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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Thermodynamic assessment of an electrically-enhanced thermochemical hydrogen production (EETHP) concept for renewable hydrogen generation

A novel concept for coupling a thermochemical cycle with an electrochemical separation device for the generation of hydrogen from steam is reported and a thermodynamic analysis of the system is presented. In a conventional thermochemical cycle, an oxygen carrier material is thermally reduced, cooled, and then reoxidized in steam thereby generating hydrogen. However, this process often requires high temperatures (>1700 K) and/or low oxygen partial pressures (<0.001 atm) in order to meet thermodynamic requirements. Such extreme conditions can adversely affect the stability of the reactive oxides, reactor materials, and system efficiency. In our proposed technology, we seek to decrease the required reduction temperature by several hundred degrees Kelvin by relaxing the requirement for spontaneous oxidation reaction at atmospheric pressure. This is accomplished by incorporating a proton-conducting membrane (PCM) to separate hydrogen produced at equilibrium concentrations from reactant steam. We also suggest the use of mixed ionic-electronic conducting (MIEC) oxygen carrier materials that reduce through a continuum of oxidation states at lower temperatures (~1200 °C). In conclusion, this concept allows the generation of a high-quality hydrogen stream while avoiding the challenging high temperatures/low partial pressures required in conventional water-splitting reaction schemes.

08 HYDROGEN↗
DOE OSTI2013

DOPPLER SIGNATURES OF THE ATMOSPHERIC CIRCULATION ON HOT JUPITERS

The meteorology of hot Jupiters has been characterized primarily with thermal measurements, but recent observations suggest the possibility of directly detecting the winds by observing the Doppler shift of spectral lines seen during transit. Motivated by these observations, we show how Doppler measurements can place powerful constraints on the meteorology. We show that the atmospheric circulation-and Doppler signature-of hot Jupiters splits into two regimes. Under weak stellar insolation, the day-night thermal forcing generates fast zonal jet streams from the interaction of atmospheric waves with the mean flow. In this regime, air along the terminator (as seen during transit) flows toward Earth in some regions and away from Earth in others, leading to a Doppler signature exhibiting superposed blueshifted and redshifted components. Under intense stellar insolation, however, the strong thermal forcing damps these planetary-scale waves, inhibiting their ability to generate jets. Strong frictional drag likewise damps these waves and inhibits jet formation. As a result, this second regime exhibits a circulation dominated by high-altitude, day-to-night airflow, leading to a predominantly blueshifted Doppler signature during transit. We present state-of-the-art circulation models including non-gray radiative transfer to quantify this regime shift and the resulting Doppler signatures; these models suggest that cool planets like GJ 436b lie in the first regime, HD 189733b is transitional, while planets hotter than HD 209458b lie in the second regime. Moreover, we show how the amplitude of the Doppler shifts constrains the strength of frictional drag in the upper atmospheres of hot Jupiters. If due to winds, the {approx}2 km s{sup -1} blueshift inferred on HD 209458b may require drag time constants as short as 10{sup 4}-10{sup 6} s, possibly the result of Lorentz-force braking on this planet's hot dayside.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Equilibration of the planar modes of ultracold two-dimensional ion crystals in a Penning trap

In this work, planar thermal equilibration is studied using direct numerical simulations of ultracold two-dimensional ion crystals in a Penning trap with a rotating wall. The large magnetic field of the trap splits the modes that describe in-plane motion of the ions into two branches: high-frequency cyclotron modes dominated by kinetic energy and low-frequency E × B modes dominated by potential energy associated with thermal position displacements. Using an eigenmode analysis we extract the equilibration rate between these two branches as a function of the ratio of the frequencies that characterize the two branches and observe this equilibration rate to be exponentially suppressed as the ratio increases. Under experimental conditions relevant for current work at NIST, the predicted equilibration time is orders of magnitude longer than any relevant experimental timescales. We also study the coupling rate dependence on the initial energy of the planar modes and the number of ions. In addition, we show how increasing the rotating wall strength improves crystal stability. These details of in-plane mode dynamics help set the stage for developing strategies to efficiently cool the in-plane modes and improve the performance of single plane ion crystals for quantum information processing.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2012

