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Mineralogical-petrological characterization of near-earth asteroids

The mineralogy and petrology of 17 near-earth asteroids are characterized using reflectance spectroscopy with ground-based telescopes. Assuming the surfaces are composed of cosmically abundant materials, the presence of certain mineralogical species can be determined from diagnostic absorption features and spectral characteristics which have been studied under known laboratory conditions and understood in terms of crystal-field theory. With one possible exception, the surface composition of near-earth asteroids consists of common rock-forming minerals such as olivine, pyroxene, and phyllosilicates. Opaque components are present but cannot be mineralogically identified with existing experimental data. The spectrum of 2201 Oljato cannot be interpreted in terms of common rock-forming minerals and is examined for cometary features because its high orbital eccentricity suggests a possible relation to comets, but no common cometary features are identified. The predominance of mafic silicate absorption features in spectra of near-earth asteroids (compared to the majority of main-belt asteroids) may be a primary compositional feature or may be the signature of relatively fresher asteroid material.

Mcfadden, L. A.↗

Reactive Transport Modeling of Hydrogen Production from Serpentinization of Olivine

Hydrogen production from serpentinization of ultramafic rocks represents a promising natural pathway for generating carbon-free energy, yet its kinetics and controlling factors remain incompletely understood. A key challenge in advancing serpentinization research lies in the heterogeneity of porosity and permeability in rocks, which leads to nonuniform fluid velocity fields, as well as uncertainties in estimating reactive surface area and identifying appropriate mineral reaction equilibria. Additional complexities arise from the role of dissolved SiO 2 , Fe 2+ /Fe 3+ partitioning, and the limited effect of pH variations within the strongly alkaline regime on hydrogen yields. These challenges hinder straightforward extrapolation from laboratory tests to practical applications of hydrogen production from natural rocks. Here, in this work, we address these questions using a simulation-based reactive transport modeling framework calibrated against controlled laboratory experiments reported elsewhere. The model couples geochemical kinetics, multiphase flow, and mineralogical feedbacks, enabling systematic evaluation of how surface area, dissolved silica concentration, Fe redox state, temperature, and pressure govern serpentinization and H2 generation. We find that surface area exerts the strongest control on reaction rates and hydrogen yields, while Fe 2+ /Fe 3+ ratios act as secondary modulators. Elevated dissolved silica concentrations suppress hydrogen production but accelerate serpentine precipitation, whereas increasing pH beyond 12 within the strongly alkaline regime produces only marginal gains. Finally, we demonstrate that integrating targeted experiments with calibrated simulations offers a powerful and efficient approach for predicting hydrogen yields and assessing parameter trade-offs in industrial-scale applications. This integration can substantially reduce the experimental burden while improving predictive capability, thereby enhancing both the mechanistic understanding and the practical feasibility of hydrogen production from serpentinization.

08 HYDROGEN↗

The composition of Martian aeolian sands: Thermal emissivity from Viking IRTM observations

Aeolian sands provide excellent surfaces for the remote determination of the mineralogic composition of Martian materials, because such deposits consist of relatively well-sorted, uniform particle sizes and might consist of chemically unaltered, primary mineral grains derived from bedrock. Dark features on the floors of Martian craters are controlled by aeolian processes and many consist largely of unconsolidated, windblown sand. Measurement of the thermal emissivity of geologic materials provides a way to identify mid-infrared absorption bands, the strength and positions of which vary with mineral structure and composition. The Viking Infrared Thermal Mapper (IRTM) had four surface-sensing mid-IR bands, three of which, the 7, 9, and 11 micron channels, correspond to absorption features characteristic of carbonates, sialic, and mafic minerals, respectively. In this study, the highest quality IRTM data were constrained so as to avoid the effects of atmospheric dust, clouds, surface frosts, and particle size variations (the latter using data obtained between 7 and 9 H, and they were selected for dark intracrater features such that only data taken directly from the dark feature were used, so as to avoid thermal contributions from adjacent but unrelated materials. Three-point emissivity spectra of Martian dart intracrater features were compared with laboratory emission spectra of minerals and terrestrial aeolian sands convolved using the IRTM response function to the four IRTM spectral channels.

