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At least 343 records · Page 19

Prototype Modeling for a Light-Trapping Planar-Cavity Enclosed Particle Solar Receiver

Concentrating solar thermal (CST) systems present a promising avenue for affordable and reliable energy production. Solar receivers are key components that determine the efficiency and longevity of these systems. Particle-based solar receivers have emerged as a compelling alternative to traditional technologies, offering several advantages that address limitations in current CST systems. This is especially true as next-generation CST technologies target applications including electricity generation, thermochemical processes, and industrial process heat, many of which necessitate higher operating temperatures than current commercial molten salt systems. Molten-salt thermal energy storage (TES) systems, commonly used in CSP, face challenges related to freezing and corrosion. Particle-based TES systems, in contrast, do not experience these issues, as particles are stable at high temperatures, exceeding 1000 degrees Celsius. This capability allows for a wider range of applications, including those requiring higher temperatures for industrial processes and efficient electricity generation. A novel innovation in particle-based solar receiver technology is the light-trapping planar cavity receiver (LTPCR) configuration developed by NREL. The LTPCR design consists of small cavity-like structures using opaque planar surfaces, enabling efficient capture and absorption of solar energy. A high incident flux concentration at the cavity aperture is absorbed on the receiver walls, and subsequently transferred to particles on the inside of cavities. The particles flow through the system, forming a fluidized bed inside of the receiver panels, effectively capturing the absorbed solar heat. Air is used as a fluidizing medium in this process to enhance particle heat transfer and mixing. The effectiveness of this design lies in its ability to manage solar flux conditions and ensure high solar-to-thermal receiver efficiency. A 100-kW prototype is currently being tested at the King Saud University in Saudi Arabia to assess the receiver performance. A range of modeling analyses for the optical, thermal, and mechanical effects were conducted to assess the performance of the receiver under on-sun conditions. The solar flux resulting from the KSU heliostat field was modeled using NREL SolTrace software and produced up to 600 kW/m2 at the receiver aperture. The solar flux absorbed on the receiver walls was then used within a computational fluid dynamics (CFD) model to predict wall temperature distributions along with radiation and convection loss. A two-phase CFD model was developed for the fluidized bed of silica sand inside the receiver panels to predict local wall-to-particle heat transfer coefficients, particle temperature distributions, and outlet temperature of the particles. We have also conducted analyses to understand the thermomechanical behavior of these innovative enclosed light-trapping solar receivers optimized for particle heating. We used finite element analysis (FEA) to predict the receiver's performance using temperature distributions obtained from CFD and based on the resulting stress profiles, evaluated creep-fatigue damage with a goal of achieving a 30-year service life. Analysis showed a significant impact of the particle-to-wall heat transfer coefficients (HTCs) on receiver performance, with higher HTCs resulting in reduced stress and increased lifespan. For instance, when using Inconel 740H, increasing the HTC from 800 W/m2 K to 1400 W/m2 K increased the creep life from 4,000 hours to over 100,000 hours. This highlights the importance of understanding and optimizing heat transfer in the design of high-efficiency receivers.

14 SOLAR ENERGY↗

Advancing Small Business Solar Equity: Final Technical Insights Report

The Advancing Small Business Solar Equity: Final Technical Insights Report represents the culmination of two years of work in participation with Round 3 of the National Renewable Energy Laboratory's Solar Energy Innovation Network (SEIN). SEIN Round 3, titled "Equitable Solar in Underserved Communities," supported eight underserved communities across the United States in "exploring new approaches to the equitable adoption of solar energy in residential and commercial-scale settings" and in "confronting the solar barriers they face and unlocking the solar benefits most relevant to their own contexts" (National Renewable Energy Laboratory 2023). This project was one of four selected to support solar access for commercial entities in underserved communities. The research conducted for this report was done within the Minnesota Twin Cities geographic context, but certain findings and the proposed Solar Hub Network model may be found applicable nationally. Community-based organizations that serve small businesses, chambers of commerce, community development finance institutions and other community lenders, municipal governments, solar incentive providers, solar industry professionals, and others may find elements of this report useful.

