the penetration threshold and the properties of the constituents. During some of these experiments high speed cameras were used to view the failure process, and full-field strain measurements were made to determine the strain at the onset of failure. However, these experiments provided only limited insight into the microscopic failure processes responsible for the wide range of impact resistance observed. In order to investigate potential microscopic failure processes in more detail, quasi-static tests were performed in tension, compression, and shear. Full-field strain measurement techniques were used to identify local regions of high strain resulting from microscopic failures. Microscopic failure events near the specimen surface, such as splitting of fiber bundles in surface plies, were easily identified. Subsurface damage, such as fiber fracture or fiber bundle splitting, could be identified by its effect on in-plane surface strains. Subsurface delamination could be detected as an out-of-plane deflection at the surface. Using this data, failure criteria could be established at the fiber tow level for use in analysis. An analytical formulation was developed to allow the microscopic failure criteria to be used in place of macroscopic properties as input to simulations performed using the commercial explicit finite element code, LS-DYNA. The test methods developed to investigate microscopic failure will be presented along with methods for determining local failure criteria that can be used in analysis. Results of simulations performed using LS-DYNA will be presented to illustrate the capabilities and limitations for simulating failure during quasi-static deformation and during ballistic impact of large unit cell size triaxial braid composites.

Littell, Justin D.↗

Further Study of near Solidus Intergranular Cracking in Inconel 718

A series of tests, performed to determine the strain necessary to initiate intergranular cracking in Inconel 718 as a function of temperature, contained enough scatter near the melting temperature that questions remained as to the best curve of curves to fit to the data. Fracture surface analysis showed that the scatter was due to incipient melting in the grain boundary region. The melting contributed to low fracture strain but had only a small on the incipient cracking strain. Gleeble tests, which could be interrupted by water quenching, were used to study the incipient intergranular melting of Inconel 718. This modified weld simulation test provided a sufficiently rapid quench to preserve the intergranular microstructure created during incipient melting. This structure was studied both microscopically and with energy dispensive X-ray analysis. The implications of incipient melting and low-strain incipient cracking on the development of microfissuring envelopes are discussed.

Thompson, R. G.↗

A Direct Probe of the Hydrogen Bond Network in Aqueous Glycerol Aerosols

The properties of aerosols are of paramount importance in atmospheric chemistry and human health. The hydrogen bond network of glycerol-water aerosols generated from an aqueous solution with different mixing ratios is probed directly with X-ray photoelectron spectroscopy. The carbon and oxygen X-ray spectra reveal contributions from gas and condensed phase components of the aerosol. It is shown that water suppresses glycerol evaporation up to a critical mixing ratio. A dielectric analysis using terahertz spectroscopy coupled with infrared spectroscopy of the bulk solutions provides a picture of the microscopic heterogeneity prevalent in the hydrogen bond network when combined with the photoelectron spectroscopy analysis. The hydrogen bond network is composed of three intertwined regions. At low concentrations, glycerol molecules are surrounded by water forming a solvated water network. Adding more glycerol leads to a confined water network, maximizing at 22 mol %, beyond which the aerosol resembles bulk glycerol. This microscopic view of hydrogen bonding networks holds promise in probing evaporation, diffusion dynamics, and reactivity in aqueous aerosols.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