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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 37 records · Page 2
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Highly supercooled riming and unusual triple-frequency radar signatures over McMurdo Station, Antarctica

Abstract. Riming of ice crystals by supercooled water droplets is an efficient ice growth process, but its basic properties are still poorly known. While it has been shown to contribute significantly to surface precipitation at mid-latitudes, little is known about its occurrence at high latitudes. In Antarctica, two competing effects can influence the occurrence of riming: (i) the scarcity of supercooled liquid water clouds due to the extremely low tropospheric temperatures and (ii) the low aerosol concentration, which may lead to the formation of fewer and larger supercooled drops potentially resulting in an enhanced riming efficiency. In this work, by exploiting the deployment of an unprecedented number of multiwavelength remote sensing systems (including triple-frequency radar measurements) in West Antarctica, during the Atmospheric Radiation Measurements West Antarctic Radiation Experiment (AWARE) field campaign, we evaluate the riming incidence at McMurdo Station and find that riming occurs at much lower temperatures when compared to previous results in the mid-latitudes. This suggests the possible occurrence of a common atmospheric state over Antarctica that includes a rather stable atmosphere inhibiting turbulent mixing, and a high riming efficiency driven by large cloud droplets. We then focus on a peculiar case study featuring a persistent layer with a particularly pronounced riming signature in triple-frequency radar data but only a relatively modest amount of supercooled liquid water. In-depth analysis of the radar observations suggests that such signatures can only be explained by the combined effects of moderately rimed aggregates or similarly shaped florid polycrystals and a narrow particle size distribution (PSD). Simulations of this case study performed with a one-dimensional bin model indicate that similar triple-frequency radar observations can be reproduced when narrow PSDs are simulated. Such narrow PSDs can in turn be explained by two key factors: (i) the presence of a shallow homogeneous droplet or humidified aerosol freezing layer aloft seeding an underlying supercooled liquid layer, and (ii) the absence of turbulent mixing throughout a stable polar atmosphere that sustains narrow PSDs, as hydrometeors grow from the nucleation region aloft to ice particles of several millimeters in size, by vapor deposition and then riming.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

CMIP5 model selection for ISMIP6 ice sheet model forcing: Greenland and Antarctica

Abstract. The ice sheet model intercomparison project for CMIP6 (ISMIP6) effort brings together the ice sheet and climate modeling communities to gain understanding of the ice sheet contribution to sea level rise. ISMIP6 conducts stand-alone ice sheet experiments that use space- and time-varying forcing derived from atmosphere–ocean coupled global climate models (AOGCMs) to reflect plausible trajectories for climate projections. The goal of this study is to recommend a subset of CMIP5 AOGCMs (three core and three targeted) to produce forcing for ISMIP6 stand-alone ice sheet simulations, based on (i) their representation of current climate near Antarctica and Greenland relative to observations and (ii) their ability to sample a diversity of projected atmosphere and ocean changes over the 21st century. The selection is performed separately for Greenland and Antarctica. Model evaluation over the historical period focuses on variables used to generate ice sheet forcing. For stage (i), we combine metrics of atmosphere and surface ocean state (annual- and seasonal-mean variables over large spatial domains) with metrics of time-mean subsurface ocean temperature biases averaged over sectors of the continental shelf. For stage (ii), we maximize the diversity of climate projections among the best-performing models. Model selection is also constrained by technical limitations, such as availability of required data from RCP2.6 and RCP8.5 projections. The selected top three CMIP5 climate models are CCSM4, MIROC-ESM-CHEM, and NorESM1-M for Antarctica and HadGEM2-ES, MIROC5, and NorESM1-M for Greenland. This model selection was designed specifically for ISMIP6 but can be adapted for other applications.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Climatology and surface impacts of atmospheric rivers on West Antarctica