14 SOLAR ENERGY↗

On the additivity of climate responses to the volcanic and solar forcing in the early 19th century

The early 19th century was the coldest period over the past 500 years, when strong tropical volcanic events and a solar minimum coincided. The 1809 unidentified eruption and the 1815 Tambora eruption happened consecutively during the Dalton minimum of solar irradiance; however, the relative role of the two forcing (volcano and solar) agents is still unclear. In this study, we examine the responses from a set of early 19th century simulations with combined and separated volcanic and solar forcing agents, as suggested in the protocol for the past1000 experiment of the Paleoclimate Modelling Intercomparison Project – Phase 4 (PMIP4). From 20-member ensemble simulations with the Max Planck Institute Earth system model (MPI-ESM1.2-LR), we find that the volcano- and solar-induced surface cooling is additive in the global mean/large scale, regardless of combining or separating the forcing agents. The two solar reconstructions (SATIRE (Spectral and Total Irradiance REconstruction-Millennia model) and PMOD (Physikalisch-Meteorologisches Observatorium Davos)) contribute to a cooling before and after 1815 of ~0.05 and ~0.15 K monthly average near-surface air cooling, respectively, indicating a limited solar contribution to the early 19th century cold period. The volcanic events provide the main cooling contributions, inducing a surface cooling that peaks at ~0.82 K for the 1809 event and ~1.35 K for Tambora. After the Tambora eruption, the temperature in most regions increases toward climatology largely within 5 years, along with the reduction of volcanic forcing. In the northern extratropical oceans, the temperature increases slowly at a constant rate until 1830, which is related to the reduction of seasonality and the concurrent changes in Arctic sea-ice extent. The albedo feedback of Arctic sea ice is found to be the main contributor to the Arctic amplification of the cooling signal. Several non-additive responses to solar and volcanic forcing happen on regional scales. In the atmosphere, the stratospheric polar vortex tends to strengthen when combining both volcano and solar forcing, even though the two forcing agents separately induce opposite-sign changes in stratospheric temperatures and zonal winds. In the ocean, when combining the two forcings, additional surface cold water propagates to the northern extratropics from the additional solar cooling in the tropics, which results in regional cooling along the propagation. Overall, this study not only quantifies the surface responses from combinations of the volcano and solar forcing, but also highlights the components that cannot be simply added from the responses of the individual forcing agents, indicating that a relatively small forcing agent (such as solar in early 19th century) can impact the response from the large forcing (such as the 1815 Tambora eruption) when considering regional climates.

54 ENVIRONMENTAL SCIENCES↗

Low-temperature solar thermal-power systems for residential electricity supply under various seasonal and climate conditions

In this work, the performance of low-temperature (<100 degrees C) solar thermal-power systems to satisfy residential electric loads was analyzed. The solar-driven system was designed to provide a fraction of the total electricity demand in a complementary operation with the electric grid. The analysis was conducted for an coperation during seven days each season, considering real solar and climate variables and residential loads at different climate zones in the United States. The efficiency of the system strongly depends on the solar radiation profile and the ambient temperature. Maximum efficiencies of around 9.5% were obtained in the cold and marine climate zones due to the high solar energy input and low heat dissipation temperatures. In these two zones, the system could supply more than 98% of the electricity demand all seasons. At mixed-humid and hot-humid regions, the system supplied around 50% of the electric load in three of the four seasons, but it only supplies about 27% of the electricity needs in the mixed-humid zone during summer and hot-humid zone during winter. The effect of the solar collector field area and the tank volume was also analyzed. In general, larger solar fields positively impact the efficiency. However, the impact of the tank volume varies depending on the solar radiation profile and the load requirements. Average efficiencies for the seven-day operation can be larger than 6% with a proper selection of the solar collector area and tank volume for an Organic Rankine Cycle with a capacity of about 2.6 kW. Finally, an economic analysis of the system was conducted, and the results were compared with a solar PV + battery system of similar capacity. It is expected that the cost for the analyzed solar-thermal system decreases in the coming years with the increased interest on low temperature applications.

