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At least 343 records · Page 19

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NASA NTRS2007

Rapid Fabrication of Carbide Matrix/Carbon Fiber Composites

Composites of zirconium carbide matrix material reinforced with carbon fibers can be fabricated relatively rapidly in a process that includes a melt infiltration step. Heretofore, these and other ceramic matrix composites have been made in a chemical vapor infiltration (CVI) process that takes months. The finished products of the CVI process are highly porous and cannot withstand temperatures above 3,000 F (approx.1,600 C). In contrast, the melt-infiltration-based process takes only a few days, and the composite products are more nearly fully dense and have withstood temperatures as high as 4,350 F (approx.2,400 C) in a highly oxidizing thrust chamber environment. Moreover, because the melt- infiltration-based process takes much less time, the finished products are expected to cost much less. Fabrication begins with the preparation of a carbon fiber preform that, typically, is of the size and shape of a part to be fabricated. By use of low-temperature ultraviolet-enhanced chemical vapor deposition, the carbon fibers in the preform are coated with one or more interfacial material(s), which could include oxides. The interfacial material helps to protect the fibers against chemical attack during the remainder of the fabrication process and against oxidation during subsequent use; it also enables slippage between the fibers and the matrix material, thereby helping to deflect cracks and distribute loads. Once the fibers have been coated with the interfacial material, the fiber preform is further infiltrated with a controlled amount of additional carbon, which serves as a reactant for the formation of the carbide matrix material. The next step is melt infiltration. The preform is exposed to molten zirconium, which wicks into the preform, drawn by capillary action. The molten metal fills most of the interstices of the preform and reacts with the added carbon to form the zirconium carbide matrix material. The zirconium does not react with the underlying fibers because they are protected by the interfacial material(s). The success of the melt-infiltration step depends on interface material selection and uniform coating of the fibers, infiltration with the correct amount of carbon, and careful control of temperature and rate of heating.

Williams, Brian E.↗

DOE OSTI2018

Development of Nano-Modified Concrete for Next Generation of Storage Systems

The goal of the research was to develop a superior concrete for the long-term storage of used nuclear fuel by engineering concrete at the nanoscale through the incorporation of nano-sized and nano-structured particles based on enhanced reactivity (not fiber reinforcement). The specific objectives were to determine for nano-modified concrete: 1. The effects of environmental weathering (i.e., wet/dry and ingress of reactive species such as chloride and sulfate from the marine environment or other sources) and exposure to radiation and thermal environments on the structural stability and microstructural evolution of the material; 2. How microstructural and morphological changes from environmental weathering and thermal and radiation damage affect the long-term, macroscale performance of the material; and, 3. Identify formulation envelopes for nanoparticle content and combinations to achieve superior concrete criteria for dry storage systems by integrating and extending existing predictive modeling approaches that couple reactive transport and thermo- chemo- and radiation induced damage. The major findings of this work are summarized as follows. The results are being processed and compiled in manuscripts for peer-reviewed publication. Due to the late access to the gamma irradiation facility, material characterization is continuing. Dispersion/agglomeration of nanoparticles in cement pastes. The dispersion/agglomeration of nanoparticles (NPs) of SiO 2 , TiO 2 , Al 2 O 3 , Fe 2 O 3 , and clay (bentonite and halloysite) in water, with and without polycarboxylate-based high range water reducer (P-HRWR), and in the environment of hydrating cement have been investigated. The intrinsic particle characteristics, surface charge, pH, monovalent and divalent ion concentrations in solution, and modes of interaction of the NPs with P-HRWR influenced the NP behavior in solution.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NASA NTRS1972

Heat transfer tests of the McDonnell-Douglas delta wing orbiter mated with -17A booster at Mach number 8

A wind tunnel test program to determine aerodynamic heat transfer distributions on the McDonnell-Douglas configurations is reported. The tests were conducted at the Arnold Engineering Development Center (AEDC) in Tunnel B of the von Karman Gas Dynamics Facility (VKF). Heat-transfer rates were determined by the phase-change paint technique on 0.011-scale Stycast models using Tempilaq as the surface temperature indicator. The nominal test conditions were; Mach 8, freestream unit Reynolds numbers of 0.8 x one million, 2.5 x one million, and 3.7 x one million, and angles of attack of -5 deg, 0 deg, +5deg. Model details, test conditions, phase-change paint photographs and reduced heat-transfer coefficients are presented.

