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At least 343 records · Page 19

Semiconductor Crystal Growth in Static and Rotating Magnetic fields

Magnetic fields have been applied during the growth of bulk semiconductor crystals to control the convective flow behavior of the melt. A static magnetic field established Lorentz forces which tend to reduce the convective intensity in the melt. At sufficiently high magnetic field strengths, a boundary layer is established ahead of the solid-liquid interface where mass transport is dominated by diffusion. This can have a significant effect on segregation behavior and can eliminate striations in grown crystals resulting from convective instabilities. Experiments on dilute (Ge:Ga) and solid solution (Ge-Si) semiconductor systems show a transition from a completely mixed convective state to a diffusion-controlled state between 0 and 5 Tesla. In HgCdTe, radial segregation approached the diffusion limited regime and the curvature of the solid-liquid interface was reduced by a factor of 3 during growth in magnetic fields in excess of 0.5 Tesla. Convection can also be controlled during growth at reduced gravitational levels. However, the direction of the residual steady-state acceleration vector can compromise this effect if it cannot be controlled. A magnetic field in reduced gravity can suppress disturbances caused by residual transverse accelerations and by random non-steady accelerations. Indeed, a joint program between NASA and the NHMFL resulted in the construction of a prototype spaceflight magnet for crystal growth applications. An alternative to the suppression of convection by static magnetic fields and reduced gravity is the imposition of controlled steady flow generated by rotating magnetic fields (RMF)'s. The potential benefits of an RMF include homogenization of the melt temperature and concentration distribution, and control of the solid-liquid interface shape. Adjusting the strength and frequency of the applied magnetic field allows tailoring of the resultant flow field. A limitation of RMF's is that they introduce deleterious instabilities above a critical magnetic field value. Growth conditions in which static magnetic fields rotational magnetic fields, and reduced gravitational levels can have a beneficial role will be described.

Volz, Martin↗

Drift shell splitting by internal geomagnetic multipoles.

Computations on an 80-coefficient model of the earth's field illustrate the 'topography' of the magnetic equatorial surface and the geometry of the drift shells of geomagnetically trapped particles. Individual terms in the spherical harmonic expansion of the geomagnetic scalar potential V(r, theta, phi) are either even or odd in cos theta, where theta = 90 deg denotes the dipole equator. Terms that are even in cos theta tend to 'warp' the equatorial surface, but do not (in first order) distort particle drift shells radially nor split the drift shells of particles having different equatorial pitch angles. Azimuthally asymmetric terms that are odd in cos theta do cause shell splitting in first order. Shell splitting at large L values (neglecting deformation of the earth's field by the solar wind) is found to be dominated by the geomagnetic octupole. At L approximately equal to 1, shell splitting is strongly enhanced by the South American and South African anomalies. When combined with pitch angle diffusion caused by atmospheric scattering, these results may be able to account for anomalous radial diffusion of inner zone electrons.

Roederer, J. G.↗

Effects of low-frequency voltage on nonlinear standing wave excitation, plasma uniformity, and ion dynamics in dual-frequency asymmetric capacitive discharges

Abstract It is known that in very-high-frequency (VHF) capacitively coupled plasmas, the higher harmonics generated by nonlinear sheath motion can enhance the standing wave effect (SWE), which can lead to center-peaked plasma density profiles. In this work, an improved nonlinear electromagnetic model incorporating a transmission line model, an electron momentum balance model, a bulk plasma model, a collisionless nonlinear numerical sheath model, and an ion Monte-Carlo collision (MCC) model is developed to study the effects of low-frequency (LF) voltage V L on the nonlinear standing wave excitation, plasma uniformity, and ion energy and angular distribution functions (IEDFs and IADFs) in dual-frequency (DF) asymmetric capacitive argon discharges at relatively low pressure of 3 Pa. The plasma diffusion in the radial direction and ion dynamics within the LF oscillating sheath are self-consistently considered. The LF voltage V L at 2 MHz varies from 0 to 700 V while the HF voltage V H at 60 MHz is fixed at 100 V. Simulation results indicate that without the addition of an LF source (i.e. V L = 0 V), there are a considerable number of high-order harmonics with short wavelengths, leading to significant SWE and central peak in the radial plasma density profile. Nevertheless, the high-order harmonic excitations tend to be weakened and merely occur around the phase of the full LF sheath collapse due to a shorter characteristic damping time of the surface waves as V L increases. This, combined with increased surface wavelengths of both the driving frequency and the higher harmonics at a higher V L , leads to suppressed standing waves and improved plasma uniformity. Meanwhile, the simulations show that both the low and the high energy peaks of IEDF move towards higher energies, and the energy peak separation width ΔEbecomes wider with the increase of V L . The IEDF at the radial center of the powered electrode exhibits a broader ΔEthan that at the edge. For the IADF, an increased V L results in more ions incident on the electrode with a smaller deflection angle. Because of a thinner sheath and a higher sheath voltage at the electrode center, the peak value of IADF at the electrode center is greater than that at the edge.