14 SOLAR ENERGY↗

Impacts of Solar Land Availability on the Evolution of the U.S. Power System

Long-term planning scenarios of the United States electricity system have not identified solar resource availability to be a limiting factor in how much solar capacity might be deployed. However, there are some smaller regions where siting challenges indicate solar deployment could be limited by solar resource availability. In this work, we use geospatial modeling tools to develop a restrictive siting scenario that significantly reduces the amount and location of utility-scale solar resources. We use that restrictive siting regime, along with other previously defined siting scenarios, to examine how solar resource availability impacts the buildout of the electricity system using business-as-usual and decarbonization futures in a national-scale capacity expansion model. The restrictive siting scenario uses observed siting pressures to exclude many types of land on which development is allowed today and results in a greater than 90% reduction in solar resource potential-to approximately 3000 GW. Even with this drastic reduction, utility-scale solar capacity grows by more than 3 times through 2050 in the business-as-usual scenarios and by more than 6 times in the decarbonization scenarios, though less solar is deployed in scenarios with lower available solar resource. We quantify how system costs and generation mixes change as solar resource availability changes.

14 SOLAR ENERGY↗

Annual simulation of photovoltaic retrofits within existing parabolic trough concentrating solar powerplants

Solar power for electricity production comes from either photovoltaics or concentrating solar power plants. The former has seen rapid growth and expansion due to the rapid fall in global prices, while the latter has seen moderate growth due to ability to cheaply store thermal energy for later use. Hybridization, or combining photovoltaics with concentrating solar power represents a potential way for lowering cost while enabling long term storage. Over 5 GW of capacity exist worldwide using parabolic trough style technology for concentrating solar power which presents a unique option for optimization in the form of a photovoltaic retrofit. While it is possible to analyze the performance with detailed physics models, it is necessary to create a model that can handle simulating the plant level performance to fully understand the potential performance. Here, the first utility scale plant level model of a hybrid photovoltaic-concentrating solar power plant is developed. The model is applied to existing concentrating solar power plants around the world utilizing RP-3 mirrors without thermal energy storage to understand the impact on electricity production. Model results indicate that the photovoltaic retrofit can increase yearly electricity production by up to 30% for plants with solar multiples exceeding 1.5, and that increasing the fraction of solar energy reflected further increases the yield. The increased electrical production declines as the plant solar multiple is decreased. The minimum LCOE observed was $0.07/kWh for plants with larger solar multiple and fraction of solar energy reflected to the PV is 50% of the total aperture.

14 SOLAR ENERGY↗

Quantifying Solar PV Variability at Multiple Timescales for Power Systems Studies: Preprint

Increasing penetration of solar photovoltaics (PV) has concerned power system operators about their ability to balance load and generation over multiple timescales and maintain acceptable frequency profile because of the variability and uncertainty associated with solar PV. This paper focuses on developing metrics to quantify solar PV variability at multiple temporal scales ranging from seconds to an hour to help power system operators and planners better understand and account for solar PV variability under high solar PV penetration. Fourier coefficients of solar irradiation spectrum and average size of solar irradiation ramps over a day are the two metrics that are used to quantity the variability. It is shown that by using the two metrics the days with highest and lowest solar irradiation variability can be identified, which is useful information for operations planning or long-term power system planning studies. The key findings of the paper are (i) single sensor-based variability quantification can significantly exaggerate the variability of a solar PV plant, particularly at seconds to 1-min temporal resolution, (ii) at 1-minute or lower temporal resolutions, single sensor-based variability quantification of an entire plant can be fairly accurate, with the accuracy increasing as the temporal resolution reduces from 1-minute to 1-hour, (iii) at each 1-minute and lower temporal resolutions, maximum solar irradiation ramps appear to be independent of the geographical location of the sensor, and (iv) significant reduction in solar PV plant variability over a region with multiple plants is possible at all temporal scales, but more high quality, high temporal resolution data is needed to quantify the reduction with high confidence.

