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At least 343 records · Page 19

Mid-Infrared Spectra of Mercury

Mid-infrared (8-13 microns) spectra of radiation emitted from the surface of solar system objects can be interpreted in terms of surface composition. However, the spectral features are weak, and require exceptionally high signal-to-noise ratio spectra to detect them. Ground-based observations of spectra in this region are plagued by strong atmospheric absorptions from water and ozone. High-altitude balloon measurements that avoid atmospheric absorptions can be affected by contamination of the optics by dust. We have developed a technique to obtain mid-infrared spectra of Mercury that minimizes these problems. The resulting spectra show evidence of transparency features that can be used to qualitatively characterize the surface composition. Additional information is contained in the original extended abstract.

Cooper, B.↗

The spectral reflectance of water-mineral mixtures at low temperatures

Laboratory reflectance spectra in the 0.325-2.5 micron region of bound water, water-mineral mixtures, mineral grains on frost, and frost on minerals are presented. The materials used in this study are montmorillonite, kaolinite, beryl, Mauna Kea red cinder, and black charcoal. It is found that the wavelengths of bound water and bound OH absorptions do not shift appreciably with temperature and can be detected when large amounts of free water ice are present. The decrease in the visible reflectance seen in many planetary reflectance spectra containing strong water ice absorptions can be explained by water-mineral mixtures, mineral grains on frost, or frost on mineral grains. Mineral grains on frost are detectable in very small quantities (fractional areal coverage less than approximately 0.005) depending on the mineral reflectance features, while it takes a thick layer of frost (greater than approximately 1 mm) to mask a mineral below 1.4 microns, again depending on the mineral reflectance. Frost on a very dark surface (albedo about 6%) is easily seen; however, a dark mineral mixed with water could completely mask the water absorptions (shortward of 2.5 microns).

Clark, R. N.↗

One-parameter scaling and exponential-sum fitting for water vapor and CO2 infrared transmission functions

A medium-sized band model for water vapor and CO2 absorption is developed using the one-parameter scaling approximation. The infrared spectrum is divided into 10 bands. The Planck-weighted diffuse transmittance is reduced to a function dependent only upon the scaled absorber amount and fit by an exponential sum. By selecting specific sets of absorption coefficients for exponential-sum fitting, computations of fluxes and cooling rate are made very fast. Compared to a broadband model, the accuracy, speed, and versatility are all enhanced. With absorption due to water vapor line, continuum, CO2 as well as O3 included, the parameterization introduces an error of less than 1.5 W/sq m in fluxes and less than 0.15 C/day in the tropospheric and lower stratospheric cooling rates.

Chou, Ming-Dah↗

Airborne differential absorption lidar system for measurements of atmospheric water vapor and aerosols

An airborne differential absorption lidar (DIAL) system has been developed at the NASA Langley Research Center for remote measurements of atmospheric water vapor (H2O) and aerosols. A solid-state alexandrite laser with a 1-pm linewidth and greater than 99.85% spectral purity was used as the on-line transmitter. Solid-state avalanche photodiode detector technology has replaced photomultiplier tubes in the receiver system, providing an average increase by a factor of 1.5-2.5 in the signal-to-noise ratio of the H2O measurement. By incorporating advanced diagnostic and data-acquisition instrumentation into other subsystems, we achieved additional improvements in system operational reliability and measurement accuracy. Laboratory spectroscopic measurements of H2O absorption-line parameters were performed to reduce the uncertainties in our knowledge of the absorption cross sections. Line-center H2O absorption cross sections were determined, with errors of 3-6%, for more than 120 lines in the 720-nm region. Flight tests of the system were conducted during 1989-1991 on the NASA Wallops Flight Facility Electra aircraft, and extensive intercomparison measurements were performed with dew-point hygrometers and H2O radiosondes. The H2O distributions measured with the DIAL system differed by less than 10% from the profiles determined with the in situ probes in a variety of atmospheric conditions.

Carter, Arlen F.↗

Single Frequency, Pulsed Laser Diode Transmitter for Dial Water Vapor Measurements at 935nm

We report a tunable, single frequency, narrow linewidth, pulsed laser diode transmitter at 935.68nm for remote sensing of atmospheric water vapor. The transmitter consists of a CW, tunable, external cavity diode laser whose output is amplified 2OdB using a tapered diode amplifier. The output is pulsed for range resolved DIAL lidar by pulsing the drive current to the diode amplifier at 4kHz with a .5% duty cycle. The output from the transmitter is 36OnJ/pulse and is single spatial mode. It maintains a linewidth of less than 25MHz as its wavelength is tuned across the water vapor absorption line at 935.68nm. The transmitter design and its use in a water vapor measurement will be discussed.

