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Results for “ABSORPTION CROSS SECTION”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Absorption cross sections of the ClO dimer

The absorption cross sections of the ClO dimer, ClOOCl, are important to the photochemistry of ozone depletion in the Antarctic. In this work, new measurements were made of the dimer cross sections at 195 K. the results yield somewhat lower values in the long wavelength region, compared to those currently recommended in the NASA data evaluation (JPL 94-26). The corresponding solar photodissociation rates in the Antarctic are reduced by about 40%.

Huder, K. J.↗
NASA NTRS1982

O2 absorption cross sections /187-225 nm/ from stratospheric solar flux measurements

The absorption cross sections of molecular oxygen are calculated in the wavelength range from 187 to 230 nm from solar flux measurements obtained within the stratosphere. Within the Herzberg continuum wavelength region the molecular oxygen cross sections are found to be about 30% smaller than the laboratory results of Shardanand and Rao (1977) from 200 to 210 nm and about 50% smaller than those of Hasson and Nicholls (1971). At wavelengths longer than 210 nm the cross sections agree with those of Shardanand and Rao. The effective absorption cross sections of O2 in the Schumann-Runge band region from 187 to 200 nm are calculated and compared to the empirical fit given by Allen and Frederick (1982). The calculated cross sections indicate that the transmissivity of the atmosphere may be underestimated by the use of the Allen and Frederic cross sections between 195 and 200 nm. The ozone column content between 30 and 40 km and the relative ozone cross sections are determined from the same solar flux data set.

Herman, J. R.↗
NASA NTRS1986

Absorption cross section measurements of oxygen in the wavelength region 195-241 nm of the Herzberg continuum

The continuous absorption cross section of oxygen in the region 205-241 nm is studied as a function of path length and oxygen pressure. The technique used to study the continuous absorption cross section is described. Cross section measurements of oxygen in the wavelength region 193-205 nm obtained by Cheung et al. (1984) are applied in this experiment. The measured cross section is analyzed in terms of a Herzberg continuum and a pressure-dependent continuum. The total measured continuum cross section, the cross section involving two molecules of O2, and the Herzberg continuum absorption cross section values are calculated. It is observed that the Herzberg continuum cross section of oxygen values measured at 1 nm intervals in the region 195-241 nm, increase from 6.3 x 10 to the -24th sq cm at 195 nm to a maximum of 6.6 x 10 to the -24th sq cm at 201 nm and then decrease to 0.85 x 10 to the -24th sq cm at 241 nm. The Herzberg values are compared with data from previous investigations and the values correlate well.

Cheung, A. S.-C.↗
NASA NTRS1984

Measurement of individual hydrometeor absorption cross sections utilizing microwave cavity perturbation techniques

A technique for measurement of individual hydrometeor absorption cross sections is presented. Cross sections are inferred by inserting the hydrometeor into a high Q resonant cavity and measuring the Q perturbation. Tests were conducted in a 10.64 GHz, TM(010) cavity. Absorption cross sections were measured at room temperature for 0.5 to 2.0 mm water drops, and were found to agree with the Rayleigh theory. Cross sections were also measured as a function of temperature, and from these the dielectric loss term lm(-K) was inferred for supercooled water down to -17 C.

Hansman, R. J., Jr.↗
NASA NTRS1992

Absolute absorption cross sections of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm

An account is given of progress of work on absorption cross section measurements of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm. In this wavelength region, the penetration of solar radiation into the Earth's atmosphere is controlled by O2 and O3. The transmitted radiation is available to dissociate trace species such as halocarbons and nitrous oxide. We have recently measured absolute absorption cross sections of O3 in the wavelength region 240-350 nm (Freeman et al., 1985; Yoshino et al., 1988). We apply these proven techniques to the determination of the absorption cross section of O3 at 300 K, 228 K and 195 K throughout the wavelength region 185-240 nm. A paper titled 'Absolute Absorption Cross Section Measurements of Ozone in the Wavelength Region 185-254 nm and the Temperature Dependence' has been submitted for publication in the Journal of Geophysical Research.

Yoshino, K.↗
NASA NTRS1981

Temperature dependent UV absorption cross sections for carbonyl sulfide

The ultraviolet absorption spectrum of carbonyl sulfide is investigated in order to assess the importance of the photolytic sink for OCS in the troposphere. Absorption cross sections were measured at wavelengths between 185 and 300 nm in a double-beam spectrometer at temperatures of 295 and 225 K. The results are found to be in good agreement with previous reports in the short wavelength region, but significantly lower than the value of 2 x 10 to the 22nd sq cm/molecule proposed by Rudolf and Inn (1981) between 280 and 300 nm, which may be attributed to trace contaminants or dimerization. A marked temperature effect is noted at wavelengths greater than 240 nm and below 190 nm. As no evidence of absorption at wavelengths greater than 270 nm was found, estimates of the solar photodissociation rate of tropospheric OCS based on the present cross sections yield a value of about 2 x 10 to the -9th/sec, corresponding to a tropospheric lifetime of about 20 years. It is therefore concluded that solar photolysis represents a negligible sink for OCS.