Physics↗

VERA and VERA-EDU 3.5 Release Notes

The Virtual Environment for Reactor Applications components included in this distribution include selected computational tools and supporting infrastructure that solve neutronics, thermal-hydraulics, fuel performance, and coupled neutronics-thermal hydraulics problems. The infrastructure components provide a simplified common user input capability and provide for the physics integration with data transfer and coupled-physics iterative solution algorithms. Neutronics analysis can be performed for 2D lattices, 2D core and 3D core problems for pressurized water reactor geometries that can be used to calculate criticality and fission rate distributions by pin for input fuel compositions. MPACT uses the Method of Characteristics transport approach for 2D problems. For 3D problems, MPACT uses the 2D/1D method which uses 2D MOC in a radial plane and diffusion or SPn in the axial direction. MPACT includes integrated cross section capabilities that provide problem-specific cross sections generated using the subgroup methodology. The code can be executed both 2D and 3D problems in parallel to reduce overall run time. A thermal-hydraulics capability is provided with CTF (an updated version of COBRA-TF) that allows thermal-hydraulics analyses for single and multiple assemblies using the simplified VERA common input. This distribution also includes coupled neutronics/thermal-hydraulics capabilities to allow calculations using MPACT coupled with CTF. The VERA fuel rod performance component BISON calculates, on a 2D or 3D basis, fuel rod temperature, fuel rod internal pressure, free gas volume, clad integrity and fuel rod waterside diameter. These capabilities allow simulation of power cycling, fuel conditioning and deconditioning, high burnup performance, power uprate scoping studies, and accident performance. Input/Output capabilities include the VERA Common Input (VERAIn) script which converts the ASCII common input file to the intermediate XML used to drive all of the physics codes in the VERA Core Simulator (VERA-CS). VERA component codes either input the VERA XML format directly, or provide a preprocessor which can convert the XML into native input. VERAView is an interactive graphical interface for the visualization and engineering analyses of output data from VERA. The python-based software is easy to install and intuitive to use, and provides instantaneous 2D and 3D images, 1D plots, and alpha-numeric data from VERA multi-physics simulations. Testing within CASL has focused primarily on Westinghouse four-loop reactor geometries and conditions with example problems included in the distribution.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

In situ observations of Io torus plasma

The physical properties of the Io plasma formation deduced from in situ observations are described. The torus plasma is characterized by spatially distinct regions with steep gradients in plasma parameters between them. The innermost region has a cool plasma which collapses toward the centrifugal equator and gives rise to a distinctive localized concentration of plasma well inside of Io's orbit. The next region has a warm plasma which includes the L-shell of Io and is the presumed injection region of the plasma. Other regions, known as the plasma ledge and ramp, are described. The changes in plasma characteristics are accounted for by centrifugally driven flux tube interchange diffusion to provide radial mass transport. The ramp is shown to result from impoundment of the plasma by the inner edge of the energetic particle population. It is also shown how the power required to excite the ultraviolet emissions of the torus and the Jovian aurora determines the rate at which new plasma is fed into the torus.

