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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

BOREAS RSS-1 PARABOLA SSA Surface Reflectance and Transmittance Data

The BOREAS RSS-1 team collected surface reflectance and transmittance data from three forested sites in the SSA. This data set contains averaged reflectance factors and transmitted radiances measured by the PARABOLA instrument at selected sites in the BOREAS SSA at different view angles and at three wavelength bands throughout the day. PARABOLA measurements were made during each of the three BOREAS IFCs during the growing season of 1994 at three SSA tower flux sites as well as during the FFC-T. Additional measurements were made in early and mid-1996 during the FFC-W and during IFC-2. The data are stored in tabular ASCII files.

Hall, Forrest G.↗

AgRISTARS: Agriculture and Resources Inventory Surveys Through Aerospace Remote Sensing. Enumerator's manual, 1981 ground data survey

General information and administrative instructions are provided for individuals gathering ground truth data to support research and development techniques for estimating crop acreage and production by remote sensing by satellite. Procedures are given for personal safety with regards to organophosphorus insecticides, for conducting interviews for periodic observations, for coding the crops identified and their growth stages, and for selecting sites for placing rain gages. Forms are included for those citizens agreeing to monitor the gages and record the rainfall. Segment selection is also considered.

Source record↗

Mars: Periglacial Morphology and Implications for Future Landing Sites

At the Mars Phoenix landing site and in much of the Martian northern plains, there is ice-cemented ground beneath a layer of dry permafrost. Unlike most permafrost on Earth, though, this ice is not liquid at any time of year. However, in past epochs at higher obliquity the surface conditions during summer may have resulted in warmer conditions and possible melting. This situation indicates that the ice-cemented ground in the north polar plains is likely to be a candidate for the most recently habitable place on Mars as near-surface ice likely provided adequate water activity approximately 5 Myr ago. The high elevation Dry Valleys of Antarctica provide the best analog on Earth of Martian ground ice. These locations are the only places on Earth where ice-cemented ground is found beneath dry permafrost. The Dry Valleys are a hyper-arid polar desert environment and in locations above 1500 m elevation, such as University Valley, air temperatures do not exceed 0 C. Thus, similarly to Mars, liquid water is largely absent here and instead the hydrologic cycle is dominated by frozen ice and vapor phase processes such as sublimation. These conditions make the high elevation Dry Valleys a key Mars analog location where periglacial processes and geomorphic features can be studied in situ. This talk will focus on studies of University Valley as a Mars analog for periglacial morphology and ice stability. We will review a landing site selection study encompassing this information gleaned from the Antarctic terrestrial analog studies plus Mars spacecraft data analysis to identify candidate landing sites for a future mission to search for life on Mars.

Martian ground ice↗

A study of morphology, provenance, and movement of desert sand seas in Africa, Asia, and Australia

The author has identified the following significant results. Recent acquisition of generally high quality color prints for most of the test sites has enabled the project to make significant advances in preparing mosaics of sand desert areas under study. Computer enhancement of imagery of selected sites, where details of complex dune forms need to be determined, has been achieved with arrival of computer-compatible ERTS-1 tapes. Further, a comparator, recently received, gives precise visual measurements of width, length, and spacing of sand bodies and so improves comparison of patterns in various test sites. Considerable additional meteorological data recently received on sand-moving winds in China, Pakistan, Libya and other areas enabled much progress to be made in developing overlays for the dune mosaics. These data show direction, speed, and frequency of winds. Other new data for use in preparing overlays used with ERTS-1 image mosaics include ground truth on moisture control, geologic settings, and plant distribution. With the addition of visual observation data and prints from hand-held photography now being obtained by the Skylab mission, much progress in interpreting the patterns of sand seas for 17 desert sites is anticipated.

Mckee, E. D.↗

Mars Lander/Rover vehicle development: An advanced space design project for USRA and NASA/OAST

The results of the studies on one particular part of the Mars Lander/Rover (MLR) system are contained: the Balloon Rover. This component vehicle was selected for further research and design because of the lack of technical literature on this subject, as compared to surface rover technology. Landing site selection; balloon system development and deployment; optics and communications; and the payload power supply are described.