photovoltaics↗

Nanotechnology for catalysis and solar energy conversion

This roadmap on Nanotechnology for Catalysis and Solar Energy Conversion focuses on the application of nanotechnology in addressing the current challenges of energy conversion: 'high efficiency, stability, safety, and the potential for low-cost/scalable manufacturing' to quote from the contributed article by Nathan Lewis. This roadmap focuses on solar-to-fuel conversion, solar water splitting, solar photovoltaics and bio-catalysis. It includes dye-sensitized solar cells (DSSCs), perovskite solar cells, and organic photovoltaics. Smart engineering of colloidal quantum materials and nanostructured electrodes will improve solar-to-fuel conversion efficiency, as described in the articles by Waiskopf and Banin and Meyer. Semiconductor nanoparticles will also improve solar energy conversion efficiency, as discussed by Boschloo et al in their article on DSSCs. Perovskite solar cells have advanced rapidly in recent years, including new ideas on 2D and 3D hybrid halide perovskites, as described by Spanopoulos et al 'Next generation' solar cells using multiple exciton generation (MEG) from hot carriers, described in the article by Nozik and Beard, could lead to remarkable improvement in photovoltaic efficiency by using quantization effects in semiconductor nanostructures (quantum dots, wires or wells). These challenges will not be met without simultaneous improvement in nanoscale characterization methods. Terahertz spectroscopy, discussed in the article by Milot et al is one example of a method that is overcoming the difficulties associated with nanoscale materials characterization by avoiding electrical contacts to nanoparticles, allowing characterization during device operation, and enabling characterization of a single nanoparticle. Besides experimental advances, computational science is also meeting the challenges of nanomaterials synthesis. The article by Kohlstedt and Schatz discusses the computational frameworks being used to predict structure–property relationships in materials and devices, including machine learning methods, with an emphasis on organic photovoltaics. The contribution by Megarity and Armstrong presents the 'electrochemical leaf' for improvements in electrochemistry and beyond. In addition, biohybrid approaches can take advantage of efficient and specific enzyme catalysts. These articles present the nanoscience and technology at the forefront of renewable energy development that will have significant benefits to society.

14 SOLAR ENERGY↗

Community Solar for the Southeast (Final Report)

The Community Solar for the Southeast project provided technical assistance for cooperative and municipal utilities in the southeastern United States that are considering community solar programs. The project provided generally applicable information for these utilities in the form of an implementation guide and other freely available materials. It also provided detailed technical assistance to specific utilities in the form of feasibility analyses for possible community-scale solar (and energy storage) projects and program designs for community solar programs, all at no direct cost to the utilities. By helping to spur development of community solar projects in a region that historically had not seen much community-scale solar development, the program provided proof-of-concept for other community solar projects in the region, and helped to open up a market segment (cooperative and municipal utilities) that may have otherwise lacked the resources to independently pursue community solar development. The overall goal of the project was an expansion of community solar capacity at municipal and cooperative utilities in the southeastern United States (in this case meaning Virginia, North Carolina, South Carolina, Georgia, Florida, Kentucky, Tennessee, Alabama, and Mississippi). The specific target was to spur the development of community solar at these utilities throughout the Southeast such that at least 200 MW of community-scale solar would be developed by 2020. In order to reach this goal the project team first aimed to develop useful materials and conduct outreach with utilities and other relevant stakeholders. The team then conducted technical assistance projects to help individual utilities evaluate and, in several cases, pursue development of projects. The team conducted nine technical assistance projects in total: five in North Carolina, two in Virginia, one in Georgia, and one in Kentucky. The team also responded to smaller scale information requests from southeastern utilities throughout the project period.

14 SOLAR ENERGY↗

Utility-Scale Solar, 2024 Edition: Empirical Trends in Deployment, Technology, Cost, Performance, PPA Pricing, and Value in the United States [Slides]

