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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Mechanical Analysis of the Short Model Magnets for the Nb $_{3}$Sn Low-$\beta$ Quadrupole MQXF

During the development of MQXF, the new Nb 3 Sn quadrupole to be used in the large hadron collider (LHC) inner triplets for the High Luminosity upgrade, three short models were tested: MQXFS1, MQXFS3, and MQXFS5. These models differ in the use of thin or thick laminations for the iron components, in the coil design, and in the superconductive strands, rod restack process (RRP) or powder in tube (PIT). In the MQXF design, the azimuthal prestress is provided at room temperature by means of the bladder-key technology, and it is further increased during the cooldown by the differential thermal contraction of the various components. Four aluminum rods provide the longitudinal prestress. Both systems allow for a flexible control of the amount of prestress applied. As a consequence, it was possible to test the models exploring different azimuthal and longitudinal prestress conditions, in an attempt to understand their impact on the magnet performances. Here, this paper studies the mechanical behavior of these short models, also providing the strain and stresses measured by means of strain gauges installed on the aluminum shell, on the winding poles and on the rods. Finally, the paper compares the measures with the results from finite element (FE) models.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Test Result of the Short Models MQXFS3 and MQXFS5 for the HL-LHC Upgrade

© 2002-2011 IEEE. In the framework of the High-Luminosity Large Hadron Collider, the installation of a new generation of quadrupole magnets is foreseen on each side of ATLAS and CMS experiments. The new magnets are based on Nb 3 Sn technology and shall be able to reach an ultimate current of 17.9 kA with a peak field of 12.3 T in the coil. In 2016 and 2017, the first two short models, called MQXFS3 and MQXFS5, have been tested at 4.2 and 1.9 K in the two new test benches at the European Organization for Nuclear Research. This paper presents the result of the quench performance of the two models; the first magnet reached nominal but failed to reach ultimate, showing detraining in one coil. MQXFS5 reached ultimate performance without any detraining phenomena, validating the PIT conductor used for the first time in this magnet program.

Bajas, Hugues↗
DOE OSTI2022

Survival, growth and tag retention of juvenile European eel ( Anguilla anguilla L.) with implanted 12 mm passive integrated transponder tags and acoustic tags

To evaluate the efficiency of tagging juvenile European eels with implanted 12 mm passive integrated transponder (PIT) tags or Eel/Lamprey acoustic transmitters (ELATs), the authors studied tag retention, survival and growth of eels (7–25 g). Experimental eels were obtained from an eel farm, tagged and then released in a series of shallow dug-out ponds with a surface area of c. 200 m 2 . Tagged and control eels were distributed evenly, with 50 tagged and 50 control eels in each of four ponds, giving a total of 200 tagged and 200 control eels mixed. After 76 days, the ponds were drained, and eels were sampled and measured. A total of 344 eels (86%) were recaptured, indicating high survival. Tag retention was 99% as only one of the recaptured PIT-tagged eels had lost the tag and none of the ELAT tagged. The results demonstrated that tagging juvenile eels >16 cm with these small tags is indeed feasible. The growth of tagged and control fish was differentiated but generally low in length and negative in mass but did not differ between the three groups.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

First Principles Determination of the Potential-of-Zero-Charge in an Alumina-Coated Aluminum/Water Interface Model for Corrosion Applications

The surfaces of most metals immersed in aqueous electrolytes have a several-nanometer-thick oxide/hydroxide surface layer. This gives rise to the existence of both metal|oxide and oxide|liquid electrotlyte interfaces, and makes it challenging to correlate atomic length-scale structures with electrochemical properties such the potential-of-zero-charge (PZC). The PZC has been shown to be correlated the onset potential for pitting corrosion. Here, we conduct large-scale Density Functional Theory and ab initio molecular dynamics to calculate the PZC of a Al(111)| γ -Al 2 O 3 (110)| water double-interface model within the context of aluminum corrosion. By partitioning the multiple interfaces involved into binary components with additive contributions to the overall work function and voltage, we predict the PZC to be -1.53 V vs SHE for this model. Furthermore, we calculate the orbital energy levels of defects like oxygen vacancies in the oxide, which are critical parameters in theories associated with pitting corrosion. We predict that the Fermi level at the PZC lies above the impurity defect levels of the oxygen vacancies, which are therefore uncharged at the PZC. From the PZC estimate, we predict the voltage needed to create oxygen vacancies with net positive charges within a flatband approximation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Review—Effects of Solution and Alloy Composition on Critical Crevice Temperature