Edgett, Kenneth S.↗

The role of geological surfaces in determining visible-near infra red spectral signatures

The goal of the study described here is to determine new criteria for improved target discrimination in areas of hydrothermal mineralization. It is noted that the portion of materials, that is, geological surfaces detected by sensing devices, must be accurately determined before elemental and mineralogical characterization. The depth from which visible-near infrared radiation is reflected from target surfaces depends on composition and fabric. Reflectance spectra are obtained from binary mixtures of hematite, goethite, kaolinite and montmorillonite with a reflecting sphere spectrometer over a wavelength range of 400-2500 nm. The reflection (or absorption) intensity is plotted vs. the sample thickness (determined by scanning electron microscopy) to determine the sample thickness at which absorption saturates. The optical depth is seen to vary as a function of mineralogy and wavelength. In general, the maximum depth from which reflection features are discerned is from 12 to 47 microns measured in the visible-near infrared spectral region.

Sommer, S. E.↗

Beagle 2: The Next Exobiology Mission to Mars

Beagle 2 is a 60 kg probe (with a 30 kg lander) developed in the United Kingdom for inclusion on the European Space Agency's 2003 Mars Express. Beagle 2 will deliver to the Martian surface a payload which consists of a high percentage of science instruments to landed spacecraft mass. Beagle 2 will be launched in June, 2003 with Mars Express on a Soyuz-Fregat rocket from the Baikonur Cosmodrome in Kazakhstan. Beagle 2 will land on Mars on December 26, 2003 in the Isidis Planitia basin (approximately 10 degrees N and 275 degrees W), a large sedimentary basin that overlies the boundary between ancient highlands and northern plains. Isidis Planitia, the third largest basin on Mars, which is possibly filled with sediment deposited at the bottom of long-standing lakes or seas, offers an ideal environment for preserving traces of life. Beagle 2 was developed to search for organic material and other volatiles on and below the surface of Mars in addition to the study of the inorganic chemistry and mineralogy. Beagle 2 will utilize a mechanical mole and grinder to obtain samples from below the surface, under rocks and inside rocks. A pair of stereo cameras will image the landing site along with a microscope for examination of surface and rock samples. Analyses will include both rock and soil samples at various wavelengths, X-ray spectrometer and Mossbauer spectrometer as well as a search for organics and other light element species (e.g. carbonates and water) and measurement of their isotopic compositions. Beagle 2 has as its focus the goal of establishing whether evidence for life existed in the past on Mars at the Isidis Planitia site or at least establishing if the conditions were ever suitable. Carbonates and organic components were first recognized as existing on Mars when they were found in the Martian meteorite Nakhla. Romanek et al showed the carbonates in ALH84001 were formed at low temperatures. McKay et al noted possible evidence of early life on Mars within the ALH84001 meteorite. Thomas-Keprta et al showed the magnetite biomarkers in ALH84001's carbonates are indistinguishable from those formed by magnetotactic bacteria found on Earth. Gibson et al showed there was significant evidence for liquid water and biogenic products present on Mars across a 3.9 billion year period. A mechanical arm (PAW) operates from the lander and is used for science operations along with sample acquisition. Instruments attached to the PAW include: stereo cameras, Mossbauer instrument, X-ray fluorescence instrument, microscope, environmental sensors, rock corer/grinder, a spoon, mirror, brushes, a mole attachment for acquisition of subsurface to depths of 1 to 2 meters and an illumination device. Each camera has 14 filters which have been optimized for mineralogy composition, dust and water vapor detection. The microscope's camera is designed for viewing the size and shape of dust particles, rock surfaces, microfossils, and characteristics of the samples prior to introduction into the gas analysis package (GAP). The camera has a resolution of 4 microns/pixel, features four color capability (red, green, blue and UV (ultraviolet) fluoresence), a depth of focus of 40 micrometers and translation stage of +3 millimeters. The heart of the Beagle 2's life detection package is the gas analysis package (GAP), which consists of a mass spectrometer with collectors at fixed masses for precise isotopic ratio measurements and voltage scanning for spectral analysis. Primary aim of the GAP is to search for the presence of bulk constituents, individual species, and isotopic fractionations for both extinct and extent life along with studying the low-temperature geochemistry of the hydrogen, carbon, nitrogen and oxygen components on Mars from both the surface and atmosphere. GAP is a magnetic sector mass spectrometer with the range of 1 to 140 amu which can be operated in both the static and dynamic modes. A triple Faraday collector array will be used for C, N and O ratios along with a double Faraday array for H/D. Pulse counting electron multiplier will be utilized for noble gases and selected organics. Anticipated detection limits are at the picomole level for operation in the static mode of operation and high precision isotopic measurements will be made in the dynamic mode. Sample processing and preparation system consists of reaction vessels along with references. Sample ovens capable of being heated are attached to the manifold for sample combustion. Surface, subsurface materials and interior rock specimens will be combusted in pure oxygen gas at various temperature intervals to release organic matter and volatiles. Combustion process will permit detection of all forms and all atoms of carbon present in the samples. A chemical processing system is capable of a variety of conversion reactions. Gases are manipulated either by cryogenic or chemical reactions and passed through the gas handling portion of the vacuum system. There are two modes of operation: quantitative analysis and precise isotopic measurements. Additional information is contained in the original extended abstract.

