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At least 343 records · Page 19

Subnanometer Substructures in Nanoassemblies Formed from Clusters under a Reactive Atmosphere Revealed Using Machine Learning

Size-selected clusters, soft-landed on an oxide substrate, is a promising and highly tunable material for heterogeneous catalysis. Agglomeration of the deposited clusters, however, leads to changes in the particle properties and structure. The latter for such cluster assemblies can also be different from that in self standing nanoparticles of similar sizes. To monitor the formation of such complex materials, in situ studies at different length scales are required. Toward that goal, we combined small-angle X-ray scattering (SAXS), X-ray absorption near-edge structure (XANES) spectroscopy, ab initio simulations, and machine learning (artificial neural network) techniques. We detected significant differences between the sizes of particle agglomerates, as probed by SAXS, and the sizes of locally ordered regions, as seen by XANES. We interpret these differences as an evidence for the fractal, grape-cluster-like structure of the agglomerates; thus, XANES and SAXS provide highly complementary structural information. This finding can have a profound effect on our understanding of particle sintering and assembly processes and of structure properties relationship in ultradispersed metal catalysts in reaction conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Sensitivity of nonlinear photoionization to resonance substructure in collective excitation

Collective behaviour is a characteristic feature in many-body systems, important for developments in fields such as magnetism, superconductivity, photonics and electronics. Recently, there has been increasing interest in the optically nonlinear response of collective excitations. Here we demonstrate how the nonlinear interaction of a many-body system with intense XUV radiation can be used as an effective probe for characterizing otherwise unresolved features of its collective response. Resonant photoionization of atomic xenon was chosen as a case study. The excellent agreement between experiment and theory strongly supports the prediction that two distinct poles underlie the giant dipole resonance. Our results pave the way towards a deeper understanding of collective behaviour in atoms, molecules and solid-state systems using nonlinear spectroscopic techniques enabled by modern short-wavelength light sources.

74 ATOMIC AND MOLECULAR PHYSICS↗

Structure and substructure analysis of DAFT/FADA galaxy clusters in the [0.4–0.9] redshift range

Context. The DAFT/FADA survey is based on the study of ~90 rich(masses found in the literature >2 x 10^14 M_⊙)and moderately distant clusters (redshifts 0.4 < z < 0.9), all withHST imaging data available. This survey has two main objectives: to constrain dark energy(DE) using weak lensing tomography on galaxy clusters and to build a database (deepmulti-band imaging allowing photometric redshift estimates, spectroscopic data, X-raydata) of rich distant clusters to study their properties.

79 ASTRONOMY AND ASTROPHYSICS↗

Partonic substructure of nucleons and nuclei with dimuon production

Dimuon production has been studied in a series of fixed-target experiments at Fermilab during the last two decades. Highlights from these experiments, together with recent results from the Fermilab E866 experiment, are presented. Future prospects for studying the parton distributions in the nucleons and nuclei using dimuon production are also discussed.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

KINEMATIC AND SPATIAL SUBSTRUCTURE IN NGC 2264

We present an expanded kinematic study of the young cluster NGC 2264 based upon optical radial velocities measured using multi-fiber echelle spectroscopy at the 6.5 m MMT and Magellan telescopes. We report radial velocities for 695 stars, of which approximately 407 stars are confirmed or very likely members. Our results more than double the number of members with radial velocities from Fűrész et al., resulting in a much better defined kinematic relationship between the stellar population and the associated molecular gas. In particular, we find that there is a significant subset of stars that are systematically blueshifted with respect to the molecular ({sup 13}CO) gas. The detection of Lithium absorption and/or infrared excesses in this blueshifted population suggests that at least some of these stars are cluster members; we suggest some speculative scenarios to explain their kinematics. Our results also more clearly define the redshifted population of stars in the northern end of the cluster; we suggest that the stellar and gas kinematics of this region are the result of a bubble driven by the wind from O7 star S Mon. Our results emphasize the complexity of the spatial and kinematic structure of NGC 2264, important for eventually building up a comprehensive picture of cluster formation.

79 ASTRONOMY AND ASTROPHYSICS↗

AN OBSERVED LACK OF SUBSTRUCTURE IN STARLESS CORES

In this paper, we present the results of a high resolution (5'') Combined Array for Research in Millimeter-wave Astronomy and Sunyaev-Zeldovich Array survey of the 3 mm continuum emission from 11 of the brightest (at 1.1 mm) starless cores in the Perseus molecular cloud. We detect 2 of the 11 cores, both of which are composed of single structures, and the median 3{sigma} upper limit for the non-detections is 0.2 M{sub sun} in a {approx}5'' beam. These results are consistent with, and as stringent as, the low detection rate of compact 3 mm continuum emission in dense cores in Perseus reported by Olmi et al. From the non-detection of multiple components in any of the 11 cores, we conclude that starless core mass functions derived from bolometer maps at resolutions range 10''-30'' (e.g., with MAMBO, SCUBA, or Bolocam) are unlikely to be significantly biased by the blending of lower mass cores with small separations. These observations provide additional evidence that the majority of starless cores in Perseus have inner density profiles shallower than r {sup -2}.

79 ASTRONOMY AND ASTROPHYSICS↗

FERMI-LAT SENSITIVITY TO DARK MATTER ANNIHILATION IN VIA LACTEA II SUBSTRUCTURE

We present a study of the ability of the Fermi Gamma-ray Space Telescope to detect dark matter (DM) annihilation signals from the Galactic subhalos predicted by the Via Lactea II N-body simulation. We implement an improved formalism for estimating the boost factor needed to account for the effect of DM clumping on scales below the resolution of the simulation, and we incorporate a detailed Monte Carlo simulation of the response of the Fermi-LAT, including a simulation of its all-sky observing mode integrated over a 10 year mission. We find that for WIMP masses up to about 150 GeV c {sup -2} in standard supersymmetric models with ({sigma}v) = 3 x 10{sup -26} cm{sup 3} s{sup -1}, a few subhalos could be detectable with >5 standard deviation significance and would likely deviate significantly from the appearance of a point source.

79 ASTRONOMY AND ASTROPHYSICS↗