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Photonuclear Production of Radioxenon for Air Samples

Radioxenon plays an important role in ensuring compliance with the Comprehensive Nuclear-Test-Ban Treaty due to its ability to be transported through the atmosphere, as well as the fact that the half-lives of its isotopes provide a window long enough to be detected but not long enough that it could become background radiation. This allows it to be correlated with specific events that indicate the testing of nuclear weapons. Idaho National Laboratory supports this mission by providing spiked air samples for monitoring stations to enable instrument calibration and ensure measurement accuracy. We tested a photonuclear method of producing one of the main isotopes of radioxenon, Xe-135. We also tested the separation of Xe-135 from the parent isotope Xe-136 using the method of kinematic recoil. Aluminum coils were placed in quartz ampoules filled with enriched Xe-136 and were irradiated by a bremsstrahlung beam with an endpoint energy of 21 MeV. The results showed that we were not only successful in producing Xe-135 but also that the Xe-135 was deposited into the coil allowing it to be removed from the Xe-136 gas. The coil and the Xe-135 can then be chemically separated. At the time of counting the coil, it was calculated that there was about 18 Bq of activity from Xe-135 remaining in the coil. Future work includes determining the optimal material and geometry of the catcher to maximize the amount of Xe-135 captured.

07 ISOTOPE AND RADIATION SOURCES

STS 134, 135 and 26S Return Samples: Air Quality aboard Shuttle (STS-134) and International Space Station

This is a very limited set of samples on which to perform an air quality assessment. However, based on these samples, we have no reason to believe that nominal ISS air is unsafe to breathe. We must continue to be vigilant when dealing with nominal atmospheres in ISS. New, unmanned modules require special attention when the crew first enters. Carbon Monoxide Accumulation aboard ISS: Beginning in late 2008 the nominal concentrations of CO began increasing gradually (Figure 1). The results from samples returned on this flight indicate that the CO concentrations, after dropping in late 2009, have cycled upward and then settled back to concentrations near 2 mg/m3. In any case, these changes are well below the 180-day SMAC for CO, which is17 mg/m3. There is no threat to crew health. Carbon Dioxide: This anthropogenic compound has drawn much attention recently because of the possibility that it could contribute to the effects of intracranial hypertension experienced because of spaceflight-induced fluid shifts. From now on we will maintain a plot (Figure 2) of carbon dioxide concentrations ( SD) by averaging the values found in the 3-5 mini-GSC samples taken each month in diverse locations of the ISS. This will enable us to estimate the average exposure of crewmembers to carbon dioxide during their stay aboard the ISS. In general, concentrations are being maintained below 3.5 mmHg. Figure 1

James, John T.

Collection and analysis of NASA clean room air samples

The environment of the HALOE assembly clean room at NASA Langley Research Center is analyzed to determine the background levels of airborne organic compounds. Sampling is accomplished by pumping the clean room air through absorbing cartridges. For volatile organics, cartridges are thermally desorbed and then analyzed by gas chromatography and mass spectrometry, compounds are identified by searching the EPA/NIH data base using an interactive operator INCOS computer search algorithm. For semivolatile organics, cartridges are solvent entracted and concentrated extracts are analyzed by gas chromatography-electron capture detection, compound identification is made by matching gas chromatogram retention times with known standards. The detection limits for the semivolatile organics are; 0.89 ng cu m for dioctylphlhalate (DOP) and 1.6 ng cu m for polychlorinated biphenyls (PCB). The detection limit for volatile organics ranges from 1 to 50 parts per trillion. Only trace quantities of organics are detected, the DOP levels do not exceed 2.5 ng cu m and the PCB levels do not exceed 454 ng cu m.

Sheldon, L. S.

The use of Whatman-41 filters for high volume air sampling

The feasibility of using W41 filter media on a routine TSP high-volume monitoring network was determined by comparison with glass fiber (GF) filtering. Results indicate that suspended particulate samples from GF filters averaged slightly, but not significantly, higher than those from Whatman-41 filters. Some extra handling procedures were required to avoid errors due to the hygroscopic nature of W41 filters; these added procedures are not overly burdensome, however, and they allow the performance of analytical work, thus extending the capabilities of high-volume sampling. It was demonstrated that W41 filters are practical for air quality monitoring and elemental analysis in environments similar to Cleveland's.

Neustadter, H. E.