Gibson, Everett K., Jr.↗

Searching for Life Underground: An Analysis of Remote Sensing Observations of a Drill Core from Rio Tinto, Spain for Mineralogical Indications of Biological Activity

Water is unstable on the surface of Mars, and therefore the Martian surface is not likely to support life. It is possible, however, that liquid water exists beneath the surface of Mars, and thus life might also be found in the subsurface. Subsurface life would most likely be microbial, anaerobic, and chemoautotrophic; these types of biospheres on Earth are rare, and not well understood. Finding water and life are high priorities for Mars exploration, and therefore it is important that we learn to explore the subsurface robotically, by drilling. The Mars Analog Rio Tinto Experiment (MARTE), has searched successfully for a subsurface biosphere at Rio Tinto, Spain [1,2,3,4]. The Rio Tinto study site was selected to search for a subsurface biosphere because the extremely low pH and high concentrations of elements such as iron and copper in the Tinto River suggest the presence of a chemoautotrophic biosphere in the subsurface beneath the river. The Rio Tinto has been recognized as an important mineralogical analog to the Sinus Meridiani site on Mars [5].

Battler, M.↗

The Search for Water and Other Volatile-bearing Phases on Mars: Mauna Kea Volcano as an Analog

Over the past 5 years, we have conducted field studies on the summit cones of Mauna Kea Volcano in Hawaii. Basaltic materials on several of these summit cones have been significantly altered by hydrothermal activity, whereas other summit cones have not undergone extensive aqueous alteration. These summit cones provide an important environment to study analogs of Martian surface alteration materials and analog surface processes (i.e., hydrothermal alteration, palagonitization. In on-going research, we have characterized the thermal and evolved gas behaviors of volatile-bearing reference minerals at reduced pressures in support of TEGA. We have expanded those studies to characterize the thermal and evolved gas behaviors of Mauna Kea samples as an analog for Mars surface materials. These samples were chosen for two reasons. First, many have chemical and spectral properties similar to what we see from remote sensing data from the Martian surface. Second, these samples have a range of mineralogical and chemical properties, ranging from simple to very complex; hence it will be challenging to characterize their thermal and evolved gas behaviors and to provide a context for their geological evolution. However, these types of studies are absolutely critical to understanding relevant geologic processes on Mars during robotic missions to the surface.