Critical temperature for localized corrosion can be a good design parameter because localized corrosion is not likely to occur below that temperature. The critical temperature depends on alloy composition, microstructure, and environment chemistry (including its redox potential). This paper reviews the literature on critical temperature for localized corrosion, expressed either as Critical Pitting Temperature (CPT) or Critical Crevice Temperature (CCT). A history of various testing methods is presented. Different approaches for modeling the temperature of transition to active pit growth are reviewed, including probabilistic aspects of critical temperature. A semi-empirical, electrolyte-based, model is described that can be useful in predicting CCT in service environments that differ from standard laboratory test environments. The model predictions are compared to experimental data for various alloys. The effect of solvent on CCT/CPT is described briefly and future avenues of research are recommended.

02 PETROLEUM↗
DOE OSTI2023

Voltage-Dependent First-Principles Simulation of Insertion of Chloride Ions into Al/Al 2 O 3 Interfaces Using the Quantum Continuum Approximation

Experiments have shown that pitting corrosion can develop in aluminum surfaces at potentials > − 0.5 V relative to the standard hydrogen electrode (SHE). Until recently, the onset of pitting corrosion in aluminum has not been rigorously explored at an atomistic scale because of the difficulty of incorporating a voltage into density functional theory (DFT) calculations. We introduce the Quantum Continuum Approximation (QCA) which self-consistently couples explicit DFT calculations of the metal-insulator and insulator-solution interfaces to continuum Poisson-Boltzmann electrostatic distributions describing the bulk of the insulating region. By decreasing the number of atoms necessary to explicitly simulate with DFT by an order of magnitude, QCA makes the first-principles prediction of the voltage of realistic electrochemical interfaces feasible. After developing this technique, we apply QCA to predict the formation energy of chloride atoms inserting into oxygen vacancies in Al(111)/α-Al 2 O 3 (0001) interfaces as a function of applied voltage. We predict that chloride insertion is only favorable in systems with a grain boundary in the Al 2 O 3 for voltages > − 0.2 V (SHE). Here our results roughly agree with the experimentally demonstrated onset of corrosion, demonstrating QCA's utility in modeling realistic electrochemical systems at reasonable computational cost.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Quantitative Defect Analysis of Ablator Capsule Surfaces Using a Leica Confocal Microscope and a High-Density Atomic Force Microscope

High-density carbon (HDC) is being evaluated as an alternative to the current National Ignition Facility (NIF) point-design ablator material (glow discharge plasma, or GDP, plastic) due to its high density and optimal opacity, which leads to a higher implosion velocity. Chemical-vapor-deposition-coated HDC capsules have a near perfect surface figure but a microscopically rough surface. After polishing, the surface becomes smooth at nanometer scales but has numerous micron-sized surface pits, whose volumes, morphology, and distribution must be quantified to guide NIF target selection. Traditional metrology tools for GDP surface defects, such as the atomic force microscope (AFM) based Spheremapper and a phase-shifting differential interferometer, lack the resolution to characterize these localized features. In this paper, we describe how this metrology challenge is met by developing automated surface metrology solutions based on a high-density (HD) AFM and a Leica confocal microscope. Furthermore, these tools are complementary in nature. HD-AFM has a 0.1-μm spatial resolution and determines the overall shape distortion and pit statistics by tracing great circles on a capsule with high throughput.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Floodplain statement of findings for corrective actions in Potrillo Canyon technical area-36, Los Alamos National Laboratory, Los Alamos, New Mexico

In 2014, baseline storm water monitoring samples for Potrillo Canyon Sample Management Area at Los Alamos National Laboratory (LANL) exceeded the National Pollutant Discharge Elimination System Individual Permit No. NM0030759 target action level (TAL) of 15 picocuries per liter (pCi/L) for gross-alpha radioactivity (393 pCi/L) and a TAL of 30 pCi/L for radium-226 and radium-228 (95.9 pCi/L). Consequently, erosion control measures within the management area are proposed to minimize sediment migration, a corrective action under the permit that is a requirement of the New Mexico Environment Department consent decree and a good management practice to limit off-site sediment migration. The area proposed for erosion controls consists of portions of Technical Area 36 that were used as firing sites primarily involving high explosives (HE) and metal (e.g., depleted uranium, lead, copper, aluminum, and steel), small-explosives experiments and burn pits (burn pits were used for burning and disposal of test debris). In addition, underground explosive tests at an approximate depth of 100 feet were also conducted. These watershed-based storm water controls will focus on addressing erosion occurring within the floodplain through mitigating and reducing both current and future channelization and head cutting.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Effects of Laser Etching on the Corrosion Susceptibility of SAVY 4000 and Hagan Containers