Compressed sensing methods with applications to advanced air sampling

Environmental sampling methods developed by the Savannah River National Laboratory (SRNL) employ collectors with sorbent media tubes set at various locations to collect airborne emissions. Laboratory analyses of these tubes results in one-dimensional signals regarding what chemicals are being released and transported within the atmosphere. The analysis process is time consuming especially when analyzing a full year’s worth of tubes (hourly sample collection results in nearly 9,000 tubes per year). Using a signal processing method such as compressed sensing allows for recreation of the full signal while greatly reducing the number of analyzed samples required. Due to the sparsity of data retrieved from the air tubes, it is possible to use measurements a fraction of the size of the original data to gain much of the same information. This would improve the overall time and cost of analysis when modeling one-dimensional sampling signals.

54 ENVIRONMENTAL SCIENCES

Compressed Sensing Methods with Applications to Advanced Air Sampling [Poster]

Environmental sampling methods developed by the Savannah River National Laboratory (SRNL) employ collectors with sorbent media tubes set at various locations to collect airborne emissions. Laboratory analyses of these tubes results in one-dimensional signals regarding what chemicals are being released and transported within the atmosphere. The analysis process is time consuming especially when analyzing a full year’s worth of tubes (hourly sample collection results in nearly 9,000 tubes per year). Using a signal processing method such as compressed sensing allows for recreation of the full signal while greatly reducing the number of analyzed samples required. Due to the sparsity of data retrieved from the air tubes, it is possible to use measurements a fraction of the size of the original data to gain much of the same information. This would improve the overall time and cost of analysis when modeling one-dimensional sampling signals.

Campbell, Cassidy [Savannah River National Laborat

Evaluation of membrane filter field monitors for microbiological air sampling

Due to area constraints encountered in assembly and testing areas of spacecraft, the membrane filter field monitor (MF) and the National Aeronautics and Space Administration-accepted Reyniers slit air sampler were compared for recovery of airborne microbial contamination. The intramural air in a microbiological laboratory area and a clean room environment used for the assembly and testing of the Apollo spacecraft was studied. A significantly higher number of microorganisms was recovered by the Reyniers sampler. A high degree of consistency between the two sampling methods was shown by a regression analysis, with a correlation coefficient of 0.93. The MF samplers detected 79% of the concentration measured by the Reyniers slit samplers. The types of microorganisms identified from both sampling methods were similar.

Fields, N. D.

STS 133 Return Samples: Air Quality Aboard Shuttle (STS-133) and International Space Station (ULFS)

The toxicological assessments of 2 canisters (mini-GSC or GSCs) from the Shuttle are reported. Analytical methods have not changed from earlier reports. The percent recoveries of the 3 surrogates (C-13-acetone, fluorobenzene, and chlorobenzene) from the 2 Shuttle GSCs averaged 86, 100, and 87, respectively. Based on the end-of-mission sample, the Shuttle atmosphere was acceptable for human respiration.

James, John T.

Stratospheric air sampling platform/sensor tradeoffs

Results of a study are described in which in-situ and remote sensing instrumentation are considered for accommodation on airborne platforms capable of reaching stratospheric altitudes. The instrumentation measures trace species of importance to present concerns regarding stratospheric pollution and possible ozone depletion. The platforms examined were the U-2, modified U-2, balloon, rocket, F-15 flown in a zoom-climb maneuver, YF-12, and remotely piloted vehicle (RPV). The sensors and performance characteristics of the platforms are described and special problems of sensor-platform integration are discussed. A typical latitudinal sampling mission is utilized to describe platform logistics problems and how the platforms might perform such missions.

Arno, R. D.

Tabulations of ambient ozone data obtained by GASP (Global Air Sampling Program) airliners, March 1975 to July 1979

Tabulations are given of GASP ambient ozone mean, standard deviation, median, 84th percentile, and 98th percentile values, by month, flight level, and geographical region. These data are tabulated to conform to the temporal and spatial resolution required by FAA Advisory Circular 120-38 (monthly by 2000 ft in altitude by 5 deg in latitude) for climatological data used to show compliance with cabin ozone regulations. In addition seasonal x 10 deg latitude tabulations are included which are directly comparable to and supersede the interim GASP ambient ozone tabulations given in appendix B of FAA-EE-80-43 (NASA TM-81528). Selected probability variations are highlighted to illustrate the spatial and temporal variability of ambient ozone and to compare results from the coarse and fine grid analyses.

Jasperson, W. H.