Ming, D. W.↗

Phoenix - the First Mars Scout Mission

As the first of the new Mars Scouts missions, the Phoenix project was selected by NASA in August of 2003. Four years later, almost to the day, Phoenix was launched from Cape Canaveral Air Station and successfully injected into an interplanetary trajectory on its way to Mars. This paper will highlight some of the key changes since the 2006 IEEE paper of the same name, as well as activities, challenges and problems encountered on the way to the launch pad. Phoenix Follows the water responding directly to the recently published data from Dr. William Boynton, PI (and Phoenix co-I) of the Mars Odyssey Gamma Ray Spectrometer (GRS). GRS data indicate extremely large quantities of water ice (up to 50% by mass) within the upper 50 cm of the northern polar regolith. Phoenix will land within the north polar region at 68.2 N, 233.4 W identified by GRS to harbor near surface water ice and provide in-situ confirmation of this extraordinary find. Our mission will investigate water in all its phases, and will investigate the history of water as evidenced in the soil characteristics that will be carefully examined by the powerful suite of onboard instrumentation. Access to the critical subsurface region expected to contain this information is made possible by a third generation robotic arm capable of excavating the expected Martian regolith to a depth of 1m. Phoenix has four primary science objectives: 1) Determine the polar climate and weather, interaction with the surface, and composition of the lower atmosphere around 70 N for at least 90 sols focusing on water, ice, dust, noble gases, and CO2. Determine the atmospheric characteristics during descent through the atmosphere. 2) Characterize the geomorphology and active processes shaping the northern plains and the physical properties of the near surface regolith focusing on the role of water. 3) Determine the aqueous mineralogy and chemistry as well as the adsorbed gases and organic content of the regolith. Verify the Odyssey discovery of near-surface ice. 4) Characterize the history of water, ice, and the polar 1 1-4244-1488-1/08/$25.00 2008 IEEE 2 IEEEAC paper#1579, Version 1, Updated 2008:01:09 climate. Determine the past and present biological potential of the surface and subsurface environments.

Mars exploration↗

Analytical, Experimental, and Modelling Studies of Lunar and Terrestrial Rocks

The goal of our research has been to understand the paths and the processes of planetary evolution that produced planetary surface materials as we find them. Most of our work has been on lunar materials and processes. We have done studies that obtain geological knowledge from detailed examination of regolith materials and we have reported implications for future sample-collecting and on-surface robotic sensing missions. Our approach has been to study a suite of materials that we have chosen in order to answer specific geologic questions. We continue this work under NAG5-4172. The foundation of our work has been the study of materials with precise chemical and petrographic analyses, emphasizing analysis for trace chemical elements. We have used quantitative models as tests to account for the chemical compositions and mineralogical properties of the materials in terms of regolith processes and igneous processes. We have done experiments as needed to provide values for geochemical parameters used in the models. Our models take explicitly into account the physical as well as the chemical processes that produced or modified the materials. Our approach to planetary geoscience owes much to our experience in terrestrial geoscience, where samples can be collected in field context and sampling sites revisited if necessary. Through studies of terrestrial analog materials, we have tested our ideas about the origins of lunar materials. We have been mainly concerned with the materials of the lunar highland regolith, their properties, their modes of origin, their provenance, and how to extrapolate from their characteristics to learn about the origin and evolution of the Moon's early igneous crust. From this work a modified model for the Moon's structure and evolution is emerging, one of globally asymmetric differentiation of the crust and mantle to produce a crust consisting mainly of ferroan and magnesian igneous rocks containing on average 70-80% plagioclase, with a large, mafic, trace-element-rich geochemical province, and a regolith that globally contains trace-element-rich material distributed from this province by the Imbrium basin-forming impact. This contrasts with earlier models of a concentrically zoned Moon with a crust of ferroan anorthosite overlying a layer of urKREEP overlying ultramafic cumulates. From this work, we have learned lessons useful for developing strategies for studying regolith materials that help to maximize the information available about both the evolution of the regolith and the igneous differentiation of the planet. We believe these lessons are useful in developing strategies for on-surface geological, mineralogical, and geochemical studies, as well. The main results of our work are given in the following brief summaries of major tasks. Detailed accounts of these results have been submitted in the annual progress reports.

Haskin, Larry A.↗

Dust Direct Radiative Effect Including Large Particles and Component Minerals

The direct radiative effect (DRE) of dust aerosols in Earth system models (ESMs) remains highly uncertain, largely due to inadequate representations of particle size distribution (PSD) and mineral composition. Using NASA's Earth Surface Mineral Dust Source Investigation (EMIT) soil mineralogy data and observed PSD in an ESM that resolves dust mineral composition and emitted diameters from 0.1 to 70 μm, we find a near-neutral global dust net DRE (−0.057 W m −2 ), weaker than most previous estimates. Large dust (diameter >10 μm) contributes 30% of the global longwave dust optical depth, providing observational constraints on large-particle abundance, and offsets 20% of the dust shortwave cooling over major source regions. Incorporation of EMIT mineralogy reduces shortwave uncertainty by more than 50%. The remaining uncertainty mainly exists in processes controlling dust abundance, particularly the poorly understood transport of large dust, and longwave optical properties, which require additional observational constraints to more accurately quantify the dust DRE.