Matthews, R. K.↗

NASA NTRS1988

Control of the boundary layer separation about an airfoil by active surface heating

Application of active control to separated flow on the RC(6)-08 airfoil at high angle of attack by localized surface heating is numerically simulated by integrating the compressible two-dimensional nonlinear Navier-Stokes equations solver. Active control is simulated by local modification of the temperature boundary condition over a narrow strip on the upper surface of the airfoil. Both mean and perturbed profiles are favorably altered when excited with the same natural frequency of the shear layer by moderate surface heating for both laminar and turbulent separation. The shear layer is found to be very sensitive to localized surface heating in the vicinity of the separation point. The excitation field at the surface sufficiently altered both the local as well as the global circulation to cause a significant increase in lift and reduction in drag.

Maestrello, Lucio↗

NASA NTRS2021

Boundary Layer Instabilities Over a Cone-Cylinder-Flare Model at Mach 6

Computations are performed to investigate the boundary-layer instabilities over a sharp cone-cylinder-flare model at zero degrees angle of attack. The model geometry and the flow conditions are selected to match the experiments conducted in the Boeing/AFOSR Mach 6 Quiet Tunnel (BAM6QT) at Purdue University. The geometry consists of a nominally sharp 5-degree half-angle cone, followed by a cylindrical segment and then a 10-degree flare. An axisymmetric separation bubble is generated as a result of the laminar shock/boundary-layer interaction in the cylinder-flare region. The comparison of the laminar flow solution and the schlieren images shows a remarkable agreement between the respective locations of both the boundarylayer edge and the reattachment shock. The predicted heat flux distribution is also in agreement with the measured values downstream of the reattachment location. The analysis of convective and global instabilities is performed for flare half angles equal to 8, 10, and 12 degrees and nosetip radii equal to 0.1, 1, and 5 mm. The linear amplification of first and second Mack mode instabilities that begin to amplify in the cone region are computed with a combination of the parabolized stability equations (PSE) and the harmonic linearized Navier-Stokes equations (HLNSE). The predicted frequency spectra of the surface pressure fluctuations associated with both planar and oblique instability waves are compared with the measured spectra at the various locations of the PCB and Kulite sensors. The comparison shows that the computational analysis captures the distinct lobes within the disturbance amplification spectra measured in the experiments, but some differences in amplification characteristics are noted at low frequencies. Overall, the oblique disturbances are found to be more amplified than the planar disturbances. To our knowledge, this represents the first successful comparison between convective instability analysis and measured surface pressure fluctuations for a hypersonic configuration with a separation bubble. Finally, the global instability analysis shows that the laminar flow becomes supercritical for flare half angles larger than 8 degrees. The unstable global mode for the experimental configuration of a 10 degrees flare and a sharp nosetip cone corresponds to a stationary three-dimensional disturbance that is concentrated in the recirculation region and achieves its maximum growth rate for an azimuthal wavenumber of 5.

