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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Computing Equilibrium Chemical Compositions

Chemical Equilibrium With Transport Properties, 1993 (CET93) computer program provides data on chemical-equilibrium compositions. Aids calculation of thermodynamic properties of chemical systems. Information essential in design and analysis of such equipment as compressors, turbines, nozzles, engines, shock tubes, heat exchangers, and chemical-processing equipment. CET93/PC is version of CET93 specifically designed to run within 640K memory limit of MS-DOS operating system. CET93/PC written in FORTRAN.

Mcbride, Bonnie J.↗

Kinetics of Nucleation and Crystal Growth in Glass Forming Melts in Microgravity

The following list summarizes the most important results that have been consistently reported for glass forming melts in microgravity: (1) Glass formation is enhanced for melts prepared in space; (2) Glasses prepared in microgravity are more chemically homogeneous and contain fewer and smaller chemically heterogeneous regions than identical glasses prepared on earth; (3) Heterogeneities that are deliberately introduced such as Pt particles are more uniformly distributed in a glass melted in space than in a glass melted on earth; (4) Glasses prepared in microgravity are more resistant to crystallization and have a higher mechanical strength and threshold energy for radiation damage; and (5) Glasses crystallized in space have a different microstructure, finer grains more uniformly distributed, than equivalent samples crystallized on earth. The preceding results are not only scientifically interesting, but they have considerable practical implications. These results suggest that the microgravity environment is advantageous for developing new and improved glasses and glass-ceramics that are difficult to prepare on earth. However, there is no suitable explanation at this time for why a glass melted in microgravity will be more chemically homogeneous and more resistant to crystallization than a glass melted on earth. A fundamental investigation of melt homogenization, nucleation, and crystal growth processes in glass forming melts in microgravity is important to understanding these consistently observed, but yet unexplained results. This is the objective of the present research. A lithium disilicate (Li2O.2SiO2) glass will be used for this investigation, since it is a well studied system, and the relevant thermodynamic and kinetic parameters for nucleation and crystal growth at 1-g are available. The results from this research are expected to improve our present understanding of the fundamental mechanism of nucleation and crystal growth in melts and liquids, and to lead improvements in glass processing technology on earth, with the potential for creating new high performance glasses and glass-ceramics.

Day, Delbert E.↗

Retrieval Assimilation and Modeling of Atmospheric Water Vapor from Ground- and Space-Based GPS Networks: Investigation of the Global and Regional Hydrological Cycles

Uncertainty over the response of the atmospheric hydrological cycle (particularly the distribution of water vapor and cloudiness) to anthropogenic forcing is a primary source of doubt in current estimates of global climate sensitivity, which raises severe difficulties in evaluating its likely societal impact. Fortunately, a variety of advanced techniques and sensors are beginning to shed new light on the atmospheric hydrological cycle. One of the most promising makes use of the sensitivity of the Global Positioning System (GPS) to the thermodynamic state, and in particular the water vapor content, of the atmosphere through which the radio signals propagate. Our strategy to derive the maximum benefit for hydrological studies from the rapidly increasing GPS data stream will proceed in three stages: (1) systematically analyze and archive quality-controlled retrievals using state-of-the-art techniques; (2) employ both currently available and innovative assimilation procedures to incorporate these determinations into advanced regional and global atmospheric models and assess their effects; and (3) apply the results to investigate selected scientific issues of relevance to regional and global hydrological studies. An archive of GPS-based estimation of total zenith delay (TZD) data and water vapor where applicable has been established with expanded automated quality control. The accuracy of the GPS estimates is being monitored; the investigation of systematic errors is ongoing using comparisons with water vapor radiometers. Meteorological packages have been implemented. The accuracy and utilization of the TZD estimates has been improved by implementing a troposphere gradient model. GPS-based gradients have been validated as real atmospheric moisture gradients, establishing a link between the estimated gradients and the passage of weather fronts. We have developed a generalized ray tracing inversion scheme that can be used to analyze occultation data acquired from space- or land-based receivers. The National Center for Atmospheric Research mesoscale model (version MM5) has been adapted for Southern California, and assimilation studies are underway. Additional information is contained in the original.