Source record↗

Multidimensional Programming Methods for Energy Facility Siting: Alternative Approaches

The use of multidimensional optimization methods in solving power plant siting problems, which are characterized by several conflicting, noncommensurable objectives is addressed. After a discussion of data requirements and exclusionary site screening methods for bounding the decision space, classes of multiobjective and goal programming models are discussed in the context of finite site selection. Advantages and limitations of these approaches are highlighted and the linkage of multidimensional methods with the subjective, behavioral components of the power plant siting process is emphasized.

Solomon, B. D.↗

Rationale for Isidis Planitia as a back-up landing site for the Mars Pathfinder mission

The present engineering constraints imposed on the Mars Pathfinder mission leave only three broad regions available for site selection: Amazonis, Chryse, and Isidis Planitia. Because of the knowledge gained by the Viking 1 mission, Chryse Planitia would make an ideal primary landing site. Geological characteristics of Isidis Planitia are discussed with a view to making it a back-up landing site.

Craddock, Robert A.↗

Enzyme-Directed Functionalization of Designed, Two-Dimensional Protein Lattices

The design and construction of crystalline protein arrays to selectively assemble ordered nanoscale materials has potential applications in sensing, catalysis and medicine. Whereas numerous designs have been implemented for the bottom-up construction of novel protein assemblies, the generation of artificial functional materials has been relatively unexplored. Enzyme-directed post-translational modifications are responsible for the functional diversity of the proteome and thus, could be harnessed to selectively modify artificial protein assemblies. In this study, we describe the use of phosphopantetheinyl transferases (PPTases), a class of enzymes that covalently modify proteins using coenzyme A (CoA), to site-selectively tailor the surface of designed, two-dimensional (2D) protein crystals. We demonstrate that a short peptide (ybbR) or a molecular tag (CoA) can be covalently tethered to 2D arrays to enable enzymatic functionalization using Sfp PPTase. Here, the site-specific modification of two different protein array platforms is facilitated by PPTases to afford both small-molecule- and protein-functionalized surfaces with no loss in crystalline order. This work highlights the potential for chemoenzymatic modification of large protein surfaces towards the generation of sophisticated protein platforms reminiscent of the complex landscape of cell surfaces.

36 MATERIALS SCIENCE↗

Dynamic conversion of solar generated heat to electricity

The effort undertaken during this program led to the selection of the water-superheated steam (850 psig/900 F) crescent central receiver as the preferred concept from among 11 candidate systems across the technological spectrum of the dynamic conversion of solar generated heat to electricity. The solar power plant designs were investigated in the range of plant capacities from 100 to 1000 Mw(e). The investigations considered the impacts of plant size, collector design, feed-water temperature ratio, heat rejection equipment, ground cover, and location on solar power technical and economic feasibility. For the distributed receiver systems, the optimization studies showed that plant capacities less than 100 Mw(e) may be best. Although the size of central receiver concepts was not parametrically investigated, all indications are that the optimal plant capacity for central receiver systems will be in the range from 50 to 200 Mw(e). Solar thermal power plant site selection criteria and methodology were also established and used to evaluate potentially suitable sites. The result of this effort was to identify a site south of Inyokern, California, as typically suitable for a solar thermal power plant. The criteria used in the selection process included insolation and climatological characteristics, topography, and seismic history as well as water availability.

Powell, J. C.↗

Ion-Electron Coupling-Driven Redox Behavior in Metal–Organic Frameworks

Redox-active metal–organic frameworks (MOFs) have long been proposed as electronic transport platforms, yet the microscopic origin of their conductivity remains debated. A theoretical demonstration reveals charge transport in a Zn(pyrazole–naphthalene diimide (NDI)) MOF arising not from delocalized band-like states but from redox hopping between discrete linker sites. Using ab initio molecular dynamics simulations combined with electronic structure analysis, we established a direct link among electron injection, structural reorganization, and transport. Electron accumulation proceeds sequentially and site-selectively from imide and carbonyl groups of the NDI core progressively involving pyrazole N atoms at higher reduction states, through a hierarchy of redox-active sites. In contrast, Zn nodes remain essentially redox-inactive, which confirms their structural role. Density-of-states analysis corroborates a transport regime dominated by linker-centered states with evolving p-character upon reduction, resulting in dynamically reconfigured conduction networks. Real-time trajectories reveal anisotropic linker-to-linker electron transfer modulated by counterion coordination. This cooperative ion–electron regime emerges from potential energy surface collapse into a single low-barrier transition (ΔG ‡ ≈ 45 meV), where ionic and electronic motions evolve adiabatically on the same free-energy landscape. Elucidating redox conductivity in Zn(pyrazole–NDI) MOFs provides a theoretical framework for use in neuromorphic computing and related technologies.