Boundary layer transition↗

NASA NTRS1991

High temperature static strain gage development

Final results are presented from a program to develop a thin film static strain gage for use on the blades and vanes of running, test stand gas turbine engines with goals of an 3 x 3 mm gage area and total errors of less than 10 pct. of + or - 2,000 microstrain after 50 hrs at 1250 K. Pd containing 13 Wt. pct. Cr was previously identified as a new strain sensor alloy that appeared to be potentially usable to 1250 K. Subsequently, it was discovered, in contrast with its behavior in bulk, that Pd-13Cr suffered from oxidation attack when prepared as a 4.5 micron thick thin film. Continuing problems with electrical leakage to the substrate and the inability of sputtered alumina overcoats to prevent oxidation led to the discovery that sputtered alumina contains appreciable amounts of entrapped argon. After the argon has been exsolved by heating to elevated temperatures, the alumina films undergo a linear shrinkage of about 2 pct. resulting in formation of cracks. These problems can be largely overcome by sputtering the alumina with the substrate heated to 870 K. With 2 micron thick hot sputtered alumina insulation and overcoat films, total 50 hr drifts of about 100 microstrain (2 tests) and about 500 microstrain (1 test) were observed at 1000 and 1100 K, respectively. Results of tests on complete strain gage systems on constant moment bend bars with Pd temperature compensation grids revealed that oxidation of the Pd grid was a major problem even when the grid was overcoated with a hot or cold sputtered alumina overcoat.

Hulse, C. O.↗

NASA NTRS2020

Advancing Development of Environmental Barrier Coatings Resistant to Attack by Molten Calcium-Magnesium-Aluminosilicate (CMAS)

Ceramic matrix composites (CMCs) are a leading material system to replace metal-based parts in the hot-section of air-breathing turbine engines to improve fuel efficiency in aircraft engines. CMCs have higher temperature capabilities and lower density compared with traditional metallic structural materials. However, silicon-based CMCs are susceptible to oxidation in the harsh combustion environment encountered in turbine engines. Consequently, environmental barrier coatings (EBCs) are being developed to protect CMC components to improve durability and extend service life of CMCs. Sand, volcanic ash and other particulate debris, which are generally comprised of calcium-magnesium-aluminosilicate (CMAS) and other trace oxides, are routinely ingested by aircraft engines. At temperatures above 1200Â°C, CMAS particulates melt. Near target operating temperatures (~1500Â°C) of future CMC-based aircraft engines, molten CMAS behaves like a viscous melt that can infiltrate and chemically interact with protective coatings. These interactions can cause premature failure of the EBC system and ultimately the overall CMC engine component. Degradation of candidate EBC materials by molten CMAS will be presented with a focus on recent work, as well as methods of evaluating the complex high-temperature materials interactions, underway at NASA Glenn Research Center.

Wiesner, Valerie L.↗

NASA NTRS1974

Glass-to-metal seals comprising relatively high expansion metals

A glass suitable for glass-to-metal seals that has a resistance to attack by moisture and a high coefficient of linear thermal expansion is introduced. Linear expansion covers the range from 12 to 14 x 10 to the minus 6 C between room temperature and 500 C. The glass is essentially composed of, by molar percent, about 9% of K2O, about 10% of Na2O, about 70% of SiO2, about 6% Al2O3, and about 5% of MgO.

Hirayama, C.↗

NASA NTRS1975

Theoretical aerodynamics of upper-surface-blowing jet-wing interaction

A linear, inviscid subsonic compressible flow theory is formulated to treat the aerodynamic interaction between the wing and an inviscid upper-surface-blowing (USB) thick jet with Mach number nonuniformity. The predicted results show reasonably good agreement with some available lift and induced-drag data. It was also shown that the thin-jet-flap theory is inadequate for the USB configurations with thick jet. Additional theoretical results show that the lift and induced drag were reduced by increasing jet temperature and increased by increasing jet Mach number. Reducing jet aspect ratio, while holding jet area constant, caused reductions in lift, induced drag, and pitching moment at a given angle of attack but with a minimal change in the curve of lift coefficient against induced-drag coefficient. The jet-deflection effect was shown to be beneficial to cruise performance. The aerodynamic center was shifted forward by adding power or jet-deflection angle. Moving the jet away from the wing surface resulted in rapid changes in lift and induced drag. Reducing the wing span of a rectangular wing by half decreased the jet-circulation lift by only 24 percent at a thrust coefficient of 2.