Dickey, Jean O.↗

G-jitter Effects on Transport and Pattern Formation

The research performed under this grant has led to an number of new insights into two general categories of fluid flows in the presence of time-dependent acceleration, as outlined briefly below. These results have been widely communicated in the scientific community through seven presentations at international conferences (4 invited, 3 contributed), five published papers (4 journal articles and 1 conference proceeding), and images from the research featured on the cover of all 2003 editions of the research journal, Nonlinearity. The work performed under this proposal also contained a substantial educational component by contributed significantly to the scientific training of one postdoctoral associate, one Ph.D. student and five undergraduate researchers. One main area of focus in this research was convective flow with time-dependent acceleration. Convection is one class of behavior that can arise from g-jitter effects. Our research focused on studies of Rayleigh-Benard system, which is an important model for understanding thermal convection; studies of this problem in the presence of acceleration modulations provided insight into the nature of g-jitter induced flow and of the effects of modulation and noise on non-equilibrium pattern formation. Our experiments on vertically vibrated Rayleigh-Benard convection demonstrated the existence of two classes of pure flow patterns (synchronous & subharmonic) patterns) that had long been predicted by theory but never before observed experimentally. Detailed studies of ranges of parameters where both classes of patterns exist simultaneously led to the discovery of a new type of patterns (called superlattices) in systems driven out of thermodynamic equilibrium.

Schatz, Michael F.↗

Catalysis in the 3rd Dimension: How Organic Molecules May be Formed

Catalysis is often little more than a word to phenomenologically describe the fact that a reaction follows a pat1 that leads to products of an unexpected kind or of unexpected yield. Low activation energy barriers for intermediates are recognized as the most likely cause why a system deviates from the thermodynamic pull towards minimizing its free energy and ends up in a metastable state. Seldom is the mechanism known. This i: particularly true for heterogeneous catalysis under hydrothermal conditions with minerals as catalysts. It is commonly assumed that catalytic action takes place across solid-fluid interfaces and that, on the atomic level, interfaces are just 2-dimensional contacts. This makes it difficult to understand, for instance, the assembly of long-chain carboxylic (fatty) acids. 3y studying single crystals that grew from a melt in the presence of H2O and CO2, we can show: (1) that numerals take up the fluid components into solid solution, (2) that some-thing happens converting them to -educedH and C, (3) that C atoms segregate into dislocations and tie C-C bonds. The products are medium-to-long chain Cn protomolecules, with some C-H attached, pre-assembled in the dislocations. Upon solvent extraction, these proto-molecules turn into carboxylic and dicarboxylic acids. This observation suggests that, in a very elementary step, catalysis under hydrothermal conditions leading to fatty acids involves the pre-assembly of Cn entities in the interface that is not 2-D but extends into the 3rd dimension, with dislocations as synthesis sites.

Freund, Friedemann↗

Behavior of a Polydisperse Cluster of Drops Evaporating in a Vortex

A model has been developed to describe the dynamics and evaporation of polydisperse collections of liquid drops in an axisymmetric, infinite, cylindrical vortex. This formulation is valid both in the dense regime, where interactions between particles are important, and in the dilute regime, where interactions between particles are not important. In contrast to the standard way of discretizing polydisperse collections of particles, where the initial size distribution is partitioned into a finite number of bins and these bins are fixed during the calculation, here it is only the initial size distribution which is partitioned into a finite number of sizes. Each initial size class thus defined is followed dynamically and thermodynamically in its own system of coordinates which moves with the drops. Therefore, each initial size class develops a continuum of sizes as the drops are centrifuged towards the hotter ambient and evaporate. The gas phase is followed in its own system of coordinates.

liquid evaporation liquid dispersal particle flow↗

Miniature reciprocating heat pumps and engines

The present invention discloses a miniature thermodynamic device that can be constructed using standard micro-fabrication techniques. The device can be used to provide cooling, generate power, compress gases, pump fluids and reduce pressure below ambient (operate as a vacuum pump). Embodiments of the invention relating to the production of a cooling effect and the generation of electrical power, change the thermodynamic state of the system by extracting energy from a pressurized fluid. Energy extraction is attained using an expansion process, which is as nearly isentropic as possible for the appropriately chosen fluid. An isentropic expansion occurs when a compressed gas does work to expand, and in the disclosed embodiments, the gas does work by overcoming either an electrostatic or a magnetic force.