The Jefferson Lab High Power Broadband THz Facility

Jefferson Lab operates a broadband terahertz (THz) facility, whose light is generated by 300 fs FWHM 135 pC bunches of electrons at an energy of 125 MeV as they traverse a magnetic compression chicane prior to entering the optical cavity of the Jefferson Lab Free Electron Laser (FEL)[1-3]. The repetition rate of the electron bunches, and hence that of the light pulses, can be as high as 75 MHz continuous. Approximately 1 microJoule of energy is emitted for each pulse, which implies an average power of up to 75W, a peak power of several MW and electric fields of MV/m. Niche applications of this unique source are pump-probe dynamics, both in and out of equilibrium, and large-scale imaging. The beamline itself is designed to deliver an f/8 beam 2mm vertical × 3mm horizontal in size and 60% vertically polarized from a subtended angle of ~200 milliradians horizontal by ~135 milliradians vertical in the accelerator. The first mirror is copper-braid cooled. The philosophy of the optical design is to use a relay optics configuration to transport the beam via reflection off metal mirrors through a series of focal points, with the final one being at a diamond window. The optical scheme was developed using the Synchrotron Radiation Workshop (SRW)[4]. This code performs a full calculation of the electric field from a relativistic electron. It does not handle multiparticle coherent enhancement[5], but it is significantly different from all the other synchrotron radiation calculations because it retains a term called the Coulomb term in which the electric field falls off as 1/R2. In addition to calculating the electric field and the intensity, the code also allows one to propagate the field through the optical focusing elements and apertures. The beam exiting the final diamond window in the THz user lab passes into a series of vacuum chambers with considerable flexibility for attenuation, collimation, and/or beam splitting for imaging, spectroscopy and 2 photon pump-probe measurements. In this talk we will discuss the details of the philosophy, optical design and operating experience of this facility and also present ideas for discussion. We deeply appreciate the excellent support of our colleagues without which these facilities would not have been built and operated. This work was supported by the U.S. Dept. of Energy under contract DE-AC05-06-OR23177, and the Commonwealth of Virginia. The FEL facility is supported by the Office of Naval Research. 1. S. V. Benson et al, ?The VUV/IR/THz Free Electron Laser Program at Jefferson Lab?, Nucl. Instr. and Meth. A649 9 (2011). 2. G.L. Carr, M.C. Martin, W.R. McKinney, K. Jordan, G.R. Neil and G.P. Williams ?High Power Terahertz Radiation from Relativistic Electrons?, Nature 420 153-156 (2002). 3. J.M. Klopf et al. ?The Jefferson Lab high power THz user facility?, Nucl. Instrum. Methods A582, 114-116 (2007). 4. O. Chubar, P. Elleaume, "Accurate And Efficient Computation Of Synchrotron Radiation In The Near Field Region", proc. of the EPAC98 Conference, 22-26 June 1998, p.1177-1179. 5. C. J. Hirschmugl, M. Sagurton and G. P. Williams, ?Multiparticle coherence calculations for synchrotron radiation emission? Physical Review A44, 1316 (1991).