Since the late 1990’s, the Hagan container was used as the primary container for packaging of plutonium-bearing materials. The Hagan design consisted of a threaded closure, a Viton® ORing, a carbon-carbon filter, and a 304L stainless steel (SS) body. Over the years, Hagans have shown vulnerability in their design [1]. In 2008, The Department of Energy (DOE) issued DOE M 441.1-1, Nuclear Material Packaging Manual, which detailed an approach to obtain highconfidence in containers by including specific design requirements, material contents and an approach to determine life span from said contents, and surveillance techniques [2]. In response to both the vulnerability issues with the Hagan and DOE M 441.1-1, the SAVY 4000 container with its twist style closure, Viton® O-Ring, Fiberfrax-Gortex filter, and annealed 316L SS body, was designed as the replacement for Hagan containers, but only for a short term lifespan of 5 years [1]. However, both the Hagan and SAVY 4000 are being pushed to maintain a lifespan of 40 years. Therefore, proper confidence must be placed on each component of each container to last a minimum of 40 years. So far, the biggest concern found during surveillance of these containers is corrosion and the potential for failure by corrosion. One concern is that the containers fail due to stress corrosion cracking (SCC), especially around the weld between the collar and the body as welds leave residual stresses. One advantage the SAVY 4000 has is that the body is annealed, but its weld is still susceptible as it was welded after annealing [3, 4]. Moreover, 316L SS is known to have a higher pitting resistance (pits are a precursor to SCC and can also lead to extensive failure of the material), than 304L SS [4]. During recent surveillance activities, two SAVY 4000’s containing Solution Assay Instrument (SAI) solutions were opened. The SAI SAVY 4000’s contained plutonium (Pu) in 3M HCl solution in plastic volumetric flasks placed inside of polyethylene bags. Historically, a SAVY 4000 containing an SAI solution is packaged for 3 weeks, however, these particular containers were not reopened until 14 months later. When opened, brown-red corrosion product was found all over the inside of the container as shown in Figure 1.

36 MATERIALS SCIENCE↗
DOE OSTI2017

FY17 Status Report: Research on Stress Corrosion Cracking of SNF Interim Storage Canisters.

This progress report describes work done in FY17 at Sandia National Laboratories (SNL) to assess the localized corrosion performance of container/cask materials used in the interim storage of spent nuclear fuel (SNF). Of particular concern is stress corrosion cracking (SCC), by which a through-wall crack could potentially form in a canister outer wall over time intervals that are shorter than possible dry storage times. Work in FY17 refined our understanding of the chemical and physical environment on canister surfaces, and evaluated the relationship between chemical and physical environment and the form and extent of corrosion that occurs. The SNL corrosion work focused predominantly on pitting corrosion, a necessary precursor for SCC, and process of pit-to-crack transition; it has been carried out in collaboration with university partners. SNL is collaborating with several university partners to investigate SCC crack growth experimentally, providing guidance for design and interpretation of experiments.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Microstructural Modeling of Dynamic Intergranular and Transgranular Fracture Modes in Zircaloys

In this time period, we have continued to focus on (i) refining the thermo-mechanical fracture model for zirconium (Zr) alloys subjected to large deformations and high temperatures that accounts for the cracking of ZrH and ZrH2 hydrides, (ii) formulating a framework to account intergranular fracture due to iodine diffusion and pit formation in grain-boundaries (GBs). Our future objectives are focused on extending to a combined population of ZrH and ZrH2 populations and understanding how thermo-mechanical behavior affects hydride reorientation and cracking. We will also refine the intergranular failure mechanisms for grain boundaries with pits.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Magnetostrictive Cold Spray Sensor Feasibility Assessment

