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Results for “ABSORPTION COEFFICIENT”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Measurements of SO2 absorption coefficients using a tunable dye laser

High-resolution measurements of SO2 absorption coefficients in the UV are presented in the wavelength interval between 2962 and 3011 A using a frequency-doubled dye laser as the radiation source. These measurements have application to pollution monitoring of SO2 using the differential absorption scattering (DAS) technique. The spectral resolution of the measurements was 0.2 A (determined by the linewidth of the dye laser) and the generated spectra exhibited considerable rotational structure on the (000) double prime to (060) prime, (070) prime, and (080) prime electronic-vibrational transitions. The latter transitions correspond to center wavelengths of 3001.8, 2981.0, and 2962 A, respectively. The laser measurements were obtained with a signal-processing technique which eliminated calibration procedures associated with conventional optical-absorption measurements. Using this technique, the statistical uncertainty associated with measured absorption coefficients has been reduced to less than plus or minus 2% with a wavelength uncertainty of the laser source of plus or minus 0.1 A.

Thompson, R. T., Jr.↗
NASA NTRS1980

Absorption coefficients of ozone for the backscatter UV experiment

Band-averaged absorption coefficients for the wavelength channels of the backscatter ultraviolet (BUV) experiment computed with the laboratory ozone absorption measurements are presented. The coefficients ranged from plus or minus 11 to plus or minus 4% about the range midpoint for the major ozone-determining channels on the BUV; these percentage uncertainties in the band absorption coefficients lead to similar uncertainties in the absolute values of derived total ozone because of their reciprocal relationship. Derived total-ozone ratios of the BUV A:B pairs, the Dobson (1963) AD:CD double pairs; and the BUV B:Dobson AD are estimated for the different sets of coefficients based on the ratios experimentally observed in the BUV and Dobson data. It is shown that the Inn and Tanaka (1959) measurements produce the most consistent results, and band-averaged coefficients for the BUV-profiling wavelengths are computed.

Klenk, K. F.↗
NASA NTRS1980

Minority carrier diffusion lengths and absorption coefficients in silicon sheet material

Most of the methods which have been developed for the measurement of the minority carrier diffusion length of silicon wafers require that the material have either a Schottky or an ohmic contact. The surface photovoltage (SPV) technique is an exception. The SPV technique could, therefore, become a valuable diagnostic tool in connection with current efforts to develop low-cost processes for the production of solar cells. The technique depends on a knowledge of the optical absorption coefficient. The considered investigation is concerned with a reevaluation of the absorption coefficient as a function of silicon processing. A comparison of absorption coefficient values showed these values to be relatively consistent from sample to sample, and independent of the sample growth method.

Dumas, K. A.↗
NASA NTRS1988

Tunable diode laser measurements of HO2NO2 absorption coefficients near 12.5 microns

A tunable diode laser spectrometer has been used to measure absorption coefficients of peroxynitric acid (HO2NO2) near the 803/cm Q branch. HO2NO2 concentrations in a low-pressure flowing gas mixture were determined from chemical titration procedures and UV absorption spectroscopy. The diode laser measured absorption coefficients, at a spectral resolution of better than 0.001/cm, are about 10 percent larger than previous Fourier transform infrared measurements made at a spectral resolution of 0.06/cm.

May, R. D.↗
NASA NTRS1974

Absorption coefficients of a hydrogen plasma for laser radiation

The formalism for the calculation of the absorption of radiation by a hydrogen plasma at common laboratory conditions is summarized. The hydrogen plasma absorption coefficient for laser radiation has been computed for a wide range of electron densities and temperatures (10,000-40,000 K). The results of this computation are presented in a graphical form that permits a determination of the absorption coefficient for the following laser wavelengths: 0.176, 0.325, 0.337, 0.442, 0.488, 0.515, 0.633, 0.694, 1.06, 1.15, 2.36, 3.39, 5.40 and 10.6 microns. The application of these results and laser radiation absorption measurements to plasma diagnostics is discussed briefly.