Sullivan, J. D.↗

Catalytic Combustion of Propane/Air Mixtures on Platinum

A honeycomb catalyst of platinum (4.2 kg/cu m loading) over cordierite, with gamma-alumina washcoat, a cross section of 2.4 x 2.4 sq cm, a length of 7.6 cm, and a characteristic channel diameter of 1.4 mm is used as a steady flow reactor. Measurements are made with C3H8/air mixtures at 650 to 800 K inlet temperatures, 110 KPa pressure, 10 to 40 m/s inlet velocity, 0.19 to 0.32 equivalence ratios, and approximately 1.5 mole percent water content. The measured quantities are the substrate tempeature at ten axial locations, the exhaust gas temperature, the exhaust concentrations of CO, CO2, O2, and total hydrocarbons, and the pressure drop across the monolith. The measured quantities are compared with those computed with a two-dimensional steady-state model for axial and radial convection and diffusion of mass, momentum, energy and homogeneous (three overall reactions) and heterogeneous (infinitely fast) reactions. It is found that, under the tested conditions, most of the fuel is converted to CO2 and H2O at the surface. Gas-phase reactions tend rapidly to become more important as the temperature and equivalence ratio are increased and the flow velocity is decreased. Surface fuel conversion is much more rapid than fuel diffusion, resulting in diffusion-controlled oxidation.

Bruno, C.↗

Particle transport in planetary magnetospheres

Particle energization in Earth's and Jupiter's magnetospheres is discussed. Understanding of the large scale magnetic and electric fields in which charged particles move is reviewed. Orbit theory in the adiabatic approximation is sketched. General conditions for adiabatic breakdown at each of three levels of periodicity are presented. High energy losses and lower energy sources argue for the existence of magnetospheric accelerations. Nonadiabatic acceleration processes are mentioned. Slow diffusive energization by particle interactions with electromagnetic fluctuations is outlined. This mechanism seems adequate at Earth but, operating alone, is unconvincing for Jupiter. Adding spatial diffusion in the radially distended Jovian magnetodisk may resolve the difficulty.

Birmingham, T. J.↗

On the structure of gaseous confined laminar diffusion flames: Numerical investigation

The structure and characteristics of gaseous confined laminar diffusion flames are investigated by numerically solving the time-dependent two-dimensional axisymmetric conservation equations. The numerical model accounts for the important chemical and physical processes involved, including axial diffusion, viscous effects, radial convection, and finite-rate chemistry. The numerical results clearly show that the flame has a finite thickness and leakage of fuel vapor into the flame zone is possible. The effect of heat release is found to induce some radial flow. Predicted flame shape and dimensions are compared to the classical Burke-Schumann flame. The numerically calculated flame is observed to be about 15 percent taller and 5 percent narrower than that of the Burke-Schumann solution under the same conditions.

Mawid, M. A.↗

Experiment 1: Orbital Processing of High-Quality Zn-Alloyed CdTe Compound Semiconductors

Zinc-alloyed cadmium telluride (Zn:CdTe) crystals were grown in unit gravity and in microgravity for comparative analysis. Two crystals were grown on USML-1/STS-50 in 1992, and two additional crystals were grown on USML-2/STS-73 in 1995. The Crystal Growth Furnace (CGF) in the seeded Bridgman-Stockbarger crystal growth geometry was utilized on both missions. Crystals grown on USML-1/STS-50 were found to have solidified with partial wall contact due to the near-absence of the hydrostatic pressure in microgravity, a residual g-vector that was not axial, and the nonwetting sample/ampoule wetting conditions. Crystals grown on USML-2/STS-73 included: a sample/ampoule identical to the USML-1/STS-73 sample/ampoule, with the addition of a restraining spring to simulate hydrostatic pressure internally, and a tapered ampoule which accomplished 2.2 cm of crystal growth without wall contact. Infrared transmission of all ground and flight samples was found to be 63-66 percent, very close to the theoretical 66 percent, suggesting good stoichiometric control. Infrared microscopy confirmed that the primary precipitates were Te and their size (1-10 microns) and density suggested that the flight- and ground-base samples experienced similar thermal histories. Longitudinal macrosegregation, calculated using scaling analysis, was predicted to be low. Nearly diffusion controlled growth was achieved even in unit gravity and macrosegregation data could be fit with a diffusion controlled model. Radial segregation was monitored and was found to vary with fraction solidified, particularly through the shoulder region, where the sample cross section was varying significantly. It was also disturbed in the flight samples in regions where asymmetric wall contact was noted. In regions where a steady state was established, the radial segregation was invariant within our experimental measurement error. Flight samples were found to be much higher in structural perfection than samples processed in unit gravity under identical growth conditions. In regions where solidification had occurred without wall contact, the free surfaces evidenced virtually no twinning, although twins appeared in the flight samples in regions of wall contact and were pervasive in the ground samples. These results were confirmed using optical microscopy and synchrotron x-ray white beam topography. Full-width half-maximum rocking curve widths (FWHM), recorded in arc-seconds, were significantly reduced from 20 a-s (1 g) to 9 a-s (micro-g) for the best regions of the crystals. The 9 a-s (FWHM) rocking curve value in the unconfined flight samples equals the best value reported terrestrially for this material. The ground samples exhibited a fully developed (111)[110] dislocation mosaic structure, whereas dislocations within the flight samples were discrete and no mosaic structure was evident. The defect density was quantitatively reduced from 75,000 (1 g) to 800 (micro-g) +/-50 percent. Dislocation etch pit density results were confirmed using transmission synchrotron white beam and monochromated beam topography. The low defect density is thought to have resulted from the near absence of hydrostatic pressure, which allowed the molten boule to solidify with little or no wall contact. This minimized the transfer of hoop stresses during solidification and post-solidification processing.