Ultrasound sensors and inspection systems are frequently used to generate acoustic waves in metal structures capable of detecting and characterizing cracks, pits, erosion, inclusions, weld anomalies, and other material and structural features. One significant problem with piezoelectric transducers is the difficulty to achieve good coupling between the transducer and the surface being examined. This is particularly true in harsh conditions with high temperatures, cyclical hot and cold temperatures, highly radioactive fields found near nuclear reactors or spent nuclear fuel, caustic or corrosive fluids, and other extreme environmental conditions, as well as in long-term monitoring applications where repair or replacement of the sensor is difficult or expensive. Typically, coupling between the surface and the transducer is achieved with water, gel, grease, viscous shear coupling material, or pressure, which might not be possible or appropriate for long-term applications in which the impedance -matching materials wear away, evaporate, or simply stop functioning due to changes in surface conditions. Fluid couplings can evaporate or drain away from the transducer-substrate interface; glue- based couplings may foul or fail and are notoriously unreliable at high temperatures and in radioactive environments. This work explores the behavior of a magnetostrictive cold-spray patch that is metallurgically bonded to a stainless steel inspection target surface, and compares it to the performance of a standard adhesively-bonded ferrous-cobalt magnetostrictive strip solution. Cold-spray is a coating process where 10 –100 micron diameter powdered metal is accelerated to Mach 2 to Mach 3 (2–3 × speed of sound) and impacted on the surface to be coated. Each powder particle forms a kinetic bond with the substrate or other coating particles to produce a metallurgically bonded layer. If the powder is nickel or cobalt with high magnetostrictive coefficients, this surface can serve as the base of a magnetostrictive sensor suitable for crack or pitting-damage inspection and monitoring that is not subject to temporal or environmental degradation.

47 OTHER INSTRUMENTATION↗
DOE OSTI2018

Hanford Double Shell Waste Tank Corrosion Studies - Final Report FY2017

Corrosion studies of Hanford Double-Shell Tanks (DSTs) at Savannah River National Laboratory (SRNL) were focused on New Limits testing using statistically design matrices for a high concentration of hydroxide (1.2 M) and testing at various interior points to establish corrosion control guidelines towards pitting corrosion. Ammonia was also added into the statistical design to determine inhibition effects. Additional electrochemical studies of individual organic species and nitrous oxide were tested in a AN-102 based simulant with no organics to compare inhibiting properties of a specific specie and measure any electrochemical improvement towards pitting corrosion.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Broad Scope Analysis of the MOX Fuel Fabrication Facility and Disposition of Plutonium

The Plutonium Management and Disposition Agreement (PMDA), signed into effect in 2000, between the United States and Russia, was made in a post-Cold War effort to dispose of military-useable material, a combined 68 metric tons of weapon-grade plutonium. The United States has been pursuing a disposition path through conversion to MOX fuel for use in current commercial nuclear reactors. The Savannah River Site’s (SRS) MOX Fuel Fabrication Facility (MFFF, the MOX facility) began construction in 2007 with intent to uphold the United States’ half of the agreement. In the FY2017 budget, the Obama administration proposed a termination of the MFFF after lack of sufficient funding to the project, which caused paralyzing delays and drastically inflated costs for completion. Prolonged construction, piled costs, and divergent policies between shifting administrations have resulted in turmoil between the United States and Russia, culminating with the proposed abandonment of the MOX disposition path and being used as a justification by Russia to withdraw from the agreement until the United States is able to identify a clear plan, fulfilling the requirements set forth by the PMDA. The leading expedient to replace MOX fuel is the dilute and dispose method, which leaves uncertainty for the SRS MFFF and places reliance on New Mexico’s Waste Isolation Pilot Plant (WIPP) to legally accommodate the additional and unaccounted waste. If the current capacity of WIPP proves insufficient, construction of a new repository for transuranic waste would only incur additional costs and regulatory burdens, along with extreme schedule delays. Future proposed adaptations of the SRS MFFF include pit production, which would require complex and costly alterations to be operational at the current site. Restrictions from Congress, such as mandating the proposed solution to abandoning MFFF must equal half of the costs required for completing the facility, have fueled severely underestimated quotations of these alternatives. The increasing pressure from both Russia and South Carolina government officials to make a decision could result in the pursuit of another doomed project, leaving the United States with even further sunk costs and strained international relations. This paper will summarize the involved history of the MFFF, explicate the recourses to salvage the facility for pit production, and provide postulation on the dilute and dispose method.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2018

Recent Progress with APC Nb 3 Sn Conductors [Slides]