Switzer, Gregg W.↗

Spacesuit Evaporator-Absorber-Radiator (SEAR)

For decades advanced spacesuit developers have pursued a regenerable, robust non-venting system for heat rejection. Toward this end, this paper investigates linking together two previously developed technologies, namely NASA's Spacesuit Water Membrane Evaporator (SWME), and Creare's lithium chloride Heat Pump Radiator (HPR). Heat from a liquid cooled garment is transported to SWME that provides cooling through evaporation. The SEAR is evacuated at the onset of operations and thereafter, the water vapor absorption rate of the HPR maintains a low pressure environment for the SWME to evaporate effectively. This water vapor captured by solid LiCl in the HPR with a high enthalpy of absorption, results in sufficient temperature lift to reject most of the heat to space by radiation. After the sortie, the HPR would be heated up in a regenerator to drive off and recover the absorbed evaporant. A one-fourth scale prototype was built and tested in vacuum conditions at a sink temperature of 250 K. The HPR was able to stably reject 60 W over a 7-hour period. A conceptual design of a full-scale radiator is proposed. Excess heat rejection above 240 W would be accomplished through venting of the evaporant. Loop closure rates were predicted for various exploration environment scenarios.

Bue, Grant C.↗

Water vapor measurements in the 0.94 micron absorption band - Calibration, measurements and data applications

This paper describes methods and presents results for sensing the columnar content of atmospheric water vapor via differential solar transmission measurements in and adjacent to the 0.94-micron water-vapor absorption band. Calibration and measurement techniques are presented for obtaining the water vapor transmission from the radiometer measurements. Models are also presented for retrieving the columnar water vapor amount from the estimated transmission. Example retrievals are presented for radiometer measurements made during the 1986 Arizona Monsoon Season to track temporal variations in columnar water vapor amount.

Reagan, J. A.↗

Observation of ice mantles toward HD 29647

The water ice absorption band at 3.1 microns has been observed in HD 29647, which is a late B type star with an anomalous ultraviolet extinction curve. The interpretation is that ice mantles are present on the dust grains in the intervening cloud and that these mantles are responsible for suppressing the 2200 A interstellar absorption feature. This is the first observation of both the 2200 A region and the 3.1 micron interstellar absorption feature toward the same star. A comparison of recent UV laboratory data of water ice with the UV spectrum of HD 29647 further supports the presence of water ice mantles in the same column density as that observed in the infrared. The diffuse interstellar features have been reported to be weakened in this star, consistent with their origin being on grain core surfaces, rather than in mantles or gaseous molecules.

Goebel, J. H.↗

Cloud and radiation experiments with a general circulation model

Interactions between cloud fields and radiation fields in GCM simulations were examined with June-July simulations with the UCLA/Goddard GCM. Modified radiation parameterizations for longwave and shortwave transfer were made to the GCM. The model generated supersaturation, boundary layer and convective clouds. The simulations were configured to consider the absence of water vapor absorption in the longwave parameterization, no appearance of anvils, and no detrainment of liquid water.

HARSHVARDHAN↗

An Intercomparison of Radiation Codes for Retrieving Upper Tropospheric Humidity in the 6.3-micron Band: A Report from the 1st GVaP Workshop

An intercomparison of radiation codes used in retrieving upper tropospheric humidity (UTH) from observations in the v2 (6.3 microns) water vapor absorption band was performed. This intercomparison is one part of a coordinated effort within the GEWEX Water Vapor Project (GVaP) to assess our ability to monitor the distribution and variations of upper tropospheric moisture from space-borne sensors. A total of 23 different codes, ranging from detailed line-by-line (LBL) models, to coarser resolution narrow-band (NB) models, to highly-parameterized single-band (SB) models participated in the study. Forward calculations were performed using a carefully selected set of temperature and moisture profiles chosen to be representative of a wide range of atmospheric conditions. The LBL model calculations exhibited the greatest consistency with each other, typically agreeing to within 0.5 K in terms of the equivalent blackbody brightness temperature (T(sub b)). The majority of NB and SB models agreed to within +/- 1 K of the LBL models, although a few older models exhibited systematic T(sub b) biases in excess of 2 K. A discussion of the discrepancies between various models, their association with differences in model physics (e.g. continuum absorption), and their implications for UTH retrieval and radiance assimilation is presented.

