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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Portable reflectance spectrometer

A portable reflectance spectrometer is disclosed. The spectrometer essentially includes an optical unit and an electronic recording unit. The optical unit includes a pair of thermoelectrically-cooled detectors, for detecting total radiance and selected radiance projected through a circular variable filter wheel, and is capable of operating to provide spectral data in the range 0.4 to 2.5 micrometers without requiring coventional substitution of filter elements. The electronic recording unit includes power supplies, amplifiers, and digital recording electronics designed to permit recordation of data on tape casettes. Both the optical unit and electronic recording unit are packaged to be manually portable.

Goetz, A. F. H.↗

Double passing the Kitt Peak 1-m Fourier transform spectrometer

Attention is given to a simple technique for performing the conversion of the Kitt Peak 1-m Fourier transform spectrometer's dual input/output optical configuration to a double pass configuration that improves spectral resolution by a factor of 2. The modification is made by placing a flat mirror in the output beam from each cat's eye, retroreflecting the beams back through the cat's eyes to the first beam splitter. A single detector is placed at the second input port, which then becomes the instrument's output.

Jennings, D. E.↗

Operating envelopes of particle sizing instrumentation used for icing research

The Forward Scattering Spectrometer Probe and the Optical Array Probe are analyzed in terms of their ability to make accurate determinations of water droplet size distributions. Sources of counting and sizing errors are explained. The paper describes ways of identifying these errors and how they can affect measurement.

Hovenac, Edward A.↗

Operating envelopes of particle sizing instrumentation used for icing research

The Forward Scattering Spectrometer Probe and the Optical Array Probe are analyzed in terms of their ability to make accurate determinations of water droplet size distributions. Sources of counting and sizing errors are explained. The paper describes ways of identifying these errors and how they can affect measurement.

Hovenac, Edward A.↗

Digital and optical shape representation and pattern recognition; Proceedings of the Meeting, Orlando, FL, Apr. 4-6, 1988

The present conference discusses topics in pattern-recognition correlator architectures, digital stereo systems, geometric image transformations and their applications, topics in pattern recognition, filter algorithms, object detection and classification, shape representation techniques, and model-based object recognition methods. Attention is given to edge-enhancement preprocessing using liquid crystal TVs, massively-parallel optical data base management, three-dimensional sensing with polar exponential sensor arrays, the optical processing of imaging spectrometer data, hybrid associative memories and metric data models, the representation of shape primitives in neural networks, and the Monte Carlo estimation of moment invariants for pattern recognition.

Juday, Richard D.↗

Scanning tunneling microscopy studies of diamond films and optoelectronic materials

In this report, we report on progress achieved from 12/1/92 to 10/1/93 under the grant entitled 'Scanning Tunneling Microscopy Studies of Diamond Films and Optoelectronic Materials'. We have set-up a chemical vapor deposition (CVD) diamond film growth system and a Raman spectroscopy system to study the nucleation and growth of diamond films with atomic resolution using scanning tunneling microscopy (STM). A unique feature of the diamond film growth system is that diamond films can be transferred directly to the ultrahigh vacuum (UHV) chamber of a scanning tunneling microscope without contaminating the films by exposure to air. The University of North Texas (UNT) provided $20,000 this year as matching funds for the NASA grant to purchase the diamond growth system. In addition, UNT provided a Coherent Innova 90S Argon ion laser, a Spex 1404 double spectrometer, and a Newport optical table costing $90,000 to set-up the Raman spectroscopy system. The CVD diamond growth system and Raman spectroscopy system will be used to grow and characterize diamond films with atomic resolution using STM as described in our proposal. One full-time graduate student and one full-time undergraduate student are supported under this grant. In addition, several graduate and undergraduate students were supported during the summer to assist in setting-up the diamond growth and Raman spectroscopy systems. We have obtained research results concerning STM of the structural and electronic properties of CVD grown diamond films, and STM and scanning tunneling spectroscopy of carbon nanotubes. In collaboration with the transmission electron microscopy (TEM) group at UNT, we have also obtained results concerning the optoelectronic material siloxene. These results were published in refereed scientific journals, submitted for publication, and presented as invited and contributed talks at scientific conferences.

Perez, Jose M.↗

Inter-comparison of Wildfire and High-resolution Interferometer Sounder (HIS) data from STORM-FEST: An investigation of wildfire spectral channel discrepancies

This simultaneous collection of HIS spectral measurements aboard the ER-2 during STORM-FEST provided a means to explore calibration problems in the infrared bands of the Wildfire instrument. Large discrepancies in brightness temperatures were noted in Wildfire bands designed to sample the 'wings' of the strong ozone absorption band centered at 9.6 microns, where the atmospheric transmittance changes rapidly with wavelength. Examination of interchannel relationships in Wildfire data and subsequent comparison to Wildfire data synthesized from the HIS measurements suggests that a wavelength shift in the channel spectral response from those determined in the laboratory may have occurred. Based on comparisons from several flights, this spectral shift has been empirically determined to be about 0.15 micron. It is speculated that this problem resulted from a slight misalignment of the spectrometer grating or other optical elements, or was a result of extreme range in temperatures experienced by the instrument throughout the course of an ER-2 flight. A consequence of this temperature fluctuation may be a change in a position of the grating in the optical path and could result in the variations in channel spectral response during flight. These findings for Wildfire may have significant bearing on future use of the MAS because of the similarities to the original Wildfire configuration.