Molina, L. T.↗
NASA NTRS1986

Absolute absorption cross sections of ozone in the 185- to 350-nm wavelength range

The absorption cross sections of ozone have been measured in the wavelength range 185-350 nm and in the temperature range 225-298 K. The absolute ozone concentrations were established by measuring the pressure of pure gaseous samples in the 0.08to 300-torr range, and the UV spectra were recorded under conditions where less than 1 percent of the sample decomposed. The temperature dependence is significant for wavelengths longer than about 280 nm. The absorption cross-section values around 210 nm were found to be about 10 percent larger than the previously accepted values.

Molina, L. T.↗
DOE OSTI2020

An Exploratory Approach Using Regression and Machine Learning in the Analysis of Mass Absorption Cross Section of Black Carbon Aerosols: Model Development and Evaluation

Mass absorption cross-section of black carbon (MAC BC ) describes the absorptive cross-section per unit mass of black carbon, and is, thus, an essential parameter to estimate the radiative forcing of black carbon. Many studies have sought to estimate MAC BC from a theoretical perspective, but these studies require the knowledge of a set of aerosol properties, which are difficult and/or labor-intensive to measure. We therefore investigate the ability of seven data analytical approaches (including different multivariate regressions, support vector machine, and neural networks) in predicting MAC BC for both ambient and biomass burning measurements. Our model utilizes multi-wavelength light absorption and scattering as well as the aerosol size distributions as input variables to predict MAC BC across different wavelengths. We assessed the applicability of the proposed approaches in estimating MAC BC using different statistical metrics (such as coefficient of determination (R 2 ), mean square error (MSE), fractional error, and fractional bias). Overall, the approaches used in this study can estimate MAC BC appropriately, but the prediction performance varies across approaches and atmospheric environments. Based on an uncertainty evaluation of our models and the empirical and theoretical approaches to predict MAC BC , we preliminarily put forth support vector machine (SVM) as a recommended data analytical technique for use. We provide an operational tool built with the approaches presented in this paper to facilitate this procedure for future users.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1984

Absolute OH absorption cross sections (for lidar measurements)

Experimental data are employed to calculate absorption cross sections for several rotational lines in the OH A-X system. The cross sections are computed as functions of the spectral and line widths and temperature of a laser beam, and account for lifetimes and branching ratios. Detection limits for the P1(2) transition of the (1,0) band were examined. The oscillator strengths and cross-sections obtained are important for quantifying OH concentrations in the stratosphere from lidar return signals.

Mcgee, T. J.↗
NASA NTRS2019

N2 and H2 Broadened Isobutane Infrared Absorption Cross Sections and Butane Upper Limits on Titan

High resolution infrared absorption cross sections of isobutane, (CH3)3CH, were measured in the 1050-1900 cm-1spectral range by Fourier transform spectroscopy. Four sample temperatures (210, 234, 265 and 296 K) were used with three pressures (10, 30 and 100 Torr) of N2and H2broadening gas. Spectra of pure isobutane samples were also recorded. These cross sections are useful for the interpretation of infrared spectra of the Giant Planets and Titan. The isobutane cross sections give an upper limit of 3.91e-8for its fractional abundance on Titan based on CIRS/Cassini infrared spectra. Using n-butane, CH3(CH2)2CH3, cross sections from the literature, we obtain an upper limit of 5.13e-7for its abundance on Titan. The combined upper limit for both isomers of butane, C4H10, on Titan of 5.52e-7is consistent with the lower limit of recent model predictions

Dan Hewett↗
NASA NTRS1993

Measurements of absolute absorption cross sections of ozone in the 185- to 254-nm wavelength region and the temperature dependence

Laboratory measurements of the relative absorption cross sections of ozone at temperatures 195, 228, and 295 K have been made throughout the 185 to 254 nm wavelength region. The absolute absorption cross sections at the same temperatures have been measured at several discrete wavelengths in the 185 to 250 nm region. The absolute cross sections of ozone have been used to put the relative cross sections on a firm absolute basis throughout the 185 to 255 nm region. These recalibrated cross sections are slightly lower than those of Molina and Molina (1986), but the differences are within a few percent and would not be significant in atmospheric applications.

Yoshino, K.↗