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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2016

Chemistry Simulations Using MERRA-2 Reanalysis with the GMI CTM and Replay in Support of the Atmospheric Composition Community

Simulations using reanalyzed meteorological conditions have been long used to understand causes of atmospheric composition change over the recent past. Using the new Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2) meteorology, chemistry simulations are being conducted to create products covering 1980-2016 for the atmospheric composition community. These simulations use the Global Modeling Initiative (GMI) chemical mechanism in two different models: the GMI Chemical Transport Model (CTM) and the GEOS-5 model developed Replay mode. Replay mode means an integration of the GEOS-5 general circulation model that is incrementally adjusted each time step toward the MERRA-2 analysis. The GMI CTM is a 1 x 1.25 simulation and the MERRA-2 GMI Replay simulation uses the native MERRA-2 approximately horizontal resolution on the cubed sphere. The Replay simulations is driven by the online use of key MERRA-2 meteorological variables (i.e. U, V, T, and surface pressure) with all other variables calculated in response to those variables. A specialized set of transport diagnostics is included in both runs to better understand trace gas transport and changes over the recent past.

Chemistry-Climate Model↗
NASA NTRS2008

Martian Chronology and Atmospheric Composition: In Situ Measurements versus Sample Return

I examine two significant issues of martian science from the point of view of in situ measurements by robotic spacecraft versus sample return and analysis in terrestrial labs. (1) To define martian history, ages of geological processes and surface features are required. Estimated ages from surface crater densities have limitations, and the ages measured for martian meteorites cannot be associated with specific martian locales. Whereas returned martian rocks could be accurately dated, some have suggested sending a robotic spacecraft to Mars to measure rock ages using the classical K- Ar-40 technique, considered the easiest to implement. (2) To understand the evolution of the martian atmosphere and its interactions with the surface, requires precise measurements of atmospheric composition. A significant amount of information has derived from measurements by Viking and of martian meteorites. Instrumentation on the Mars Science Lander (MSL) spacecraft to be launched in the near future promises to determine atmospheric composition even more precisely. If MSL is successful, which questions about atmospheric composition will remain and thus will require atmospheric sample return to answer?

Bogard, Donald D.↗
NASA NTRS2017

Chemistry Simulations using the MERRA-2 Reanalysis with the GMI CTM and Replay in Support of the Atmospheric Composition Community

Simulations using reanalysis meteorological fields have long been used to understand the causes of atmospheric composition change in the recent past. Using the new MERRA-2 reanalysis, we are conducting chemistry simulations to create products covering 1980-2016 for the atmospheric composition community. These simulations use the Global Modeling Initiative (GMI) chemical mechanism in two different models: the GMI Chemical Transport Model (CTM) and the GEOS-5 model in Replay mode. Replay mode means an integration of the GEOS-5 general circulation model that is incrementally adjusted each time step toward the MERRA-2 reanalysis. The GMI CTM is a 1 deg x 1.25 deg simulation and the MERRA-2 GMI Replay simulation uses the native MERRA-2 grid of approximately 1/2 deg horizontal resolution on the cubed sphere. A specialized set of transport diagnostics is included in both runs to better understand trace gas transport and its variability in the recent past.

MERRA-2↗
NASA NTRS2016

Planning, Implementation, and Scientific Goals of the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) Field Missions

The Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) field mission based at Ellington Field, Texas, during August and September 2013 employed the most comprehensive airborne payload to date to investigate atmospheric composition over North America. The NASA ER-2, DC-8, and SPEC Inc. Learjet flew 57 science flights from the surface to 20 km. The ER-2 employed seven remote sensing instruments as a satellite surrogate and eight in situ instruments. The DC-8 employed 23 in situ and five remote sensing instruments for radiation, chemistry, and microphysics. The Learjet used 11 instruments to explore cloud microphysics. SEAC4RS launched numerous balloons, augmented Aerosol RObotic NETwork, and collaborated with many existing ground measurement sites. Flights investigating convection included close coordination of all three aircraft. Coordinated DC-8 and ER-2 flights investigated the optical properties of aerosols, the influence of aerosols on clouds, and the performance of new instruments for satellite measurements of clouds and aerosols. ER-2 sorties sampled stratospheric injections of water vapor and other chemicals by local and distant convection. DC-8 flights studied seasonally evolving chemistry in the Southeastern U.S., atmospheric chemistry with lower emissions of NOx and SO2 than in previous decades, isoprene chemistry under high and low NOx conditions at different locations, organic aerosols, air pollution near Houston and in petroleum fields, smoke from wildfires in western forests and from agricultural fires in the Mississippi Valley, and the ways in which the chemistry in the boundary layer and the upper troposphere were influenced by vertical transport in convective clouds.

Toon, Owen B.↗
NASA NTRS1988

An assessment model for atmospheric composition

Predicting future perturbations to global air quality and climate requires, as a prerequisite, prognostic models for the composition of the Earth's atmosphere. Such assessment models are needed to evaluate the impact on our environment of different social choices that affect emissions of the photochemically and radiatively important trace gases. Our presentation here of a prototype assessment model is intended to encourage public scientific discussions of the necessary components of the model and their interactions, with the recognition that models similar to this will likely be used by the Environmental Protection Agency and other regulatory agencies in order to assess the effect of changes in atmospheric composition on climate over the next century.

Prather, Michael J.↗
NASA NTRS2008

LEOMAC: A Future 'Global Atmospheric Composition Mission' (CACM) Concept

Resolution of important outstanding questions in air quality, climate change and ozone layer stability demands global observations of multiple chemical species with high horizontal and vertical resolution from the boundary layer to the stratopause. We present a mission concept that delivers the needed atmospheric composition observations, along with cloud ice and water vapor data needed for improvements in climate and weather forecasting models. The mission comprises ultraviolet and infrared nadir and microwave limb viewing instruments observing wide swaths each orbit. We review the scientific goals of the mission and the measurement capabilities this concept will deliver. We describe how precessing orbits offer significant improvements in temporal resolution and diurnal coverage compared to sun-synchronous orbits. Such improvements are needed to quantify the impact of critical 'fast processes' such as deep convection on the composition and radiative properties of the upper troposphere, a region where water vapor and ozone are strong but poorly understood greenhouse gases. This concept can serve as the 'Global Atmospheric Composition Mission' (GACM) recently recommended by the National Academy of Sciences decadal survey as one of 17 priority earth science missions for the coming decade.

chemistry↗
NASA NTRS2009

Satellite Observations for Detecting and Tracking Changes in Atmospheric Composition

The satellite observations provide constraints on detailed atmospheric modeling, including emissions inventories, indications of transport, harmonized data over vast areas suitable for trends analysis, and a link between spatial scales ranging from local to global, and temporal scales from diurnal to interannual. 1 The National Oceanic and Atmospheric Administration's (NOAA) long-term commitments help provide these observations in cooperation with international meteorological organizations. NASA s long-term commitments will advance scientifically important observations as part of its Earth Science Program, and will assist the transition of the science measurements to applied analyses through the Applied Science Program. Both NASA and NOAA have begun to provide near realtime data and tools to visualize and analyze satellite data,2 while maintaining data quality, validation, and standards. Consequently, decision-makers can expect satellite data services to support air quality decision making now and in the future. The international scientific community's Integrated Global Atmosphere Chemistry Observation System Report3 outlined a plan for ground-based, airborne and satellite measurements and models to integrate the observations into a four-dimensional representation of the atmosphere (space and time) to support assessment and policy information needs. This plan is being carried out under the Global Earth Observation System of Systems (GEOSS). Demonstrations of such an integrated capability4 provide new understanding of the changing atmosphere and link policy decisions to benefits for society. In this article, we highlight the use of satellite data to constrain biomass burning emissions, to assess oxides of nitrogen (NO(x)) emission reductions, and to contribute to state implementation plans, as examples of the use of satellite observations for detecting and tracking changes in atmospheric composition.