Abstract. Atmospheric rivers (ARs) transport large amounts of moisture from the mid- to high-latitudes and they are a primary driver of the most extreme snowfall events, along with surface melting, in Antarctica. In this study, we characterize the climatology and surface impacts of ARs on West Antarctica, focusing on the Amundsen Sea Embayment and Marie Byrd Land. First, we develop a climatology of ARs in this region, using an Antarctic-specific AR detection tool combined with the Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2) and the European Centre for Medium-Range Weather Forecasts (ECMWF) Reanalysis v5 (ERA5) atmospheric reanalyses. We find that while ARs are infrequent (occurring 3 % of the time), they cause intense precipitation in short periods of time and account for 11 % of the annual surface accumulation. They are driven by the coupling of a blocking high over the Antarctic Peninsula with a low-pressure system known as the Amundsen Sea Low. Next, we use observations from automatic weather stations on Thwaites Eastern Ice Shelf with the firn model SNOWPACK and interferometric reflectometry (IR) to examine a case study of three ARs that made landfall in rapid succession from 2 to 8 February 2020, known as an AR family event. While accumulation dominates the surface impacts of the event on Thwaites Eastern Ice Shelf (> 100 kg m−2 or millimeters water equivalent), we find small amounts of surface melt as well (< 5 kg m−2). The results presented here enable us to quantify the past impacts of ARs on West Antarctica's surface mass balance (SMB) and characterize their interannual variability and trends, enabling a better assessment of future AR-driven changes in the SMB.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1982

Sounding rockets in Antarctica

Sounding rockets are versatile tools for scientists studying the atmospheric region which is located above balloon altitudes but below orbital satellite altitudes. Three NASA Nike-Tomahawk sounding rockets were launched from Siple Station in Antarctica in an upper atmosphere physics experiment in the austral summer of 1980-81. The 110 kg payloads were carried to 200 km apogee altitudes in a coordinated project with Arcas rocket payloads and instrumented balloons. This Siple Station Expedition demonstrated the feasibility of launching large, near 1,000 kg, rocket systems from research stations in Antarctica. The remoteness of research stations in Antarctica and the severe environment are major considerations in planning rocket launching expeditions.

Alford, G. C.↗
NASA NTRS1983

The future of space - Space tomorrow: The Antarctica model

The exploration and settling of Antarctica with permanent bases are used as illustrative points for establishing a permanent human presence in near-earth space. NASA activities since 1958 have spawned the computer science, solid-state electronics, medical electronics, and communications satellites industries, which are also rapidly expanding in other countries, as are space-faring capabilities. Antarctica is a paradigm for space exploration in that it is hard to reach, hostile to human life, and a great amount of planning is necessary to arrive at the destination and survive. Aircraft made permanent settlements possible on Antarctica, just as the Shuttle does for space. A space station would provide the remote base from which exploration of other planets and settling on the moon could proceed.

Beggs, J.↗
NASA NTRS1987

Enhanced LANDSAT images of Antarctica and planetary exploration

Since early in the LANDSAT program, black-and-white paper prints of band 7 (near infrared) of the LANDSAT multispectral scanner have been used extensively to prepare semicontrolled maps of Antarctica. Image-processing techniques are now employed to enhance fine detail and to make controlled image-mosaic maps in color. LANDSAT multispectral images of Antarctica help to expand our knowledge of extraterrestrial bodies by showing bare-ice areas as bright blue patches; on such patches meteorites tend to be concentrated and are collected. Many subtle flow features in Antarctic ice streams resemble features at the mouths of Martian outflow channels, which suggests that the channels also contained ice. Furthermore, flow lines in Antarctic ice sheets that merge with ice shelves resemble Martian flow features associated with dissected terrain along the Martian northern highland margin, and support the concept that ice was involved in the transport of material from the southern highlands to the northern lowland plains. In Antarctica, as on Mars, the virtual absence of fluvial activity over millions of years has permitted the growth of glacial and eolian features to unusually large sizes.

Lucchitta, B. K.↗
NASA NTRS1988

Large-scale variations in ozone and polar stratospheric clouds measured with airborne lidar during formation of the 1987 ozone hole over Antarctica