Klopf, John↗
NASA NTRSDate not supplied

Meteorite Sample Section Repair at NASA Johnson Space Center

Introduction: Meteorite thin and thick sections are routinely shipped from NASA Johnson Space Center to fulfill sample allocation requests from principle investigators around the world. Sections are also re-turned to JSC when researchers are finished studying them since, in most cases, they can be reused for other studies. The sections are very fragile unfortunately, and sometimes return to us needing repairs. The fol-lowing should give you an idea of how we repair sections here in the very lab where they were created. NOTE: Please do not attempt to repair ANSMET meteorite sections that are in your possession. We will perform the repairs for you at NASA JSC if you send the section back to us. Section Delamination: The majority of the meteorite sections that we produce here are secured to the glass slide using a high quality, two-part epoxy. Occasionally, we are asked to use superglue if the researcher wishes to dismount the section from the slide. Both epoxy and superglue are excellent adhesives, but they both tend to embrittle with time which results in delamination from the slide. Exposure to vacuum can also degrade the adhesion between the sample section and the glass slide. Repeated handling of the slide edges can accelerate delamination and, as a preventive measure, the outer 1-2 mm of epoxy is trimmed from newly created sections at JSC. If conductive tapes (copper, carbon, etc.) are used on the section during analysis, great care must be taken in removing the tape so that the epoxy is not pulled up with it. If in doubt, the tape can be left on the section when it is returned to JSC. Before we perform any repairs to sample sections, carbon, gold, or other coatings are removed. We accomplish this using a slurry of 0.05 micron alumina and 190 proof ethyl alcohol applied to a felt polishing pad fitted to a rotating lap wheel. Coatings are re-moved in this manner from all sections that are re-turned to JSC. The extent of the delamination determines how we proceed with the section repair. If the meteorite sample area of the section is not disturbed, then we carefully remove the delaminated epoxy. This is done using a binocular microscope with a 6X zoom, cut-proof gloves, and a very sharp, single edged razor blade. We cut the delaminated epoxy with the blade angled away from the sample area and using very light pressure. The trimmed section is then cleaned in an ultrasonic bath of 200 proof ethyl alcohol for no more than 10 seconds and carefully dried using a lint-free clean room wipe. The section is then placed into a lab oven at 110o F in preparation for epoxy. We mix the resin and hardener components of the low viscosity epoxy and very small amounts are applied to the cut edges of the section using a needle probe and the binocular microscope. Warming the epoxy helps secure the existing section by filling any voids between the glass slide and the section. After the new epoxy cures, we give the section a light polish on a lap wheel fitted with cotton polishing paper that is charged with 1 micron diamond paste. If the section has delaminated to the point of sample area being lifted from the glass, then it may be irreparable. We employ the above technique along with clamping the section in a Teflon pad arrangement in order to flatten the sample while the epoxy cures. Otherwise, the sample will tend to curl. This works to some degree, but once the sample area curls, it seldom re-turns to the original flatness without cracking or bending. Canada Balsam and Crystalbond: We repair damaged sections that had originally been prepared using Canada Balsam or Crystalbond adhesives through the gradual application of heat. We take great care with these samples since these bonding materials tend to get brittle with age. The section is heated in gradual steps (40-50o F per hour) to the melting point of the adhesive. We repair the sample while the adhesive is fluid and then the section is cooled in the same gradual manner in which it was heated. Slide Cracks and Breaks: Accidents happen. Especially with something as small and fragile as a thin/thick section. We all know someone who has driven a microscope objective into a section. As bad as the damage may look, the section can be repaired in most instances. NOTE: Please do not try to tape or glue section pieces back together prior to returning the dam-aged section. This practice usually renders the section irreparable. If the glass slide is cracked but the section is still in one piece, we repair it by infilling the crack with the low viscosity epoxy mentioned earlier. If the slide is in pieces, we can reassemble it with epoxy on a new backer slide. This is a tricky task as the pieces need to be in the correct plane with respect to each other, especially if the sample area is split among several pieces.

Meteorite↗
DOE OSTI2016

A transmissive, spectrum-splitting concentrating photovoltaic module for hybrid photovoltaic-solar thermal energy conversion

Here, a spectrum splitting, transmissive concentrating photovoltaic (tCPV) module is proposed and designed for a hybrid photovoltaic-solar thermal(PV/T) system. This module enables the system to more fully utilize the full spectrum of incoming sunlight. By utilizing III-V triple junction solar cells with bandgaps of 2.1eV/1.7eV/1.4eVin the module, ultraviolet (UV) and visible light will be absorbed and converted to electricity, while infrared (IR) light will pass through and be captured by a solar thermal receiver and stored as heat. The stored heat energy may be dispatched as electricity or process heat, as needed.Numerical analysis based on the Finite Elemental Method (FEM), ray tracing, circuit analysis, device modelling, and more is employed to design this tCPV module. According to these simulations, the tCPV module can perform with overall power conversion efficiency exceeding 43.5% for above bandgap (in-band)light under a standard AM1.5D solar spectrum, under an average concentration ratio of 400 suns.Passive and active cooling methods, keeping cells below 110°C, are also investigated and discussed, indicating that a transparent active cooling design could improve the CPV module efficiency by around 1%(absolute), relative to a passive design,by reducing the maximum cell working temperature by ~16°C. Furthermore, cost analysis shows that installation cost of around 1.9/W–2.2/W could be reached for the tCPV based PV/T system,which shows a competitive economic advantage compared to a more conventional PV with battery system.