1.Development of APC-PIT multi wires started in 2017. Since then progress has been fast; 2.Tests up to 31 T at 4.2 K show that B irr is 26-27 T, B c2 is 27-28 T, ~1-2 T higher than RRP; 3. R&D in the past two years has led to significant improvement of wire recipe and quality. The non-Cu J c is on similar level with present RRP wires, in spite that the Nb 3 Sn % is still low and grain size is not fully refined due to unoptimized wire recipe and heat treatment; 4.The Nb 3 Sn layer J c at 16 T is ~2.5 times of RRP despite grain size not fully refined; 5.The improvement is still ongoing. The following levels are expected: 1) By improving conductor recipe and quality and heat treatment, the fine-grain Nb 3 Sn fraction can be increased to ~40%, as in standard tube type and PIT wires; 2) By optimizing O content and heat treatment, the grain size can be reduced to 50-65 nm or less, which leads to a Nb 3 Sn layer J c of 5000-6000 A/mm 2 for 4.2 K, 16 T. If so, this means the 4.2 K, 16 T non-Cu Jc can reach 2000-2400 A/mm 2 . This will surpass the FCC spec and also provide >30% margin. Above 16 T, the APC conductors should give extra Jc gain due to higher B irr and shift in F p -B curve peak to higher fields.

43 PARTICLE ACCELERATORS↗
DOE OSTI2016

SNL API-653 In-Service Tank Inspection and Evaluation Tank ID: 981-A2-T0 (West)

An API Standard 653 In-Service inspection was completed on Tank 981-A2-T0 (West) located at the Sandia National Laboratories TAIV tank farm in Albuquerque, NM on September 22, 2015. The inspection was completed to collect data to evaluate the mechanical integrity and fitness for continued service of the tank. No indication or records of any previous inspection were identified for this tank. The inspection and engineering evaluation were completed using API-653, 5 th Edition and conservative engineering practices. The tank was not removed from service, so an internal inspection could not be completed. The tank was also fully insulated. The insulation was removed in specified areas of the tank shell and tank chime to accommodate an acoustic emission scan of the tank and an ultrasonic thickness evaluation of portions of the tank. The acoustic emission scan resulted in a grade of B / I - II indicating an overall TANKPAC grade B and composite grade II indicating minor active damage with highly concentrated sources related to corrosion found in the southeast and west side section of the tank. Eight Potential Localized Damage sources were found mainly in the west side (re-test in 2 years). The tank chime could not be inspected due to the configuration of the insulation welded angle support. An ultrasonic guided bulk wave inspection was completed on the tank shell to assess the lower shell section. At the time of the inspection the limited data collected showed minimal material loss from the shell at the thickness monitoring locations, however, visual inspection and pit depth gauge measurements showed > 3/16” inch pitting and significant general external surface corrosion on the shell at the shell to floor joint. This corrosion is caused by the insulation sheeting support welded angle iron trapping moisture and dirt against the tank shell. This tank should be removed from service, internally inspected, and repaired. Ultrasonic thickness measurement locations were established on this tank and the data is included in this report. The limited data collected indicated minimal material loss at these locations, with the only noted corrosion occurring on the tank shell to floor joint as noted above. An API-653 Annex B Evaluation of Tank Bottom Settlement was completed and the results are included in this report. No significant settlement issues were identified.

42 ENGINEERING↗
DOE OSTI2019

Benchmarking 3D-MHD simulations of electrothermal instability growth by studying z-pinches with engineered defects

The electrothermal instability (ETI) is driven by Joule heating and arises from the dependence of resistivity on temperature. ETI may drive azimuthally correlated surface density variations which seed magneto Rayleigh-Taylor (MRT) instability growth. Liner implosion studies suggest that dielectric surface coatings reduce the amplitude of ETI driven perturbations. Furthermore, previous fundamental physics studies suggest that non-metallic inclusions within the metal can seed ETI growth. In this project, we aimed to (1) determine how dielectric coatings modify ETI growth by varying the coating thickness and the surface structure of the underlying metal, and (2) study overheating from engineered defects—designed lattices of micron-scale pits. Engineered pits divert current density and drive local overheating in a way that can be compared with 3DMHD simulations. All experiments were executed on the Sandia Mykonos Facility. Facility and diagnostic investments enabled high quality data to be gathered in support of project deliverables.

42 ENGINEERING↗
DOE OSTI2020

ARIES team achieves major milestone in support of nonproliferation

The Advanced Recovery and Integrated Extraction System (ARIES) Program is a great example of LANL’s Weapons and Global Security programs working together to achieve important nuclear security mission goals. Executed at PF-4, a facility better known for its pit production mission, the ARIES Program is helping the nation meet its nonproliferation commitments by preparing surplus weapons-grade plutonium for final disposition. ARIES recently met a major milestone of producing 1 metric ton of plutonium oxide from material removed from surplus pits. The milestone was celebrated in an awards ceremony at LANL on January 28.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