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At least 343 records · Page 19

Magnetocaloric Pumping of Liquid Oxygen

The field-induced force density on a magnetic fluid is proportional to the magnetic susceptibility times the gradient of the magnetic field squared. The direction of the force is towards increasing magnetic field (positive gradient). Applying a magnetic field to a magnetic fluid will result in a force from all directions towards the location of peak field. Since the magnetic field is conservative and there are no magnetic monopoles, the net field-induced force on any fluid of constant susceptibly will be zero. The only manner to obtain a nonzero net field-induced force is to vary the susceptibility of the fluid. At the gas/liquid interface of liquid oxygen, the susceptibility varies drastically, and the exploitation of the resultant large net forces. An alternative method of varying the magnetic susceptibility is to vary the temperature of the fluid. The magnetic susceptibility of paramagnetic liquid oxygen obeys the Curie-Weiss law: it is inversely proportional to temperature. By applying a temperature gradient in the presence of a symmetric magnetic field, a nonzero net force results. Much of the theory of the so-called Magnetocaloric Effect has previously been developed for and applied to ferromagnetic fluids, or ferrofluids, but is readily applied to paramagnetic liquid oxygen.

Immer, Christopher↗

Acetate as a Platform for Carbon-Negative Production of Renewable Fuels and Chemicals (Final Technical Report)

This project was an industrial-academic collaboration between experts at the University of Wisconsin-Madison, the University of Kentucky, and LanzaTech, a world leader in the use of gas fermentation to sustainably produce fuels and chemicals. The project developed technologies to create an integrated process for converting carbon dioxide and renewable hydrogen into molecules that can be blended with liquid transportation fuels or used in an array of chemical applications. The project was motivated by the Program Objectives of eliminating carbon dioxide release in the production of chemicals by integrating the unique and efficient capabilities of two microorganisms into a single process. The first microbe, an acetogen, produces acetate from carbon dioxide and hydrogen while the second microbe upgrades acetate from acetogen fermentation permeates to higher-value chemical products. The carbon dioxide released in the upgrading process is recycled internally to produce more acetate. As such, the process can be designed to operate with zero carbon dioxide release and net positive carbon dioxide capture. The process has the potential to provide an alternative paradigm to the current bioeconomy – one in which acetate is the primary energy carrier instead of sugars. Our process by-passes photosynthesis and the barriers created by biomass as primary chemical feedstock. As such, the process can be scaled to meet existing sources of carbon dioxide emissions and located anywhere renewable hydrogen can be provided. Our work developed microorganisms with optimized metabolism for producing acetate and other microorganisms with improved conversion of acetate to dodecanol and dodecyl-acetate. We developed synthetic biology tools for a promising non-model bacterium that could enhance metabolic engineering efforts to convert acetate to chemical products. We conducted protein engineering studies to improve the activity of key enzymes involved in our metabolic pathways. We conducted a full technoeconomic analysis that set technical targets for each strain to meet economic goals. We identified key technical barriers in our process and proposed strategies to overcome them.

09 BIOMASS FUELS↗

Thermochemical water decomposition processes

Thermochemical processes which lead to the production of hydrogen and oxygen from water without the consumption of any other material have a number of advantages when compared to other processes such as water electrolysis. It is possible to operate a sequence of chemical steps with net work requirements equal to zero at temperatures well below the temperature required for water dissociation in a single step. Various types of procedures are discussed, giving attention to halide processes, reverse Deacon processes, iron oxide and carbon oxide processes, and metal and alkali metal processes. Economical questions are also considered.

Chao, R. E.↗

Metabolic and endocrine studies - The second manned Skylab mission

Complete metabolic collections were performed on the Skylab 3 crew in the preflight, inflight, and postflight phases of the mission. Changes in fluid and electrolyte balance have been correlated with weight loss, changes in the excretion of aldosterone, vasopressin, and fluid compartments. The initial changes observed were consistent with an increase in thoractic blood volume upon transition to a zero gravity environment, producing a net fluid loss. Compensatory mechanisms reestablished positive water balance. The indicators investigated returned to thin preflight levels during the recovery period postflight

Leach, C. S.↗

Parametric amplification and oscillation at 36 GHz using a point-contact Josephson junction

The paper reports observation of doubly degenerate parametric amplification and oscillation at 36 GHz from a single point-contact Josephson junction. The experimental results agree qualitatively with theoretical calculations based on the resistively shunted junction model. The estimated noise temperature of an amplifier with 11 dB net gain is consistent with zero, but has an upper limit of 50 K. Attempts to observe parametric amplification in the singly degenerate mode with a pump frequency of 72 GHz were not successful.