Observed and model-calculated NO2/NO ratios in tropospheric air sampled during the NASA GTE/CITE-2 field study

Airborne measurements of NO2/NO ratios in the free troposphere, obtained using two-photon LIF (TP-LIF) and chemiluminescence (CL) detectors during the NASA Global Tropospheric Experiment Chemical Instrumentation Test and Evaluation 2 (CITE 2) program in summer 1986, are analyzed and compared with the predictions of a photochemical model. The derivation of the model is outlined, with an emphasis on the role of peroxy radicals in the fast photochemical cycling of NO and NO2 and the production of O3; the CITE 2 instruments and flight protocols are described; and the results are presented in extensive tables and graphs and discussed in detail. It was found that on three CITE 2 flights the CL data were systematically greater than the TP-LIF data; when these data were removed, the averaged values of the two instruments agreed to within 1 percent. The NO2/NO ratios predicted by the model are shown to be consistent with the measurements, although usually 20-25 percent lower.

Chameides, W. L.

Stratospheric Age Spectra and Mean Ages from In Situ Observations of Carbon Dioxide

In situ observations of CO2 obtained from 1992 through 2000 using the NASA ER-2 aircraft and high-altitude balloons show that seasonal and interannual variations in CO2 mixing ratios propagate from the troposphere into the lower stratosphere via the tropical tropopause, along with the long-term trend due to fossil fuel combustion. These signals spread laterally and vertically, providing detailed quantitative information about the transport history of sampled air. We have used these data to derive age spectra and mean ages that can be compared with results from models of the stratospheric circulation. For an air parcel at a point in the stratosphere, the age spectrum is defined as the probability distribution function for transit times from the tropical tropopause for each fluid element comprising the parcel. The mean age is the average transit time, corresponding to the first moment of the age spectrum. Age spectra have been derived for altitudes below approximately 20 km for the tropics and for northern midlatitudes where there is sufficient data and where the amplitudes of the seasonal and interannual oscillations in CO2 mixing ratios are large enough to be detected. Tropical age spectra are narrow, with seasonal variation indicating faster ascent during northern winter, consistent with a circulation driven by breaking of extratropical waves. The midlatitude CO2 data are consistent with bimodal age spectra, which could result from a subtropical "barrier" to horizontal exchange over a substantial altitude region. Seasonally resolved mean ages are available with nearly pole-to-pole coverage below 20 km and in the tropics and at middle and high northern latitudes up to the maximum altitude reached by the balloons (approximately 30 km). At ER-2 altitudes, steep meridional gradients in mean age are observed in the subtropics. Between 20 and 30 km, midlatitude air is approximately 2 years older than tropical air at the same altitude. The oldest air sampled was in the Arctic polar vortex with a mean age of .5 plus or minus 0.5 years. This value is much younger than mean ages inferred from simultaneous and previous observations of SF6 in the Arctic vortex, providing evidence for a mesospheric sink for SF6. The mean age in the midlatitude middle stratosphere (approximately 25-32 km) is nearly constant with respect to altitude at 5 plus or minus 0.5 years. Comparison with earlier balloon observations of CO2 dating back to the 1970s shows that the mean age of air in this region has been relatively invariant over the last 25 years.

Andrews, Arlyn E.

Stratospheric Age Spectra and Mean Ages From In Situ Observations of Carbon Dioxide

Tropospheric CO2 mixing ratios exhibit latitudinally varying seasonal and interannual oscillations superimposed on the long-term positive trend due to fossil fuel combustion. In situ observations of CO2 obtained from 1992-2000 using the NASA ER-2 aircraft and high-altitude balloons show that these time-varying signals propagate into the stratosphere, providing information about the transport history of sampled air. We have used these data to derive age spectra and mean ages that can be compared with results from models of the stratospheric circulation. Age spectra have been derived for altitudes below approximately 20 km for the tropics and for northern midlatitudes, where there is sufficient data and where the amplitudes of the seasonal and interannual oscillations are large enough to be detected. The midlatitude CO2 data are consistent with bimodal age spectra, which may result from a subtropical "barrier" to horizontal exchange. Seasonally resolved mean ages are available with nearly pole-to-pole coverage below 20 km and in the tropics and at middle and high northern latitudes up to the maximum altitude reached by the balloons (approximately 30 km). The oldest air sampled was in the Arctic polar vortex with a mean age of 6.5 +/- 0.5 years.

Andrews, Arlyn E.