Thiesen, Jack H.↗

Analyzing Changes in the Complexity of Climate in the Last Four Decades Using MERRA-2 Radiation Data

The energy balance of the Earth is controlled by the shortwave and longwave radiation emitted to space. Changes in the thermodynamic state of the system over time afect climate and are noticeable when viewing the system as a whole. In this paper, we study the changes in the complexity of climate in the last four decades using data from the Modern-Era Retrospective analysis for Research and Applications, Version 2 (MERRA-2). First, we study the complexity of the shortwave and longwave radiation felds independently using Approximate Entropy and Sample Entropy, observing that the rate of complexity change is faster for shortwave radiation. Then, we study the causality of those changes using Transfer Entropy to capture the non-linear dynamics of climate, showing that the changes are mainly driven by the variations in shortwave radiation. The observed behavior of climatic complexity could be explained by the changes in cloud amount, and we research that possibility by investigating its evolution from a complexity perspective using data from the International Satellite Cloud Climatology Project (ISCCP).

Delgado-Bonal, Alfonso↗

Frequency-dependent hydrodynamic inductance and the determination of the thermal and quantum noise of a superfluid gyroscope

We reexamine mass flow in a superfluid gyroscope containing a superfluid Josephson weak link. We introduce a frequency-dependent hydrodynamic inductance to account for an oscillatory flow of the normal fluid component in the sensing loop. With this hydrodynamic inductance, we derive the thermal phase noise, and hence the thermal rotational noise of the gyroscope. We examine the thermodynamic stability of the system based on an analysis of the free energy. We derive a quantum phase noise, which is analogous to the zero-point motion of a simple harmonic oscillator. The configuration of the studied gyroscope is analogous to a conventional superconducting RF SQUID. We show that the gyroscope has very low intrinsic noise (1.9x10(-13) rad s(-1)/root Hz), and it can potentially be applied to study general relativity, Earth science, and to improve global positioning systems (GPS).

Penanen, Konstantin↗

Sustainable Resource Recovery from Trash, Waste, and Overboard Venting

Space travel and planetary missions for long-endurance human presence require Environmental Control and Life Support (ECLS) loop-closure. The air and water resource loops are generally closed with their processes having been established through extensive development, testing, and long-term use on International Space Station. Closure of the air and water loops have enabled oxygen and hydrogen sustainability. Carbon sustainability has yet to be addressed. Waste and trash, which also contains hydrogen and oxygen and abundant carbon have not been developed to the extent air and water have. Waste and trash have generally been dealt with in terms of simple safening, storage, and disposal. In externally disposing of waste, which includes C1 and C2 hydrocarbon gases, lost resources not only increase mission cost they can result in space and planetary pollution that can lead to unfavorable public opinion. With all this in mind, we explore the idea of carbon sustainability within closed-cycle waste, trash, and C1/C2 reprocessing. Starting from the current ECLS System roadmap, we identify resources that are not yet captured in closed-cycle processes but are lost when crossing the thermodynamic boundaries of an open system. Such pseudo-resources are trash, waste, and the gaseous carbon products of carbon dioxide reduction. We then consider different means and processes for minimizing pseudo-resource loss so as to “close the carbon loop.” There are cases in which pseudo-resources need to be externally discarded, such as reducing spacecraft acceleration mass. In this case we examine various processes that can be beneficial to missions even when these pseudo-resources are lost. An example would be the conversion of waste into propellant, which can produce thrust while at the same time reducing mass for transit acceleration (and ultimately propellant mass at launch), in which case we propose a means for evaluating the value of converting waste into propellant for different propulsion systems.

waste↗

An Introduction to Thermodynamic Performance Analysis of Aircraft Gas Turbine Engine Cycles Using the Numerical Propulsion System Simulation Code

This document is intended as an introduction to the analysis of gas turbine engine cycles using the Numerical Propulsion System Simulation (NPSS) code. It is assumed that the analyst has a firm understanding of fluid flow, gas dynamics, thermodynamics, and turbomachinery theory. The purpose of this paper is to provide for the novice the information necessary to begin cycle analysis using NPSS. This paper and the annotated example serve as a starting point and by no means cover the entire range of information and experience necessary for engine performance simulation. NPSS syntax is presented but for a more detailed explanation of the code the user is referred to the NPSS User Guide and Reference document (ref. 1).