Taur, Y.↗

The systematic radial downflow in the transition region of the quiet sun from limb-to-limb observations of the C IV resonance lines

This paper presents absolute velocities of C IV 1548, 1550 nm measured as a function of position along the solar equator, which was free of both active regions and coronal holes, and uniformly representative of the quiet sun. These observations were made with moderate spatial resolution (18 arcsec) using an EUV spectrometer dedicated to measuring absolute wavelengths (velocities) by direct comparison with a platinum spectrum generated on board the sounding rocket. On the assumption that systematic horizontal motions cancel statistically so that the line-of-sight velocities approach zero at the limb, a net radial downflow of 7.5 + or - 1.0 km/sec was found. The assumption was tested using the wavelength reference and found to be valid within the absolute accuracy of the rest wavelengths of the C IV lines.

Rottman, Gary J.↗

Electroform/Plasma-Spray Laminates for X-Ray Optics

Electroform/plasma-spray laminates have shown promise as lightweight, strong, low-thermal-expansion components for xray optics. The basic idea is to exploit both (1) the well-established art of fabrication of optical components by replication and (2) plasma spraying as a means of reinforcing a thin replica optic with one or more backing layer(s) having tailorable thermomechanical properties. In x-ray optics as in other applications, replication reduces the time and cost of fabrication because grinding and polishing can be limited to a few thick masters, from which many lightweight replicas can thereafter be made. The first step in the fabrication of a component of the type in question is to make a replica optic by electroforming a thin layer of nickel on a master. Through proper control of the electroforming process conditions, it is possible to minimize residual stress and, hence, to minimize distortion in the replica. Next, a powder comprising ceramic particles coated with a metal compatible with the electroformed nickel is plasma-sprayed onto the backside of the nickel replica. Then through several repetitions and variations of the preceding steps or perhaps a small compressive stress, alternating layers of electroformed nickel and plasma-sprayed metal-coated ceramic powder are deposited. The thicknesses of the layers and the composition of the metal-coated ceramic powder are chosen to optimize the strength, areal mass density, and toughness of the finished component. An important benefit of using both electroforming and plasma spraying is the possibility of balancing stresses to a minimum level, which could be zero or perhaps a small net compressive stress designed to enhance the function of the component in its intended application.

Ulmer, Melville P.↗

Sea-Level Rise: Projections for Maryland 2018

In fulfillment of requirements of the Maryland Commission on Climate Change Act of 2015, this report provides updated projections of the amount of sea-level rise relative to Maryland coastal lands that is expected into the next century. These projections represent the consensus of an Expert Group drawn from the Mid-Atlantic region. The framework for these projections is explicitly tied to the projections of global sea-level rise included in the Intergovernmental Panel on Climate Change Fifth Assessment (2014) and incorporates regional factors such as subsidence, distance from melting glaciers and polar ice sheets, and ocean currents. The probability distribution of estimates of relative sea-level rise from the baseline year of 2000 are provided over time and, after 2050, for three different greenhouse gas emissions pathways: Growing Emissions (RCP8.5), Stabilized Emissions (RCP4.5), and meeting the Paris Agreement (RCP2.6). This framework has been recently used in developing relative sea-level rise projections for California, Oregon, Washington, New Jersey, and Delaware as well as several metropolitan areas. The Likely range (66% probability) of the relative rise of mean sea level expected in Maryland between 2000 and 2050 is 0.8 to 1.6 feet, with about a one-in-twenty chance it could exceed 2.0 feet and about a one-in-one hundred chance it could exceed 2.3 feet. Later this century, rates of sea-level rise increasingly depend on the future pathway of global emissions of greenhouse gases during the next sixty years. If emissions continue to grow well into the second half of the 21st century, the Likely range of sea-level rise experienced in Maryland is 2.0 to 4.2 feet over this century, two to four times the sea-level rise experienced during the 20th century. Moreover, there is a one-in-twenty chance that it could exceed 5.2 feet. If, on the other hand, global society were able to bring net greenhouse gas emissions to zero in time to meet the goals of the Paris Climate Agreement and reduce emissions sufficient to limit the increase in global mean temperature to less than 2°Celsius over pre-industrial levels, the Likely range for 2100 is 1.2 to 3.0 feet, with a one-in-twenty chance that it would exceed 3.7 feet. The difference in sea-level rise between these contrasting scenarios would diverge even more during the next century, with the failure to reduce emissions in the near term resulting in much greater sea-level rise 100 years from now. Moreover, recent research suggests that, without imminent and substantial reductions in greenhouse gas emissions, the loss of polar ice sheets-and thus the rate of sea-level rise-may be more rapid than assumed in these projections, particularly under the Growing Emissions scenario. These probabilistic sea-level rise projections can and should be used in planning and regulation, infrastructure siting and design, estimation of changes in tidal range and storm surge, developing inundation mapping tools, and adaptation strategies for high-tide flooding and saltwater intrusion.