14 SOLAR ENERGY↗
DOE OSTI2023

DAHe white dwarfs from the DESI Survey

A new class of white dwarfs, dubbed DAHe, that present Zeeman-split Balmer lines in emission has recently emerged. However, the physical origin of these emission lines remains unclear. Here, we present here a sample of 21 newly identified DAHe systems and determine magnetic field strengths and (for a subset) periods that span the ranges of ≃6.5–147 MG and ≃0.4–36 h, respectively. All but four of these systems were identified from the Dark Energy Spectroscopic Instrument survey sample of more than 47 000 white dwarf candidates observed during its first year of observations. We present detailed analysis of the new DAHe WD J161634.36+541011.51 with a spin period of 95.3 min, which exhibits an anticorrelation between broad-band flux and Balmer line strength that is typically observed for this class of systems. All DAHe systems cluster closely on the Gaia Hertzsprung–Russell diagram where they represent ≃1 per cent of white dwarfs within that region. This grouping further solidifies their unexplained emergence at relatively late cooling times and we discuss this in context of current formation theories. Nine of the new DAHe systems are identifiable from Sloan Digital Sky Survey spectra of white dwarfs that had been previously classified as featureless DC-type systems. We suggest high-S/N (signal-to-noise ratios), unbiased observations of DCs as a possible route for discovering additional DAHe systems.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Building America Case Study: Evaluating Through-Wall Air Transfer Fans, Pittsburgh, Pennsylvania (Fact Sheet)

In this project, Building America team IBACOS performed field testing in a new construction unoccupied test house in Pittsburgh, Pennsylvania to evaluate heating, ventilating, and air conditioning (HVAC) distribution systems during heating, cooling, and midseason conditions. Four air-based HVAC distribution systems were assessed:-a typical airflow ducted system to the bedrooms, a low airflow ducted system to the bedrooms, a system with transfer fans to the bedrooms, and a system with no ductwork to the bedrooms. The relative ability of each system was considered with respect to relevant Air Conditioning Contractors of America and ASHRAE standards for house temperature uniformity and stability, respectively.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2011

Polarization of nuclear spins by a cold nanoscale resonator

A cold nanoscale resonator coupled to a system of nuclear spins can induce spin relaxation. In the low-temperature limit where spin-lattice interactions are ''frozen out,'' spontaneous emission by nuclear spins into a resonant mechanical mode can become the dominant mechanism for cooling the spins to thermal equilibrium with their environment. We provide a theoretical framework for the study of resonator-induced cooling of nuclear spins in this low-temperature regime. Relaxation equations are derived from first principles, in the limit where energy donated by the spins to the resonator is quickly dissipated into the cold bath that damps it. A physical interpretation of the processes contributing to spin polarization is given. For a system of spins that have identical couplings to the resonator, the interaction Hamiltonian conserves spin angular momentum, and the resonator cannot relax the spins to thermal equilibrium unless this symmetry is broken by the spin Hamiltonian. The mechanism by which such a spin system becomes ''trapped'' away from thermal equilibrium can be visualized using a semiclassical model, which shows how an indirect spin-spin interaction arises from the coupling of multiple spins to one resonator. The internal spin Hamiltonian can affect the polarization process in two ways: (1) By modifying the structure of the spin-spin correlations in the energy eigenstates, and (2) by splitting the degeneracy within a manifold of energy eigenstates, so that zero-frequency off-diagonal terms in the density matrix are converted to oscillating coherences. Shifting the frequencies of these coherences sufficiently far from zero suppresses the development of resonator-induced correlations within the manifold during polarization from a totally disordered state. Modification of the spin-spin correlations by means of either mechanism affects the strength of the fluctuating spin dipole that drives the resonator. In the case where product states can be chosen as energy eigenstates, spontaneous emission from eigenstate populations into the resonant mode can be interpreted as independent emission by individual spins, and the spins relax exponentially to thermal equilibrium if the development of resonator-induced correlations is suppressed. When the spin Hamiltonian includes a significant contribution from the homonuclear dipolar coupling, the energy eigenstates entail a correlation specific to the coupling network. Simulations of dipole-dipole coupled systems of up to five spins suggest that these systems contain weakly emitting eigenstates that can trap a fraction of the population for time periods >>100/R{sub 0}, where R{sub 0} is the rate constant for resonator-enhanced spontaneous emission by a single spin 1/2. Much of the polarization, however, relaxes with rates comparable to R{sub 0}. A distribution of characteristic high-field chemical shifts tends to increase the relaxation rates of weakly emitting states, enabling transitions to states that can quickly relax to thermal equilibrium. The theoretical framework presented in this paper is illustrated with discussions of spin polarization in the contexts of force-detected nuclear-magnetic-resonance spectroscopy and magnetic-resonance force microscopy.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2014