Charge transfer↗

Comparison of Satellite-Derived TOA Shortwave Clear-Sky Fluxes to Estimates from GCM Simulations Constrained by Satellite Observations of Land Surface Characteristics

Clear-sky, upwelling shortwave flux at the top of the atmosphere (S(sub TOA raised arrow)), simulated using the atmospheric and land model components of the Community Climate System Model 3 (CCSM3), is compared to corresponding observational estimates from the Clouds and Earth's Radiant Energy System (CERES) sensor. Improvements resulting from the use of land surface albedo derived from Moderate Resolution Imaging Spectroradiometer (MODIS) to constrain the simulations are also examined. Compared to CERES observations, CCSM3 overestimates global, annual averaged S(sub TOA raised arrow) over both land and oceans. However, regionally, CCSM3 overestimates S(sub TOA raised arrow) over some land and ocean areas while underestimating it over other sites. CCSM3 underestimates S(sub TOA raised arrow) over the Saharan and Arabian Deserts and substantial differences exist between CERES observations and CCSM3 over agricultural areas. Over selected sites, after using groundbased observations to remove systematic biases that exist in CCSM computation of S(sub TOA raised arrow), it is found that use of MODIS albedo improves the simulation of S(sub TOA raised arrow). Inability of coarse resolution CCSM3 simulation to resolve spatial heterogeneity of snowfall over high altitude sites such as the Tibetan Plateau causes overestimation of S(sub TOA raised arrow) in these areas. Discrepancies also exist in the simulation of S(sub TOA raised arrow) over ocean areas as CCSM3 does not account for the effect of wind speed on ocean surface albedo. This study shows that the radiative energy budget at the TOA is improved through the use of MODIS albedo in Global Climate Models.

Anantharaj, Valentine G.↗

Lacie phase 1 Classification and Mensuration Subsystem (CAMS) rework experiment

An experiment was designed to test the ability of the Classification and Mensuration Subsystem rework operations to improve wheat proportion estimates for segments that had been processed previously. Sites selected for the experiment included three in Kansas and three in Texas, with the remaining five distributed in Montana and North and South Dakota. The acquisition dates were selected to be representative of imagery available in actual operations. No more than one acquisition per biophase were used, and biophases were determined by actual crop calendars. All sites were worked by each of four Analyst-Interpreter/Data Processing Analyst Teams who reviewed the initial processing of each segment and accepted or reworked it for an estimate of the proportion of small grains in the segment. Classification results, acquisitions and classification errors and performance results between CAMS regular and ITS rework are tabulated.

Chhikara, R. S.↗

K 2 CO 3 /18-Crown-6-Catalyzed Selective H/D Exchange of Heteroarenes with Bromide as a Removable Directing Group

Here, the K 2 CO 3 /18-crown-6-catalyzed H/D exchange of heretoarenes in high atom % deuterium incorporation is disclosed. The use of a weak base as a catalyst leads to excellent site selectivity and broad functional group tolerance. Control experiments indicated that the use of bromide, which enhances the adjacent C–H bond reactivity, as a removable directing group is essential. Moreover, conversion of bromide to other functional groups is also performed to construct other useful deuterated compounds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mechanistic insights into rubidium ion adsorption at the quartz (101) surface from quantum chemical metadynamics