Boesch, D. F.↗

Transforming Windows from Energy Liabilities to Zero-Energy Assets: Next-Generation Solutions for Buildings

Windows have traditionally contributed to a building's HVAC load, but they can also become a source of net energy gain or even operate as zero-energy components. For heating applications, highly insulating windows can harness more solar heat than the energy lost through them, transforming windows from energy liabilities to assets. Dynamic glazings provide further benefits by regulating solar heat gain, reducing cooling loads in summer and heating demands in winter. This simulation study focuses on developing the next generation of zero-energy windows (ZEW) for residential new construction. Through annual energy simulations across climate zones 1-8, ZEW performance benchmarks were established based on current code-level buildings, and we've identified the regions where meeting ZEW standards are most achievable. This work evaluates both static and dynamic window technologies, assessing their effects on annual energy use and cost. Key findings demonstrate that ZEW performance is achievable across diverse climate zones, with specific regional requirements. Most climate zones from 3-8 can achieve ZEW with specific configurations, while some warm climates (1-2) appear challenging for ZEW implementation. Climate zones 4-6 consistently allow for zero energy window implementation, offering multiple pathways through either static or dynamic window technologies. Colder climate zones (7-8) ZEW products allow for higher SHGC values while requiring low U-values.

Yu, Lili↗

Global Patterns in Human Consumption of Net Primary Production

The human population and its consumption profoundly affect the Earth's ecosystems. A particularly compelling measure of humanity's cumulative impact is the fraction of the planet's net primary production that we appropriate for our Net primary production-the net amount of solar energy converted to plant organic matter through photosynthesis-can be measured in units of elemental carbon and represents the primary food energy source for the world's ecosystems. Human appropriation of net primary production, apart from leaving less for other species to use, alters the composition of the atmosphere, levels of biodiversity, flows within food webs and the provision of important primary production required by humans and compare it to the total amount generated on the landscape. We then derive a spatial ba!mce sheet of net primary production supply and demand for the world. We show that human appropriation of net primary production varies spatially from almost zero to many times the local primary production. These analyses reveal the uneven footprint of human consumption and related environmental impacts, indicate the degree to which human populations depend on net primary production "imports" and suggest policy options for slowing future growth of human appropriation of net primary production.

Imhoff, Marc L.↗

Summary Report of the Carbon-Negative Hydrogen Workshop

This report summarizes the outcomes of the Carbon-Negative Hydrogen Workshop held at the National Renewable Energy Laboratory in Golden, Colorado on June 22-23, 2023. The workshop was co-sponsored by Lawrence Livermore National Laboratory and the National Energy Technology Laboratory and focused on developing a shared understanding of the importance of and opportunities for generation and use of carbon-negative hydrogen in industrial decarbonization. For the purposes of this workshop, carbon-negative hydrogen was defined as hydrogen (H 2 ) produced in a manner that leads to net carbon dioxide removal from the atmosphere thus giving rise to a life cycle cradle-to-grave carbon intensity that is below zero.

08 HYDROGEN↗

Solution‐Processed Spin‐Polarized Light‐Emitting Diodes of Colloidal Quantum Wells and Magnetic Nanoparticles

Electrical injection of spin-polarized carriers into semiconductors enables circularly-polarized emission from spin-polarized light-emitting diodes (spin-LEDs). The incredible level of tunability of magnetic and electronic properties in colloidal nanocrystals offers unprecedented opportunities for the modulation of polarization of light in solution-processed spin-LEDs based on magnetic nanoparticles unlike epitaxially grown spin-LEDs restricted by a very limited range of materials for their exploitation, and solution-processed spin-LEDs based on chiral molecules, which do not allow the modulation of polarization in general. Here, it is shown that electrical injection of spin-polarized electrons from magnetic Fe 3 O 4 nanoparticles into CdSe/CdZnS core/shell colloidal quantum wells (CQWs) in solution-processed LEDs that allows for polarization modulation of electroluminescence. In this structure, a monolayer of face-down oriented CQWs is deposited as an active layer to avoid polarization losses due to the hopping of the electrons between the CQWs before the radiative recombination process. In this solution-processed spin-LED, the circular polarization reaches 4.5% at 3 K and survives up to 100 K. A net circular polarization is observed at zero magnetic field up to 100 K because of the remnant magnetization of the Fe 3 O 4 nanoparticles. This new colloidal spin-LED architecture presents significant prospects for future solution-processed advanced opto-spintronic devices.

circularly polarized electroluminescence↗

Radial forces in a misaligned radial face seal

Radial forces on the primary seal ring of a flat misaligned seal are analyzed, taking into account the radial variation in seal clearance. An analytical solution for both hydrostatic and hydrodynamic effects is presented that covers the whole range from zero to full angular misalignment. The net radial force on the primary seal ring is always directed so as to produce a radial eccentricity which generates inward pumping. Although the radial force is usually very small, in some cases it may be one of the reasons for excessive leakage through both the primary and secondary seals of a radial face seal.