Jones, Scott M.↗

BIPS Turboalternator-Compressor characteristics and application to the NASA Solar Dynamic Ground Demonstration Program

The NASA-sponsored 2kW(e) Solar Dynamic Space Power System Ground Test Demonstration Program requires the physical and the thermodynamic integration of the Brayton Isotope Power System (BIPS) Turboalternator-Compressor (TAC) and recuperator with a heat receiver, solar concentrator, and radiator based on Space Station Freedom designs. The aim of the designs is to provide a cost-effective, minimal-risk, viable ground test system. This paper describes the BIPS TAC configuration and performance characteristics along with the cycle analysis of BIPS TAC.

Amundsen, Peter C.↗

Advanced Developments for Low Temperature Turbo-Brayton Cryocoolers

Turbo-Brayton cryocooler technology that has been space qualified and demonstrated on the NICMOS cryocooler is being adapted for applications with lower cooling loads at lower telqoeratures. The applications include sensor cooling for space platforms and telescopes at temperatures between 4 K and 35 K, where long life and reliable, vibration-free operation are important. This paper presents recent advances in the miniaturization of components that are critical to these systems. Key issues addressed in adapting the NICMOS cryocooler technology to lower temperatures involve reducing parasitic losses when scaling to smaller size machines. Recent advances include the successful design and testing of a small, permanent magnet driven compressor that operates at up to 10,000 rev/sec and the successful demonstration of self acting gas bearings supporting a I mm. diameter shaft. The compressor is important for cryocoolers with input powers between 50 W and 100 W. The miniature shaft and bearing system has applications in compressors and turbines at temperatures from 300 K to 6 K. These two technology milestones are fundamental to achieving exceptional thermodynamic performance from the turboBrayton system in low temperature systems. The paper discusses the development of these components and test results, and presents the implications of their performance on cryocooler systems.

Nellis, G. F.↗

Fusion for Space Propulsion

There is little doubt that humans will attempt to explore and develop the solar system in this century. A large amount of energy will be required for accomplishing this. The need for fusion propulsion is discussed. For a propulsion system, there are three important thermodynamical attributes: (1) The absolute amount of energy available, (2) the propellant exhaust velocity, and (3) the jet power per unit mass of the propulsion system (specific power). For human exploration and development of the solar system, propellant exhaust velocity in excess of 100 km/s and specific power in excess of 10 kW/kg are required. Chemical combustion can produce exhaust velocity up to about 5 km/s. Nuclear fission processes typically result in producing energy in the form of heat that needs to be manipulated at temperatures limited by materials to about 2,800 K. Using the energy to heat a hydrogen propellant increases the exhaust velocity by only a factor of about two. Alternatively the energy can be converted into electricity which is then used to accelerate particles to high exhaust velocity. The necessary power conversion and conditioning equipment, however, increases the mass of the propulsion system for the same jet power by more than two orders of magnitude over chemical system, thus greatly limits the thrust-to-weight ratio attainable. The principal advantage of the fission process is that its development is relatively mature and is available right now. If fusion can be developed, fusion appears to have the best of all worlds in terms of propulsion - it can provide the absolute amount, the propellant exhaust velocity, and the high specific jet power. An intermediate step towards pure fusion propulsion is a bimodal system in which a fission reactor is used to provide some of the energy to drive a fusion propulsion unit. The technical issues related to fusion for space propulsion are discussed. The technical priorities for developing and applying fusion for propulsion are somewhat different from those for terrestrial electrical power generation. Thus fusion schemes that are initially attractive for electrical power generation might not necessarily be attractive also for propulsion and vice versa, though the underlying fusion science and engineering enjoy much overlap. Parallel efforts to develop these qualitatively differently fusion schemes for the two applications could benefit greatly from each other due to the synergy in the underlying physics and engineering. Pulsed approaches to fusion have not been explored to the same degree as steady-state or long-pulse approaches to fusion in the fusion power research program. The concerns early on were several. One was that the pulsed power components might not have the service lifetimes meeting the requirements of a practical power generating plant. Another was that, for many pulsed fusion schemes, it was not clear whether the destruction of hardware per pulse could be minimized or eliminated or recycled to such an extent as to make economical electrical power generation feasible, Significant development of the underlying pulsed power component technologies have occurred in the last two decades because of defense and other energy requirements. The state of development of the pulsed power technologies are sufficiently advanced now to make it compelling to visit or re-visit pulsed fusion approaches for application to propulsion where the cost of energy is not so demanding a factor as in the case of terrestrial power application. For propulsion application, the overall mass of the fusion system is the critical factor. Producing fusion reactions require extreme states of matter. Conceptually, these extreme states of matter are more readily realizable in the pulsed states, at least within appropriate bounds, than in the steady states. Significant saving in system mass may result in such systems. Magnetic fields are effective in confining plasma energy, whereas inertial compression is an effective way of heating and containing the plasma. Intensive research in developing magnetic energy containment and inertial plasma compression are being pursued in distinctively different fusion experiments in the terrestrial fusion power program. Fusion schemes that attempt to combine the favorable attributes of these two aspects into one single integrated fusion scheme appear to have benefits that are worth exploring for propulsion application.