Neil, Doreen O.↗
NASA NTRS2017

Challenges in Discerning Atmospheric Composition in Directly Imaged Planets

One of the justifications motivating efforts to detect and characterize young extrasolar giant planets has been to measure atmospheric composition for comparison with that of the primary star. If the enhancement of heavy elements in the atmospheres of extrasolar giant planets, like it is for their solar system analogs, is inversely proportional to mass, then it is likely that these worlds formed by core accretion. However in practice it has been very difficult to constrain metallicity because of the complex effect of clouds. Cloud opacity varies both vertically and, in some cases, horizontally through the atmosphere. Particle size and composition, both of which impact opacity, are difficult challenges both for forward modeling and retrieval studies. In my presentation I will discuss systematic efforts to improve cloud studies to enable more reliable determinations of atmospheric composition. These efforts are relevant both to discerning composition of directly imaged young planets from ground based telescopes and future space based missions, such as WFIRST and LUVOIR.

young extrasolar giant planets↗
NASA NTRSDate not supplied

The Use of Atmospheric Composition Variable Standard Names in Airborne and Field Data Products

The number of variables measured during airborne field campaigns has increased more than tenfold over the last thirty years. With this increase in measurements, the complexity for distributed active archive centers (DAACs) to distribute the data and for data users to search for and find measurements of interest has also increased. Part of this complexity arises from the unique variable names in suborbital atmospheric composition field studies. With limited guidelines related to variable naming, variable names and structures can vary significantly, even for the same type of variable. It is common for instrument scientists to use their intended measurable quantity as the data variable name. This can make it difficult for users to locate and interact with a particular variable across multiple data sets. One effective solution to this problem, identified by the Earth Science Data System (ESDS) ICARTT Refresh Working Group [1], was to introduce variable standard names that can be used as tags for each data variable. This allows similar measurements (e.g., dew point) to be categorized and located across field campaigns, regardless of what variable name the instrument scientist has used. From this the atmospheric composition variable standard names were developed with the goal to use Findable, Accessible, Interoperable, and Reusable (FAIR) principles [2] and provide context for all users, while remaining connected to those in the subject area. These standard names have been successfully implemented in FIREX-AQ, CAMP 2EX, ACTIVATE, and DCOTSS field campaigns.

metadata↗
NASA NTRS2022

Polarization performance simulation for the GeoXO atmospheric composition instrument: NO2 retrieval impacts

NOAA’s Geostationary Extended Observations (GeoXO) constellation will continue and expand on the capabilities of the current generation of geostationary satellite systems to support US weather, ocean, atmosphere, and climate operations. It is planned to consist of a dedicated atmospheric composition instrument (ACX) to support air quality forecasting and monitoring by providing similar capabilities to missions such as TEMPO (Tropospheric Emission: Monitoring Pollution), currently planned to launch in 2023, and Ozone Monitoring Instrument (OMI), TROPOMI (TROPOspheric Monitoring Instrument), and GEMS (Geostationary Environment Monitoring Spectrometer) currently in operation. As the early phases of ACX development are progressing, design trade-offs are being considered to understand the relationship between instrument design choices and trace gas retrieval impacts. Some of these choices will affect the instrument polarization sensitivity (PS), which can have radiometric impacts on environmental satellite observations. We conducted a study to investigate how such radiometric impacts can affect NO2 retrievals by exploring their sensitivities to time of day, location, and scene type with an ACX instrument model that incorporates PS. The study addresses the basic steps of operational NO2 retrievals: the spectral fitting step and the conversion of slant column to vertical column via the air mass factor (AMF). The spectral fitting step was performed by generating at-sensor radiance from a clear sky scene with a known NO2 amount, the application of an instrument model including both instrument PS and noise, and a physical retrieval. The spectral fitting step was found to mitigate the impacts of instrument PS. The AMF-related step was considered for clear sky and partially cloudy scenes, where instrument PS can lead to errors in interpreting the cloud content, propagating to AMF errors and finally to NO2 retrieval errors. For this step, the NO2 retrieval impacts were small but non-negligible for high NO2 amounts; we estimated that a typical high NO2 amount can cause maximum of 0.25 x 10^15 molecules/cm^2 for a PS of 5%. These simulation capabilities were designed to aid in the development of a GeoXO atmospheric composition instrument that will improve our ability to monitor and understand the Earth’s atmosphere.