Berkeley Lab’s “Utility-Scale Solar, 2024 Edition” presents analysis of empirical plant-level data from the U.S. fleet of ground-mounted photovoltaic (PV), PV+battery, and concentrating solar-thermal power (CSP) plants with capacities exceeding 5 MWAC (PV plants of 5 MWAC or less, including residential rooftop systems, are covered separately in Berkeley Lab’s companion annual report, Tracking the Sun). Key findings from this year’s report include: -18.5 GWAC of new utility-scale PV capacity came online in 2023, bringing cumulative installed capacity to more than 80.2 GWAC across 47 states. Installed costs continued to fall in 2023. Relative to 2022, capacity-weighted averages decreased by 8% to -$\$1.43$/WAC (or $\$1.08$/WDC). Costs, based on a 7.1 GWAC sample of 76 plants completed in 2023, have fallen by 75% (averaging 10% annually) since 2010. Plant-level capacity factors vary widely, from 6% to 36% (on an AC basis), with a sample median of 24%. -Levelized cost of energy (LCOE) of new 2023 projects increased slightly to $\$46$/MWh prior to the application of tax credits but continued to fall to $\$31$/MWh when accounting for federal incentives. PPA prices have largely followed the decline in solar’s LCOE over time, but newly signed longer-term PPA prices have increased since 2021, to an average of $\$35$/MWh (levelized, in 2023 dollars). -Solar’s average energy and capacity value (i.e., ability to offset costs of other power generation sources) across the U.S. was $\$45$/MWh in 2023. Solar’s average market value was lowest in CAISO ($\$27$/MWh), the market with the greatest solar generation share, and highest in ERCOT ($\$67$/MWh). -Newer solar projects had greater market value in 2023 than their generation costs, yielding $\$1.1$ billion in benefits. Projects built in 2022 delivered on average $\$15$/MWh more market value than their costs in 2023. -Solar’s combined value from wholesale electricity markets, public health and climate damage reduction were greater than generation costs and incentives, yielding $\$13.7$ billion in net benefits in 2023. We estimate U.S. health benefits of $\$24$/MWh and reduced global climate damages of $\$101$/MWh. -Adding battery storage is one way to increase the value of solar. Deployment of 52 new PV+battery hybrid plants set a record with 5.3 GW installed in 2023. Our public data file tracks metadata and PPA prices from more than 100 PV+battery hybrid projects that are already online or that have secured offtake arrangements. -Looking ahead, a massive pipeline of at least 1,085 GW of solar capacity dominates the nation’s interconnection queues at the end of 2023. Nearly 571 GW, or 53%, of that total was paired with a battery – in CAISO it was a staggering 98%. Historically only 10% of the requested solar capacity is built. -For more information, and to explore related interactive data visualizations, go to utilityscalesolar.lbl.gov.

14 SOLAR ENERGY↗

Spinel Cu–Mn–Cr Oxide Nanoparticle-Pigmented Solar Selective Coatings Maintaining >94% Efficiency at 750 °C

High-temperature concentrating solar power (CSP) system is capable of harvesting and storing solar energy as heat towards cost-effective dispatchable solar electricity. Solar selective coating is a critical component to boost its efficiency by maximizing solar absorptance and minimizing thermal emittance losses. However, maintaining a high solar-thermal conversion efficiency >90% for long-term operation at ≥750 ºC remains a significant challenge. Herein, we report spray-coated spinel Cu-Mn-Cr oxide nanoparticle-pigmented solar selective coatings on Inconel tube sections maintaining ≥94% efficiency at 750 ºC and ≥92.5% at 800 ºC under 1000x solar concentration after 60 simulated day-night thermal cycles in air, each cycle comprising 12h at 750 ºC/800 ºC and 12h cooling to 25 ºC. The solar spectral selectivity is intrinsic to the band-to-band and d-d transitions of non-stoichiometric spinel Cu-Mn-Cr oxide nanoparticles. Furthermore, this feature offers a large fabrication tolerance in nanoparticle volume fraction and coating thickness, facilitating low-cost and scalable spray-coated high-efficiency solar selective absorbers for high-temperature CSP systems.

14 SOLAR ENERGY↗

Rooftop Solar in Lawrence, MA: Community Perspectives, Deceptive Practices, and Financing Options

This report was prepared as part of the U.S. Department of Energy's Communities Local Energy Action Program (Communities LEAP) pilot competitive technical assistance for the Lawrence Massachusetts Stakeholder Coalition (LSC) composed of The City of Lawrence, All In Energy, MassDevelopment, Mill City Community Investments, BlocPower and Groundwork Lawrence, and led by Browning the Green Space. The LSC identified rooftop solar photovoltaics as a top priority for this technical assistance opportunity. Lawrence faces high energy burden and electricity prices, thus rooftop solar can be a tool to help lower those costs. However, the coalition received feedback that some solar companies were using deceptive and unfair practices when marketing, selling, or financing solar energy, costing residents more money than utility rates and increasing the energy burden. This project sought to address rooftop solar community priorities through two pathways: 1. facilitating community engagement to understand community perspectives and experiences with rooftop solar development; and 2. conducting a financial cash-flow analysis highlighting the varying fiscal outcomes for rooftop solar adopters based off rooftop solar leasing, ownership, or buying electricity from the utility (National Grid).

