Development of radiation hardened lithium- doped solar cells Final report
Fabrication techniques to improve initial efficiency and radiation tolerance of radiation hardened lithium-diffused silicon solar cells
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Fabrication techniques to improve initial efficiency and radiation tolerance of radiation hardened lithium-diffused silicon solar cells
The results of an experimental evaluation of the real-time degradation characteristics of lithium-diffused silicon solar cells are reported. A strontium-90 radioisotope was used for simulation of a typical earth-orbital electron environment. The experiment was performed in an ion pump vacuum chamber with samples maintained at -50, +20, +50, and +80 C. Samples were illuminated during the 6-month exposure run with solar cell 1-5 characteristics measured periodically in situ. This 6-month exposure corresponded to a 1 MeV equivalent fluence of approximately 10 to the 14th power electrons/sq cm. Several types of lithium cells were irradiatied and compared directly with conventional N/P cells. The best lithium cells compared favorably with N/P cells, particularly at the higher test temperatures. With a slight improvement of initial performance characteristics, lithium cells appear feasible for 5 to 10 year missions at synchronous altitude. Based on the reported results and those of other irradiation experiments, lithium cells would appear to be superior to N/P cells in proton-dominated earth-orbital environments. Another important conclusion of the effort was that illuminated/loaded cells degrade more rapidly than do dark/unloaded cells. The irradiation experiment provided data of high quality with a high degree of confidence because of the experimental and statistical analysis techniques utilized.
Theoretical and experimental research is outlined for indium phosphide solar cells, other solar cells for space applications, fabrication and performance measurements of shallow homojunction InP solar cells for space applications, improved processing steps and InP material characterization with applications to fabrication of high efficiency radiation resistant InP solar cells and other opto-electronic InP devices, InP solar cells fabricated by thermal diffusion, experiment-based predicted high efficiency solar cells fabricated by closed-ampoule thermal diffusion, radiation resistance of diffused junction InP solar cells, chemical and electrochemical characterization and processing of InP diffused structures and solar cells, and progress in p(+)n InP diffused solar cells.
Diffusion models for solar proton propagation in interplanetary medium
Topographical variations in carrier concentration delta N/N across the surface of n(+) on p diffused silicon solar cell material are studied by utilizing electrolyte electroreflectance with a spatial resolution of 100 microns within approximately 500 A of the surface. The topographical variations of delta N/N approximately 10 - 20% are found to be comparable to Czochralski grown material. The electroreflectance method can also be utilized to investigate other semiconductors such as GaAs.
In the present, water-vapor diffusive redistribution and condensation model of solid material abundance enhancement in the solar nebula's Jupiter-formation region, the assumed turbulent nebula temperatures decrease inversely with radial distance from the center, and time-scales are set by turbulent viscosities. The length scale for condensation of diffusively-transported water vapor is about 0.4 AU, and the surface density of ice in the Jupiter-formation zone undergoes enhancement by a factor of as much as 75; this surface density enhancement is enough to precipitate the rapid accretion of planetesimals into a solid core.
A simple one-dimensional time-dependent diffusion-convection model for the modulation of cosmic rays is presented. This model predicts that the observed intensity at a given time is approximately equal to the intensity given by the time independent diffusion convection solution under interplanetary conditions which existed a time iota in the past, (U(t sub o) = U sub s(t sub o - tau)) where iota is the average time spent by a particle inside the modulating cavity. Delay times in excess of several hundred days are possible with reasonable modulation parameters. Interpretation of phase lags observed during the 1969 to 1970 solar maximum in terms of this model suggests that the modulating region is probably not less than 10 a.u. and maybe as much as 35 a.u. in extent.
A ground-based remote sensing system - SMART (Surface Measurements for Atmospheric Radiative Transfer) - was deployed during both the SAFARI-2000 and the ARREX-1999 dry season campaigns. The measurement site is the Skukuza airport. The operation period for 1999 is from August 16 to September 10. The main instruments include shortwave (approximately 0.28-2.8 micrometers) and longwave (approximately 4-50 micrometers) broadband radiometers, a shadow-band radiometer, a micro-pulse lidar, and a microwave radiometer. We also did some measurements of solar spectral flux by using an ASD spectrometer. The operation period for 2000 is from August 15 to September 22. This time we added a few new features to the SMART system: a solar tracker for direct and diffuse components of solar fluxes; the scanning capability to the microwave radiometer; a whole sky camera for documenting the sky conditions every minute; and a mini-weather station for atmospheric pressure, temperature, humidity, wind speed/direction. A surface SSFR (Solar Spectral Flux Radiometer) from NASA Ames also joined us for the measurements. This is a unique data set with reasonably long observational period and high accuracy. The data show good correlation with the local weather patterns. We also see diurnal change and some special events, such as fierce fires nearby. To quantify the surface radiative forcing of biomass burning aerosols, many pyranometers, pyrgeometers, and pyrheliometers measure the global, direct, and diffuse irradiance at the surface. These fluxes combining with the collocated optical thickness retrievals from sun photometer (or shadow-band radiometer), the solar radiative forcing, proportional to delta F/delta tau, can be investigated. Integrated with measurements of other instruments at the site, these data sets will serve as "ground truth" for the satellite measurements and modeling.