Lan, C. E.↗

NASA NTRS1975

Abort-once-around entry dispersion corridor analysis

Abort-Once-Around (AOA) entry dispersion corridors were determined for Shuttle Mission 3A. These corridors are presented as plots of entry interface flight path angle versus range to target. The methods used to determine the corridors are discussed. Major dispersion sources are discussed and results presented. While specific trajectory inputs and constraints are subject to change, the dispersion corridors show the trends under consideration. The corridors presented show the delta V advantage of the two-burn over the one-burn AOA. The atmospheric dispersion study illustrates the need to target for the seasonal atmosphere. The 40 deg/30 deg angle of attack (alpha) (TPS design) profile did not provide adequate crossrange capability with worst case aerodynamic dispersions. This problem was alleviated with the change to a 38 deg/28 deg alpha profile. The backface temperatures calculated were generally higher than the present limits.

Kyle, H. C.↗

NASA NTRS1990

Analysis of a six-component, flow-through, strain-gage, force balance used for hypersonic wind tunnel models with scramjet exhaust flow simulation

The thermal effects of simulant gas injection and aerodynamic heating at the model's surface on the measurements of a non-watercooled, flow through balance were investigated. A stainless steel model of a hypersonic air breathing propulsion cruise missile concept (HAPCM-50) was used to evaluate this balance. The tests were conducted in the 20-inch Mach 6 wind tunnel at NASA-Langley. The balance thermal effects were evaluated at freestream Reynolds numbers ranging from .5 to 7 x 10(exp 6) ft and angles of attack between -3.5 to 5 deg at Mach 6. The injection gases considered included cold air, hot air, and a mixture of 50 percent Argon and 50 percent Freon-12. The stagnation temperatures of the cold air, hot air, and Ar-Fr(12) reached 111, 214, and 283 F, respectively within the balance. A bakelite sleeve was inserted into the inner tube of the balance to minimize the thermal effects of these injection gases. Throughout the tests, the normal force, side force, yaw moment, roll moment, and pitching moment balance measurements were unaffected by the balance thermal effects of the injection gases and the wind tunnel flow. However, the axial force (AF) measurement was significantly affected by balance heating. The average zero shifts in the AF measurements were 1.9, 3.8, and 5.9 percent for cold air, hot air, and Ar-Fr(12) injection, respectively. The AF measurements decreased throughout these tests which lasted from 70 to 110 seconds. During the cold air injection tests, the AF measurements were accurate up to at least ten seconds after the model was injected into the wind tunnel test section. For the hot air and Ar-Fr(12) tests, the AF measurements were accurate up to at least five seconds after model injection.

Kniskern, Marc W.↗

DOE OSTI2024

Direct propylene epoxidation via water activation over Pd-Pt electrocatalysts

Direct electrochemical propylene epoxidation by means of water-oxidation intermediates presents a sustainable alternative to existing routes that involve hazardous chlorine or peroxide reagents. Here, we report an oxidized palladium-platinum alloy catalyst (PdPtO x /C), which reaches a Faradaic efficiency of 66 ± 5% toward propylene epoxidation at 50 milliamperes per square centimeter at ambient temperature and pressure. Embedding platinum into the palladium oxide crystal structure stabilized oxidized platinum species, resulting in improved catalyst performance. The reaction kinetics suggest that epoxidation on PdPtO x /C proceeds through electrophilic attack by metal-bound peroxo intermediates. This work demonstrates an effective strategy for selective electrochemical oxygen-atom transfer from water, without mediators, for diverse oxygenation reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1953

Effect of Ice and Frost Formations on Drag of NACA 65(sub 1) -212 Airfoil for Various Modes of Thermal Ice Protection