Soden, B.↗

A 94/183 GHz multichannel radiometer for Convair flights

A multichannel 94/183 GHz radiometer was designed, built, and installed on the NASA Convair 990 research aircraft to take data for hurricane penetration flights, SEASAT-A underflights for measuring rain and water vapor, and Nimbus-G underflights for new sea ice signatures and sea surface temperature data (94 GHz only). The radiometer utilized IF frequencies of 1, 5, and 8.75 GHz about the peak of the atmospheric water vapor absorption line, centered at 183.3 GHz, to gather data needed to determine the shape of the water molecule line. Another portion of the radiometer operated at 94 GHz and obtained data on the sea brightness temperature, sea ice signatures, and on areas of rain near the ocean surface. The radiometer used a multiple lens antenna/temperature calibration technique using 3 lenses and corrugated feed horns at 94 GHz and 183 GHz. Alignment of the feed beams at 94 GHz and 183 GHz was accomplished using a 45 deg oriented reflecting surface which permitted simultaneous viewing of the feeds on alternate cycles of the chopping intervals.

Gagliano, J. A.↗

Infrared Measurements of Several Nitrogen Species Above the South Pole in December 1980 and November - December 1986

In December 1980 and November-December 1986, the University of Denver atmospheric spectroscopy group recorded numerous high-resolution infrared solar absorption spectra from the Amundsen-Scott south pole station. These spectra were obtained by Frank J. Murcray and Frank H. Murcray with a Michelson-type Fourier transform spectrometer and show absorption features of a number of minor and trace atmospheric gases with a minimum of atmospheric water vapor absorption. Quantifications of the total column amounts of O3, CH4, N2O, and H2O from the 1980 observations and RCI from the 1986 observations have been reported along with an atlas of the 750-960/ cm spectral region. In the present study, we report measurements of HNO3 total column amounts deduced from both data sets and NO, and NO2 total column amounts from the 1986 data set. Nitric acid may be important in the chemistry which creates the spring Antarctic ozone minimum, since it may condense in the cold winter polar stratosphere and become the dominant component of polar stratospheric clouds. The present measurements were obtained shortly after the austral spring ozone minimum and define for the first time the ambient levels of these nitrogen species immediately following the breakup of the polar vortex.

Murcray, F. J.↗

Lunar Flashlight

The Lunar Flashlight is a Jet Propulsion Laboratory project, with NASA Marshall Space Flight Center (MSFC) serving as the principal investigator and providing the solar sail propulsion system. The goal of Lunar Flashlight is to determine the presence and abundance of exposed lunar water ice within permanently shadowed regions (PSRs) at the lunar south pole, and to map its concentration at the 1-2 kilometer scale to support future exploration and use. After being ejected in cis-lunar space by the launch vehicle, Lunar Flashlight deploys solar panels and an 85-square-meter solar sail and maneuvers into a low-energy transfer to lunar orbit. The solar sail and attitude control system work to bring the satellite into an elliptical polar orbit, spiraling down over a period of 18 months to a perilune of 30-10 kilometers above the south pole for data collection. Lunar Flashlight uses its solar sail to shine reflected sunlight onto the lunar surface, measuring surface reflectance with a four-filter point spectrometer. The spectrometer measures water ice absorption features (1.5, 1.95 microns) and the continuum between them (1.1, 1.9 microns). The ratios of water ice bands to the continuum will provide a measure of the abundance of surface frost and its variability across PSRs. Water ice abundance will be correlated with other data from previous missions, such as the Lunar Reconnaissance Orbiter and Lunar Crater Observation and Sensing Satellite, to provide future human and robotic explorers with a map of potential resources. The mission is enabled by the use of an 85-square-meter solar sail being developed by MSFC.