Jedlovec, G. J.↗

In Site Analysis of a High Temperature Cure Reaction in Real Time Using Modulated Fiber-Optic FT-Raman Spectroscopy

The vibrational spectrum of a high temperature (330 C) polymerization reaction was successfully monitored in real time using a modulated fiber-optic FT-Raman spectrometer. A phenylethynyl terminated monomer was cured, and spectral evidence for two different reaction products was acquired. The products are a conjugated polyene chain and a cyclized trimer. This is the first report describing the use of FT-Raman spectroscopy to monitor a high temperature (greater than 250 C) reaction in real time.

Cooper, John↗

Nano-Bio Quantum Technology for Device-Specific Materials

The areas discussed are still under development: I. Nano structured materials for TE applications a) SiGe and Be.Te; b) Nano particles and nanoshells. II. Quantum technology for optical devices: a) Quantum apertures; b) Smart optical materials; c) Micro spectrometer. III. Bio-template oriented materials: a) Bionanobattery; b) Bio-fuel cells; c) Energetic materials.

Choi, Sang H.↗

Spectrally and Radiometrically Stable Wide-Band on Board Calibration Source for In-Flight Data Validation in Imaging Spectroscopy Applications

The quality of the quantitative spectral data collected by an imaging spectrometer instrument is critically dependent upon the accuracy of the spectral and radiometric calibration of the system. In order for the collected spectra to be scientifically useful, the calibration of the instrument must be precisely known not only prior to but during data collection. Thus, in addition to a rigorous in-lab calibration procedure, the airborne instruments designed and built by the NASA/JPL Imaging Spectroscopy Group incorporate an on board calibrator (OBC) system with the instrument to provide auxiliary in-use system calibration data. The output of the OBC source illuminates a target panel on the backside of the foreoptics shutter both before and after data collection. The OBC and in-lab calibration data sets are then used to validate and post-process the collected spectral image data. The resulting accuracy of the spectrometer output data is therefore integrally dependent upon the stability of the OBC source. In this paper we describe the design and application of the latest iteration of this novel device developed at NASA/JPL which integrates a halogen-cycle source with a precisely designed fiber coupling system and a fiber-based intensity monitoring feedback loop. The OBC source in this Airborne Testbed Spectrometer was run over a period of 15 hours while both the radiometric and spectral stabilities of the output were measured and demonstrated stability to within 1% of nominal.

visible spectrometers↗

Micro spectrometer for parallel light and method of use

A spectrometer system includes an optical assembly for collimating light, a micro-ring grating assembly having a plurality of coaxially-aligned ring gratings, an aperture device defining an aperture circumscribing a target focal point, and a photon detector. An electro-optical layer of the grating assembly may be electrically connected to an energy supply to change the refractive index of the electro-optical layer. Alternately, the gratings may be electrically connected to the energy supply and energized, e.g., with alternating voltages, to change the refractive index. A data recorder may record the predetermined spectral characteristic. A method of detecting a spectral characteristic of a predetermined wavelength of source light includes generating collimated light using an optical assembly, directing the collimated light onto the micro-ring grating assembly, and selectively energizing the micro-ring grating assembly to diffract the predetermined wavelength onto the target focal point, and detecting the spectral characteristic using a photon detector.

Park, Yeonjoon↗

Methane on Mars: New Insights into the Sensitivity of CH4 with the NOMAD/ExoMars Spectrometer Through Its First In-Flight Calibration

The Nadir and Occultation for MArs Discovery instrument (NOMAD), onboard the ExoMars Trace Gas Orbiter (TGO) spacecraft was conceived to observe Mars in solar occultation, nadir, and limb geometries, and will be able to produce an outstanding amount of diverse data, mostly focused on properties of the atmosphere. The infrared channels of the instrument operate by combining an echelle grating spectrometer with an Acousto- Optical Tunable Filter (AOTF). Using in-flight data, we characterized the instrument performance and parameterized its calibration. In particular: an accurate frequency calibration was achieved, together with its variability due to thermal effects on the grating. The AOTF properties and transfer function were also quantified, and we developed and tested a realistic method to compute the spectral continuum transmitted through the coupled grating and AOTF system. The calibration results enabled unprecedented insights into the important problem of the sensitivity of NOMAD to methane abundances in the atmosphere. We also deeply characterized its performance under realistic conditions of varying aerosol abundances, diverse albedos and changing illumination conditions as foreseen over the nominal mission. The results show that, in low aerosol conditions, NOMAD single spectrum, 1σ sensitivity to CH4 is around 0.33 ppbv at 20 km of altitude when performing solar occultation's, and better than 1 ppbv below 30 km. In dusty conditions, we show that the sensitivity drops to 0 below 10 km. In Nadir geometry, results demonstrate that NOMAD will be able to produce seasonal maps of CH4 with a sensitivity around 5 ppbv over most of planet's surface with spatial integration over 5×5° bins. Results show also that such numbers can be improved by a factor of ~10 to ~30 by data binning. Overall, our results quantify NOMAD's capability to address the variable aspects of Martian climate.