Stallcop, J. R.↗
NASA NTRS1984

Measurement of the absorption coefficient using the sound-intensity technique

The possibility of using the sound intensity technique to measure the absorption coefficient of a material is investigated. This technique measures the absorption coefficient by measuring the intensity incident on the sample and the net intensity reflected by the sample. Results obtained by this technique are compared with the standard techniques of measuring the change in the reverberation time and the standing wave ratio in a tube, thereby, calculating the random incident and the normal incident adsorption coefficient.

Atwal, M.↗
NASA NTRS1993

Absorption coefficients for water vapor at 193 nm from 300 to 1073 K

Measurements of the water absorption coefficient at 193 nm from 300 to 1073 K are reported. The measurements were made using broadband VUV radiation and a monochromator-based detection system. The water vapor was generated by a saturator and metered into a flowing, 99 cm absorption cell via a water vapor mass flow meter. The 193 nm absorption coefficient measurements are compared to room temperature and high temperature shock tube measurements with good agreement. The absorption can be parameterized by a nu3 vibrational mode reaction coordinate and the thermal population of the nu3 mode.

Kessler, W. J.↗
NASA NTRS1974

Optimization of the acoustic absorption coefficients of certain functional absorbents

The sound absorption coefficients of some functional absorbents (mineral wool plates) are determined by the reverberation chamber method. The influence of the angle of inclination of the sound absorbing material with respect to the surface to be treated is analyzed as well as the influence of the covering index, defined as the ratio of the designed area of a plate and the area of the treated surface belonging to another plate. As compared with the conventional method of applying sound-absorbing plates, the analyzed structures have a higher technological and economical efficiency. The optimum structure corresponds to an angle of inclination of 15 deg and a covering index of 0.8.

Pocsa, V.↗
DOE OSTI2022

Near-infrared spectra and molar absorption coefficients of trivalent lanthanides dissolved in molten LiCl–KCl eutectic

Determining the concentration of the dissolved lanthanide species in LiCl–KCl eutectic salt is important to the development of pyrochemical reprocessing of used nuclear fuel. In this process, lanthanide fission products are found dissolved in the electrorefiner electrolyte in their trivalent oxidation state. The presence of dissolved trivalent lanthanides increases the liquidus temperature of the electrolyte mixture and can lead to the formation of insoluble oxide or oxychloride phases and must therefore be continuously monitored and controlled during the operation. Absorbance spectroscopy is a promising method for continuous measurement of the concentration of lanthanides and other elements dissolved in the electrolyte. The absorption of light by elements is linearly proportional to the concentration of the element for relatively dilute solutions according to the Beer-Lambert law. Although measurement of the absorption of ultraviolet and visible range light by lanthanides in LiCl–KCl eutectic molten salt have been explored previously, near infrared (NIR) absorption spectroscopy has received far less attention. It may, however, provide a better analytical signal when insoluble phases are present due to less Raleigh scattering compared to shorter wavelength radiation. Additionally, it may allow for concentration determination for certain elements using NIR absorption features where UV and visible range features are overlapping with features from other species. In this study, we report the UV–Vis–NIR spectra of the trivalent lanthanide chlorides of neodymium, samarium, and dysprosium in LiCl–KCl eutectic. Molar absorption coefficients are reported for analytically useful absorption maxima, with a focus on the molar absorption coefficients for NIR absorption maxima which have not been reported previously. Additionally, we observe a NIR-range absorption band of Nd3+ which was previously predicted but never experimentally observed. Here, we compare the calculated crystal field levels to the newly observed absorbance band and find them to be in good agreement with previous predictions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2008

Remote Sensing of the Absorption Coefficients and Chlorophyll a Concentration in the U.S. Southern Middle Atlantic Bight from SeaWiFS and MODIS-Aqua