trace gases↗
NASA NTRS2022

Polarization Performance Simulation for the GeoXO Atmospheric Composition Instrument: NO2 Retrieval Impacts

NOAA's Geostationary Extended Observations (GeoXO) constellation will continue and expand on the capabilities of the current generation of geostationary satellite systems to support US weather, ocean, atmosphere, and climate operations. It is planned to consist of a dedicated atmospheric composition instrument (ACX) to support air quality forecasting and monitoring by providing capabilities similar to missions such as TEMPO (Tropospheric Emission: Monitoring Pollution), currently planned to launch in 2023, as well as OMI (Ozone Monitoring Instrument), TROPOMI (TROPOspheric Monitoring Instrument), and GEMS (Geostationary Environment Monitoring Spectrometer) currently in operation. As the early phases of ACX development are progressing, design trade-offs are being considered to understand the relationship between instrument design choices and trace gas retrieval impacts. Some of these choices will affect the instrument polarization sensitivity (PS), which can have radiometric impacts on environmental satellite observations. We conducted a study to investigate how such radiometric impacts can affect NO2 retrievals by exploring their sensitivities to time of day, location, and scene type with an ACX instrument model that incorporates PS. The study addresses the basic steps of operational NO2 retrievals: the spectral fitting step and the conversion of slant column to vertical column via the air mass factor (AMF). The spectral fitting step was performed by generating at-sensor radiance from a clear-sky scene with a known NO2 amount, the application of an instrument model including both instrument PS and noise, and a physical retrieval. The spectral fitting step was found to mitigate the impacts of instrument PS. The AMF-related step was considered for clear-sky and partially cloudy scenes, for which instrument PS can lead to errors in interpreting the cloud content, propagating to AMF errors and finally to NO2 retrieval errors. For this step, the NO2 retrieval impacts were small but non-negligible for high NO2 amounts; we estimated that a typical high NO2 amount can cause a maximum retrieval error of 0.25×1015 molec. cm−2 for a PS of 5 %. These simulation capabilities were designed to aid in the development of a GeoXO atmospheric composition instrument that will improve our ability to monitor and understand the Earth's atmosphere.

Aaron Pearlman↗
NASA NTRS1975

Lunar atmospheric composition experiment

Apollo 17 carried a miniature mass spectrometer, called the Lunar Atmospheric Composition Experiment (LACE), to the moon as part of the Apollo Lunar Surface Experiments Package (ALSEP) to study the composition and variations in the lunar atmosphere. The instrument was successfully deployed in the Taurus-Littrow Valley with its entrance aperture oriented upward to intercept and measure the downward flux of gases at the lunar surface. During the ten lunations that the LACE operated, it produced a large base of data on the lunar atmosphere, mainly collected at night time. It was found that thermal escape is the most rapid loss mechanism for hydrogen and helium. For heavier gases, photoionization followed by acceleration through the solar wind electric field accounted for most of the loss. The dominant gases on the moosn were argon and helium, and models formed for their distribution are described in detail. It is concluded that most of the helium in the lunar atmosphere is of solar wind origin, and that there also exist very small amounts of methane, ammonia, and carbon dioxide.