Baker, John↗

G-band FMCW Radar for Humidity Profiling Inside Boundary Layer Clouds

We are developing a G-band FMCW radar for remote sensing of vertical water vapor profiles and total column water vapor. The radar utilizes the frequency-dependent absorption near the 183 GHz water absorption line to obtain a differential signal from which we can derive range-resolved humidity measurements. This proof-of-concept instrument will eventually be tested from an airborne platform. In this report, we discuss recent measurements and a humidity profile retrieval algorithm based on an absorption line shape fitting model

Monje, Raquel↗

A radiative transfer model for surface radiation budget studies

A high resolution spectral radiative transfer model of the troposphere for computing downwelling radiance and flux density at the surface in the 5-200 micron region has been developed. The model is fast and accurate and takes into consideration all major and minor constituents active in this region, namely, water vapor, carbon dioxide, ozone, nitrous oxide, and methane. It uses the quasi-random band model of absorption for computing atmospheric transmittances due to various bands. Continuum absorption by water vapor in the 8-14 micron region has also been taken into account. The model has been used to examine the sensitivity of downwelling flux to variations of surface water vapor pressure (or surface relative humidity), water vapor scale-height and concentrations of other gaseous constituents of the atmosphere. In addition, sensitivity to changes in a number of cloud parameters, namely, fractional cloud cover, cloud height, and high-cloud emissivity, has also been examined. Results obtained with the present model compare well with those from the empirical and semi-empirical correlations. The present work demonstrates, for the first time, the feasibility of using a high-resolution narrow-band model for computing this flux for a meteorological application.

Gupta, S. K.↗

The distribution of water frost on Charon

We present high-spatial-resolution imaging observations of the Pluto-Charon system taken with ProtoCAM on the Infrared Telescope Facility (IRTF). Our dataset consists of measurements from eight nights at widely separated rotational longitudes and covering five wavelengths -- standard J, H, and K, plus two special narrow band filters at 1.5 and 1.75 microns. The relative flux contributions of Pluto and Charon were extracted, when possible, by fitting a two-source Gaussian image model to the observed images. At K, we find the Charon-Pluto magnitude difference to be on average 1.8 mag, somewhat less than the value of 2.2 mag found by Bosh et al. (1992). The average differential magnitude at 1.5 and 1.75 microns is 2.0 and 1.6, respectively. The larger magnitude difference at 1.5 microns is due to a water-frost absorption band on the surface of Charon. Our observations are consistent with a surface of Charon dominated by water frost at all longitudes.

Buie, Marc W.↗

Measurement of Low Amounts of Precipitable Water Vapor Using Ground-Based Millimeterwave Radiometry

Extremely dry conditions characterized by amounts of precipitable water vapor (PWV) as as 1-2 mm commonly occur in high-latitude regions during the winter months. While such atmospheres carry only a few percent of the latent heat energy compared to tropical atmospheres, the effects of low vapor amounts on the polar radiation budget - both directly through modulation of longwave radiation and indirectly through the formation of clouds - are considerable. Accurate measurements of precipitable water vapor (PWV) during such dry conditions are needed to improve polar radiation models for use in understanding and predicting change in the climatically sensitive polar regions. To this end, the strong water vapor absorption at 183.310 GHz provides a unique means of measuring low amounts of PWV. Weighting function analysis, forward model calculations based upon a 7-year radiosonde dataset, and retrieval simulations consistently predict that radiometric measurements made using several millimeter-wavelength (MMW) channels near the 183 GHz line, together with established microwave (MW) measurements at the 22.235 GHz water vapor line and -3 1 GHz atmospheric absorption window can be used to determine within 5% uncertainty the full range of PWV expected in the Arctic. This unique collective capability stands in spite of accuracy limitations stemming from uncertainties due to the sensitivity of the vertical distribution of temperature and water vapor at MMW channels. In this study the potential of MMW radiometry using the 183 GHz line for measuring low amounts of PWV is demonstrated both theoretically and experimentally. The study uses data obtained during March 1999 as part of an experiment conducted at the Department of Energy s Cloud and Radiation Testbed (CART) near Barrow, Alaska. Several radiometers from both NOAA and NASA were deployed during the experiment to provide the first combined MMW and MW ground-based data set during dry arctic conditions. Single-channel retrievals of PWV were performed using the MW and MMW data. Discrepancies in the retrieved values were found to be consistent with differences observed between measured brightness temperatures (TBs) and forward-modeled TBs based on concurrent radiosonde profiles. These discrepancies are greater than can be explained by measurement error alone and are attributed to absorption model uncertainty. We discuss here the measurements, retrieval technique, and line model discrepancies along with difficulties and potential of MMW/MW PWV measurement.

Racette, Paul E.↗