Rovibronic structure in slow photoelectron velocity-map imaging spectroscopy of CH{sub 2}CN{sup −} and CD{sub 2}CN{sup −}

We report high-resolution anion photoelectron spectra of the cryogenically cooled cyanomethide anion, CH{sub 2}CN{sup −}, and its isotopologue, CD{sub 2}CN{sup −}, using slow photoelectron velocity-map imaging (SEVI) spectroscopy. Electron affinities of 12 468(2) cm{sup −1} for CH{sub 2}CN and 12 402(2) cm{sup −1} for CD{sub 2}CN are obtained, demonstrating greater precision than previous experiments. New vibrational structure is resolved for both neutral species, especially activity of the ν{sub 5} hydrogen umbrella modes. The ν{sub 6} out-of-plane bending mode fundamental frequency is measured for the first time in both systems and found to be 420(10) cm{sup −1} for CH{sub 2}CN and 389(8) cm{sup −1} for CD{sub 2}CN. Some rotational structure is resolved, allowing for accurate extraction of vibrational frequencies. Temperature-dependent SEVI spectra show marked effects ascribed to controlled population of low-lying anion vibrational levels. We directly measure the inversion splitting between the first two vibrational levels of the anion ν{sub 5} umbrella mode in both species, finding a splitting of 130(20) cm{sup −1} for CH{sub 2}CN{sup −} and 81(20) cm{sup −1} for CD{sub 2}CN{sup −}. Franck-Condon forbidden activity is observed and attributed to mode-specific vibrational autodetachment from the CH{sub 2}CN{sup −} and CD{sub 2}CN{sup −} dipole bound excited states. We also refine the binding energy of the anion dipole bound states to 39 and 42 cm{sup −1}, respectively, for CH{sub 2}CN{sup −} and CD{sub 2}CN{sup −}.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2021

Evaluation of Clouds, Radiation, and Precipitation in CMIP6 Models Using Global Weather States Derived from ISCCP-H Cloud Property Data

A clustering methodology is applied to cloud optical depth cloud top pressure (TAU-PC) histograms from the new, 1-degree resolution, ISCCP-H dataset, to derive an updated global Weather State (WS) dataset. Then, PC-TAU histograms from current-climate CMIP6 model simulations are assigned to the ISCCP-H WSs along with their concurrent radiation and precipitation properties, to evaluate model cloud, radiation, and precipitation properties in the context of the Weather States. The new ISCCP-H analysis produces WSs that are very similar to those previously found in the lower resolution ISCCP-D dataset. The main difference lies in the splitting of the ISCCP-D thin stratocumulus WS between the ISCCP-H shallow cumulus and stratocumulus WSs, which results in the reduction by one of the total WS number. The evaluation of the CMIP6 models against the ISCCP-H Weather States, shows that, in the ensemble mean, the models are producing an adequate representation of the frequency and geographical distribution of the WSs, with measurable improvements compared to the WSs derived for the CMIP5 ensemble. However, the frequency of shallow cumulus clouds continues to be underestimated, and, in some WSs the good agreement of the ensemble mean with observations comes from averaging models that significantly overpredict and underpredict the ISCCP-H WS frequency. In addition, significant biases exist in the internal cloud properties of the model WSs, such as the model underestimation of cloud fraction in middle-top clouds and secondarily in midlatitude storm and stratocumulus clouds, that result in an underestimation of cloud SW cooling in those regimes.