Thio, Y. C. Francis↗

Transport-induced shifts in condensate dew-point and composition in multicomponent systems with chemical reaction

Partial heterogeneous condensation phenomena in multicomponent reacting systems are analyzed taking into consideration the chemical element transport phenomena. It is demonstrated that the dew-point surface temperature in chemically reactive systems is not a purely thermodynamic quantity, but is influenced by the multicomponent diffusion and Soret-mass diffusion phenomena. Several distinct dew-points are shown to exist in such systems and, as a result of transport constraints, the 'sharp' locus between two chemically distinct condensates is systematically moved to a difference mainstream composition.

Rosner, D. E.↗

Hydrogen interactions with metals

Review of the literature on the nature and extent of hydrogen interactions with metals and the role of hydrogen in metal failure. The classification of hydrogen-containing systems is discussed, including such categories as covalent hydrides, volatile hydrides, polymeric hydrides, and transition metal hydride complexes. The use of electronegativity as a correlating parameter in determining hydride type is evaluated. A detailed study is made of the thermodynamics of metal-hydrogen systems, touching upon such aspects as hydrogen solubility, the positions occupied by hydrogen atoms within the solvent metal lattice, the derivation of thermodynamic functions of solid solutions from solubility data, and the construction of statistical models for hydrogen-metal solutions. A number of theories of hydrogen-metal bonding are reviewed, including the rigid-band model, the screened-proton model, and an approach employing the augmented plane wave method to solve the one-electron energy band problem. Finally, the mechanism of hydrogen embrittlement is investigated on the basis of literature data concerning stress effects and the kinetics of hydrogen transport to critical sites.

Mclellan, R. B.↗

Compressed gas handbook

Handbook includes thermodynamic and related fluid flow data required to analyze high pressure compressible and incompressible fluid systems. Some theory and applications include thermodynamic fundamentals, gas behavior, adiabatic and isentropic flow, shock waves, flow measurement, and adiabatic and isothermal friction flow in pipes.

Cota, R. A.↗

Transferring superfluid helium in space

A simple thermodynamic model of a transfer system for resupplying liquid helium in space is presented, with application to NASA projects including the Space Infrared Telescope Facility, the Large Deployable Reflector, and the Hubble Space Telescope. The relations between different thermodynamic regimes that can be expected in the transfer line are used to study the relative efficiencies of various possible transfer techniques. Low heat leak into the transfer line, particularly at point sources such as the coupling, is necesssary for efficient transfer of liquid helium, and proper selection of supply tank temperature is important during helium resupply.

Kittel, Peter↗