A joint field experiment between NASA and NOAA was conducted during August to September 1987 to obtain in situ and remote measurements of key gases and aerosols from aircraft platforms during the formation of the ozone (O3) hole over Antarctica. The ER-2 (advanced U-2) and DC-8 aircraft from the NASA Ames Research Center were used in this field experiment. The NASA Langley Research Center's airborne differential absorption lidar (DIAL) system was operated from the DC-8 to obtain profiles of O3 and polar stratospheric clouds in the lower stratosphere during long-range flights over Antarctica from August 28 to September 29, 1987. The airborne DIAL system was configured to transmit simultaneously four laser wavelengths (301, 311, 622, and 1064 nm) above the DC-8 for DIAL measurements of O3 profiles between 11 to 20 km ASL (geometric altitude above sea level) and multiple wavelength aerosol backscatter measurements between 11 to 24 km ASL. A total of 13 DC-8 flights were made over Antarctica with 2 flights reaching the South Pole. Polar stratospheric clouds (PSC's) were detected in multiple thin layers in the 11 to 21 km ASL altitude range with each layer having a typical thickness of less than 1 km. Two types of PSC's were found based on aerosol backscattering ratios: predominantly water ice clouds (type 2) and clouds with scattering characteristics consistent with binary solid nitric acid/water clouds (type 1). Large-scale cross sections of O3 distributions were obtained. The data provides additional information about a potentially important transport mechanism that may influence the O3 budget inside the vortex. There is also some evidence that strong low pressure systems in the troposphere are associated with regions of lower stratospheric O3. This paper discusses the spatial and temporal variations of O3 inside and outside the polar vortex region during the development of the O3 hole and relates these data to other measurements obtained during this field experiment.

Browell, Edward V.↗
NASA NTRS1988

Infrared aircraft measurements of stratospheric composition over Antarctica during September 1987

The JPL Mark IV interferometer recorded high resolution, infared solar spectra from the NASA DC-8 aircraft during flights over Antarctica in September 1987. The atmospheric absorption features in these spectra were analyzed to determine the overburdens of O3, NO, NO2, HNO3, ClONO2, HCl, HF, CH4, N2O, CO, H2O and CFC-12. The spectra were obtained at latitudes which ranged between 64 degrees S and 86 degrees S, allowing the composition in the interior of the polar vortex to be compared with that at the edge. The latitude dependence observed for NO, HO2, HNO3, ClONO2, HCl and HF are summerized. The values at 30 deg S were observed on the ferry flight from New Zealand to Hawaii. The dashed lines connecting the two were interpolated across the region for which there are no measurements. The chemically perturbed region is seen to consist of a collar of high HNO3 and ClONO2 surrounding a core in which the overburdens of these and of HCl and NO2 are very low. Clear increases in the overburdens of HF and HNO3 were observed during the course of September in the vortex core. HCl and NO2 exhibited smaller, less significant increases. The overburdens of the tropospheric source gases, N2O, CH4, CF2Cl2, and H2O were observed to much smaller over Antarctica than at mid-latitudes. This, together with the fact that HF over Antarctica was more that double its mid-latitude value, suggests that downwelling has occurred.

Toon, Goeff C.↗
NASA NTRS1989

Infrared aircraft measurements of stratospheric composition over Antarctica during September 1987

The Jet Propulsion Laboratory Mark IV interferometer recorded high-resolution, infrared solar spectra from the NASA DC-8 aircraft during flights over Antarctica in September 1987. The atmospheric absorption features in these spectra have been analyzed to determine the burdens of O3, NO, NO2, HNO3, ClNO3, HCl, HF, CO2, CH4, N2O, HCN, CO, H2O, CFCl3, and CF2Cl2. The results show a 'collar' of high HNO3 and ClNO3 surrounding a 'core' in which the burdens of these and of HCl and NO2 are very low. Clear increases in the burdens of HF and HNO3 were observed during the course of September in the vortex core. HCl and NO2 exhibited smaller, less significant increases. The burdens of the tropospheric source gases, N2O, CH4, HCN, CFCl3, CF2Cl2, CO, and H2O, were observed to be much smaller over Antarctica than at midlatitudes. This, together with the fact that HF over Antarctica was more than double its midlatidue value, suggests that downwelling had occurred.

Toon, G. C.↗
NASA NTRS1994

Live from Antarctica: the Coldest, Windiest Place on Earth

In this first part of a four part 'Passport to Knowledge Special', hosted by Camille Jennings from Maryland Public Television, children from Maryland and Texas schools had the opportunity to directly interact with and ask questions of scientists and researchers in Antarctica live. The physical characteristics of Antarctica are featured, along with their effects on the human and microbiological organisms living in the region. The reasons behind the clothing worn in the Antarctic and the importance of the meteorological station are featured. Interviews with Professor Ian Dolziel (U of Texas) and Lt. commander John Joseph, NSFA (the head of the Navy Meteorology Center) occur with the school children, along with actual video footage of the surrounding geological features and geography. The 'Weatherops' is located at McMurdo Station, Antarctica.