Li, Longlei [Cornell Univ., Ithaca, NY (United Sta↗

The Viking X ray fluorescence experiment - Analytical methods and early results

Ten samples of the Martian regolith have been analyzed by the Viking lander X ray fluorescence spectrometers. Because of high-stability electronics, inclusion of calibration targets, and special data encoding within the instruments the quality of the analyses performed on Mars is closely equivalent to that attainable with the same instruments operated in the laboratory. Determination of absolute elemental concentrations requires gain drift adjustments, subtraction of background components, and use of a mathematical response model with adjustable parameters set by prelaunch measurements on selected rock standards. Bulk fines at both Viking landing sites are quite similar in composition, implying that a chemically and mineralogically homogeneous regolith covers much of the surface of the planet. Important differences between samples include a higher sulfur content in what appear to be duricrust fragments than in fines and a lower iron content in fines taken from beneath large rocks than those taken from unprotected surface material. Further extensive reduction of these data will allow more precise and more accurate analytical numbers to be determined and thus a more comprehensive understanding of elemental trends between samples.

Clark, B. C., III↗

On prediction and discovery of lunar ores

Sampling of lunar material and remote geochemical, mineralogical, and photogeologic sensing of the lunar surface, while meager, provide first-cut information about lunar composition and geochemical separation processes. Knowledge of elemental abundances in known lunar materials indicates which common lunar materials might serve as ores if there is economic demand and if economical extraction processes can be developed, remote sensing can be used to extend the understanding of the Moon's major geochemical separations and to locate potential ore bodies. Observed geochemical processes might lead to ores of less abundant elements under extreme local conditions.

Haskin, Larry A.↗

Soil mineralogy and chemistry on Mars - Possible clues from salts and clays in SNC meteorites

If the shergottite, nakhlite, and chassignite (SNC) meteorites' parent planet is Mars, then the aqueous precipitates found in them imply that oxidizing, water-based solutions may have been chemically active on that planet over the past 200-1300 million yrs. It is suggested that the mixture of aqueous precipitates found in the SNCs furnish a self-consistent model for the bulk elemental composition of surface sediments at the Viking Lander sites. Further mineralogical and stable-isotope studies of the secondary minerals may establish the limits for biological activity over the last 1300 million years of Mars' water-based chemistry.

Gooding, James L.↗

MASTER: An Orbiter for the Detailed Study of Vesta

MASTER (Mainbelt Asteroid Exploration/Rendezvous), a Discovery-class orbiter, will carry out a global geological and geochemical survey of Vesta. Primary goals include determining Vesta's mean density and interior structure through detailed mapping of the gravity field, imaging surface morphology at 3-m resolution, mapping mineralogy between 0.4 and 2.5 microns, and determining abundances of key elements through X-ray and gamma-ray spectroscopy. Spectroscopic evidence indicates the presence of basaltic lava flows on Vesta and suggests that impact basins may have exposed mantle materials. These possibilities, combined with the likelihood that Vesta is the ultimate source of HED meteorites, makes this asteroid an important target for a comprehensive orbiter mission. MASTER's global survey, combined with ongoing studies of HED meteorites, will be a major step in understanding the chemical, thermal, and geological evolution of Vesta. A particularly attractive opportunity involves a launch in June 2003 with arrival at Vesta in November 2009. The orbital phase of the mission is scheduled to last one year. A flyby of another mainbelt asteroid enroute to Vesta may be possible.

Veverka, J.↗

Reflectance Spectroscopy and Lunar Sample Science: Finally a Marriage After Far Too Long an Engagement