Etsion, I.↗

Radial forces in a misaligned radial face seal

Radial forces on the primary seal ring of a flat misaligned seal are analyzed, taking into account the radial variation in seal clearance. An analytical solution for both hydrostatic and hydrodynamic effects is presented that covers the whole range from zero to full angular misalignment. The net radial force on the primary seal ring is always directed so as to produce a radial eccentricity which generates inward pumping. Although the radial force is usually very small, in some cases it may be one of the reasons for excessive leakage through both the primary and secondary seals of a radial face seal.

Etsion, I.↗

Contact discontinuities in a cold collision-free two-beam plasma

The structure of contact discontinuities in a collision-free plasma is examined using a model of a plasma which consists of two oppositely directed cold ion beams and a background of cold massless electrons such that exact charge neutrality is maintained and that the electric field is zero. The basic equations describing self-consistent equilibria are obtained for the more general situation where a net flow across the layer takes place and where the magnetic field has two nonzero tangential components but where the electric field remains zero. These equations are then specialized to the case of no net plasma flow where one of the tangential components is zero, and four different classes of sheets are obtained, all having thickness the order of the ion inertial length. The first class is for layers separating two identical plasma and magnetic field regions, the second is for an infinite array of parallel layers producing an undulated magnetic field, the third is for layers containing trapped ions in closed orbits which separate two vacuum regions with uniform identical magnetic fields, and the fourth is for layers which reflect a single plasma beam, leaving a vacuum with a reversed and compressed tangential field on the other side.

Kirkland, K. B.↗

Transition from an incommensurate spin density wave to a commensurate magnetic order in a triangular lattice compound Ho 2 PdAl 6 Ge 4

Rare-earth (RE) intermetallics on a triangular lattice are promising candidates for generating interesting magnetic phases due to the complex interplay between Ruderman-Kittel-Kasuya-Yoshida (RKKY) interaction and geometrical frustration. Here, in this work, we report the exotic magnetic structure of a layered compound Ho 2 PdAl 6 Ge 4 with triangular lanthanide nets. Magnetization and heat capacity measurements in zero magnetic field reveal two magnetic phase transitions at T N1 = 10.8 K and T N2 = 6.0 K. Neutron powder diffraction demonstrates a commensurate antiferromagnetic phase with k 1 = (0, 0, 1.5) below T N2 . With increasing temperature, another incommensurate vector appears and therefore, the magnetic structure of the intermediate state is identified as an unusual incommensurate spin density wave with two propagation vectors k 1 = (0, 0, 1.5) and k 2 = (0.0492, 0.0492, 1.5). The magnetic moments in the intermediate state rotate continuously and form an unusual S-shaped wave arrangement in the ab plane, sharing similarities with typical cycloid and helix magnetic orders. These results identify Ho 2 PdAl 6 Ge 4 as a candidate for exploring field-induced topological magnetic phases such as skyrmions, opening the way for further investigations on the family of RE 2 PdAl 6 Ge 4 materials.

36 MATERIALS SCIENCE↗

A note on the interference of two collinear cracks in a cylindrical shell

A simple interference problem in shells is evaluated and the results are compared with the obtained data for flat plates. A pressurized shallow cylindrical shell containing two collinear axial through cracks of equal lengths is investigated. It is found that as the size of the net ligament between the two cracks approaches zero, the stress intensity factors at the inner crack tips go to infinity, and the factors at the outer tips approach values that correspond to a single crack except that they are twice as long.

Erdogan, F.↗

The macroscopic behavior of cumulus ensembles simulated by a cumulus ensemble model

A number of simulation experiments are performed with the 2D UCLA cumulus ensemble model to study the macroscopic behavior of cumulus convection under a variety of different large-scale and underlying surface conditions. Specifically, the modulation of cumulus activity by the imposed large-scale processes and the eddy kinetic energy (EKE) budget are investigated in detail. In all simulations, cumulus convection is rather strongly modulated by large-scale advective processes in spite of the existence of some nonmodulated high-frequency fluctuations. The modulation exhibits some phase delays, however, when the basic wind shear is strong. This is presumably associated with the existence of mesoscale convective organization. The EKE budget analysis shows that the net eddy buoyancy generation rate is nearly zero for a wind range of cumulus ensembles.

Xu, Kuan-Man↗