The minority carrier diffusion length (Lp) and the surface recombination velocity (Vs) were measured as a function of distance (x) from the p-n junction in GaAs p/n concentrator solar cells. The measured Vs values were used in a theoretical expression for the normalized electron-beam-induced current. A fitting procedure was then used to fit this expression with experimental values to obtain Lp. The results show that both Vs and Lp vary with x. Lp measured in irradiated cells showed a marked reduction. These values were compared to those measured previously which did not account for Vs.
Unified interplanetary diffusion model for time behavior of intensity of several solar cosmic ray events, accounting for decay phases
U.S. theoretical research efforts have addressed three areas within the International Magnetospheric Study. The first, solar wind/magnetosphere interaction, is presently concerned with the suggestion that magnetic merging may predominantly occur near the polar cusps rather than near the subsolar point. Mechanisms have been proposed for noncollisional diffusion of solar wind plasma across the closed magnetopause entailed by such a phenomenon. The second area considers the importance to magnetotail dynamics of a continuous source of solar wind plasma, and of sporadic plasma loss associated with an unsteady convection cycle. In the third area, the electrodynamic magnetosphere/ionosphere interaction, an advanced state has been reached in the understanding of the relevant physics, with respect both to coupling in the subauroral region and the large scale structure of auroral zone electric fields parallel, and perpendicular to, the magnetic field.
In order to better understand the physical processes involved in defoliation assessment from remotely sensed data, a field study was designed to investigate the effect of forest canopy closure and other environmental variables on incoming solar radiation. Diffuse radiation measurements were recorded in red, infrared, and middle infrared wavelengths using the Mark 2 three band field radiometer. Results to date indicate that the percent canopy closure is the single most important variable affecting incoming solar radiation. In the visible and near infrared regions, interaction between time of day and date (defined later as solar zenith angle) also affect radiometric response. Aspect has only limited influence on radiance response. These same variables do not influence middle infrared response, however. Uniformity of the forest canopy appears to be more important. These results are compared to LANDSAT MSS classification results of gypsy moth defoliation.
The Solar Backscatter Ultraviolet Radiometer, Model 2 (SBUV/2) instruments, as part of their regular operation, deploy ground aluminum reflective diffusers to deflect solar irradiance into the instrument's field-of-view. Previous SBUV instrument diffusers have shown a tendency to degrade in their reflective efficiencies. This degradation will add a trend to the ozone measurements if left uncorrected. An extensive in-flight calibration system was designed into the SBUV/2 instruments to effectively measure the degradation of the solar diffuser (Ball Aerospace Systems Division 1981). Soon after launch, the NOAA-9 SBUV/2 calibration system was unable to track the diffuser's reflectivity changes due, in part, to design flows (Frederick et al. 1986). Subsequently, the NOAA-11 SBUV/2 calibration system was redesigned and an analysis of the first 2 years of data (Weiss et al. 1991) indicated the NOAA-11 SBUV/2 onboard calibration system's performance to be exceeding preflight expectations. This paper will describe the analysis of the first three years NOAA-11 SBUV/2 calibration system data.
Current photovoltaic (PV) panels typically contain interconnected solar cells that are vacuum laminated with a polymer encapsulant between two pieces of glass or glass with a polymer backsheet. This packaging approach is ubiquitous in conventional photovoltaic technologies such as silicon and thinfilm solar modules, contributing to thermal management, mechanical reinforcement, and environmental protection to enable the long lifetimes necessary to become financially acceptable. Commercial vacuum lamination processes typically occur at 150 °C to ensure cross-linking and/or glass bonding of the encapsulant to the glass and PV cells. Perovskite solar cells (PSCs) have emerged as a promising next-generation PV technology that is known to degrade under thermal stresses, especially at temperatures above 100 °C. In this study, we determine degradation modes during lamination and engineer internal diffusion barriers within the PSC to withstand the harsh thermal conditions of vacuum lamination. PSCs with self-assembled monolayers at the ITO interface and SnO X layers deposited by atomic layer deposition at the electron extraction side of the device endured vacuum lamination at conditions typical of commercial PV processes (150 °C) without degradation. This work demonstrates that perovskite PV can be integrated into the existing module lamination process, enabling future single- and multijunction modules utilizing perovskite absorbers.
Models which describe the diffusion of energetic solar particles in the interplanetary medium are reviewed. Most attention is paid to the case of impulsive emission from solar flares, taking into account the effects of the interplanetary magnetic field, diffusion near the sun, convection, and energy losses associated with the expansion of the solar wind. The case of continuous emission is also considered briefly.
Radiation effects in lithium diffused silicon for solar cell output degradation studies when space radiation irradiated
Radiation resistance of silicon webbed dendritic solar cells - diffusion techniques, drift field, structures, and effect of vacuum environment on damage rates
Recent observational data and models for the structure of the solar envelope are discussed, with emphasis on those physical processes in the envelope which are decisive in determining solar wind states at 1 AU. Diffusion of relativistic solar flare protons, collisionless damping of a variable flux of hydromagnetic waves, heat transfer from electrons to protons, acceleration by Alfven waves, and magnetic field effects are examined from the viewpoint of possible contributions to solar wind behavior.