Larson, D. J., Jr.↗

The Role of Ring Current on Slot Region Penetration

During magnetic quiet times, the inner belt, slot region and the outer belt are well defined regions. However, during some major storms, outer belt particles penetrate inward and significantly fill the slot region. In some extreme events, the outer belt particles travel through the slot and create a new belt in the inner region that persists from months to years. In this paper, we examine the role of the ring current on this radiation belt penetration into the slot region. The storm-time intensification of the ring current produces strong magnetic depression in the inner magnetosphere. This perturbation and its fluctuation enhance the radial transport and diffusion of the outer radiation belt particles. We perform kinetic and test-particle calculations to quantitatively assess the effects of the ring current field on filling of the slot region. Simulation results during major storms will be presented and discussed.

Fok, Mei-Ching↗

Is diffuse intracluster light a good tracer of the galaxy cluster matter distribution?

We explore the relation between diffuse intracluster light (central galaxy included) and the galaxy cluster (baryonic and dark) matter distribution using a sample of 528 clusters at 0.2 ≤ z ≤ 0.35 found in the Dark Energy Survey (DES) Year 1 data. The surface brightness of the diffuse light shows an increasing dependence on cluster total mass at larger radius, and appears to be self-similar with a universal radial dependence after scaling by cluster radius. We also compare the diffuse light radial profiles to the cluster (baryonic and dark) matter distribution measured through weak lensing and find them to be comparable. The IllustrisTNG galaxy formation simulation, TNG300, offers further insight into the connection between diffuse stellar mass and cluster matter distributions – the simulation radial profile of the diffuse stellar component does not have a similar slope with the total cluster matter content, although that of the cluster satellite galaxies does. Regardless of the radial trends, the amount of diffuse stellar mass has a low-scatter scaling relation with cluster’s total mass in the simulation, out-performing the total stellar mass of cluster satellite galaxies. We conclude that there is no consistent evidence yet on whether or not diffuse light is a faithful radial tracer of the cluster matter distribution. Nevertheless, both observational and simulation results reveal that diffuse light is an excellent indicator of the cluster’s total mass.

79 ASTRONOMY AND ASTROPHYSICS↗

Turbulent drifts of impurity ions as an explanation for anomalous radial transport in the far-SOL of DIII-D