Hoffman, J. H.↗
NASA NTRS2004

Predicting the Atmospheric Composition of Extrasolar Giant Planets

To date, approximately 120 planet-sized objects have been discovered around other stars, mostly through the radial-velocity technique. This technique can provide information about a planet s minimum mass and its orbital period and distance; however, few other planetary data can be obtained at this point in time unless we are fortunate enough to find an extrasolar giant planet that transits its parent star (i.e., the orbit is edge-on as seen from Earth). In that situation, many physical properties of the planet and its parent star can be determined, including some compositional information. Our prospects of directly obtaining spectra from extrasolar planets may improve in the near future, through missions like NASA's Terrestrial Planet Finder. Most of the extrasolar giant planets (EGPs) discovered so far have masses equal to or greater than Jupiter's mass, and roughly 16% have orbital radii less than 0.1 AU - extremely close to the parent star by our own Solar-System standards (note that Mercury is located at a mean distance of 0.39 AU and Jupiter at 5.2 AU from the Sun). Although all EGPs are expected to have hydrogen-dominated atmospheres similar to Jupiter, the orbital distance can strongly affect the planet's temperature, physical, chemical, and spectral properties, and the abundance of minor, detectable atmospheric constituents. Thermochemical equilibrium models can provide good zero-order predictions for the atmospheric composition of EGPs. However, both the composition and spectral properties will depend in large part on disequilibrium processes like photochemistry, chemical kinetics, atmospheric transport, and haze formation. We have developed a photochemical kinetics, radiative transfer, and 1-D vertical transport model to study the atmospheric composition of EGPs. The chemical reaction list contains H-, C-, O-, and N-bearing species and is designed to be valid for atmospheric temperatures ranging from 100-3000 K and pressures up to 50 bar. Here we examine the effect of stellar distance (e.g., incident ultraviolet flux, atmospheric temperature) on the chemical properties of EGPs. The model is applied to two generic Class II and III intermediate temperature EGPs located at 3.3 and 0.27 AU from a solar-like parent star, and the results are compared with a model for Jupiter at 5.2 AU.

Sharp, A. G.↗
NASA NTRS1973

Lunar atmospheric composition experiment

On the Apollo 17 mission, a miniature mass spectrometer, called the lunar atmospheric composition experiment (LACE), was carried to the moon as part of the Apollo lunar surface experiments package (ALSEP) to study the composition of and variation in the lunar atmosphere. The instrument was successfully deployed in the Taurus-Littrow valley with its entrance aperture oriented upward to intercept and measure the downward flux of gases at the lunar surface. Initial activation of the LACE instrument occurred on December 27, 1972, approximately 50 hr after sunset, and operation continued throughout the first lunar night. Sunrise brought a high background gas level and necessitated discontinuing operation during lunar daytime except for a brief check near noon. Near sunset, operation was resumed and continued throughout the night. This sequence was repeated for the second and third lunations.

J. H. Hoffman↗
NASA NTRS1973

OGO-6 neutral atmospheric composition experiment

The continued analysis of data obtained from the neutral atmospheric composition experiment flown on OGO-V6 is discussed. The effort was directed toward the study of five specific areas of interest for which the OGO-V6 data were especially useful.

Taeusch, D. R.↗
NASA NTRS1982

Venus - Chemical weathering of igneous rocks and buffering of atmospheric composition

Data from the Pioneer Venus radar mapper, combined with measurements of wind velocity and atmospheric composition, suggest that surface erosion on Venus varies with altitude. Calcium- and magnesium-rich weathering products are produced at high altitudes by gas-solid reactions with igneous minerals, then removed into the hotter lowlands by surface winds. These fine-grained weathering products may then rereact with the lower atmosphere and buffer the composition of the observed gases carbon dioxide, water vapor, sulfur dioxide, and hydrogen fluoride in some regions of the surface. This process is a plausible mechanism for the establishment in the lowlands of a calcium-rich mineral assemblage, which had previously been found necessary for the buffering of these species.

Nozette, S.↗