Clouds↗
NASA NTRS2024

Molecules in Cool Stars: The A 2 Π − X 2 Σ + and the B 2 Σ + − X 2 Σ + Band Systems of CaCl

Cool red giant stars exhibit absorption bands of calcium monochloride (CaCl) in the optical region. In this work, the bands of CaCl corresponding to the A 2 Π − X 2 Σ + transition with v' ≤ 4 and v'' ≤ 4, and B 2 Σ + − X 2 Σ + transition with v' ≤ 2 and v'' ≤ 2 are rotationally analyzed with PGOPHER, a multipurpose program for simulating and fitting molecular spectra. All bands were analyzed using high-resolution absorption spectra collected at the National Solar Observatory in 1985, calibrated with atomic lines from a high-resolution emission spectrum obtained in a separate hollow cathode experiment. The results are compared with previous laser-induced fluorescence measurements. Overall, the accuracy of spectroscopic constants for the A2Π and B2Σ+ states is improved. Scaled transition dipole moment calculations were used to obtain line strengths. Line lists are provided with Einstein A coefficients and oscillator strengths, which can be used to determine CaCl stellar abundances. Additionally, isotope splittings allowed us to estimate band origins for the 40 Ca 37 Cl isotopologue based on band-head positions.

Léo Lavy↗
DOE OSTI2014

Passive Room-to-Room Air Transfer, Fresno, California (Fact Sheet)

Field testing was performed in a retrofit unoccupied test house in Fresno, California. Three air-based heating, ventilation, and air conditioning (HVAC) distribution systems - a typical airflow ducted system to the bedrooms, a low airflow ducted system to the bedrooms, and a system with no ductwork to the bedrooms - were evaluated during heating, cooling, and midseason conditions. The relative ability of each of the three systems was assessed with respect to relevant Air Conditioning Contractors of America (ACCA) and ASHRAE standards for house temperature uniformity and stability, respectively. Computational fluid dynamics (CFD) modeling also was performed and refined based on comparison to field test results to determine the air flow rate into the bedrooms of over-door and bottom-of-door air transfer grilles.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2006

SiC Composite Turbine Vanes

Turbine inlet guide vanes have been fabricated from composites of silicon carbide fibers in silicon carbide matrices. A unique design for a cloth made from SiC fibers makes it possible to realize the geometric features necessary to form these vanes in the same airfoil shapes as those of prior metal vanes. The fiber component of each of these vanes was made from SiC-fiber cloth coated with boron nitride. The matrix was formed by chemical-vapor infiltration with SiC, then slurry-casting of SiC, followed by melt infiltration with silicon. These SiC/SiC vanes were found to be capable of withstanding temperatures 400 F (222 C) greater than those that can be withstood by nickel-base-superalloy turbine airfoils now in common use in gas turbine engines. The higher temperature capability of SiC/SiC parts is expected to make it possible to use them with significantly less cooling than is used for metallic parts, thereby enabling engines to operate more efficiently while emitting smaller amounts of NOx and CO. The SiC/SiC composite vanes were fabricated in two different configurations. Each vane of one of the configurations has two internal cavities formed by a web between the suction and the pressure sides of the vane. Each vane of the other configuration has no web (see Figure 1). It is difficult to fabricate components having small radii, like those of the trailing edges of these vanes, by use of stiff stoichiometric SiC fibers currently preferred for SiC/SiC composites. To satisfy the severe geometric and structural requirements for these vanes, the aforementioned unique cloth design, denoted by the term Y-cloth, was conceived (see Figure 2). In the regions away from the trailing edge, the Y-cloth features a fiber architecture that had been well characterized and successfully demonstrated in combustor liners. To form a sharp trailing edge (having a radius of 0.3 mm), the cloth was split into two planes during the weaving process. The fiber tows forming the trailing-edge section were interlocked, thereby enhancing through-thickness strength of the resulting composite material. For vanes of the webless configuration, each made from a layup of six plies of Ycloth, the length of each Y-cloth layer was cut so that the two strips corresponding to the aforementioned two planes would wrap around the perimeter of a graphite vane preform tool with a 10-mm overlap. The overlap was used to join the two strips in a fringe splice. To make the external sixth ply, a standard woven cloth was cut to the required final length and a fringe splice joined the two ends of the cloth at the trailing edge. The cloth was then prepregged. The entire assembly was then placed into an aluminum compaction tool designed to form the outer net shape of the vane. After the prepreg material was allowed to dry, the preform was removed from the aluminum tooling and placed into an external graphite tool before being shipped to a vendor for matrix infiltration. To make the SiC fiber preform for a vane having an internal web, a slightly different initial approach was followed. Each of two sections forming the internal cavities (and ultimately the web) was created by first slipping two concentric layers of a two-dimensional, 2-by-2, 45 - braided tube around a net-shape graphite mandrel. The tubes on both mandrels were prepregged and allowed to dry. The resulting two subassemblies were put together, then four additional plies were wrapped around them in the same fashion as that described above for the six plies of the vaneless configuration. The consolidation of the SiC fiber preforms into SiC/SiC composite parts was performed by commercial vendors using their standard processes. The capability of two of the webless SiC/SiC turbine vanes was demonstrated in tests in a turbine environment. The tests included 50 hours of steady-state operation and 102 two-minute thermal cycles. A surface temperature of 1,320 C was reached during the tests.