At present, satellite remote sensing of coastal water quality and constituent concentration is subject to large errors as compared to the capability of satellite sensors in oceanic waters. In this study, field measurements collected on a series of cruises within U.S. southern Middle Atlantic Bight (SMAB) were applied to improve retrievals of satellite ocean color products in order to examine the factors that regulate the bio-optical properties within the continental shelf waters of the SMAB. The first objective was to develop improvements in satellite retrievals of absorption coefficients of phytoplankton (a(sub ph)), colored dissolved organic matter (CDOM) (a(sub g)), non-pigmented particles (a(sub d)), and non-pigmented particles plus CDOM (a(sub dg)), and chlorophyll a concentration ([Chl_a]). Several algorithms were compared to derive constituent absorption coefficients from remote sensing reflectance (R(sub rs)) ratios. The validation match-ups showed that the mean absolute percent differences (MAPD) were typically less than 35%, although higher errors were found for a(sub d) retrievals. Seasonal and spatial variability of satellite-derived absorption coefficients and [Chl_a] was apparent and consistent with field data. CDOM is a major contributor to the bio-optical properties of the SMAB, accounting for 35-70% of total light absorption by particles plus CDOM at 443 nm, as compared to 30-45% for phytoplankton and 0-20% for non-pigmented particles. The overestimation of [Chl_a] from the operational satellite algorithms may be attributed to the strong CDOM absorption in this region. River discharge is important in controlling the bio-optical environment, but cannot explain all of the regional and seasonal variability of biogeochemical constituents in the SMAB.

Pan, Xiaoju↗
NASA NTRS1995

Microwave Resonator Measurements of Atmospheric Absorption Coefficients: A Preliminary Design Study

A preliminary design study examined the feasibility of using microwave resonator measurements to improve the accuracy of atmospheric absorption coefficients and refractivity between 18 and 35 GHz. Increased accuracies would improve the capability of water vapor radiometers to correct for radio signal delays caused by Earth's atmosphere. Calibration of delays incurred by radio signals traversing the atmosphere has applications to both deep space tracking and planetary radio science experiments. Currently, the Cassini gravity wave search requires 0.8-1.0% absorption coefficient accuracy. This study examined current atmospheric absorption models and estimated that current model accuracy ranges from 5% to 7%. The refractivity of water vapor is known to 1% accuracy, while the refractivity of many dry gases (oxygen, nitrogen, etc.) are known to better than 0.1%. Improvements to the current generation of models will require that both the functional form and absolute absorption of the water vapor spectrum be calibrated and validated. Several laboratory techniques for measuring atmospheric absorption and refractivity were investigated, including absorption cells, single and multimode rectangular cavity resonators, and Fabry-Perot resonators. Semi-confocal Fabry-Perot resonators were shown to provide the most cost-effective and accurate method of measuring atmospheric gas refractivity. The need for accurate environmental measurement and control was also addressed. A preliminary design for the environmental control and measurement system was developed to aid in identifying significant design issues. The analysis indicated that overall measurement accuracy will be limited by measurement errors and imprecise control of the gas sample's thermodynamic state, thermal expansion and vibration- induced deformation of the resonator structure, and electronic measurement error. The central problem is to identify systematic errors because random errors can be reduced by averaging. Calibrating the resonator measurements by checking the refractivity of dry gases which are known to better than 0.1% provides a method of controlling the systematic errors to 0.1%. The primary source of error in absorptivity and refractivity measurements is thus the ability to measure the concentration of water vapor in the resonator path. Over the whole thermodynamic range of interest the accuracy of water vapor measurement is 1.5%. However, over the range responsible for most of the radio delay (i.e. conditions in the bottom two kilometers of the atmosphere) the accuracy of water vapor measurements ranges from 0.5% to 1.0%. Therefore the precision of the resonator measurements could be held to 0.3% and the overall absolute accuracy of resonator-based absorption and refractivity measurements will range from 0.6% to 1.

Walter, Steven J.↗
NASA NTRS1995

Accelerated line-by-line calculation of spectral absorption coefficients with high numerical accuracy

To model radiative transfer through the atmosphere with high accuracy, one must resort to the calculation of spectral absorption coefficients on a line-by-line basis. The calculation of these coefficients is computationally expensive for three reasons: (1) thousands of spectral lines can contribute to absorption at a single frequency; (2) the tails of spectral line profiles are long (i.e., a given line can contribute to absorption over a wide range of frequencies); and (3) the sampling frequencies at which monochromatic radiances are to be calculated must be spaced sufficiently close together to resolve the thinnest lines of interest (e.g., those that arise in the stratosphere). We have developed a new algorithm to accelerate the calculation of spectral absorption coefficients while retaining high numerical accuracy.

Sparks, L.↗