The effects of primary and. runback icing and frost formations on the drag of an 8-foot-chord NACA 651-212 airfoil section were investigated over a range of angles of attack from 20 to 80 and airspeeds up to 260 miles per hour for icing conditions with liquid-water contents ranging from 0.25 to 1.4 grams per cubic meter and datum air temperatures of -30 to 30 F. The results showed that glaze-ice formations, either primary or runback, on the upper surface near the leading edge of the airfoil caused large and rapid increases in drag, especially at datum air temperatures approaching 32 F and in the presence of high rates of water catch. Ice formations at lower temperatures (rime ice) did not appreciably increase the drag coefficient over the initial (standard roughness) drag coefficient. Cyclic de-icing of the primary Ice formations on the airfoil leading-edge section permitted the drag coefficient to return almost to the bare airfoil drag value. Runback icing on the lower surface did not present a serious drag problem except when heavy spanwise ridges of runback ice occurred aft of the heatable area. Frost formations caused rapid and large increases in drag with incipient stalling of the airfoil.

Gray, V. H.↗

NASA NTRS1973

Wind-tunnel calibration and requirements for in-flight use of fixed hemispherical head angle-of-attack and angle-of-sideslip sensors

Wind-tunnel tests were conducted with three different fixed pressure-measuring hemispherical head sensor configurations which were strut-mounted on a nose boom. The tests were performed at free-stream Mach numbers from 0.2 to 3.6. The boom-angle-of-attack range was -6 to 15 deg, and the angle-of-sideslip range was -6 to 6 deg. The test Reynolds numbers were from 3.28 million to 65.6 million per meter. The results were used to obtain angle-of-attack and angle-of-sideslip calibration curves for the configurations. Signal outputs from the hemispherical head sensor had to be specially processed to obtain accurate real-time angle-of-attack and angle-of-sideslip measurements for pilot displays or aircraft systems. Use of the fixed sensors in flight showed them to be rugged and reliable and suitable for use in a high temperature environment.

Montoya, E. J.↗

NASA NTRS1954

Effect of Ice Formations on Section Drag of Swept NACA 63A-009 Airfoil with Partial-Span Leading-Edge Slat for Various Modes of Thermal Ice Protection

The effects of primary and runback ice formations on the section drag of a 36 deg swept NACA 63A-009 airfoil section with a partial-span leading-edge slat were studied over a range of angles of attack from 2 to 8 deg and airspeeds up to 260 miles per hour for icing conditions with liquid-water contents ranging from 0.39 to 1.23 grams per cubic meter and datum air temperatures from 10 to 25 F. The results with slat retracted showed that glaze-ice formations caused large and rapid increases in section drag coefficient and that the rate of change in section drag coefficient for the swept 63A-009 airfoil was about 2-1 times that for an unswept 651-212 airfoil. Removal of the primary ice formations by cyclic de-icing caused the drag to return almost to the bare-airfoil drag value. A comprehensive study of the slat icing and de-icing characteristics was prevented by limitations of the heating system and wake interference caused by the slat tracks and hot-gas supply duct to the slat. In general, the studies showed that icing on a thin swept airfoil will result in more detrimental aerodynamic characteristics than on a thick unswept airfoil.

VonGlahn, Uwe H.↗

NASA NTRS1989

Low-speed flowfield characterization by infrared measurements of surface temperatures

An experimental program was aimed at identifying areas in low speed aerodynamic research where infrared imaging systems can make significant contributions. Implementing a new technique, a long electrically heated wire was placed across a laminar jet. By measuring the temperature distribution along the wire with the IR imaging camera, the flow behavior was identified. Furthermore, using Nusselt number correlations, the velocity distribution could be deduced. The same approach was used to survey wakes behind cylinders in a wind-tunnel. This method is suited to investigate flows with position dependent velocities, e.g., boundary layers, confined flows, jets, wakes, and shear layers. It was found that the IR imaging camera cannot accurately track high gradient temperature fields. A correlation procedure was devised to account for this limitation. Other wind-tunnel experiments included tracking the development of the laminar boundary layer over a warmed flat plate by measuring the chordwise temperature distribution. This technique was applied also to the flow downstream from a rearward facing step. Finally, the IR imaging system was used to study boundary layer behavior over an airfoil at angles of attack from zero up to separation. The results were confirmed with tufts observable both visually and with the IR imaging camera.