Ion sorption extent and mechanism depend in part on the mineral surface termination, which can be highly complex. Variations in surface functional groups, particularly with defect density and surface roughness, influence mineral reactivity towards solutes. In this work, we investigate the adsorption of a rubidium cation (Rb + ) at pristine and defect quartz (101) surface sites using well-tempered metadynamics, based on simulations with the quantum chemical density-functional tight-binding (DFTB) method. We compare the relative energetics of Rb + adsorption across selected sites for each surface, with nanosecond-level sampling, highlighting similarities between vicinal and geminal silanol sites. We find that the positive Rb + partial atomic charge can increase by as much as 0.5e as it approaches the surface, with implications for modulation of ion adsorption strength and extent at the quartz (101) surface with surface vacancies, silanol coverage, and charge.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Mars Sample Return from Meridiani Planum

The NASA Mars Exploration Program has four main goals: (i) determine if life ever arose there, (ii) understand the processes and history of its climate, (iii) determine the evolution of its surface and interior, and (iv) prepare for human exploration of Mars. These goals are embodied in the NASA Mars exploration strategy Follow the Water. Current Mars exploration tactics for lander missions build on knowledge gained by prior orbital investigations; the science rationale for choosing landing sites is based on the current best interpretation of the geology. A future Mars sample return mission will greatly exceed in cost typical lander missions because of the need to design for return to Earth and the infrastructure needed on Earth to curate and process the samples safely and cleanly. Because of this added cost burden, expectations for science return are higher. There must be some prospect that the returned samples will allow for testing higher level hypotheses relevant to NASA's goals. Site selection must be based on knowledge gained from prior in situ measurements to enhance the prospects for successfully meeting these goals. I will argue that Meridiani Planum should be that site.

Mittlefehldt, David W.↗

Selective bond scission in formic acid by low-energy electrons

We report recent results of mass-resolved anion fragment momentum imaging experiments to investigate dissociative electron attachment to formic acid, for incident energies between 5 eV and 9 eV. A remarkable site-selectivity is found for a resonance at 8.5 eV by comparing anion fragment yields for two deuterated isotopologues of formic acid. This results in an H – fragment from the O-H bond of the transient anion, with negligible contribution from C-H break. In contrast, a lower-energy resonance at 7.1 eV dissociates by C–H or O–H break to produce H – and the neutral radicals HOCO or HCOO.

74 ATOMIC AND MOLECULAR PHYSICS↗

Candidate sites for lunar observatories, with a recommended example - The NE Orientale Basin

This paper discusses site selection criteria for a moon-based observatory, using an area on the NE flank of the Orientale Basin at 80 deg W on the lunar equator as a recommended example. Such a site would provide the following advantages: visibility of essentially the entire celestial sphere, continual line of sight to earth, dynamic accessibility for minimum energy landings and takeoffs, closeness to the far-side for installation of instruments requiring a radio silent environment, trafficable and workable terrain, closeness to geologically important features, and closeness to volcanic features with potential resources. Polar and far-side sites have advantages as well, and no one site can meet all requirements. It is suggested that other candidate sites be evaluated by the criteria used for the Orientale Basin.

Lowman, Paul D., Jr.↗

Life-Cycle Cost/Benefit Assessment of Expedite Departure Path (EDP)

This report presents a life-cycle cost/benefit assessment (LCCBA) of Expedite Departure Path (EDP), an air traffic control Decision Support Tool (DST) currently under development at NASA. This assessment is an update of a previous study performed by bd Systems, Inc. (bd) during FY01, with the following revisions: The life-cycle cost assessment methodology developed by bd for the previous study was refined and calibrated using Free Flight Phase 1 (FFP1) cost information for Traffic Management Advisor (TMA, or TMA-SC in the FAA's terminology). Adjustments were also made to the site selection and deployment scheduling methodology to include airspace complexity as a factor. This technique was also applied to the benefit extrapolation methodology to better estimate potential benefits for other years, and at other sites. This study employed a new benefit estimating methodology because bd s previous single year potential benefit assessment of EDP used unrealistic assumptions that resulted in optimistic estimates. This methodology uses an air traffic simulation approach to reasonably predict the impacts from the implementation of EDP. The results of the costs and benefits analyses were then integrated into a life-cycle cost/benefit assessment.

Wang, Jianzhong Jay↗