Source record↗
NASA NTRS2000

Meteorites and Microbes: Meteorite Collection and Ice Sampling at Patriot Hills, Thiel Mountains, and South Pole, Antarctica

During the Antarctica 2000 Expedition, sponsored by the Planetary Studies Foundation, meteorites and ice microbiota were collected from the Patriot Hills, and Thiel Mountains of Antarctica and snow samples were at the South Pole. Psychrophilic and psychrotrophic microbiota were obtained from blue ice, cryoconite and ice-bubble systems. Twenty frozen meteorites were collected using aseptic techniques from the blue ice fields near the Moulton Escarpment of the Thiel Mountains (85 S, 94 W) and from the Morris Moraine of the Patriot Hills (80 S, 81 W) Ellsworth Mountains. These ice and meteorite samples are of potential significance to Astrobiology. They may help refine chemical and morphological biomarkers and refine characteristics of microbial life in one of the harshest environments on Earth. We discuss the Antarctica 2000 Expedition and provide preliminary results of the investigation of the meteorites and ice microbiota recovered.

Sipiera, Paul P.↗
NASA NTRS2000

Cryoconite and Ice-bubble Microbial Ecosystems in Antarctica

During the Antarctica 2000 Expedition samples of rocks and ice bubbles entrained in ice were collected from the blue ice fields near the Moulton Escarpment of the Thiel Mountains (85S, 94W) and the Morris Moraine of the Patriot Hills (80S, 8 1 W) Ellsworth Mountains of Antarctica. Investigation of the microbiota of these cryoconite and ice bubble ecosystems are now being conducted to help refine chemical and morphological biomarkers of potential significance to Astrobiology. The Antarctica 2000 Expedition will be discussed and the preliminary results of the studies of the ice bubble and cryoconite microbial ecosystems discussed. Recent ESEM images of the Antarctic microbiota will be presented a the relevance of ice ecosystems to Astrobiology will be discussed.

Hoover, Richard B.↗
NASA NTRS2005

Antarctica Cloud Cover for October 2003 from GLAS Satellite Lidar Profiling

Seeing clouds in polar regions has been a problem for the imagers used on satellites. Both clouds and snow and ice are white, which makes clouds over snow hard to see. And for thermal infrared imaging both the surface and the clouds cold. The Geoscience Laser Altimeter System (GLAS) launched in 2003 gives an entirely new way to see clouds from space. Pulses of laser light scatter from clouds giving a signal that is separated in time from the signal from the surface. The scattering from clouds is thus a sensitive and direct measure of the presence and height of clouds. The GLAS instrument orbits over Antarctica 16 times a day. All of the cloud observations for October 2003 were summarized and compared to the results from the MODIS imager for the same month. There are two basic cloud types that are observed, low stratus with tops below 3 km and high cirrus form clouds with cloud top altitude and thickness tending at 12 km and 1.3 km respectively. The average cloud cover varies from over 93 % for ocean and coastal regions to an average of 40% over the East Antarctic plateau and 60-90% over West Antarctica. When the GLAS monthly average cloud fractions are compared to the MODIS cloud fraction data product, differences in the amount of cloud cover are as much as 40% over the continent. The results will be used to improve the way clouds are detected from the imager observations. These measurements give a much improved understanding of distribution of clouds over Antarctica and may show how they are changing as a result of global warming.

Spinhirne, J. D.↗
NASA NTRS2005

Analysis of ICESat Data Using Kalman Filter and Kriging to Study Height Changes in East Antarctica

We analyze ICESat derived heights collected between Feb. 03-Nov. 04 using a kriging/Kalman filtering approach to investigate height changes in East Antarctica. The model's parameters are height change to an a priori static digital height model, seasonal signal expressed as an amplitude Beta and phase Theta, and height-change rate dh/dt for each (100 km)(exp 2) block. From the Kalman filter results, dh/dt has a mean of -0.06 m/yr in the flat interior of East Antarctica. Spatially correlated pointing errors in the current data releases give uncertainties in the range 0.06 m/yr, making height change detection unreliable at this time. Our test shows that when using all available data with pointing knowledge equivalent to that of Laser 2a, height change detection with an accuracy level 0.02 m/yr can be achieved over flat terrains in East Antarctica.