Calomino, Anthony M.↗
DOE OSTI2014

Simplified Space Conditioning in Low-Load Homes: Results from the Fresno, California, Retrofit Unoccupied Test House

Field testing was performed in a retrofit unoccupied test house in Fresno, California. Three air-based heating, ventilation, and air conditioning (HVAC) distribution systems -- a typical airflow ducted system to the bedrooms, a low airflow ducted system to the bedrooms, and a system with no ductwork to the bedrooms -- were evaluated during heating, cooling, and midseason conditions. The relative ability of each of the three systems was assessed with respect to relevant Air Conditioning Contractors of America (ACCA) and ASHRAE standards for house temperature uniformity and stability, respectively. Computational fluid dynamics (CFD) modeling also was performed and refined based on comparison to field test results to determine the air flow rate into the bedrooms of over-door and bottom-of-door air transfer grilles.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2013

BiNb{sub 3}O{sub 9}, a metastable perovskite phase with Bi/vacancy ordering: Crystal structure and dielectric properties

The perovskite, BiNb{sub 3}O{sub 9}, is a metastable phase in the Bi{sub 2}O{sub 3}:Nb{sub 2}O{sub 5} system that forms only when cooled from a liquid phase. Crystals of BiNb{sub 3}O{sub 9} prepared in this way display pseudocubic 2a×2a×2a diffraction patterns, due to non-merohedral twinning of a tetragonal a×a×2a cell, with the doubled axis oriented along all three pseudocubic axes. The structure was refined using data collected on a twinned crystal to R{sub 1}=0.034 for 318 observed reflections. BiNb{sub 3}O{sub 9} has tetragonal symmetry, P4/mmm with a=3.9459(3) Å, c=7.8919(6) Å. Partial ordering of Bi atoms and vacancies occurs, with alternate (0 0 1) planes having 28% and 42% Bi occupancies. The Bi atoms are displaced from the A-site special positions by up to 0.4 Å. The compound exhibits a relatively high permittivity value of ∼230 at room temperature, and shows a sharp increase with increasing temperature towards an apparent diffuse phase transition above ∼180 °C, with an associated frequency dependent peak in the dielectric loss. - Graphical abstract: Structure for BiNb{sub 3}O{sub 9}, showing split Bi atoms. Highlights: ► First characterisation of a new perovskite phase with potentially useful dielectric properties. ► Solving of the structure using single crystal data on a multiply twinned crystal. ► Measurement of dielectric properties that show the phase has a high dielectric permittivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Modeling Summary of ASNF in DOE Sealed Standard Canisters