14 SOLAR ENERGY↗

In-depth analysis of solar models with high-metallicity abundances and updated opacity tables

Context. As a result of the high-quality constraints available for the Sun, we are able to carry out detailed combined analyses using neutrino, spectroscopic, and helioseismic observations. These studies lay the ground for future improvements of the key physical components of solar and stellar models because ingredients such as the equation of state, the radiative opacities, or the prescriptions for macroscopic transport processes of chemicals are then used to study other stars in the Universe. Aims. We study the existing degeneracies in solar models using the recent high-metallicity spectroscopic abundances by comparing them to helioseismic and neutrino data and discuss the effect on their properties of changes in the micro and macro physical ingredients. Methods. We carried out a detailed study of solar models computed with a high-metallicity composition from the literature based on averaged 3D models that were claimed to resolve the solar modelling problem. We compared these models to helioseismic and neutrino constraints. Results. The properties of the solar models are significantly affected by the use of the recent OPLIB opacity tables and the inclusion of macroscopic transport. The properties of the standard solar models computed using the OPAL opacities are similar to those for which the OP opacities were used. We show that a modification of the temperature gradient just below the base of the convective zone is required to remove the discrepancies in solar models, particularly in the presence of macroscopic mixing. This can be simulated by a localised increase in the opacity of a few percent. Conclusions. We conclude that the existing degeneracies and issues in solar modelling are not removed by using an increase in the solar metallicity, in contradiction to what has been suggested in the recent literature. Therefore, standard solar models cannot be used as an argument for a high-metallicity composition. While further work is required to improve solar models, we note that direct helioseismic inversions indicate a low metallicity in the convective envelope, in agreement with spectroscopic analyses based on full 3D models.

74 ATOMIC AND MOLECULAR PHYSICS↗

Solar Farm Development Impacts on Eastern Box Turtle ( Terrapene carolina ) Home Ranges

Eastern Box Turtle (Terrapene carolina) populations have declined drastically since 1970 because of continued destruction and fragmentation of their habitat. Although they are known to shift their home ranges because of environmental degradation, it is unknown how solar arrays impact Eastern Box Turtles. From 2011–2018, we collected data on Eastern Box Turtle movement and occupancy in a 79-ha solar farm. The solar farm is divided into six fenced areas, each containing wildlife openings for movement of terrestrial fauna every 23 m around the fenced solar arrays. For this work, we hypothesized that the solar arrays changed the home range sizes of turtles that interacted with the field. We fitted 41 Eastern Box Turtles with radio transmitters and tracked their locations twice per week in June–August from 2011–2018. Seventeen turtles had home ranges that overlapped with the solar arrays whereas 24 turtles had home ranges that never interacted with the solar arrays. We calculated home range sizes and tested for differences between overlapping and nonoverlapping groups. We further considered if the number of observations within the solar farm impacted home range size and displacement. We found that Eastern Box Turtles that used the solar farm exhibited 55–83% larger home ranges on average than turtles in natural habitats, but there was no significant association of home range size with the amount of time observed within the solar farm. Finally, we discuss strategies to mitigate negative impacts of solar farm development on turtles.