Liuzzi, Giuliano↗

Above-Cloud Aerosol Radiative Effects based on ORACLES 2016 and ORACLES 2017 Aircraft Experiments

Determining the direct aerosol radiative effect (DARE) of absorbing aerosols above clouds from satellite observations alone is a challenging task, in part because the radiative signal of the aerosol layer is not easily untangled from that of the clouds below. In this study, we use aircraft measurements from the NASA ObseRvations of CLouds above Aerosols and their intEractionS (ORACLES) project in the southeastern Atlantic to derive it with as few assumptions as possible. This is accomplished by using spectral irradiance measurements (Solar Spectral Flux Radiometer, SSFR) and aerosol optical depth (AOD) retrievals (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research, 4STAR) during vertical profiles (spirals) that minimize the albedo variability of the underlying cloud field – thus isolating aerosol radiative effects from those of the cloud field below. For two representative cases, we retrieve spectral aerosol single scattering albedo (SSA) and the asymmetry parameter (g) from these profile measurements and calculate DARE given the albedo range measured by SSFR on horizontal legs above clouds. For mid-visible wavelengths, we find SSA values from 0.80 to 0.85 and a significant spectral dependence of g. As the cloud albedo increases, the aerosol increasingly warms the column. The transition from a cooling to a warming top-of-aerosol radiative effect occurs at an albedo value (critical albedo) just above 0.2 in the mid-visible wavelength range. In a companion paper, we use the techniques introduced here to generalize our findings to all 2016 and 2017 measurements and parameterize aerosol radiative effects.

Cloud aerosol↗

Dual Fiber Spectrometer for Highly Non-Degenerate Entanglement Source

NASA is developing quantum metrology capabilities for potential space-based quantum components in future navigation and communications systems. Innate knowledge of component operation is key for the space qualification of these components. This paper focuses on the measurement and analysis of an important characteristic of an entanglement source, the joint spectrum. We describe a spectrometer based on dispersive optical fibers and present experimental measurements of the joint spectrum of a highly non-degenerate SPDC-based entanglement source that emits entangled photons in the near-infrared and telecommunications bands. How the analysis of such a joint spectrum could be applied to the modeling and simulation of entanglement swapping operations as possible extensions of quantum networks is examined. Lastly, we discuss how the separability of the two-photon state is quantified via Schmidt decomposition and how the degree of separability impacts the spectral purity of heralded single-photon emissions.

SPDC↗

A New Linear Polarizer Design for Application in the Far-Ultraviolet Spectral Range

New mission concepts that are under consideration by NASA (such as the Polstar MIDEX mission concept) call for the design and implementation of Far Ultraviolet (FUV) polarizer technologies that have not been developed yet. A team that includes members from the NASA Goddard Space Flight Center (GSFC), Arizona State University (ASU), and Woodruff Consulting, worked on the design and development of a polarizer design that may produce extinction ratios higher than have ever been reported before in the FUV spectral range (100-200 nm). This polarizer consists of transmitting linearly polarized light through a series of reflections from a combination of two silicon carbide (SiC) and two lithium fluoride (LiF) crystals positioned at angles of incidence (relative to surface normal) close to the LiF Brewster’s angle. The performance of this polarizer concept was fabricated and tested with an existing McPherson 225 Vacuum Ultraviolet (VUV) spectrometer located in the Optics Branch at NASA-GSFC. Initial testing has shown that in the FUV spectral range, this design can produce state-of-the-art extinction ratios at the Hydrogen Lyman-Alpha (Ly-α) wavelength of 121.6 nm. A polarizer with such a performance has never been reported and it signifies a breakthrough in FUV polarization technology. The levels of effectiveness paired with the design’s compact design allows for a new polarizer capability that would one day be implemented in a future spectropolarimetry space mission. In addition, this polarizer concept could potentially be used to characterize the optical properties of new mirror coatings that will be used in a future Habitable World Observatory (HWO) mission concept as proposed by the 2020 Decadal Survey.2

Far Ultraviolet (FUV), polarimetry, instrumentatio↗

The NEID Port Adapter at WIYN: On-Sky Fast Guiding Performance

NEID (NN-explore Exoplanet Investigations with Doppler spectroscopy) is an optical, fiber-fed spectrometer installed on the WIYN 3.5m Telescope. The radial velocity precision that NEID is expected to reach requires the stellar jitter (i.e., the slight irregular movement of the stellar image induced by atmospheric turbulence, wind-shake, etc.) to be controlled within 0.05 arc-seconds 90% of the time in nominal observing conditions (i.e., 0.8-arcsecond seeing and mild winds). To achieve that, the NEID Port Adapter incorporates a fast, first-order wavefront correction system, which implements an Electron-Multiplying CCD camera and a tip/tilt piezo stage to capture and stabilize the stellar image. Here, we use on-sky data to demonstrate the performance of this system under various observing conditions.

Dan Li↗