Inferences about the igneous and impact evolution of planetary bodies are based upon spectral remote sensing of their surfaces. However, it is not the rocks of a body that are seen by the remote sensing, but rather the regolith, that may contain small pieces of rock but also many other phases as well. Indeed, recent flybys of objects even as small as asteroid Ida have shown that these objects are covered by a regolith. Thus, spectral properties cannot be directly converted into information about the igneous history of the object. It is imperative to fully understand the nature of the regolith, particularly its finer fraction termed "soil," to appreciate the possible effects of "space weathering" on the reflectance spectra. We have initiated a study of our nearest, regolith-bearing body, the Moon, as "ground truth" for further probes of planetary and asteroidal surfaces. the foundation for remote chemical and mineralogical analyses lies in the physics underlying optical absorption and the linking of spectral properties of materials measured in the laboratory to well understood mineral species and their mixtures. From this statement, it is obvious that there should be a thorough integration of the material science of lunar rocks and soils with the remote-sensing observations. That is, the lunar samples returned by the Apollo missions provide a direct means for evaluation of spectral characteristics of the Moon. However, this marriage of the remote-sensing and lunar sample communities has suffered from a prolonged unconsummated betrothal, nurtured by an obvious complacency by both parties. To make more direct and quantitative links between soil chemistry/mineralogy and spectral properties, we have initiated a program to (1) obtain accurate characterization of the petrography of lunar soils (in terms relevant to remote analyses), coupled with (2) measurement of precise reflectance spectra, with testing and use of appropriate analytical tools that identify and characterize individual mineral and glass components. It is the finest-sized fractions of the bulk lunar soil that dominate the observed spectral signatures.

Taylor, Lawrence A.↗

Unambiguous Spectral Evidence for High- (and Low-) Calcium Pyroxene In Asteroids and Meteorites

Spectroscopy remains a powerful tool for inferring the modal mineralogy and mafic mineral composition of asteroid surfaces. Since similar measurements can be made on meteorite samples, spectroscopy can help link the two populations and add spatial and geologic context to detailed geo knowledge derived from meteorite samples. For example, analysis of the recent NEAR-Shoemaker mission to Eros include detailed study of NIS spectra to assess the affinity of Eros to ordinary chondrites. As discussed in these studies, pyrox (PYX) and olivine (OLV) absorption are readily detectable in the spectra. Furthermore, subtleties in band parameters (position vs. area) suggest the presence of both low- and high-calcium pyroxene (LCP and HCP), as expected from the petrology of ordinary chondrites. However unambiguous identification and detailed compositional inferences for both LCP and HCP (and OLV) are difficult from band parameters analysis. In this study, we examine spectra of S-asteroids and meteorites with the Modified Gaussian Model (MGM), an absorption band model, to explore the role of HCP in these silicate-rich spectra.

Sunshine, J. M.↗

Unambiguous Spectral Evidence for High- (and Low-) Calcium Pyroxene in Asteroids and Meteorites

Spectroscopy remains a powerful tool for inferring the modal mineralogy and mafic mineral composition of asteroid surfaces. Since similar measurements can be made on meteorite samples, spectroscopy can help link the two populations and add spatial and geologic context to detailed geochemical knowledge derived from meteorite samples. For example, analysis of the recent NEAR-Shoemaker mission to Eros include detailed study of NIS spectra to assess the affinity of Eros to ordinary chondrites. As discussed in these studies, pyroxene (PYX) and olivine (OLV) absorption are readily detectable in the spectra. Furthermore, subtleties in band parameters (position vs. area) suggest the presence of both low- and high-calcium pyroxene (LCP and HCP), as expected from the petrology of ordinary chondrites. However unambiguous identification and detailed compositional inferences for both LCP and HCP (and OLV) are difficult from band parameters analysis. In this study, we examine spectra of S-asteroids and meteorites with the Modified Gaussian Model (MGM), an absorption band model, to explore the role of HCP in these silicate-rich spectra.

Sunshine, J. M.↗

A Compact Instrument for Remote Raman and Fluorescence Measurements to a Radial Distance of 100 m

Compact remote spectroscopic instruments that could provide detailed information about mineralogy, organic and biomaterials on a planetary surface over a relatively large area are desirable for NASA s planetary exploration program. Ability to explore a large area on the planetary surfaces as well as in impact craters from a fixed location of a rover or lander will enhance the probability of selecting target rocks of high scientific contents as well as desirable sites in search of organic compounds and biomarkers on Mars and other planetary bodies. We have developed a combined remote inelastic scattering (Raman) and laser-induced fluorescence emission (LIFE) compact instrument capable of providing accurate information about minerals, organic and biogenic materials to a radial distance of 100 m. Here we present the Raman and LIFE (R-LIFE) data set.

Sharma, S. K.↗