Herring, Thomas A.↗
NASA NTRS2008

The Bess-Polar II Long Duration Flight Above Antarctica

The Balloon-borne Experiment with a Superconducting Spectrometer, BESS, has been developed to study elementary particle phenomena in the early universe through measurements of low energy antiprotons to investigate their origin and through a search for antihelium. The BESS collaboration carried out nine northern latitude flights between 1993 and 2002. BESS-Polar is an advanced program of the BESS collaboration to study these topics with much greater precision using long duration flights above Antarctica. The BESS-Polar spectrometer was successfully developed to accumulate much larger numbers of events during long duration flights around the South Pole. Approximately a factor of four reductions in the amount of material in the particle beam enables measurement of much lower energy antiprotons down to 100 MeV (at top of atmosphere). The first BESS-Polar flight (BESS-Polar I) of 8.5 days was carried out above Antarctica in December 2004. recording 900 million cosmic-ray events. The second BESS-Polar flight (BESS-Polar 11) was successfully carried out in the austral summer season of 2007-2008. Based on experience with BESS-Polar I, the spectrometer was improved in performance and achieved long term stability during the flight. A newly constructed magnet with a larger liquid He capacity and improved thermal insulation and an upgraded data storage system with larger capacity of hard disk drives (HDDs) enabled longer observation time. BESS-Polar II was launched on December 22, 2007 from Williams Field, McMurdo Station, in Antarctica. The spectrometer worked properly and observed cosmic rays for about 24.5 days at float altitude, recording 4.6 billion events on the HDDs until the limit of the magnet operation was reached on January 16, 2008. The flight was terminated and the spectrometer was safely landed on the West Antarctic ice sheet (1000 km from the South Pole) on January 21, 2008. Here, the BESS-Polar instrument is discussed, highlighting improvements made for BESS-Polar II, and overviews of the flight and performance are reported.

Sasaki, Makoto↗
NASA NTRS2009

Anaerobic Psychrophiles from Lake Zub and Lake Untersee, Antarctica

The study of samples from Antarctica 2008 and 2009 expeditions organized and successfully conducted by Richard Hoover led to the isolation of diverse anaerobic strains with psychrotolerant and psychrophilic physiology. Due to the fact that Lake Untersee has never been subject to microbiological study, this work with the samples has significant and pioneering impact to the knowledge about the biology of this unique ecosystem. Also, the astrobiological significance for the study of these ecosystems is based on new findings of ice covered water systems on other bodies of our solar system. Anaerobic psychrotolerant strain LZ-22 was isolated from a frozen sample of green moss with soils around the rhizosphere collected near Lake Zub in Antarctica. Morphology of strain LZ-22 was observed to be motile, rod shaped and spore-forming cells with sizes 1 x 5-10 micron. This new isolate is a mesophile with the maximum temperature of growth at 40C. Strain LZ-22 is able to live on media without NaCl and in media with up to 7% (w/v) NaCl. It is catalase negative and grows only on sugars with the best growth rate being on lactose. The strain is a neutrophile and grows between pH 5 and 9.0 with the optimum at 7.8. Another two strains UL7-96mG and LU-96m7P were isolated from deep water samples of Lake Untersee. Proteolytic strain LU-96m7P had a truly psychrophilic nature and refused to grow at room temperature. Sugarlytic strain UL7-96mG was found to be psychrotolerant, but its rate of growth at 3C was very high compared with other mesophiles. Two homoacetogenic psychrophilic strains A7AC-96m and AC-DS7 were isolated and purified from samples of Lake Untersee; both of them are able to grow chemolithotrophically on H2+CO2. In the presence of lactate, these strains are able to grow only at 0-18C, and growth at 22C was observed only with yeast extract stimulation. In this paper, physiological and morphological characteristics of novel psychrophilic and psychrotolerant isolates from Antarctica 2008 and 2009 expeditions will be discussed.