Radio telemetry↗

Impact of undoped substrates on high performance silicon solar cells

Today's highest-efficiency silicon solar cells typically operate near the threshold between low-level and high-level injection. It is not well understood if pushing further into a regime in which the cell operating point is solidly in high-level injection at all times of the day has further benefits for the solar cell performance. From a reliability perspective, cells fabricated on lower doped silicon have a larger breakdown voltage. This advantage can affect the design of modules allowing higher voltages and a relaxation of the number of bypass diodes needed. In this project, we present a comprehensive assessment, both experimental and using simulation, of how bulk resistivity, light intensity, and operation temperature impact the performance of the silicon solar cell. This work incorporates a comprehensive device physics analysis assisted by numerical simulation. The source code is now available under General Public License (GPL3), and to further leverage the findings of this project and outreach people outside of the scientific community, we are working with www.pveducation.org (which receives >1 million visitors a year) to create interactive content using our simulation results. The simulation results indicate that high bulk resistivity wafers (>>10 Ωcm) require bulk Shockley-Read-Hall (SRH) lifetimes in the millisecond range to outperform wafers with standard bulk resistivities (<10 Ωcm). Additionally, above bulk resistivities of 10 Ωcm (the exact value depends on the bulk characteristics of the wafer), the cell efficiency is weakly dependent on the bulk resistivity. As a result, ingot manufactures may have an opportunity to further reduce wafer cost by growing higher resistivity ingots that are more tolerant to resistivity variations. This project is particularly relevant today, as solar cell architectures with improved surface passivation and milliseconds lifetimes wafers are commercially available, leveraging potential benefits of using higher bulk resistivities. Outside of interdigitated back contact (IBC) cell, reported studies on high resistivity silicon (>100 Ωcm) are very limited. To the best of our knowledge, this project provides for the first-time experimental insight on solar cells fabricated on wafers with bulk resistivities up to several thousand Ωcm, delivering a comprehensive vision of their performance under real-world temperature and light intensity operation conditions. We manufactured and characterized solar cells with bulk resistivities in the range of 1 Ωcm to >15k Ωcm. Under standard testing conditions (STC), we measured solar cells efficiencies over 20% over the entire range of bulk resistivities, using our baseline cell processing. To evaluate the cell performance in real-world operation conditions, the solar cells were measured at different temperatures (25-80°C) and at different light intensities (0.1-1 suns). The measurements show that the bulk resistivity does not impact the solar cell response to temperature and light intensity. Similar thermal coefficients (TC) were measured for standard and high bulk resistivities, and they are comparable with the TC values reported in the literature for standard bulk resistivities <10 Ωcm. After light soaking, the solar cell didn’t show signs of light-induced degradation (LID). This result was expected since n-type float zone (FZ) wafers were used in this work, i.e. low traces of boron and low concentration of oxygen (oxygen is typically found in the seed end of Czochralski (CZ) ingots). We measured for high bulk resistivities (>10 Ωcm) extremely high breakdown voltages (>1000V). In conclusion, the insight provided by this project can positively impact the levelized cost of energy (LCOE) of the photovoltaic systems through its effect on cell and ingot manufacturing yield, silicon cell power output, and module reliability.

14 SOLAR ENERGY↗

Distributed Solar Adoption in Orlando: A Household-Level Model for Distribution Resource Planning

Potential for rooftop solar in Florida is massive (47% of retail sales, 3rd overall nationally), yet adoption lags (12th nationally). A 2018 Florida Public Service Commission ruling authorizing solar third-party ownership (leasing) has substantially increased attention on distributed solar in the state. The city of Orlando has committed to a 100% clean-energy target by 2050 and deployment of solar and storage are expected to contribute significantly to reaching the goal. Deployment of customer-adopted solar, unlike utility-procured solar, is uncertain, but known to be spatially correlated with demographic factors and existing adoption. We develop a new method to adapt NREL's dGen model in order to represent building-level agents in adoption forecasts for the Orlando Utility Commission (OUC) service territory. Using the agent-based model we develop projections of solar adoption, subject to scenarios varying future solar costs and valuation, and aggregate adoption predictions by OUC distribution feeder. We find substantial spatial heterogeneity in the projected level of adoption by OUC distribution feeder. For instance, 25% of all projected adoption through 2050 would be concentrated on just 5% of feeders and 88% of projected adoption on 50% of feeders. Because of the uncertainty in adoption, bottoms-up solar adoption forecasting methods at the household-level are integral to long-term resource planning by anticipating system needs as customers increasingly adopt distributed solar, storage, electric vehicles, and other distributed energy resources.

14 SOLAR ENERGY↗

Collaboration to Enable Higher Penetrations of Solar Power Generation Using the Natural Gas Pipeline System for Energy Storage (CRADA CRD-14-00567)