Gartenberg, E.↗

NASA NTRS1992

Large scale crystallization of protein pharmaceuticals in microgravity via temperature change

The major objective of this research effort is the temperature driven growth of protein crystals in large batches in the microgravity environment of space. Pharmaceutical houses are developing protein products for patient care, for example, human insulin, human growth hormone, interferons, and tissue plasminogen activator or TPA, the clot buster for heart attack victims. Except for insulin, these are very high value products; they are extremely potent in small quantities and have a great value per gram of material. It is feasible that microgravity crystallization can be a cost recoverable, economically sound final processing step in their manufacture. Large scale protein crystal growth in microgravity has significant advantages from the basic science and the applied science standpoints. Crystal growth can proceed unhindered due to lack of surface effects. Dynamic control is possible and relatively easy. The method has the potential to yield large quantities of pure crystalline product. Crystallization is a time honored procedure for purifying organic materials and microgravity crystallization could be the final step to remove trace impurities from high value protein pharmaceuticals. In addition, microgravity grown crystals could be the final formulation for those medicines that need to be administered in a timed release fashion. Long lasting insulin, insulin lente, is such a product. Also crystalline protein pharmaceuticals are more stable for long-term storage. Temperature, as the initiation step, has certain advantages. Again, dynamic control of the crystallization process is possible and easy. A temperature step is non-invasive and is the most subtle way to control protein solubility and therefore crystallization. Seeding is not necessary. Changes in protein and precipitant concentrations and pH are not necessary. Finally, this method represents a new way to crystallize proteins in space that takes advantage of the unique microgravity environment. The results from two flights showed that the hardware performed perfectly, many crystals were produced, and they were much larger than their ground grown controls. Morphometric analysis was done on over 4,000 crystals to establish crystal size, size distribution, and relative size. Space grown crystals were remarkably larger than their earth grown counterparts and crystal size was a function of PCF volume. That size distribution for the space grown crystals was a function of PCF volume may indicate that ultimate size was a function of temperature gradient. Since the insulin protein concentration was very low, 0.4 mg/ml, the size distribution could also be following the total amount of protein in each of the PCF's. X-ray analysis showed that the bigger space grown insulin crystals diffracted to higher resolution than their ground grown controls. When the data were normalized for size, they still indicated that the space crystals were better than the ground crystals.

Long, Marianna M.↗

DOE OSTI2022

Understanding Hydrogenation Chemistry at MgB 2 Reactive Edges from Ab Initio Molecular Dynamics

Solid-state hydrogen storage materials often operate via transient, multistep chemical reactions at complex interfaces that are difficult to capture. Here, we use direct ab initio molecular dynamics simulations at accelerated temperatures and hydrogen pressures to probe the hydrogenation chemistry of the candidate material MgB 2 without a priori assumption of reaction pathways. Focusing on highly reactive ($10\overline{1}0$) edge planes where initial hydrogen attack is likely to occur, we track mechanistic steps toward the formation of hydrogen-saturated BH 4 – units and key chemical intermediates, involving H 2 dissociation, generation of functionalities and molecular complexes containing BH 2 and BH 3 motifs, and B–B bond breaking. Further, the genesis of higher-order boron clustering is also observed. Different charge states and chemical environments at the B-rich and Mg-rich edge planes are found to produce different chemical pathways and preferred speciation, with implications for overall hydrogenation kinetics. The reaction processes rely on B–H bond polarization and fluctuations between ionic and covalent character, which are critically enabled by the presence of Mg 2+ cations in the nearby interphase region. Our results provide guidance for devising kinetic improvement strategies for MgB 2 -based hydrogen storage materials, while also providing a template for exploring chemical pathways in other solid-state energy storage reactions.

08 HYDROGEN↗