A pathway for road-ready and final disposition packaging configurations for the aluminum-clad spent nuclear fuel (ANSF) fuel dictates storage within helium backfilled sealed DOE standard canisters. The typical packaging configuration for the 15-foot DOE canisters places 10 advance test reactor (ATR) elements within a Type 1a basket, and three baskets are loaded within each DOE canister. During in-reactor operations and cooling pond storage conditions, oxyhydroxide layers form on the surface of the aluminum clad fuel. These layers produce hydrogen gas over time due to the fuel’s radiation field. As part of the packing procedure, the ATR fuel should be dried to remove any residual physio-/chemi- sorbed water bound to the surface. The results of this modeling will include results at fully saturated and fully dried conditions. In addition, fuels that are currently stored at the Savannah River Site were also studied for their potential for hydrogen and pressure build up. These two additional fuels modeled were the Missouri University Research Reactor (MURR) fuel, which is packaged in the same configuration as the ATR, but with a 10-foot-tall DOE standard canister. This was selected due to its relatively high decay heat compared to other DOE-managed ASNF. The second additional fuel studied with the modeling effort was the High Flux Isotope Reactor (HFIR) fuel. This fuel is modeled as two separate DOE canisters with the inner and outer annulus split for storage. The HFIR was selected for study due to its high aluminum cladding surface area. In the associated experimental work, Task 2 - Oxyhydroxide Layer Radiolytic Gas Generation Resolution, additional tests were completed in a helium environment, and updated G-values for the radiolytic production of hydrogen from the oxyhydroxide layers were provided. These values were 2.92 ×10 -4 µmol/J at 50% relative humidity and 4.12 ×10 -4 µmol/J at 100% relative humidity. These values are lower than the value for Argon that was used in prior modeling results. In addition, prior modeling results have been completed with the G-value applied to just the mass of the corrosion layer, and this has been updated to apply the G-value for hydrogen generation to the full mass of the fuel. These two effects combine to show much smaller pressure and hydrogen build up for the sealed canister model. For a nominal scenario of stored ATR fuel, after 50 years the model results give a 1.36 atm total pressure, 7% mole percent hydrogen, for the upper decay heat, 1.51 atm total pressure, 16% mole percent hydrogen, and for upper decay heat with undried fuel 2.6 atm total pressure, 15% mole percent hydrogen. For the MURR nominal case, the model results give 1.34 atm and 6% hydrogen, for upper decay heat this gives 1.41 atm total pressure with 10.8 % hydrogen, and for upper decay heat with undried fuel, this gives 2.38 atm total pressure with 9.9% hydrogen. The nominal scenario for HFIR fuel gives 1.39 atm total pressure with 9.9% hydrogen, the upper decay heat case gives 1.43 atm with 12.1% hydrogen, and the upper decay heat with undried fuel gives 2.17 atm total pressure with 11.9% hydrogen. These results confirm the ATR scenario bounds the other intact ASNF modeled here. No case modeled yields significant oxygen, and the lower decay heat cases for all fuels modeled have hydrogen concentrations that are under the 4% flammability limit after 50 years of storage. In addition, the modeled pressures for all cases are all significantly below the 500-psi limit for the DOE standard sealed canister.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

High-resolution CH stretch spectroscopy of jet-cooled cyclopentyl radical: First insights into equilibrium structure, out-of-plane puckering, and IVR dynamics

First, high-resolution sub-Doppler infrared spectroscopic results for cyclopentyl radical (C 5 H 9 ) are reported on the α-CH stretch fundamental with suppression of spectral congestion achieved by adiabatic cooling to T rot ≈ 19(4) K in a slit jet expansion. Surprisingly, cyclopentyl radical exhibits a rotationally assignable infrared spectrum, despite 3N – 6 = 36 vibrational modes and an upper vibrational state density (ρ ≈ 40–90 #/cm –1 ) in the critical regime (ρ ≈ 100 #/cm –1 ) necessary for onset of intramolecular vibrational relaxation (IVR) dynamics. Such high-resolution data for cyclopentyl radical permit detailed fits to a rigid-rotor asymmetric top Hamiltonian, initial structural information for ground and vibrationally excited states, and opportunities for detailed comparison with theoretical predictions. Specifically, high level ab initio calculations at the coupled-cluster singles, doubles, and perturbative triples (CCSD(T))/ANO0, 1 level are used to calculate an out-of-plane bending potential, which reveals a C 2 symmetry double minimum 1D energy surface over a C 2v transition state. Here, the inversion barrier [V barrier ≈ 3.7(1) kcal/mol] is much larger than the effective moment of inertia for out-of-plane bending, resulting in localization of the cyclopentyl wavefunction near its C 2 symmetry equilibrium geometry and tunneling splittings for the ground state too small (<1 MHz) to be resolved under sub-Doppler slit jet conditions. The persistence of fully resolved high-resolution infrared spectroscopy for such large cyclic polyatomic radicals at high vibrational state densities suggests a “deceleration” of IVR for a cycloalkane ring topology, much as low frequency torsion/methyl rotation degrees of freedom have demonstrated a corresponding “acceleration” of IVR processes in linear hydrocarbons.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