This unique project explored one possible solution for photovoltaic (PV) generation to become a reliable and dispatchable energy resource similar to conventional baseload fossil fuel electricity generation. Solar power generation is a renewable resource that varies naturally from day-to-day as well as seasonally. To use solar power as a baseload generation asset requires a flexible storage system that can recover power on both a daily and seasonal basis. Converting solar power to natural gas (i.e., first to hydrogen and then to methane) and having access to utility-scale storage in the natural gas network has the potential to make solar power generation a baseload asset. This will: 1) Increase the net energy yield from solar resources by increasing the effective capacity factor and maximize the energy produced during the assets’ lifetimes. 2) Improve the economics of energy storage for solar project developers, thereby accelerating the deployment of new solar generation. 3) Reduce the impact of increasing solar penetration on congestion of the electrical transmission system by shifting power delivery in time using the gas pipeline network for long-duration storage. 4) Reduce the impact of increasing solar generation on electrical distribution system control. 5) Offer alternative revenue sources for solar power generation beyond electricity including: hydrogen (H 2 ) production for stationary fuel cells and fuel cell electric vehicles, conversion of carbon dioxide (CO 2 ) to methane (CH 4 ) as a direct drop-in replacement for fossil natural gas use, and transmission as high volumetrically-dense CH 4 for use in transportation, heating, power generation, chemical production or conversion back to H2 at the point of use. Additional work was added to this CRADA in modification 4 having a primary objective to characterize the performance of the electrolyzer, Southern California Gas (SoCalGas) bioreactor and balance of plant to demonstrate production of renewable natural gas (RNG) from renewable H 2 and CO 2 using single-cell, self-replicating organisms. The additional scope of work allowed researchers to ramp up gas flowrates and pressure of the system over the designed range to grow the cells and begin to show the load-following capabilities of this anaerobic gas fermentation process. These activities enabled the research team to predict system performance at much greater scales; namely 10’s of mega-watts (MWs) of electrolyzer nameplate capacity.

14 SOLAR ENERGY↗

Solar Steam on Demand

INTRODUCTION: This Report summarizes the research and development project performed by Sunvapor and the subrecipient National Renewable Energy Laboratory (NREL) during the period of 10/01/2018-9/30/2021. The work was aimed at the economic integration of solar steam with an industrial process, and in particular, the advantages that a novel type of thermal energy storage and collector design could bring to the system. The completed work includes experimental research on the storage material, design of the collector, engineering of a complete solar steam plant, and economic analysis. The plant was, in the end, not constructed, due to COVID-19 impacts to the project host. PURPOSE: The purpose of the project was to test the hypothesis that a levelized cost of heat (LCOH) of 2¢/kWh delivered to a steam-consuming process, including energy discharged from storage, could be feasibly achieved. PROJECT OBJECTIVES: For Budget Period 1 our objectives were to engineer a prototype industrial solar steam generation system, and design and test a Latent Heat Energy Storage (LHES) lab-scale system. For Budget Period 2 our objectives were to construct and test the solar steam prototype plant, and to build and factory-test a full LHES module. For Budget Period 3 our objective was to integrate the storage module with the solar steam generator, show successful long duration energy tests of the combined system, and use the results to project the LCOH of delivered steam to a second-generation plant. PROJECT OUTCOMES: Various phase change materials (PCMs) for the LHES were tested for compatibility with industrial steam uses as measured by phase change temperature, stability of latent heat of fusion, and their corrosive effects on steel (the heat exchanger material). Two of these materials (sodium formate and sodium/ potassium) showed potential to meet the technical criteria. The estimated cost of a complete LHES module with these materials did not meet economic targets. The developmental collector design builds from previous work to exploit the potential cost advantages of a spaceframe of lumber construction. Design improvements were achieved in assembly efficiency and structural performance. A complete engineering package was completed for the solar steam system without storage that included the developmental as well as commercial arrays. The plant was permitted for construction. The storage CAPEX for a reference plant was estimate to be greater than $\$ 57$/kWh. The LCOH of the system without storage and with developmental collectors of lumber construction was projected to be 2¢/kWh, assuming a FCR of 8.2% over thirty years. PROJECT MILESTONES: The Milestones fully achieved in the first Budget Period includes obtaining a Letter of Intent from an industrial steam-consuming project host, issuance of a construction permit, and corrosion resistance. The Milestone that was partly achieved was the degradation in the latent heat of fusion. Milestones associated with Budget Periods 2 and 3, related to the construction and operation of the plant were not achieved as a result of the host shutting down the plant due to COVID-19 impacts. CONCLUSIONS: Sunvapor was able to secure an agreement with a host to build a fully engineered and permitted solar steam plant that met the host’s economic goals. As a basis for comparison, the solar field design was comprised of eight commercial collector arrays and one developmental Green Parabolic Trough Collector (GPTC) array. The projected LCOH with a solar field entirely populated with a second generation GPTC met the goal of 2¢/kWh. The experimental program concerning the PCM indicated the feasibility of meeting their technical requirements for industrial steam uses. The cost of the complete LHES exceeded its $\$ 14$/kWh target, and therefore the inclusion of LHES could not be economically justified. Due to COVID-19 impacts on the host, the solar steam plant was not constructed.

14 SOLAR ENERGY↗