Townsend, Alisa↗
NASA NTRS2010

A Combined Observational and Modeling Approach to Study Modern Dust Transport from the Patagonia Desert to East Antarctica

The understanding of present atmospheric transport processes from Southern Hemisphere (SH) landmasses to Antarctica can improve the interpretation of stratigraphic data in Antarctic ice cores. In addition, long range transport can deliver key nutrients normally not available to marine ecosystems in the Southern Ocean and may trigger or enhance primary productivity. However, there is a dearth of observational based studies of dust transport in the SH. This work aims to improve current understanding of dust transport in the SH by showing a characterization of two dust events originating in the Patagonia desert (south end of South America). The approach is based on a combined and complementary use of satellite retrievals (detectors MISR, MODIS, GLAS ,POLDER, OMI,), transport model simulation (HYSPLIT) and surface observations near the sources and aerosol measurements in Antarctica (Neumayer and Concordia sites). Satellite imagery and visibility observations confirm dust emission in a stretch of dry lakes along the coast of the Tierra del Fuego (TdF) island (approx.54deg S) and from the shores of the Colihue Huapi lake in Central Patagonia (approx.46deg S) in February 2005. Model simulations initialized by these observations reproduce the timing of an observed increase in dust concentration at the Concordia Station and some of the observed increases in atmospheric aerosol absorption (here used as a dust proxy) in the Neumayer station. The TdF sources were the largest contributors of dust at both sites. The transit times from TdF to the Neumayer and Concordia sites are 6-7 and 9-10 days respectively. Lidar observations and model outputs coincide in placing most of the dust cloud in the boundary layer and suggest significant de- position over the ocean immediately downwind. Boundary layer dust was detected as far as 1800 km from the source and approx.800 km north of the South Georgia Island over the central sub-Antarctic Atlantic Ocean. Although the analysis suggests the presence of dust at approx.1500 km SW of South Africa five days after, the limited capabilities of existing satellite platforms to differentiate between aerosol types do not permit a definitive conclusion. In addition, the model simulations show dust lifting to the free troposphere as it travels south but it could not be confirmed by the satellite observations due to cloudiness. This work demonstrates that complementary information from existing transport models, satellite and surface data can yield a consistent picture of the dust transport from the Patagonia desert to Antarctica. It also illustrates the limitation of using any of these approaches individually to characterize the transport of dust in a heavily cloudy area.

Gasso, S.↗
NASA NTRS2015

Carbon and Oxygen Isotope Measurements of Ordinary Chondrite (OC) Meteorites from Antarctica Indicate Distinct Carbonate Species Using a Stepped Acid Extraction Procedure

The purpose of this study is to characterize the stable isotope values of terrestrial, secondary carbonate minerals from five Ordinary Chondrite (OC) meteorites collected in Antarctica. These samples were identified and requested from NASA based upon their size, alteration history, and collection proximity to known Martian meteorites. They are also assumed to be carbonate-free before falling to Earth. This research addresses two questions involving Mars carbonates: 1) characterize terrestrial, secondary carbonate isotope values to apply to Martian meteorites for isolating in-situ carbonates, and 2) increase understanding of carbonates formed in cold and arid environments with Antarctica as an analog for Mars. Two samples from each meteorite, each approximately 0.5 grams, were crushed and dissolved in pure phosphoric acid for 3 sequential reactions: a) R times 0 for 1 hour at 30 degrees Centigrade (fine calcite extraction), b) R times 1 for 18 hours at 30 degrees Centigrade (course calcite extraction), and c) R times 2 for 3 hours at 150 degrees Centigrade (siderite and/or magnesite extraction). CO (sub 2) was distilled by freezing with liquid nitrogen from each sample tube, then separated from organics and sulfides with a TRACE GC using a Restek HayeSep Q 80/100 6 foot 2 millimeter stainless column, and then analyzed on a Thermo MAT 253 Isotope Ratio Mass Spectrometer (IRMS) in Dual Inlet mode. This system was built at NASA/JSC over the past 3 years and proof-tested with known carbonate standards to develop procedures, assess yield, and quantify expected error bands. Two distinct species of carbonates are found: 1) calcite, and 2) non-calcite carbonate (future testing will attempt to differentiate siderite from magnesite). Preliminary results indicate the terrestrial carbonates are formed at approximately sigma (sup 13) C equal to plus 5 per mille, which is consistent with atmospheric CO (sub 2) sigma (sup 13) C equal to minus 7 per mille and fractionation of plus12 per mille based upon polar temperature of -20 degrees Centigrade. The oxygen values fractionate sigma (sup 18) O equal to minus 10-20 per mille lighter between the R times 0 and R times 1 reactions at 30 degrees Centigrade. The carbonate oxygen isotope measurements are consistently heavier than expected with meteoric water and temperatures from Antarctica, perhaps due to secondary carbonate formation during curation in Houston, TX.

Evans, Michael E.↗