Abstract Successful fusion reactor operation relies on minimal core contamination by impurities, otherwise too much power may be radiated and harm performance. This requires reliable predictions of impurity transport from the scrape-off layer (SOL) into the core, beyond the traditional ‘anomalous’ diffusion approach. We report a set of far-SOL tungsten transport simulations that demonstrate the role of turbulent drifts on radial impurity transport. A turbulent plasma background is simulated using the gyrokinetic SOL code Gkeyll. Tungsten ions are followed within the plasma background using only their drifts. We find that tungsten tends to travel radially outwards with velocities between v r = 300–1200 m s −1 primarily due to polarization drift. We also extract an anomalous radial diffusion coefficient that varies from D r anom = 5–20 m 2 s −1 . These results are compared to and agree with previous interpretive modeling results. We also show how the turbulent polarization drift can transport some tungsten ions from the wall inwards with effective pinch velocities up to 10 000 m s −1 . We conclude that turbulent drifts are a likely explanation for historically anomalous radial impurity transport.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Dust transport in MRI turbulent disks: Ideal and non-ideal MHD with ambipolar diffusion

We study dust transport in turbulent protoplanetary disks using three-dimensional global unstratified MHD simulations including Lagrangian dust particles. The turbulence is driven by the magnetorotational instability (MRI) with either ideal or non-ideal MHD that includes ambipolar diffusion (AD). In ideal MHD simulations, the surface density evolution (except for dust that drifts fastest), turbulent diffusion, and vertical scale height of dust can all be reproduced by simple one-dimensoinal and/or analytical models. However, in AD dominated simulations which simulate protoplanetary disks beyond 10s of AU, the vertical scale height of dust is larger than previously predicted. To understand this anomaly in more detail, we carry out both unstratified and stratified local shearing box simulations with Lagrangian particles, and find that turbulence in AD dominated disks has very different properties (e.g., temporal autocorrelation functions and power spectra) than turbulence in ideal MHD disks, which leads to quite different particle diffusion efficiency. For example, MRI turbulence with AD has a longer correlation time for the vertical velocity, which causes significant vertical particle diffusion and large dust scale height. In ideal MHD the Schmidt numbers (Sc) for radial and vertical turbulent diffusion are Sc{sub r}∼1 and Sc{sub z}≳3, but in the AD dominated regime both Sc{sub r} and Sc{sub z} are ≲1. Particle concentration in pressure bumps induced by MRI turbulence has also been studied. Since non-ideal MHD effects dominate most regions in protoplanetary disks, our study suggests that modeling dust transport in turbulence driven by MRI with non-ideal MHD effects is important for understanding dust transport in realistic protoplanetary disks.

79 ASTRONOMY AND ASTROPHYSICS↗

The distribution of warm ionized gas in NGC 891

Narrow-band imaging is presented of the edge-on spiral NGC 891 in the H-alpha and S II 6716, 6731 A forbidden lines. Emission from H II regions confined to the plane of the galaxy and from diffuse gas up to about 4 kpc off the plane is readily detected. The full radial extent of the diffuse emission in the plane is about 30 kpc. NGC 891 is found to have a surface density of diffuse ionized gas twice the Galactic value, a thicker ionized gas layer, and a larger surface density of ionized gas relative to neutral gas. These are interpreted as consequences of a relatively high level of star formation in this galaxy. Other star formation tracers indicate the same conclusion. Many vertical H-alpha filaments, or 'worms,' extending to over 2 kpc off the plane of the galaxy are seen. These worms are interpreted in terms of chimney models for the interstellar media of spirals.

Rand, Richard J.↗

Conduction Channel Formation and Dissolution Due to Oxygen Thermophoresis/Diffusion in Hafnium Oxide Memristors

Due to the favorable operating power, endurance, speed, and density., transition-metal-oxide memristors, or resistive random-access memory (RRAM) switches, are under intense development for storage-class memory. Their commercial deployment critically depends on predictive compact models based on understanding nanoscale physiocochemical forces, which remains elusive and controversial owing to the difficulties in directly observing atomic motions during resistive switching, Here, using scanning transmission synchrotron X-ray spectromicroscopy to study in situ switching of hafnium oxide memristors, we directly observed the formation of a localized oxygen-deficiency-derived conductive channel surrounded by a low-conductivity ring of excess oxygen. Subsequent thermal annealing homogenized the segregated oxygen, resetting the cells toward their as-grown resistance state. We show that the formation and dissolution of the conduction channel are successfully modeled by radial thermophoresis and Fick diffusion of oxygen atoms driven by Joule heating. This confirmation and quantification of two opposing nanoscale radial forces that affect bipolar memristor switching are important components for any future physics-based compact model for the electronic switching of these devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